Chapter 3
Chapter 3
CHAPTER
Thermodynamics
First Law of
Thermodynamics
FIRST LAW OF THERMODYNAMICS
ENERGY ANALYSIS
OF CLOSED SYSTEM
2
First Law of
Thermodynamics
The First Law is usually referred to as the Law of
Conservation of Energy, i.e. energy can neither be
created nor destroyed, but rather transformed from one
state to another.
Closed
Heat System V
Work
z
Reference Plane, z = 0
2
V2 V1
2
g ( z 2 z1 )
qnet wnet u 2 u1
(kJ / kg )
2000 1000
2
V2 V1
2
g ( z 2 z1 )
Q net W net m u 2 u1
(kJ )
2000 1000
For a constant volume process,
2
V2 V1
2
g ( z 2 z1 )
Q net W net m u2 u1
2000 1000
2
V2 V1
2
g ( z 2 z1 )
Q net m u2 u1
2000 1000
11
For a constant pressure process,
2
V2 V1
2
g ( z 2 z1 )
Q net W net m u2 u1
2000 1000
2
V2 V1
2
g ( z 2 z1 )
Q net P (V2 V1 ) m u2 u1
2000 1000
2
V2 V1
2
g ( z 2 z1 )
Q net m u2 u1 P (V2 V1 )
2000 1000
2
V2 V1
2
g ( z 2 z1 )
Q net m h2 h1
2000 1000
12
• Heat transferred in to the system is positive
Qin is +ve
• Heat transferred out of the system is
negative
Qout is -ve
• Work done on the system increases energy of
the system.
Win is +ve
• Work done by the system decreases energy of
the system.
Wout is -ve
Example of Closed Systems
14
Example 3.1
A closed system of mass 2 kg Rearrange the equation
undergoes an adiabatic process. V2 2 V12 g ( z2 z1 )
Qnet W net m u2 u1
The work done on the system is 2000 1000
30 kJ. The velocity of the system V2 2 V12 g ( z2 z1 )
Wnet m u2 u1
changes from 3 m/s to 15 m/s. 2000 1000
During the process, the elevation 152 32 9.8145
of the system increases 45 meters. 30 2u 2 2
2000 1000
Determine the change in internal u 14.451 kJ Ans..
energy of the system.
Solution:
Energy balance,
2
V2 V1
2
g ( z 2 z1 )
Q net W net m u 2 u1
2000 1000
15
Example 3.2 Solution:
s1 s f 1 x1 s fg1
2.1792 0.92 4.3744
6.204 kgkJ. K
16
For a rigid container,
v2=v1=0.1634 m3/kg
State2 superheated
3
at P2 2000 kPa, v2 0.1634 mkg
v u s
0.15122 2945.9 7.1292
0.1634 u2 s2
0.17568 3116.9 7.4337
0.1634 0.15122
u2 2945.9 3116.9 2945.9
0.17568 0.15122
3030.42 kJ
kg
0.1634 0.15122
s2 7.1292 7.4337 7.1292
0.17568 0.15122
7.2790 kgkJ. K
17
Amount of heat supplied, Q
Q m u2 u1
0.05 3030.42 2441.9
29.43 kJ
s s2 s1
7.2790 6.204
1.075 kgkJ. K
18
Example 3.3 Solution:
A rigid tank is divided into two equal
State1
parts by a partition. Initially one side Comp. liquid 3
P1 200 kPa,
v1 v f @ 25 C 0.001003 kg
m
of the tank contains 5 kg water at 200 o
T1 25 C
kPa and 25°C, and the other side is
initial volume of half resevoir
evacuated. The partition is then
V1 mv
removed, and the water expands into
5 0.001003
the entire tank. The water is allowed to
0.005 m3
exchange heat with its surroundings
until the temperature in the tank The initial volume for entire tank
returns to the initial value of 25°C.
Vresevoir 2 0.005
Determine (a) the volume of the tank
0.01 m3
(b) the final pressure (c) the heat
transfer for this process.
