REVISION

ASSIGNMENT MEA1
A SS I GN M E N T– 0 1 T HE R MO D YN A MI C S C HE MI S T R Y
1. Which is an extensive property ? 8. The H for the complete combustion of
(1) Viscosity (2) Temperature hydrogen, benzene (C 6H 6 ) and cyclohexane
(3) Volume (4) Refractive index (C 6H 12 ) are –57.9, –757.5 and –881.7 kcal/
2. In thermodynamic a process is called reversible mol, respectively. Use the 'additivity of
if :- reactions and heat' method to calculate the H
for the reaction :
(1) System and surrounding changes into each
3H2 + C6H6(g)  C6H12(g)
other.
(1) –1,812.6 kcal (2) –49.5 kcal
(2) There is no boundary between system and
(3) 66.4 kcal (4) 182.0 kcal
surrounding.
9. A + ½ O2  AO ; H = –50 Kcal

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(3) The surrounding are always in equilibrium
AO + ½ O2  AO2 ; H = 100 Kcal
with the system.
Then H for A + O2  AO2 is :-
(4) The system changes into the surrounding (1) – 50 Kcal (2) 50 Kcal
spontaneously (3) 100 Kcal (4) 150 Kcal
3. If the door of a refrigerator is kept open, the 10. For the reaction FeCO3(s)  FeO(s) + CO2(g);
room in whcih the refrigerator is kept :- H = 82.8 KJ at 27°C.What is U ?
(1) gets cooled (1) 82.8 KJ (2) 80.32 KJ
(2) gets heated (3) 51.71 KJ (4) 86.2 KJ
11. During an isothermal expansion of an ideal gas,
(3) neither gets cooled nor gets heated
its :-
(4) gets cooled or heated depending on the (1) internal energy increases
initial temperature of the room (2) enthalpy decreases
4. The state function is :- (3) enthalpy remains unaffected
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(4) enthalpy reduces to zero
(1) Temperature (2) Work 12. If the internal energy of an ideal gas decreases
(3) Internal energy (4) Both (1) and (3) by the same amount as the work done by the
5. H = E for the case :- system, the process is :-
(1) C2H4(g) + H2(g)  C2H6(g) (1) cyclic (2) isothermal
(2) C(s) + CO2(g)  2CO(g) (3) adiabatic (4) isolated
13. For a cyclic process the condition is :-
(3) NH4HS(s)  NH3(g) + H2S(g)
(1) E = 0
(4) CH4(g) + 2O2(g)  CO2(g) + 2H2O(g) (2) H = 0
6. An ideal gas expands against a constant (3) E > 0 and H > 0
external pressure of 2.0 atomosphere from 20 (4) both E = 0 and H = 0
litre to 40 litre and absorbs 10 kJ of heat from 14. Entropy change in reversible adiabatic process is:-
A

surrounding. What is the change in internal (1) Infinite

energy of the system? (Given : 1 atm-litre = (2) Zero
101.3 J) (3) Equal to CvT
(1) 4052 J (2) 5948 J V 
(3) 14052 J (4) 9940 J (4) Equal to nR n  2 
 V1 
7. One mole of an ideal gas undergoes a change 15. The enthalpy change of a reaction does not
of state (2.0 atm, 3.0L) to (2.0 atm, 7.0L) With depend on :-
a change in internal energy (U) = 30 L-atm. (1) initial and final enthalpy change of the
The change in enthalpy (H) of the process in reaction
L-atm :- (2) state of reactants and products
(1) 22 (2) 38 (3) different intermediate reactions
(3) 25 (4) None of these (4) nature of reactants and products
Assignment 1
16. Which of the following is correct? 24. Which of the following is not equal to zero in a
cyclic process ?
 U   H 
(1) C V    (2) C P    (1) G (2) w
 T  P  T  V
(3) S (4) H
25. Temperature of one mole of ideal gas is
 U  –a
(3) CP – CV = R (4)    2 increased by 1°C, hence increase in internal
 V  t V

