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Xii HOLIDAY HOMEWORK Ch-SOLUTIONSGGGGHHHH

The document outlines holiday homework for a Chemistry class, focusing on solutions and related concepts. It includes multiple-choice questions, assertions and reasons, calculations of molarity, freezing point depression, and osmotic pressure. Additionally, it covers laws such as Henry's law and Raoult's law, along with practical applications and definitions of key terms.

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28 views3 pages

Xii HOLIDAY HOMEWORK Ch-SOLUTIONSGGGGHHHH

The document outlines holiday homework for a Chemistry class, focusing on solutions and related concepts. It includes multiple-choice questions, assertions and reasons, calculations of molarity, freezing point depression, and osmotic pressure. Additionally, it covers laws such as Henry's law and Raoult's law, along with practical applications and definitions of key terms.

Uploaded by

dineshpanda6842
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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BUXI JAGABANDHU ENGLISH MEDIUM SCHOOL - II, SATYABHAMAPUR

HOLIDAY HOMEWORK-XII
SUB – CHEMISTRY (043)
Ch.-SOLUTIONS
1. In comparison to a 0.01M solution of glucose, the depression in freezing point of 0.01M
MgCl2 solution is ____________________.
(a) the same (b) about twice (c) about three times (d) about six times
2. Which of the following solutions will have the highest boiling point in water?
(a)1% KCl (b)1% glucose (c)1% urea (d)1% CaCl2
3. The value of Henry’s constant KH is ________________
(a) Greater for gases with higher solubility
(b) Greater for gases with lower solubility
(c) Constant for all gases
(d) Not related to the solubility of gases

4. If a compound undergoes dissociation then Van’t Hoff factor (i) is


(a) i<1 (b) i>1 (c) i=0 (d) Can’t predict

5. If we place the blood cells in a solution containing less that 0.9% (m/v) sodium chloride. They would swell,
this is because
(a)the solution is hypotonic (b)the solution is isotonic
(c)the solution is hypertomic (d)none of these

6. Which of the following is temperature dependant?


(a)Molarity (b)Molality (c)Mole fraction (d) ppm

7. 50 mL of an aqueous solution of glucose C6H12O6 (Molar mass: 180 g/mol) contains


6.02 x 1022 molecules. The concentration of the solution will be
(a)0.1M (b)0.2M (c)1M (d) 2M

8. Low concentration of oxygen in the blood and tissues of people living at high altitude is
due to
(a) high atmospheric pressure
(b) low temperature
(c) low atmospheric pressure
(d) both low temperature and high atmospheric pressure

9. Assertion: Non ideal solution always form azeotropes.


Reason: Boiling point at an azeotrope may be higher or lower than boiling point of both components

10. Assertion: The solubility at a gas in liquid increases with increase of pressure
Reason: The solubility at a gas in liquid is directly proportional to the pressure at a gas

11. Assertion: Aqueous solution at urea and sucrose of same molality will freeze at same temperature.
Reason: Freezing point at a solution is inversely proportional to the concentration of solution.

12. Assertion(A): Molality of a solution in liquid state changes with temperature.


Reason(R): The volume of solution changes with the change in temperature.
13. Assertion(A): An ideal solution obeys Henry's law.

Reason(R): In an ideal solution, solute-solute as well as solvent-solvent interactions


are similar to solute-solvent interaction.
14. Under what condition do non-ideal solutions show negative deviations?
15. State Henry's law. Write its one application. What is the effect of temperature on solubility of
gases in liquid.
16. State Raoult's law for the solution containing volatile components.
17. Write two differences between an ideal solution and non-ideal solution.
18. What type of deviation from Raoult's law is shown by a solution of chloroform and acetone and
Why?
19. State Henry’s law. Henry’s law constant (KH) for the solution of methane in benzene at
298K is 4.27 x 105 mm of Hg. Calculate the solubility of methane in benzene at 298 K
under 760mm of Hg.
20. Define molarity.Calculate the molarity of 9.8% (W/W) solution of H2SO4 if the density
of the solution is 1.02gm/ml.
21. What type of deviation from Raoult’s law is shown by a solution of acetone and
ethanol?
22. Give reasons for the followings
(i)Aquatic species are more comfortable in cold water than in warm water.
(ii)At higher altitudes people suffer from anoxia resulting in inability to think.
(iii)0.1M KCl has higher boiling point than 0.1M glucose.

23. The boiling point of benzene is 353.23K.When 1.80gm of a non-volatile solute was
dissolved in 90gm of benzene, the boiling point is raised to 354.11K.Calculate the molar
mass of the solute.(Kb=2.53K Kg mol-1)
24. (i) Define colligative properties.
(ii) Define Azeotropes.

25. For a 10% solution of urea (molar mass=60gm/mol),calculate the osmotic pressure at
300K.[R=0.0821L atm K-1 mol-1]
26. 2 gm of benzoic acid (C5H5 COOH) dissolved in 25 gm of benzene shows a depression
in freezing point equal to 1.62k. Metal depresson constant for benzene is 4.9k kg mol-1.
What is the percentage association at acid if it forms dimer in solution.
27. The freezing point of a solution containing 0.3gm of CH3COOH in 30gm of benzene is
lowered by 0.45K.Calculate Van’t Hoff factor i.[Kf=5.12KKgmol-1]
28. At 298K 100ml of a solution containing 3.02gm of a solute exhibits an osmotic
pressure of 2.55atm.What is the molar mass of solute?
29. Calculate the freezing point of the solution when 31gm of ethylene glycol (C2H6O2) is
dissolved in 250gm of water. (Kf = 1.86 K kg mol-1)
30. Define Van’t Hoff factor.
31. Define isotonic solutions.
32. State Raoult’s law for a solution containing volatile components. What is the similarity
between Raoult’s law and Henry’s law?
33. (i) 2.82 g of glucose (molar mass = 180) are dissolved in 30 g of water. Calculate
(a) the molality (b) mole fraction of glucose and water.
(ii) Why is air diluted with helium in the tanks used by scuba divers?

34. (i)Which type of deviation is shown by the following mixtures?


(a) Ethanol and water (b) Chloroform and benzene
(ii)Benzene and toluene form nearly ideal solution. At a certain temp. the vapour
pressure of the pure benzene is 150 mm of Hg and that of pure toluene is 50 mm
of Hg .Calculate the vapour pressure of the solution containing equal weights of
two substances at this temp.

35. 0.3gm of acetic acid (Molar mass=60gm/mol)dissolved in 30gm of benzene shows a


depression in freezing point equal to 0.450C.Calculate the percentage association of acid
if it forms a dimer in the solution.(Kf=5.12 KKgMol-1)
36. (a) A and B liquids on mixing show rise in temperature. Which type of deviation from
Raoult’s law is there and why?
(b)Why can azeotropic mixture not separated by fractional distillation?
37. When 19.5gm of F-CH2-COOH(molar mass=78g/mol) is dissolved in 500gm of water
the depression in freezing point is observed to be 10C.Calculate the degree of dissociation
of F-CH2-COOH.[Kf=1.86KKgMol-1]
38. Give reasons: Measurement of osmotic pressure method is preferred for the
determination of molar masses of macromolecules such as proteins and polymers.

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