CONCENTRATION TERMS(MAINS LEVAL)

1. 25 ml of 3.0 M HNO3 are mixed with75 ml of 4.0 M HNO3. If the volumes are additive,
the molarity of the final mixture would be:
(A) 3.25 M (B) 4.0 M (C) 3.75 M (D) 3.50 M
C
2. The number of millimoles present in 200 ml of 0.2 M of a solution is
(A) 4 (B) 0.4 (C) 40 (D) 400
C
3. Which of the following is temperature independent term?

w
(A)   % (B) molarity (C) mole fraction (D) All of these
v

4 In order to prepare 0.1 m sodium chloride solution, the amount of NaCl required to
be added to 100 gm of water is

(A) 5.85 g (B) 58.5 g (C) 0.1 g (D) 0.585 g

5 Molarity of 4% (w/v) NaOH solution is

(A) 1 M (B) 4 M (C) 0.1 M (D) 0.4 M

6. Molarity of a solution containing 4.9 gm of H2SO4 in 100 cm3 of its solution is

(A) 1 M (B) 0.5 M (C) 5 M (D) 0.1 M

7 The number of millimoles present in 200 cm3 of 0.2 M of a solution is

(A) 4 (B) 0.4 (C) 40 (D) 400

8. Molarity of a solution containing 6.023 x 1022 molecules of oxalic dihydrate in

500 cm3 of its solution is

(A) 0.1 M (B) 0.2 M (C) 0.4 M (D) 1 M

9 The molarity of a solution containing 0.4 gm of NaOH in 100 cm3 of its solution is

(A) 0.1 M (B) 0.4 M (C) 0.2 M (D) 1 M

A
10 The molarity of a solution is 2 M. It is diluted by four times. What is the final molarity

(A) 0.1 M (B) 0.5 M (C) 2 M (D) 1.5 M

11 The molarity of a solution obtained by mixing 200 cm3 of water with 300 cm3 of 0.5 M
of NaOH solution is

(A) 0.3 M (B) 0.6 M (C) 0.1 M (D) 0.03 M

12. To prepare 3 M solution from 2 M and 6 M solutions, in what volume ratio they must
be mixed

(A) 3 : 1 (B) 6 : 1 (C) 4 : 1 (D) 1 : 2

13. Which of the following best describes the concentration of a solution formed by
dissolving 4 gm of NaOH in 1 kg of water

(A) 4 gm L-1 (B) 0.1 M (C) 0.1 m (D) 4 m

14 The molality of Na2CO3 solution is 0.1 m. How many grams of Na2CO3 are present in
500 gm of water

(A) 10.6 gm (B) 5.3 gm (C) 53 gm (D) 1.06 gm

15 Calculate the concentration of Ca+2 ions in 1000 ml of 222g CaCl2 solution is

(A) 2M (B) 4M (C) 6M (D) 8M

w 
16. Ethanol water–mixture has 46% ethanol  C2H5 OH   . Hence, mole fraction of H2O
W 
is:
(A) 0.46 (B) 0.54 (C) 0.25 (D) 0.75
D
17. Mole fraction of urea in an aqueous solution containing 10% urea by mass of solution
is:
(A) 0.032 (B) 0.968 (C) 0.90 (D) 0.10
A
18. 1g methanol ( d  0.75 g mL1 ) is mixed with 1g water ( d = 1.00g mL–1) hence, volume %
of methanol (v/V) is:
(A) 42.86 (B) 57.14 (C) 50.00 (D) 25.00
B
19 100 mL of conc. H2SO4  d  1.8 g / mL  is mixed with 100 mL H2O  d  1.0 g / mL  , mass
per cent (by mass of solution) of H2SO4 is:
(A) 50 (B) 60.0 (C) 64.3 (D) 35.7
C
20 Sucrose solution 40% by mass of solution is heated such that solution is 50% by
mass of solution. Hence, water lost due to heating of 100g solution is:
(A) 10g (B) 15g (C) 20g (D) 25g
C
21 Mass of the solution of 1 molal glucose solution to get 0.2 mole of glucose is:
(A) 200g (B) 300g (C) 236g (D) 108g
C
22 Aqueous urea solution is 3m. Hence mole fraction of urea is:
(A) 0.25 (B) 0.33 (C) 0.66 (D) 0.051
D
23 H2 SO 4 solution is 5 M (d = 1.8g / mL) hence, its molality is:
(A) 3.82 m (B) 2.68 m (C) 1.2 m (D) 0.7 m
A
24 Molality of sucrose solution changes if:
(A) Temperature is increased (B) Some water is added
(C) In both cases (D) In none of the cases
B
25. Equal moles of H2O and NaCl are present in a solution. Hence molality of NaCl
solution is:
(A) 0.55 (B) 55.5 (C) 1.00 (D) 0.18
B
26. 50 gm of NaOH neutralizes 100 gm of 36.5% HCl solution. the percentage impurity of
NaOH is
(A) 20% (B) 30% (C) 40% (D) 15%
A
27. The volume of 98% H2SO4 (density 1.8 gm cm-3) which completely reacts with 4 gm
of NaOH is
(A) 1.5 cm3 (B) 2..77 cm3 (C) 4.56 cm3 (D) 5.6 cm3
B

