19-05-2025

4602CJA105021250001 JM

PART-1 : PHYSICS

SECTION-I

1) The magnitude of scalar product of two vectors is 8 and that of vector product is The angle
between them is :

(A) 30º
(B) 60º
(C) 90º
(D) 150º

2)

(A) x + cos x + c

(B)

(C)

(D) x – cos x + c

3) Find value of : sin1° + sin2° + tan4° + sin30°

(A)

(B)

(C)

(D)

4) If y = nx + ex, find d2y/dx2.

(A)

(B)

(C)

(D) None of these

5)

(A)

(B) 2
(C) 28

(D)

6) For the given curve y = x4 find the area under curve from x = 1 to x = 2

(A)

(B) 3

(C)

(D) 13

7) If Q = 4v3 + 3v2 , then the value of 'v' for maximum 'Q' is -

(A) 0

(B)

(C)

(D) none

8) If y = ℓn(sin x) then is :

(A) cot x
(B) tan x
(C) –cot x
(D) –tan x

9) Three non zero vectors satisfy the relation & . Then can be
parallel to :

(A)
(B)
(C)
(D)

10) Let be two non-null vectors such that . Then the value of may be :
(A)

(B)

(C) 0
(D) 2

11) A car is moving on a straight road due east with a uniform speed of 10 km h–1 when it turns left
through 90º. If the speed remains unchanged after turning, the change in the velocity of the car in
the turning process is :

(A) zero
(B) km h–1 S-W direction
(C) km h–1 N-W direction
(D) 10 km h–1 due west

12) If units, then will be :

(A) 80
(B) 200
(C) –100
(D) –40

13) If is a unit vector then is

(A) 1

(B)

(C)

(D)

14) What is the component of

(A)

(B)

(C)

(D)

15) The position vector of a particle is given as . The time after which the
velocity vector and acceleration vector becomes perpendicular to each other is equal to
(A) 1 sec
(B) 2 sec
(C) 1.5 sec
(D) Not possible

16) A car starts from P and follows the path as shown in figure. Finally, car stops at R. Find the

distance travelled and displacement of the car if a = 7 m, b = 8 m and r = m. [Take ]

(A) 48m, 36m

(B) 36m, 48m
(C) 81m, 36m
(D) 48m, 48m

17) A particle moves on x-axis as per equation

x = (t3 – 9t2 + 15 t + 2)m. Distance travelled
by the particle between t = 0 and t = 5 s is

(A) 25 m
(B) 39 m
(C) 23 m
(D) 52 m

18) Statement 1 : When velocity of a particle is zero then acceleration of particle is zero.
Statement 2 : Acceleration is equal to rate of change of velocity.

(A) Statement-1 is true, Statement-2 is true; Statement-2 is correct explanation for Statement-1.
Statement-1 is true, Statement-2 is true; Statement-2 is NOT a correct explanation for
(B)
statement-1.
(C) Statement-1 is true, Statement-2 is false.
(D) Statement-1 is false, Statement-2 is true.

19) A particle is moving with speed along positive x-axis. Calculate the speed of the particle
at time t = τ (assume that the particle is at origin at t = 0).

(A)

(B)

(C) b2 τ

(D)
20) A body falls freely from rest. It covers as much distance in the last second of its motion as
covered in the first three seconds. The body has fallen for a time of :

(A) 3 s
(B) 5 s
(C) 7 s
(D) 9 s

SECTION-II

1) A particle moves such that x (m) = t2 + t – 3 ; where t is in second. Find its average velocity(in
m/s)from t = 2 sec to t = 5 sec.

2) A body starting from rest is moving under a constant acceleration in straight line. Suppose S1 is

the displacement in first 10 sec., S2 is the displacement in the next 10 sec. Find .

3) If in a new system of unit, unit of mass is three times, units of length and time are increased four
times, by what factor is the unit of energy is increased in the new system.

4) If the speed of light (c), acceleration due to gravity (g), and pressure (p) are taken as fundamental
units. The sum of powers of dimensions of gravitational constant G is

5) Viscous force acting on a spherical ball is given by F = 6π ηrv, where r is radius of the ball, v is
the velocity of the ball & η is coefficient of viscosity. Dimension formula of η is given by
[η] = MaL–bT–c. Find the value of a + b + c.

