16-06-2025

4602CJA105021250006 JA

PART-A-PHYSICS

SECTION-I(i)

1) Two buses P and Q start from a point at the same time and move in a straight line and their
positions are represented by XP (t) = at + bt2 and XQ (t) = ft – t2. At what time, both the buses have
same velocity ?

(A)

(B)

(C)

(D)

2) The position vector of a particle is given by at a given time t . The net

displacement of the particle after 10 s is:

(A) 500m
(B) 400m
(C) 300m
(D) 700m

3) A ball is thrown with a velocity of u making an angle θ with the horizontal. Its velocity vector
normal to initial vector (u) after a time interval of:

(A)

(B)

(C)

(D)

4) Two bodies are projected vertically upwards from one point with the same initial velocities v0, the
τ s after the first. How long after will the bodies meet ?

(A) τ

(B)
(C)

(D)

5) Two boats were going downstream with different velocities. When one overtook the other a
plastic ball was dropped from one of the boats. Some time later both boats turned back
simultaneously & went at the same speeds as before (relative to the water) towards the spot where
the ball had been dropped. Which boat will reach the ball first?

(A) The boat which has greater velocity (relative to water)

(B) The boat which has lesser velocity (relative to water)
(C) Both will reach the ball simultaneously
Cannot be decided unless we know the actual values of the velocities and the time after which
(D)
they turned around.

6) The position co-ordinates of a particle moving in a 3-D coordinate system is given by

x = a cosωt
y = a sinωt
and z = aωt
The speed of the particle is :

(A) aω
(B) aω
(C) aω
(D) 2aω

SECTION-I(ii)

1) In the given figure is shown position-time graph of a particle moving in a straight-line. The correct

statement(s) is/are :-

(A) Average velocity between a & b is less than instantaneous velocity at b.

(B) Average velocity between b & d is equal to instantaneous velocity at c.
(C) Direction of average velocity from a to d is opposite to instantaneous velocity at d.
(D) Average velocity in interval a to c is less than average velocity in interval a to d.

2) Two particles projected from the same point with same speed u at angles of projection α and β
strike the horizontal ground at the same point. If h1 and h2 are the maximum heights attained by
projectiles, R be the range for both and t1 and t2 be their time of flights respectively then :
(A)

(B)

(C)

(D)

3) A man at rest holds an umbrella at 30° with the vertical to keep himself dry. He, then runs at a
speed of 10 m/s and finds the rain drops to be hitting vertically. Study the following statements and
find the correct options.

(A) Velocity of rain w.r.t earth is 20 m/s.

(B) Velocity of rain w.r.t. running man is m/s
(C) Velocity of rain w.r.t. earth is 30 m/s
(D) Velocity of rain w.r.t. man is m/s

4) A cart is moving along +ve x-direction with a speed of 4 m/s. A person on the cart throws a stone
with a velocity of 6 m/s w.r.t. himself. In the frame of reference of the cart the stone is thrown in the
y-z plane making an angle of 30° with the vertical z-axis. Then w.r.t. an observer on the ground :

(A) initial speed of the stone is 10 m/s

(B) the initial speed of the stone is m/s
(C) the speed at the highest point of its motion is zero
(D) the speed at the highest point of its motion is 5 m/s

5) A boat can travel at a speed of 3 m/s in still water. The speed of the river is 4 m/s, boatman starts
from A. B is a point directly across A on the opposite bank. Boat man wants to cross the river while

covering the shortest possible distance.

(A) The direction in which he must row the boat makes an angle = sin–1 , upstream with the line
AB.
(B) The magnitude of resultant velocity of boat is m/s.
(C) The boat will reach point B.
(D) The boat will reach to a point which is on the right side of point B.

6) A jet plane starts from rest at S = 0 and it is subjected to the acceleration shown [s is
displacement]

(A) Velocity at S = 60 m is 46.47 m/s

(B) Velocity at S = 150 m is 58.1 m/s
(C) Acceleration at S = 60 is 13.5 m/s
(D) Velocity will be maximum at S = 75

SECTION-III

1) In the arrangement shown, wedge is moving with constant velocity (v0) on a horizontal plane. A
particle is projected horizontally from point A with velocity 10 m/s. If particle strkes the plane
perpendicularly after 2 sec of projection, then find the value of v0 in m/s.