17. One mole of an ideal gas at 25°C expands in energy is  Cv  3 R  :-

 2 
volume from 1.0 L to 4.0 L at constant
temperature. What work (in J) is done if the gas (1) 7 cal (2) 5 cal
expands against vacuum (Pexternal = 0)? (3) 3.5 cal (4) 3 cal
(1) –4.0 × 102 (2) –3.0 × 102 26. Predict which of the following reaction(s) has
(3) –1.0 × 102 (4) Zero a negative entropy change ?
(I) CH4(g) + 2O2(g)  CO2(g) + 2H2O(l)

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18. 5 moles of oxygen gas are heated at constant
volume from 10°C to 20°C. What will be the (II) NH3(g) + HCl(g)  NH4Cl(s)
change in internal energy of gas ? (III) 2KClO4(s)  2KClO3(s) +O2(g)
[Given : CV = 5cal mol–1 K–1] (1) III (2) II
(1) 250 cal (2) 350 cal (3) I and II (4) I
(3) 250 J (4) 350 J 27. The difference between heats of reaction at
19. The work done during the expansion of a gas constatnt pressure and constant volume for the
from a volume of 4 dm 3 to 6 dm 3 against a reaction
constant external pressure of 3 atm is :- 2C6H6(I) + 15O2 (g)  12CO2(g) + 6H2O (l) at
(1) –608 J (2) +304 J 25° in kJ mol–1 is :-
(3) –304 J (4) –6 J
(1) –7.43 (2) +3.72
20. A piston filled with 0.04 mol of an ideal gas expand
(3) –3.72 (4) +7.43
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reversibily from 50.0 mL to 375 mL at a constant
temperature of 37ºC. As it does so it absorb 208 J 28. One mole of ideal gas is allowed to expand
of heat. The value of q and w for the process will reversibly and adiabatically from a temperature
be :- (R = 8.314 J / mol K) (ln 7.5 =2.01) of 27°C. If the work done by the gas in the
(1) q = – 208 J, w = + 208 J process is 3kJ, the final temperature will be
(2) q = + 208 J, w = + 208 J equal to (CV = 20 J/K mol)
(3) q = + 208 J, w = – 208 J (1) 100 K (2) 450 K
(4) q = – 208 J, w = – 208 J (3) 150K (4) 400 K
21. A system absorbs 600 J of heat and does 250 J of 29. The temperature of an ideal gas increases in an:-
work. The change in internal energy would be:- (1) adiabatic expanision
(1) 850 J (2) 350 J (2) isothermal expansion
A

(3) – 350 J (4) – 850 J (3) adiabatic compression

22. (H – E) is maximum at a given temperature (4) isothermal compression
in case of :- 30. The heat change for the following reaction at
(1) PCl5(g)  PCl3(g) + Cl2(g) 298 K and constant pressure is +7.3 kcal.
(2) CaCO3(s)  CaO(s) + CO2(g)
(3) NH4HS(s)  NH3(g) + H2S(g) 1
A2B(s)  2A(s) + B2 (g) ; H = +7.3 kcal
(4) N2(g) + O2(g)  2NO(g) 2
23. The work of expansion for a system is 500 cal. The heat change at constant volume would be:-
The heat given to the system is 80 cal. The (1) +7.3 kcal
change in internal energy in the process will be:- (2) more than 7.3 kcal
(1) 80 cal (2) 500 cal (3) less than 7.3 kcal
(3) –420 cal (4) 420 cal (4) zero
Assignment 2
31. In which one of the sets, all properties belong 38. In the reaction :-
to the same category (all extensive or all Y  Z; H = +100 kcal/mol and for the
intensive) ? reaction, Z  X; H = –80 kcal/mol, then
(1) Mass, Volume, Pressure decreasing order of stability is :-
(2) Temperature, Pressure, Volume (1) Y, X, Z (2) Y, Z, X
(3) Heat capacity, Density, Mass (3) X, Z, Y (4) X, Y, Z
(4) Enthalpy, Internal energy, Volume
39. The internal energy changes when a system goes
32. In which of the following entropy decreases :-
from state A to B is 40 KJ/mol. If the system goes
(1) A liquid crystallizes into solid.
from A to B by a reversible path and returns to state
(2) Temperature of a crystalline solid is raised
A by an irreversible path, what would be the net
from 0 K to 115 K.
change in internal energy ?
(3) 2NaHCO 3 (s)  Na 2 CO 3 (s) + CO 2 (g) +
(1) 40 KJ (2) >40 KJ
H2O(g)
(3) <40 KJ (4) zero
(4) H2(g)  2H(g)