PART-2 : CHEMISTRY

SECTION-I

1) The ratio of the energy of a photon of 2000 Å wavelength radiation to that of 4000 Å radiation is

(A) 1 / 4
(B) 4
(C) 1 / 2
(D) 2

2) The region in the electromagnetic spectrum where the Balmer series lines appear is

(A) Visible
(B) Microwave
(C) Ultraviolet
(D) Infrared

3) For emission line of atomic hydrogen from ni = 8 to nf = n the plot of wave number against

will be (The Rydberg constant, RH is in wave number unit).

(A) Linear with slope - RH

(B) Linear with intercept - RH
(C) Non linear
(D) Linear with slope RH

4) Which of the following has the maximum number of unpaired electrons ?

(A) Mg2+
(B) Ti3+
(C) V3+
(D) Fe2+

5) After np orbitals are filled, the next orbital filled will be :-

(A) n + 1) s
(B) (n + 2) p
(C) (n + 1) d
(D) (n + 2) s

6) Uncertainty in position of a particle of 25 g in space is 10–5 m. Hence uncertainty in velocity (ms–1)

is (Planck's constant h = 6.6 × 10–34 Js)

(A) 2.1 × 10–28

(B) 2.1 × 10–34
(C) 0.5 × 10–34
(D) 5.0 × 20–24

7) The transition from the state n = 4 to n = 3 in a hydrogen like atom results in ultraviolet
radiation. Infrared radiation will be obtained in the transition :

(A) 2 → 1
(B) 3 → 2
(C) 4 → 2
(D) 5 → 4

8) In two H-atoms A and B, the electron are revolving around the nucleus in circular orbits of radius
r and 4r, respectively. The ratio of time takes by them to complete one revolution is :

(A) 1 : 2
(B) 1 : 4
(C) 1 : 8
(D) 1 : 64

9) If 13.6 eV energy is required to ionize the hydrogen atom, then the energy required to remove an
electron from n = 2 is-

(A) 10.2 eV
(B) 0 eV
(C) 3.4 eV
(D) 6.8 eV

10)

Calculate the ratio of radius of 2nd orbits of Li2+ ion to 3rd orbits He+ ion.

(A) 8/27
(B) 2/9
(C) 4/27
(D) 5/16

11) A gaseous mixture contains CO2 (g) and N2O (g) in a 2 : 5 ratio by mass. The ratio of the number
of molecules of CO2(g) and N2O(g) is :-

(A) 5 : 2
(B) 2 : 5
(C) 1 : 2
(D) 5 : 4

12) Which of the following contain largest number of carbon atoms ?

(A) 15 gm ethane, C2H6

(B) 40.2 gm sodium oxalate, Na2C2O4
(C) 72 gm glucose, C6H12O6
(D) 35 gm pentene, C5H10

13) Volume of 0.5 mole of a gas at 1 atm pressure and 273K is:

(A) 22.4 L
(B) 11.2 L
(C) 44.8 L
(D) 5.6 L

14) The atomic weight of Cu is 63.546. There are only two naturally occurring isotopes of copper
63
Cu and 65Cu. The natural abundance of the 63Cu isotope must be approximately :

(A) 10%
(B) 30%
(C) 50%
(D) 72.7%

15) A hydrocarbon contains 80% of carbon, then the hydrocarbon is -

(A)
(B)
(C)
(D)

16) Insulin contains 3.4% sulphur ; the minimum molecular weight of insulin is :

(A) 941.176
(B) 944
(C) 945.27
(D) None

17) A certain alkaloid has 70.8% carbon, 6.2% hydrogen, 4.1% nitrogen and the rest oxygen. What is
its empirical formula :

(A) C20H21NO4
(B) C20H20NO4
(C) C21H20NO3
(D) C20H19NO3

18) Na2SO4. xH2O has 50% H2O. Hence, x is :

(A) 4
(B) 5
(C) 6
(D) 8

19) The charge on 1 gram ions of Al3⊕ is :

(A)
coulomb

(B)
coulomb

(C)
coulomb
(D) 3 × NAe coulomb

20) A gaseous hydrocarbon gives upon combustion 0.72 g of water and 3.08 g of CO2. The empirical
formula of the hydrocarbon is
(A) C2H4
(B) C3H4
(C) C6H5
(D) C7H8

SECTION-II

1) Element B exist in nature in two isotopic form B-10 (20%) and B -11 (80%). What is average
atomic mass of B ?

2) Calculate mass (in gm) of O atoms in 6 gm CH3COOH ?

3) Haemoglobin contains 0.25% iron by mass. The molecular mass of of Haemoglobin is 89600. The
number of iron atoms per molecule of Haemoglobin (Atomic mass of Fe = 56) -

4) The K.E. of an electron emitted from tungsten surface is 3.06 eV. What voltage would be required
to bring the electron to rest.