2) Two ball A and B collide in air. The value of v is 3α, then α is :

3) A small ball is projected up a smooth inclined plane with an initial speed of 10 m/s along the
direction at 30° to the bottom edge of the slope. It returns to the edge after 2s. The ball is in contact

with the inclined plane throughout the motion. The angle of inclination of incline plane is given by .

Then β is :-

4) A motor boat covers the distance between two fixed spots on the river in t1 = 3 h and t2 = 6 h
downstream and upstream respectively. What is the time (in hours) required for motorboat to cover
this distance in still water?

5) The horizontal range of a projectile is times its maximum height. If the angle of projectile is
 . Find (α + β)

PART-B-CHEMISTRY

SECTION-I(i)

1) Select non existing species :

(A) PH3
+
(B) PH4
–
(C) [PF6]
(D) None of these

2) Which of the following has been arranged in order of decreasing bond length ?

(A) P–O > Cl–O > S–O

(B) P–O > S–O > Cl–O
(C) S–O > Cl–O > P–O
(D) Cl–O > S–O > P–O

3) Which of the following should be the correct order of the second ionisation potential of Li, Be B
and C :-

(A) Li < Be > B > C

(B) Be < B < C < Li
(C) Be < C < B < Li
(D) Li < C < B < Be

4) Choose the Incorrect statements :

(A) dP–F (axial) > dP–F (equatorial) in PF3Cl2

(B) dP–F > dP–Cl in PF2Cl3
(C) dP–Cl (PF2Cl3) > dP–Cl (PF3Cl2)
(D) All dP–Cl (in PF2Cl3) are identical while all dP–F (in PF3Cl2) ae not identical

5) If each orbital can hold a maximum of three electrons, the number of elements in 9th period of
periodic table (long form) will be :

(A) 48
(B) 162
(C) 50
(D) 75
6) The correct order of hydration enthalpies of alkali metal ions is :-

(A) Li+ > Na+ > K+ > Rb+ > Cs+

(B) Li+ > Na+ > K+ > Cs+ > Rb+
(C) Na+ > Li+ > K+ > Rb+ > Cs+
(D) Na+ > Li+ > K+ > Cs+ > Rb+

SECTION-I(ii)

1) Which of the following do not exist ?

(A) He2
(B) HeH+
(C) Be2
(D) HeH−

2) Which of the following compounds contain ionic, covalent and co-ordinate bonds?

(A) NH4Cl
(B) KCN
(C) NaBF4
(D) NaOH

3) In which of the following molecules/ions, all bonds are equal?

(A) XeF4
–
(B) BF4
(C) SF4
(D) SiF4

4) In which of the following process(s) hybridisation of underlined atom does not change ?

(A)

(B)

(C)

(D)

5) Select correct order of size :

(A) Ti2+ < Ti < Zr

(B) Ti2+ < Ti < Hf
(C) Zr2+ < Zr ≈ Hf
(D) Hf2+ < Hf ≈ Zr

6) Choose the incorrect order of hydrated size of the ions :

(A)

(B)

(C)

(D)

SECTION-III

1) Sum of numbers of σ and π bond in toulene

Fill your answer as sum of digits till you get the single digit answer.

2) Total number of molecules in which d-orbital is used in bonding. SO2, SF4, SF6, XeF6, SOF4, XeOF4,
XeO2F2

3) In the electronic configuration of Zn, find total number of orbitals which do not possess any nodal
plane.

4) Find the number of acidic oxide from the following.

NO2, Cl2O7, Cr2O3, NO, CO2, Cl2O, Mn2O7, CrO3, SO2, Al2O3, N2O5, SO3

5) The energy required to convert all atoms present in 1.2 g magnesium to Mg2+ ions if IE1 and IE2 of
magnesium are 120 kJ mol–1 and 240 kJ mol–1 respectively. (Write the answer as sum up of all digits)

PART-C-MATHEMATICS

SECTION-I(i)

1) The sum of three numbers in A.P. is 21. If the second number is reduced by 1 while third is
increased by 1, three resulting numbers form an increasing G.P., the common ratio of the G.P. is

(A) 2
(B) 3
(C) 4
(D) 7
2) If (20)19 + 2(21) (20)18 + 3(21)2 (20)17 + ... + 20(21)19 = k(20)19 then k is equal to