EN
33. Two litres of an ideal gas at a pressure of 10 40. A gas under high pressure is allowed to expand
atm expands isothermally into a vacuum until isothermally against vacuum then which is
its total volume is 10 litres. Heat absorbed in incorrect?
the expansion is :- (1) G < O (2) E = O
(1) –80 Litre – atm (2) +80 Litre – atm (3) W = O (4) NOTA
(3) –16.1 litre – atm (4) Zero 41. A baloon filled with a gas absorbs 1 kJ of heat
34. Which reactions occurs with the greatest expands against a constant pressure of 1
increase in entropy? atmosphere from a volume of 20 litres to 23
(1) 2H2O(l)  2H2(g) + O2(g) litres. The value of E would be approximately
(2) 2NO(g)  N2(g) + O2(g) (1) 600J (2) 1200J
(3) C(s) + O2(g)  CO2(g) (3) 700J (4) 500J
(4) Br2(g) + Cl2(g)  2BrCl(g) 42. The heat of combustion of naphthalene
35. Out of the following which is not the set of [C10H8(s)] at constant volume was measured to
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intensive properties :- be – 5133 J mol–1 at 300 K. Calculate the value
(1) Boiling point, pH, molarity of heat of combustion at constant pressure :-
(2) Volume, area, length (1) 10121 J (2) 5133 J
(3) Freezing point, boiling point, molar volume (3) – 10121 J (4) –5133 J
(4) Molarity, molality, density 43. At 350ºC temperature and constant pressure, the
36. Select Incorrect statement (s) :- heat of formation of ammonia (H), is –50.2 kJ
(1) An adiabatic system can exchange energy mole –1. At the same temperature the heat of
with its surroundings. formation of ammonia at constant volume V will
be (kJ mol–1)
(2) A thermodynamic property which is
intensive is additive. (1) –60.5 (2) –50.2
A

(3) Work done may be zero in a cyclic process (3) –45 (4) 60.5
(4) For a simple compressible substance, the 44. For isothermal expansion in case of an ideal
relation dq–P.d = 0 is true for any cycle gas
involving mechanical work only (1) G = S (2) G = H
37. One mole of an ideal gas is heated from 300K (3) G =–TS (4) G =TS
to 700K at constant pressure. The change in 45. When a gas is subjected to adiabatic expansion
internal energy of the gas for this process is 8 it gets cooled due to :-
kJ. What would be the change in enthalpy for (1) Fall in temperature
the same process? (2) Less in kinetic energy
(1) 4.8 kJ (2) 11.2 kJ (3) Decrease in velocity
(3) –4.8 kJ (4) –11.2 kJ (4) Energy spent in doing work

Assignment 3
 REVISION
ASSIGNMENT MEA1
A SS I GN M E N T– 0 1 T HE R MO D YN A MI C S C HE MI S T R Y

ANSWER KEY
1. 3 2. 3 3. 2 4. 4 5. 4 6. 2 7. 2

8. 2 9. 2 10. 2 11. 3 12. 3 13. 4 14. 2

15. 3 16. 3 17. 4 18. 1 19. 1 20. 3 21. 2

22. 3 23. 3 24. 2 25. 4 26. 3 27. 1 28. 3

EN
29. 3 30. 3 31. 4 32. 1 33. 4 34. 1 35. 2

36. 2 37. 2 38. 1 39. 4 40. 4 41. 3 42. 3

43. 3 44. 3 45. 4

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A

Assignment 4