5) A certain dye absorbs 4530 A° and fluoresence at 5080 A° these being wavelengths of maximum
absorption that under given conditions 47% of the absorbed energy is emitted. Calculate the ratio of
the no. of quanta emitted to the number absorbed.

PART-3 : MATHEMATICS

SECTION-I

1) The solution set of x2 + 2 ≤ 3x ≤ 2x2 – 5, is

(A) R
(B) [1, 2]

(C)

(D) ϕ

2) If , then sum of possible values

of is equal to

(A) 0
(B) 2
(C) 4
(D) 6
3) Least positive integral value of x such that

, is

(A) 1
(B) 2
(C) 3
(D) 4

4) If (a + b) (b + c) (c + a) = 11 & a + b + c = 11
then value of a3 + b3 + c3 is

(A) 1320
(B) 1364
(C) 1164
(D) 1298

5) Number of integral solutions of

, is

(A) 0
(B) 5
(C) 7
(D) 10

6) The value of

is equal to

(A) 9
(B) 10
(C) 11
(D) 12

7) If a,b,c denotes the length of sides of the triangle such that

9a2 + 16b2 + 25c2 – 12ab – 20bc – 15ac = 0, then ratio of a : b : c is

(A) 20 : 15 : 12
(B) 3 : 4 : 5
(C) 2 : 1 : 2
(D) 1 : 2 : 3

8) If ,
then the complete set of values of x is

(A) [7, 9]
(B) (–∞, 7] ∪ [9, ∞)
(C) R
(D) [–5, –1] ∪ [1, 7] ∪ [9, ∞)

9) If x + 2 is a factor of x3 + 2x2 + ax + 8 then value of a is

(A) 1
(B) 2
(C) 4
(D) 3

10) is

(A) 4-x
(B) 4+x
(C) 2-x
(D) 2+x

11)

If when and
then the value of (x + y) is

(A) 2
(B) 4
(C) 6
(D) 8

12) If ,
then which of the following statements holds good?

(A) x < 0
(B) 0 < x < 2
(C) 2 < x < 4
(D) 3 < x < 4

13) If x1 & x2 are the two values of x satisfying the equation,

then (x1 + x2) equals

(A) 0
(B) 1
(C) –1
(D) 7

14) The number of integral solutions of

is

(A) 1
(B) 2
(C) 3
(D) 0

15) If ,
then number of solutions of the equation is

(A) 0
(B) 1
(C) 2
(D) infinitely many

16) If loga(10) + loga(102) + ..... + loga(108) = 72

then a equals to

(A)
(B) 10
(C) 20

(D)

17) The value of x satisfying log5(5x + x – 5) = x is

(A) 4
(B) 2
(C) 5
(D) 3

18) If (loga)3 + (logb)3 + (logc)3 = 3.loga.logb.logc, then

(A) abc = 0
(B) a3 + b3 + c3 = 3abc
(C) a ≠ b = c
(D) abc = –5

19) Let p be the integral part of log3108 and q be the integral part of log5375, then p + q – pq is

(A) –5
(B) 5
(C) 7
(D) –7

20) The sum of solutions of the equation ||x – 7| – 4| = 8 is

(A) – 14
(B) 13
(C) 14
(D) –13

SECTION-II

1) The number of solution(s) of the equation

is equal to

2) Total number of integers between 1 to 30

with satisfies ≤ 1 are

3) Number of integral solutions of

4) If is a polynomial such that when it is divided by (x –1) and (x + 1)

then remainders are 5 and 19 respectively. If f(x) is divided by (x – 2), then remainder is

5) Number of non negative integral values

of x satisfying the inequality

is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B A D A D C B A D D C C B D A A B D B B

SECTION-II

Q. 21 22 23 24 25
A. 8.00 3.00 3.00 1.00 3.00

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D A D D A A D C C A B D B D C A A D D D

SECTION-II

Q. 46 47 48 49 50
A. 10.80 3.20 4.00 3.06 0.527

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D C B D C C A B C A D C B A A A C B A C

SECTION-II

Q. 71 72 73 74 75
A. 1.00 26.00 2.00 10.00 3.00
 SOLUTIONS

PART-1 : PHYSICS

1)

= 60º

2)

3) When θ is small sin θ = θ and tan θ = θ

4)

5)

6) area =

7) Q = 4V3 + 3V2

= 12V2 + 6V

V=0,–

= 24 v + 6 ⇒ = 6 (+ve)
 = – 12 + 6 = – 6 (-ve)
V = – 1/2 for maximum Q.