(A) 400
(B) 100
(C) 441
(D) 420

3) If x > 1, y > 1, z > 1 are in G.P., then are in

(A) A.P.
(B) G.P.
(C) H.P.
(D) None of these

4) The value of is equal to

(A)

(B)

(C)

(D)

5)

(A)

(B)

(C)

(D)

6) The sum of the series is

(A)

(B)

(C)
(D)

SECTION-I(ii)

1) Let up to n terms, n ∈ N, then Sn is less

than

(A) n
(B) 2n
(C) 3n
(D) 4n

2) Let a, b, c, d are positive real numbers, then

(A)

(B)

(C)
Minimum value of is 50.

(D)
Minimum value of is 30.

3) Let be a sequence of real number such that

and then

(A)

(B)

(C)

(D)

4) Consider the series . If Sn is the sum of first n terms and an is the nth term of the
series, then

(A)

(B)

(C)
(D)

5) Consider the A.P. a1,a2, ....,an, and the G.P. b1,b2....... bn such that a1 =b1 = 1; a9 =b9
and then

(A) b6=27
(B) b7=27
(C) b8=81
(D) b9=81

6) Let a1, a2, a3, .......be an arithmetic progression with a1 = 7 and common difference 8. Let T1, T2,
T3,....be such that T1 = 3 and Tn+1 – Tn = an for . Then, which of the following is/are TRUE?

(A)
(B)
(C)
(D)

SECTION-III

1) If sum of first n terms of an A.P is then the value of

2) 'n' arithmetic means A1,A2......, An are inserted between 7 and 49 such that sum of these means is

364. If the G.M. of A3 and A6 is k, then is equal to

3) The value then value of is

4) Let a, b, c be positive integers such that is an integer. If a, b, c are in geometric progression and

the arithmetic mean of a, b, c is b + 2, then the value of is

5) The minimum value of the sum of real numbers a–5, a–4, 3a–3, 1, a8 and a10 with a > 0 is
 ANSWER KEYS

PART-A-PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5 6
A. D A C B C C

SECTION-I(ii)

Q. 7 8 9 10 11 12
A. A,B,C A,B,C,D A,B B,D A,B,D A,B,C

SECTION-III

Q. 13 14 15 16 17
A. 5 5 6 4 5

PART-B-CHEMISTRY

SECTION-I(i)

Q. 18 19 20 21 22 23
A. D B C B D A

SECTION-I(ii)

Q. 24 25 26 27 28 29
A. A,C,D A,C A,B,D A,C A,B,C,D C

SECTION-III

Q. 30 31 32 33 34
A. 9 7 5 9 9

PART-C-MATHEMATICS

SECTION-I(i)

Q. 35 36 37 38 39 40
A. A A C A D C

SECTION-I(ii)

Q. 41 42 43 44 45 46
A. B,C,D A,B,C A,B,D A,C B,D A,C,D
 SECTION-III

Q. 47 48 49 50 51
A. 2 5 2 4 8
 SOLUTIONS

PART-A-PHYSICS

1)

2) At t =0,
At t = 10s,

3)
;

4)

5) W.r.t. water velocities of both boats are moving for same time. Ball is stationary w.r.t. river.
Both will reach the ball simultaneously.

6)

vx = –awsinωt
⇒ vy = awcosωt
vz = aω

⇒
7) Average velocity in an interval is slope of chord of x-t graph. So
For (A) : slope of chord < slope of tangent at b.
For (B) : slope of chord = slope of tangent at c= 0
For (C) : slope of chord is (+ve) but slope of tangent at d (–ve)
For (D) : slope of chord in a to c > slope of chord in a to d.

8) As range is same for two angle of projection with same speed

α+β=

R= =

h1 =

h2 = =

so = =

t1 =

t2 = =

9)

vy = 10 m/s
vx = 10 m/s

10) Initial velocity of stone w.r.t. air observer on ground

⇒ and at highest point

11) m/sec sin θ =

Boat can never reach point B as v < 4
12)

= Area under graph

(1)
a = 13.5 m/s2

Area =
v = 46.47 m/s
(2) S = 150

Are

13)

tan θ =

tan 53° =
10 +v0 = 15
v0 = 5 m/s

14)
v = 15 m/s

15)

T= =2

16) ,

Time to cover this distance in still water

17)
 α+β=2+3=5

PART-B-CHEMISTRY

18) (A)PH3

(B) PH4+
(C) [PF6]–
P can expand its octet using 3d orbitals and accept lone pair also.
So [PF6]– is exist using 3d orbitals.
All 3 PH3 , PH4+, [PF6]– existing specie.