19
The final pressure
u1 u f @ 25 C 104.88 kJ
kg
State 2
u2 u f x2 u fg
T2 25 C v 0.001003 m 3
f kg v2 v f
0.01 3 3 x2
v2 0.002 mkg vg 43.34 mkg v fg
5
check region ! 2.3 10 5
104.83 2.3 10 (2304.3)
2304.9
5
v f v vg saturated mixture u2 104.88
then : P2 Psat 3.169 kPa 104.93
104.88 kJ
kg
Then :
The heat transfer for this process
Qnet 5 104.93 104.88
(104.88-104.83)
Qnet Wnet m u ke Pe 0.25 kJ
Qnet Wnet m u ke Pe
+ve sign indicates heat transfer
Qnet mu m u2 u1
into the system.
20
Supplementary Problems 1
1. Two tanks are connected by a valve. Tank A contains 2 kg of carbon
monoxide gas at 77°C and 0.7 bar. Tank B holds 8 kg of the same gas
at 27°C and 1.2 bar. Then the valve is opened and the gases are
allowed to mix while receiving energy via heat transfer from the
surrounding. The final equilibrium temperature is found to be 42°C.
Determine (a) the final pressure (b) the amount of heat transfer. Also
state your assumption. [P2=105 kPa, Q =
+37.25 kJ]
21
Supplementary Problems 1
3. A piston-cylinder device contains 6 kg of refrigerant-134a at 800 kPa
and 50oC. The refrigerant is now cooled at constant pressure until it
exist as a liquid at 24oC. Show the process on T-v diagram and
determine the heat loss from the system. State any assumption made.
[1210.26
4. kJ]0.5 m3 rigid tank contains refrigerant-134a initially at 200 kPa and 40
A
percent quality. Heat is now transferred to the refrigerant until the
pressure reaches 800 kPa. Determine (a) the mass of the refrigerant in
the tank and (b) the amount of heat transferred. Also, show the process
on a P-v diagram with respect to saturation lines.
[12.3 kg, 2956.2
5. kJ]
An insulated tank is divided into two parts by a partition. One part of
the tank contains 6 kg of an ideal gas at 50°C and 800 kPa while the
other part is evacuated. The partition is now removed, and the gas
expands to fill the entire tank. Determine the final temperature and the
pressure in the tank.
[50°C, 400 kPa] 22
Closed System First Law of a Cycle
P
2
1 5
24
According to a law of P V n constant
25
Various forms of work are expressed as follows
isothermal V2
W12 P1V1 ln
V1
polytropic
P2V2 P1V1
W12
isentropic 1 n
26
Example 3.4
Process 1-2: isobaric work output of 10.5 kJ from an initial volume of 0.028
m3 and pressure 1.4 bar,
Process 2-3: isothermal compression, and
Process 3-1: isochoric heat transfer to its original volume of 0.028 m 3 and
pressure 1.4 bar.
Calculate (a) the maximum volume in the cycle, in m3, (b) the isothermal work,
in kJ, (c) the net work, in kJ, and (d) the heat transfer during isobaric expansion,
in kJ.
27
Solution:
Process by process analysis, The isothermal work
Section 1 2 isobaric Section 2 3 isothermal
W12 P V2 V1 10.5
2 2 PV
PV 3 3
140 V2 0.028 10.5 0.103
P3 140 515 kPa
V2 0.103 m3 0.028
V3
W23 PV 2 2 ln
V2
0.028
140 0.103 ln
0.103
18.78 kJ
28
The net work
Section 3 1isochoric
W31 0
Wnet W12 W23 W31
10.5 18.78
8.28 kJ
29
Example 3.5
30
Solution:
Process by process analysis,
Section 1 2 isothermal
1 1 PV
PV 2 2
115
V1 0.22 0.12
415
0.00732 m3
V2
W12 PV
1 1 ln
V1
0.0264
415 0.00732 ln
0.00732
3.895 kJ
31
Section 2 3 isobaric Section 4 1 PolytroPic
0.525 P1 V4
V3 0.0264
115 n
62 0.00732
0.03097 m3
415 0.03097
ln 0.1494 n ln 0.2364
n 1.3182
Section 3 4 isochoric 1 1 PV
PV
W41 4 4
W34 0 1 n
415 0.0072 62 0.03097
1 1.3182
3.5124 kJ
1. A mass of 0.15 kg of air is initially exists at 2 MPa and 350 oC. The air
is first expanded isothermally to 500 kPa, then compressed
polytropically with a polytropic exponent of 1.2 to the initial state.
Determine the boundary work for each process and the net work of the
cycle.
2. 0.078 kg of a carbon monoxide initially exists at 130 kPa and 120 oC. The
gas is then expanded polytropically to a state of 100 kPa and 100 oC.
