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5.4 Oxidation-Reduction Reactions

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21 views13 pages

5.4 Oxidation-Reduction Reactions

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© © All Rights Reserved
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Chapter 5

Chemical Reactions and Quantities


5.4
Oxidation-Reduction Reactions

1
Oxidation and Reduction

An oxidation-reduction reaction

• provides us with energy from food.


• provides electrical energy in
batteries.
• occurs when iron rusts.

4Fe(s) + 3O2(g) 2Fe2O3(s)

2
Electron Loss and Gain

An oxidation-reduction reaction
• transfers electrons from one reactant to another.

• loses electrons in oxidation. (LEO)

Zn(s) Zn2+(aq) + 2e- (loss of


electrons)

• gains electrons in reduction. (GER)


Cu2+(aq) + 2e- Cu(s) (gain of
electrons)

3
Oxidation and Reduction

4
Zn and Cu2+

Zn(s) Zn2+(aq) + 2e- oxidation


Silvery metal

Cu2+(aq) + 2e- Cu(s) reduction


Blue orange

5
Electron Transfer from Zn to Cu2+

Oxidation: electron loss

Reduction: electron gain

6
Learning Check
Identify each of the following as
1) oxidation or 2) reduction.

__A. Sn(s) Sn4+(aq) + 4e−


__B. Fe3+(aq) + 1e− Fe2+(aq)
__C. Cl2(g) + 2e− 2Cl-(aq)

7
Solution
Identify each of the following as
1) oxidation or 2) reduction.

1 A. Sn(s) Sn4+(aq) + 4e−


2 B Fe3+(aq) + 1e− Fe2+(aq)
2 C. Cl2(g) + 2e− 2Cl-(aq)

8
Writing Oxidation and Reduction
Reactions
Write the separate oxidation and reduction reactions
for the following equation.

2Cs(s) + F2(g) 2CsF(s)

A cesium atom loses an electron to form cesium ion.


Cs(s) Cs+(s) + 1e− oxidation

Fluorine atoms gain electrons to form fluoride ions.


F2(s) + 2e- 2F−(s) reduction

9
Learning Check

In light-sensitive sunglasses, UV light initiates


an oxidation-reduction reaction.

uv light
Ag+ + Cl− Ag + Cl

A. Which reactant is oxidized?

B. Which reactant is reduced?

10
Solution

In light-sensitive sunglasses, UV light initiates


an oxidation-reduction reaction.

uv light
Ag+ + Cl− Ag + Cl

A. Which reactant is oxidized? Cl− Cl + 1e−

B. Which reactant is reduced? Ag+ + 1e− Ag

11
Learning Check

Identify the substances that are oxidized and reduced in


each of the following reactions.

A. Mg(s) + 2H+(aq) Mg2+(aq) + H2(g)

B. 2Al(s) + 3Br2(g) 2AlBr3(s)

12
Solution

A. Mg is oxidized Mg(s) Mg2+(aq) +


2e−
H+ is reduced2H+ + 2e− H2

B. Al is oxidized Al Al3+ + 3e−


Br is reduced Br + e− Br −

13

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