19) P–O > S–O > Cl–O (Bond length order)

As size of atom ↓ bond length also ↓ because internuclear distance also ↓
Across the period from left to right size ↓ hence bond length order is P–O > S–O > Cl–O
P > S > Cl (size order)

20)

Be < C < B < Li

21)

22)

Number of elements = 3m2

= 3 × 52 = 75

23) HYDRATION ENTHALPY OF CATION

For alkali metal cations charge is same and size increases on moving down the group hence
hydration enthalpy decreases.
HYDRATION ENTHALPY: Li+ > Na+ > K+ > Rb+ > Cs+

24)

Bond order is zero for

−
He2, Be2 and HeH

25)

(A) NH4Cl contains (ionic , covalent and coordinate bond)

(B) KCN Contain (ionic and covalent bond)

(C) NaBF4 Contain ( ionic , covalent and coordinate bond)

(D) NaOH Contain (ionic and covalent bond)

26)

There is no partial double bond character.

27)

28) All are correct

29) Hydrated size decreases down the group.

30) σ = 15, π = 3 ⇒ 15 + 3 = 18 ⇒ 1 + 8 = 9

31)

In all of the given species d-orbital is used in bonding because if an element expand its octet
than its vacant d-orbitals are used for bonding.
 32)

Zn = 1s2 2s2 2p6 3s2 3p6 4s2 3d10

No nodal plane = 1s, 2s, 3s, 4s, 3dz2

33)

Acidic oxides
NO2, Cl2O7, CO2, Cl2O,
Mn2O7, CrO3, SO2, N2O5,
SO3
Neutral oxide
NO,
Amphoteric oxides
Cr2O3 , Al2O3

34) Moles of Mg = = 0.05 moL

2+ –
Mg → Mg + 2e
I.E. = I.E1 + I.E2 = 120 + 240
1 moL = 360 kJ/moL
0.05 moL = 360 × 0.05 = 18 kJ

PART-C-MATHEMATICS

35) Let three numbers in A.P. be a - d, a, a + d.

As 21 = (a - d) + a + (a + d) = 3a
a=7
Also, 7 - d, 7 - 1, 7 + d + 1 are in G.P.
62 = (7 - d) (8 + d)
36 = 56 - d - d2
d2 + d - 20 = 0
(d + 5) (d - 4) = 0
d = -5, 4
As, 7 - d, 6, 8 + d is an increasing G.P., d = 4. The common ratio of the G.P. is

36) Dividing by (20)19, we can write k = 1 + 2x + 3x2 + ... + 20x19

where x = 21/20.

37) As x, y, z are in G.P.

y2 = xz

2(1 + ln(y)) = (1 + ln (x)) + (1 + ln (z))

 1 + ln(x), 1 + ln(y), 1 + ln(z) are in A.P.

are in H.P.

38)

39)

40)

41)

42)

Let numbers

43)
44)

45)
= 2+8d=82
= d = 10

46)

an = 8n – 1
Tn+1 – Tn = 8n –1
T2 – T1 = 8 × 1 –1
T3 – T2 = 8 × 2 –1
T4 – T3 = 8 × 3 – 1
.
.

Tn+1 – T1 = 4n(n+1) – n
Tn+1 = 4n2+3n+3

47)

Also

48) We have A1 + A2 + .... + An =

⇒ n = 13
Hence 49 = 7 + 14d ⇒ d = 3
∴ A1 = 7 + 3 = 10, A2 = 13, A3 = 16, ...., A6 = 25
⇒

49)

n = 10

50)

Let b = ar, c = ar2 ⇒ r is Integers.

Also = ar + 2 ⇒ a + ar2 = 2ar + 6

⇒ a(r – 1)2 = 6 ⇒ r must be 2 and a = 6.

Thus, = = 4 Ans.

51) Use AM ≥ GM