8) Theory

9) are non-zero vector

&
is ⊥ to
is ⊥ to
∴ × is parallel to

10) a2 + b2 + 2ab cos θ = a2 + 4b2 – 4ab cos θ

or cos θ = ≤1
∴ b ≤ 2a

11) Change in velocity =

N-W direction.

12)

13)

14) Component of parallel to

15)
if are perpendicular

16) Distance = a + πr + b + 2πr

= a + b + 3πr

= 7 + 8 + 3π ×
= 48 m
Displacement = a + 2r + b + 4r

=7+8+6×
= 15 + 21 = 36 m

17)

v = 3t2 – 18t + 15 = 3 (t – 1) (t – 5)
Motion diagram

18) Example : Top most point of a particle for motion under gravity.

19) n =

a=

a=

n= τ

20) u = 0
9 = 2t – 1
10 = 2t
t = 5 sec

21)

average velocity =

22) U = 0 (given)

∴ S1 = [S = ut + at2] ....... (1)

v1 = u + at1 = 0 + a(10) = 10a

∴ S2 = [S = ut + ]

= (10a) · 10 +
= 100 a + 50 a =150 a ....(2)
From (1) & (2)

23) n1u1 = n2u2

n1[ML2T –2] = n2[(3M)(4L)2(4T)–2]
n1 = 3n2

24) [G] = [L]x[g]y[p]z & x + y + z = 1

25)

F = 6π ηrv
⇒ [η] = [F] [r]–1[v]–1
= [M1L1T–2][L–1][L–1T1] = [M1L–1T–1]
⇒a+b+c=3
PART-2 : CHEMISTRY

26) E1 = E2 =

27) Balmer series give visible lines For H-atom

28)

m = RH
Linear with slope RH

29) Fe2+ has 4 unpaired electrons.

30) Acc to (n + ℓ) rule, after np, (n + ℓ) s always filled.

31)

= 2.1 × 10–28

32) 5 → 4 Transition energy from 5 to 4 will be lessthan from 4 → 3. All other transition energy
are higher than that for 4 → 3.

33)

34) Energy required to ionize a atom from nth orbit is = +

35)

36)

CO2 N2 O
Mass = 2m 5m

Mole =

Molecules =

37)

No. of C-atoms in 35 gm C5H10

= × 5 × 6.022 × 1023

38) Given, Moles, n = 0.5 moles

Pressure, P = 1 atm
Temperature, T = 273K
Ideal gas equation;
PV = nRT
R = 0.0821 atm.L/mol.K

L = 11.2 L

39)

Avg. mass =

63.546 =
6354.6 = 63x + 6500 – 65 x
2x = 145.4 ⇒ x = 72.7 %

40)

(1) % of C in = 75

(2) % of C in = 85.71
(3) % of C in = 80

(4) % of C in = 92.3

41)

For minimum molecular weight of insulin at 1 mole of sulphur should be in 1 mol of insulin.
∴ 3.4 g sulphur present in = 100 g insulin

∴ 32 g sulphur present in = = 941.176 g

For minimum weight of insulin the minimum molecule of sulphur will be 1.

42)
So, E.F. = C20H20NO4

43)

% by wt. of H2O(H2O%) =

50 =
71 + 9x = 18xx
= 71/9 = 7.88 ≈ 8

44)

1 gram ion = 1 mole ion = NA ion

1 mol Al3⊕ ion = NA × 3 ion
Charge (e) on 1 mol Al3⊕ ion = NA × 3 × e coulomb.

45)
a

– xa

ay = 0.08 ….(1) xa = 0.07 ….(2)

⇒ From (1) and (2) → Empirical formula = C7H8

 46)

47)
60 gm CH3COOH has 32 gm O
6 gm CH3COOH will hvae 3.2 gm O-atoms

48) Mass of Fe = × 89600 = 224

No. of Fe-atoms =

49)

K.E. = 3.06 eV

V0 = 3.06 volt

50) E of light absorbed in one photon =

Let n1 photons are absorbed, therefore,

Total energy absorbed =

Now, E of light re-emitted out in one photon =

Total energy re-emitted out = n2 ×

As given Eabsorbed × = Ere-emitted out

∴ =

∴ = 0.527

PART-3 : MATHEMATICS

51) x2 + 2 – 3x ≤ 0 and 2x2 – 3x – 5 ≥ 0

(x – 1)(x – 2) ≤ 0 and (2x – 5)(x + 1) ≥ 0

1≤x≤2 and x ≤ –1, x ≥

No intersection ⇒ Ans. ϕ

52)
∴ 2t + t = 27 ⇒ t = 9
so,
⇒ log4x = 2
⇒ x = 16

53)

54) (a + b + c)3 = a3 + b3 + c3 + 3(a + b)(b + c)(c + a)

⇒ (11)3 = a3 + b3 + c3 + 3 × 11
⇒ a3 + b3 + c3 = 1331 – 33
= 1298 Ans.