28 To neutralize completely 20 ml of 0.1 M aqueous solution of phosphorus acid, the

volume of 0.1 M aqueous KOH solution required is H3PO3  2KOH  K 2HPO3  2H2O

(A) 10 ml (B) 40 ml (C) 60 ml (D) 80 ml

29. Density of a 2.05 M solution of acetic acid in water is 1.02 g/ml. The molality of the
solution is

(A) 1.14 mol kg1 (B) 3.28molkg1 (C) 2.28 mol kg1 (D) 0.44 mol kg1

30 2 M HCl solution will have same molar conc. Of H+ as that of

 (A) 4.0 M H2SO4 (B) 1 M H2 SO4 (C) 0.5 M H2 SO4 (D) 2 M H2 SO4

31 Mole fraction of solute in aqueous HCl solution is 0.2. The molality of HCl solution is

(A) 13.88 (B) 1.388 (C) 0.138 (D) 0.0138

32. The mole fraction of solute in 1 molal aqueous solution is

(A) 0.0176 (B) 1.8 (C) 0.05 (D) 0.98

33 The number of moles of NaCl in 3L of 3M NaCl solution is

(A) 1 (B) 3 (C) 9 (D) 6

34. The molality of a solution containing 5g of sodium hydroxide in 250g of solution

(A) 0.5 m (B) 1.0 g (C) 2.0 m (D) 0.1 m

35. Molarity of 15.6% (w/w) CH3OH is (d = 0.96 g/ml)

(A) 4.68M (B) 2M (C) 1M (D) 9.76M

Paragraph for questions 31 and 32

A solution is 25% water, 25% C2H5OH and 50% CH3COOH by mass

36 Mole-fraction of water is

(A) 0.5 (B) 0.2 (C) 0.4 (D) 0.1

37. Mole-fraction of acetic acid (CH3COOH) is

(A) 0.5 (B) 0.3 (C) 0.196 (D) 0.4

38. Number of moles of Na ions in 20 litre of 0.4 M Na3 PO 4 is:

(A) 8 (B) 24 (C) 16 (D) 12
B
Paragraph for questions
An aqueous solution of NaOH having density 1.1 kg/dm3 contains 0.02 mole fraction of
NaOH.

39 The molality and molarity of NaOH solution respectively are:

(A) 0.986, 1.134 (B) 1.134, 1.193 (C) 1.134, 1.02 (D) 1.034, 1.134

40 Volume of water required to prepare 1litre 0.5 M solution of NaOH from V mL

solution of NaOH

[V < 1000 mL]:

(A) 336 mL (B) 118 mL (C) 653 mL (D) 580 mL

41. Equal volumes of 0.1 M AgNO3 & 0.2 M NaCl are mixed. The concentration of NO3
in the final solution is

AgNO3 + NaCl  AgCl  + NaNO3

(A) 0.1 (B) 0.05 (C) 0.2 (D) 0.15

w 
42 38%   solution of HCl has density equal to 1.2 g/ml. The molality and molarity
W
respectively are

(A) 12.49, 16.79 (B) 16.79 , 12.49 (C) 12.49, 12.2 (D) 16.79, 16.79

43 How many g of KCl would have to be dissolved in 60g H2O to give 20% by weight of
solution ?

(A) 15g (B) 1.5g (C) 11.5g (D) 31.5g

44 100 mL of 20.8% BaCl2 solution and 50 mL of 9.8% H2SO4 solution will form BaSO4 :

(Ba = 137, Cl = 35.5, S = 32, H = 1, O = 16)

BaCl2 + H2SO4  BaSO4 + 2HCl

(A) 23.3g (B) 11.65g (C) 30.6g (D) none of these

45 Calculate no. of oxalic acid molecules in 100 ml of 0.02 N oxalic acid.

(A) 6 x 1021 (B) 12 x 1024 (C) 6 x 1020 (D) 12 x 1021