Sketch the P-V diagram for this process. Also determine the value of n
(index) and the boundary work done during this process.
[1.248,1.855 kJ]
33
3. Two kg of air experiences the three-
process cycle shown in Fig. 3-14.
Calculate the net work.
34
FIRST LAW OF THERMODYNAMICS
35
Conservation of Mass
Conservation of mass is one of the most fundamental
principles in nature. We are all familiar with this
principle, and it is not difficult to understand it!
36
Mass and Volume Flow
Rates
Mass flow through a cross-sectional area per unit time is called the
mass flow rate. Note the dot over the mass symbol indicates a time
rate of change. It is expressed as
m V .dA
If the fluid density and velocity are constant over the flow cross-
sectional area, the mass flow rate is
AV
m AV
1
where
is called specific voulme
37
Principal of Conservation of Mass
38
Flow Work & The Energy of a Flowing
Fluid
As the fluid upstream pushes mass across the control volume, work
done on that unit of mass is
A
W flow F dL F dL PdV Pv m
A
W flow
w flow Pv
m
39
Total Energy of a Flowing Fluid
V2 V2
energy u P 2 gz h 2 gz
The first law for a control volume can be written as
. . . Vout
2
. Vin
2
Q net W net mout hout gzout min hin gzin
out 2 in 2
40
Total Energy of a Flowing Fluid
The steady state, steady flow conservation of mass and first law of
thermodynamics can be expressed in the following forms
2
V2 V1
2
g ( z 2 z1 )
qnet wnet h2 h1
(kJ / kg )
2000 1000
2
V2 V1
2
g ( z 2 z1 )
Q net W net
m h2 h1 (kJ )
2000 1000
. . . 2
V2 V1
2
g ( z 2 z1 )
Q net W net m h2 h1
(kW )
2000 1000
41
Steady-flow Engineering Devices
42
Nozzle & Diffuser
Nozzle - device that increases
the velocity fluid at the expense
of pressure.
Diffuser - device that increases
pressure of a fluid by slowing it
down.
Commonly utilized in jet
engines, rockets, space-craft
and even garden hoses.
Q = 0 (heat transfer from the
fluid to surroundings very
small
W = 0 and ΔPE = 0
43
Energy balance (nozzle & diffuser):
. . . Vin
2
. . . Vout
2
Q in W in min hin
gzin Q out W out mout hout
gzout
in 2 out 2
. Vin
2 . Vout
2
min hin mout hout
2 2
V1
2
V2
2
h1 h2
2 2
44
Example 3.6 Simplified energy balance:
Steam at 0.4 MPa, 300ºC, V12 V2 2
enters an adiabatic nozzle with h1 h2
2 2
a low velocity and leaves at 0.2
MPa with a quality of 90%. State 1
Find the exit velocity. P1 0.4 MPa h1 3067.1 kJ
kg
T1 300o C sup erheated
Solution:
State 2
State1 State 2 P2 0.2 MPa h2 h f x2 h fg
P1 0.4 MPa P2 0.2 MPa
x2 0.9 h2 2486.1 kJ kg
h1 h2
1
of the air and (b) the temperature 2 2
of the air leaving the diffuser.
From Ideal Gas Law:
RT1 3
v1 1.015 mkg
P1
46
Mass flow rate From energy balance:
1 V12
m V1 A1 h2 h1
v1 2000
1 2002
284.42
200 0.4 2000
1.015
304.42 kJ
78.8 kgs kg
h2
T2
Cp
Enthalpy at state 1
304.42
h1 C pT1 1.005 283
1.005
284.42 kJ
kg
302.9 K
47
Turbine & Compressor
48
Energy balance: for turbine
. . . Vin
2
. . . Vout
2
Q in W in min hin gzin Q out W out mout hout gzout
in 2 out 2
. . .
min hin W out mout hout
. .
W out m h1 h2
49
Energy balance: for compressor, pump and fan
. . . Vin
2
. . . Vout
2
Q in W in min hin gzin Q out W out mout hout gzout
in 2 out 2
. . .
W in min hin mout hout
. .
W in m h2 h1
50
Example 3.8
51
Solution:
From energy balance:
State1 . .