55) |x – 1| + 2 ≤ 5
⇒ |x – 1| ≤ 3
⇒ –3 ≤ x – 1 ≤ 3
⇒ –2 ≤ x ≤ 4
∴ Integral value of x = –2, –1, 0, 1, 2, 3, 4

56) Let
rationalize denominator

= 11

57)

(3a)2 + (4b)2 + (5c)2 – (3a) (4b) – (4b) (5c)

–(5c) (3a) = 0
⇒ 3a = 4b = 5c

⇒
∴ a : b : c = 20 : 15 : 12

58) (x – 7) (x – 9) ≥ 0

59)
Put x = –2
–8 + 8 – 2a + 8 = 0
a=4

60)

61)
log2x + log2y = log2y.log2x
a + b = ab
⇒ a = b = 2 ⇒ log2x = log2y = 2
⇒ x = 4, y = 4

62)

22x – 2x = 56
⇒ 22x – 2x – 56 = 0
Let 2x = t
∴ t2 – t – 56 = 0
t = 8 and t = – 7x
2x = 8 ∴ 2x = 23
⇒x=3
∴2<x<4

63)

a2 – 2ab + b2 = 0
(a – b)2 = 0
⇒a=b
⇒ x2 = x + 12
x2 – x – 12 = 0
x2 – x – 12 = 0
x2 – 4x + 3x – 12 = 0
(x + 3) (x – 4) = 0
x = 4, –3

64) |2log5x – 4| = 2 + |log5x – 3|

|2t – 4| = 2t|t – 3| Let log5x = t

|2t – 4| – |t – 3| = 2
Case (1) t < 2
–2t + 4 = 2 – t + 3
t = –1

log5x = – 1 ⇒
Case (2) 2 t < 3 Case (3) t 3
2t – 4 = 2 – t + 3 2t – 4 = 2 + t – 3 t=3
3t = 9 log5x = 3
t=3 x = 125
log5x = 3
∴ The number of integral solution = 1

65)
(1 – t)2 = 3 – t
t2 – t – 2 = 0
t = 2, – 1 reject (t should be +ve)

x=3
Reject : does not satisfy given solution.

66) loga(101.102.103......108) = 72
a72 = 1036

67) log5(5x + x – 5) = x
5x + x – 5 = 5x
x=5

68) logabc = 0 ⇒ abc = 1

or loga = logb = logc
⇒a=b=c
∴ a3 + b3 + c3 = 3abc

69) 34 < 108 < 35 ∴ log3108 = 4 + fraction ∴ p=4

53 < 375 < 54 ∴ log5375 = 3 + fraction ∴ q=3

70) |x – 7| – 4 = ±8
|x – 7| = 12, –4 (rej)
x – 7 = ± 12
x = 19, –5
19 – 5 = 14

71) ⇒ (x – 3)4 = 16
⇒ (x – 3)2 = 4 ⇒ x – 3 = ±2
∴ x = 5,1
but x ≠ 1
∴x=5
72) (i) ≤ 1 ⇒ –1 ≤ ≤1

⇒ + 1 ≥ 0 and –1≤0

⇒ ≥ 0 and ≤0

⇒ ≥ 0 and ≥0

⇒ ≥ 0 and ≥0

x ∈ (–∞, –4] ∪ (–2, 1] ∪ (2, ∞)

x ∈ (–∞, –2) ∪ [–1, 2) ∪ [4, ∞)

Ans. : x ∈ (–∞, –4] ∪ [–1, 1] ∪ [4, ∞)

73) ∵

(always negative)

∴ inequality holds when is defined.

⇒x∈ ~ {0}

74) P(1)= 5 ⇒ 2 – a + b = 5 ⇒ b – a = 3 .......(i)

Solving (i) and (ii)
b = 8, a = 5
so, remainder = P(2) = 10

75)

x – 2 ≤ 0, x ≠ –1
x ≤ 2, x ≠ –1
x ∈ (–∞, 2] – {–1}
Non negative integers = 0, 1, 2