. Vin 2
Qin W in min hin gzin
p1 2 MPa sup erheated 2
in
T1 400o C h1 3247.6
3248.4 kJ
.
kg . . Vout 2
State 2 Q out W out mout hout gzout
out 2
P2 15 kPa
sat. mixture Solve the equation:
x2 0.9
h2 h f 2 x2 h fg 2
h h2 h1 -887.39
885.87 kJ
225.94 0.9 (2372.3)
2373.1
kg
V2 2 V12
2361.73
2361.01 kJ
kg
KE 14.95 kJkg
2000
g z2 z1
PE 0.04 kJ
kg
1000
52
the work done per unit mass
V12 V2 2 g z1 z2
Wout h1 h2
2000 1000
885.87
887.39 14.95 0.04
870.96 kJ
872.48 kg
W out 5000
m 5.73 kgs
5.74
Wout 870.96
872.48
53
Solution:
Example 3.9
simplified energy balance:
Air at 100 kPa and 280 K is
compressed steadily to 600 W in m h2 h1 Q out
kPa and 400 K. The mass m h2 h1 mqout
flow rate of the air is 0.02
kg/s, and a heat loss of 16 State1
kJ/kg occurs during the air
P1 100 kPa
process. Assuming the
T1 280 K h1 280.13 kJkg
changes in kinetic and
potential energies are State 2
negligible, determine the P2 600 kPa air
necessary power input to the
T2 400 K h2 400.98 kJkg
compressor.
54
Thus
55
Throttling Valve
56
Example 3.10
State1 Steam enters a throttling valve at
8000 kPa and 300°C and leaves
P1 8000 kPa sup erheated at a pressure of 1600 kPa.
Determine the final temperature
T1 300 C h1 2786.5 kJkg
o
and specific volume of the
State 2 steam.
P2 1600 kPa
make int erpolation
h2 h1
P kPa T C
o vf vg hf hg
1500 198.29 0.001154 0.131710 844.55 2791
1600 T2 vf 2 vg 2 hf 2 hg 2
1750 205.72 0.001166 0.113440 878.16 2795.2
57
At state 2, the region is sat. Specific volume at state 2
mixture
v2 v f 2 x2v fg 2
T2 Tsat 201.3o C 0.0011588
Getting the quality at state 2 0.997 0.124402 0.0011588
m3
0.1240
h2 h f 2 kg
x2
hg 2 h f 2
2786.5 857.994
2792.68 857.994
0.997
58
Mixing Chamber
59
Mixing Chamber
Energy Balance:
1h1 m2 h2 m3h3
m
1h1 m3 m1 h2 m3 h3
m
1 h1 h2 m3 h3 h2
m
h3 h2
1 m3
m
h
1 h2
60
Heat Exchanger
62
the minimum mass flux of the water the rate of heat transfer
so that the water does not
completely vaporize
Q w m w h2 w h1w
ms C p , s T1s T2 s 4.62 2794.2 88.61
m w
h2 w h1w 12.5 MW
100 1.25 450 350
2794.2 88.61
4.62 kgs
63
Supplementary Problems 3
1. Air flows through the supersonic nozzle . The inlet conditions are 7 kPa
and 420°C. The nozzle exit diameter is adjusted such that the exiting
velocity is 700 m/s. Calculate ( a ) the exit temperature, ( b )the mass flux,
and ( c ) the exit diameter. Assume an adiabatic quasiequilibrium flow.
3. Steam enters a turbine at 4000 kPa and 500oC and leaves as shown in Fig
A below. For an inlet velocity of 200 m/s, calculate the turbine power
output. ( a )Neglect any heat transfer and kinetic energy change ( b )Show
that the kinetic energy change is negligible.
64
Figure A
4. Consider an ordinary shower where hot water at 60°C is mixed with cold
water at 10°C. If it is desired that a steady stream of warm water at 45°C
be supplied, determine the ratio of the mass flow rates of the hot to cold
water. Assume the heat losses from the mixing chamber to be negligible
and the mixing to take place at a pressure of 150 kPa.
5. Refrigerant-134a is to be cooled by water in a condenser. The refrigerant
enters the condenser with a mass flow rate of 6 kg/min at 1 MPa and 70ºC
and leaves at 35°C. The cooling water enters at 300 kPa and 15°C and
leaves at 25ºC. Neglecting any pressure drops, determine (a) the mass
flow rate of the cooling water required and (b) the heat transfer rate from
the refrigerant to water.
65