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Freezing Point Depression

The document outlines learning competencies related to the effect of solute concentration on the colligative properties of solutions, specifically focusing on freezing point depression. It includes pre-test questions, definitions of key terms such as electrolyte and non-electrolyte, and a laboratory activity to observe the effects of solutes on freezing points. Additionally, it provides assignments for calculating freezing point depression and determining molar masses of solutes.
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0% found this document useful (0 votes)
13 views54 pages

Freezing Point Depression

The document outlines learning competencies related to the effect of solute concentration on the colligative properties of solutions, specifically focusing on freezing point depression. It includes pre-test questions, definitions of key terms such as electrolyte and non-electrolyte, and a laboratory activity to observe the effects of solutes on freezing points. Additionally, it provides assignments for calculating freezing point depression and determining molar masses of solutes.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
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LEARNING COMPETENCIES

1. Describe the effect of


concentration on the
Colligative properties of
solution. (STEM_GC11PP-IIId-f-115)
Pre - Test
1. FOR A LIQUID SOLVENT,
ADDING SOLUTE PARTICLES WILL
__________ THE FREEZING
TEMPERATURE.
A. INCREASE
B. DECREASE
C. NOT AFFECT
A. NUMBER OF SOLUTE
PARTICLES
B. NUMBER OF COVALENT
BOND
C. NUMBER OF HYDROGEN
BONDS
D. NUMBER OF DIPOLE-
DIPOLE INTERACTIONS
CONSTANT
B.MOLAR FREEZING POINT
CONSTANT
C.MICRO FREEZING POINT
CONSTANT
D.MOLAL FREEZING POINT
CONSTANT
4. THE AMOUNT OF A SOLUTE
DISSOLVED IN A GIVEN
AMOUNT OF SOLVENT IS
REPRESENTED BY THE
A. MASS OF THE SOLUTION
B. VOLUME OF THE SOLUTION

C. CONCENTRATION OF THE
SOLUTION
5. What is the freezing point
depression?
a. The depression people tend to feel
as they begin to freeze
b. Where the freezing point of a liquid
decreases as solutes are added
c. A chart showing different freezing
points of liquids
d. A phenomena where a liquid will
randomly decrease its freezing point
ANSWER KEY
Word Study
E_e_t_ _ _yte
A substance that breaks up
into ions when it is
dissolved in water.
Examples of ions are
sodium and chloride.
Electrolyte
A substance that breaks up
into ions when it is
dissolved in water.
Examples of ions are
sodium and chloride.
N_n-_le_t_ol_ _e
A substances that do not have
any distinct ionic form to exist
in when they are dissolved in
an aqueous solution such as
sugar or ethanol
Non-electrolyte
A substances that do not have
any distinct ionic form to exist
in when they are dissolved in
an aqueous solution such as
sugar or ethanol
N_n-_olat_ _e sol_te
A substances that does not
readily evaporate into a gas
under existing conditions.
Non-volatile solute
A substances that does not
readily evaporate into a gas
under existing conditions.
Co_ _ig_ _ _ve
A physical property of a
substance that depends
on the concentrations of
atoms, ions, and
molecules
Colligative
A physical property of a
substance that depends
on the concentrations of
atoms, ions, and
molecules
_ree_in_ _oin_
Temperature at which a
liquid becomes a solid
Freezing Point
Temperature at which a
liquid becomes a solid
Activity Title -
Effect of solute to
the freezing point
of solution
E: 1. Determine the
effect of solute to the
freezing point of a
solution.
2. Define Freezing
Point Depression
PREPARATION OF
MATERIALS:
NaCl/salt, paper
cup/beaker, thermometer,
water, ice/ice water,
graduated cylinder, glass
stirring rod,
PROCEDURE
DATA TO BE COLLECTED
GUIDE
QUESTIO
NS
1. WHAT HAPPEN TO THE
TEMPERATURE WHEN SALT
WAS ADDED TO THE ICE?
NOTE SOME PHYSICAL
CHANGE THAT HAPPEN
UPON ADDITION OF SALT.
2. BASED ON THE DATA,
WHAT IS THE EFFECT OF
SALT TO THE TEMPERATURE
OF ICE/ICE WATER (TF) )?
FREEZING POINT (ΔTF ) ,
ALSO CALLED AS
FREEZING POINT
DEPRESSION, WHAT IS
FREEZING POINT
DEPRESSION?
Laboratory Proper
Post laboratory
Discussion
LET’S ANSWER
THE GUIDE
QUESTIONS
1. WHAT HAPPEN TO THE TEMPERATURE
WHEN SALT WAS ADDED TO THE ICE?
NOTE SOME PHYSICAL CHANGE THAT
HAPPEN UPON ADDITION OF SALT.
2. BASED ON THE DATA, WHAT IS THE
EFFECT OF SALT TO THE TEMPERATURE
OF ICE/ICE WATER (TF)?
3. IF THE CHANGE IN FREEZING POINT
(ΔTF ) , ALSO CALLED AS FREEZING
POINT DEPRESSION, WHAT IS FREEZING
POINT DEPRESSION?
WHAT IS FREEZING POINT
DEPRESSION?

FREEZING POINT DEPRESSION THE


_________ BETWEEN THE FREEZING
POINT OF A PURE SOLVENT AND THE
FREEZING POINT OF SOLUTION
WHAT IS FREEZING POINT
DEPRESSION?

FREEZING POINT DEPRESSION THE


DIFFERENCE BETWEEN THE
FREEZING POINT OF A PURE SOLVENT
AND THE FREEZING POINT OF
SOLUTION
WHAT IS FREEZING POINT
DEPRESSION?
FREEZING POINT DEPRESSION IS THE
PHENOMENA THAT DESCRIBES
THE _________ OF THE FREEZING
POINT OF THE _________ AS A RESULT OF
ADDING A NON-VOLATILE SOLUTE TO A
___________.
WHAT IS FREEZING POINT
DEPRESSION?
FREEZING POINT DEPRESSION IS
THE PHENOMENA THAT DESCRIBES THE
LOWERING/DECREASING OF
THE FREEZING POINT OF THE
SOLUTION AS A RESULT OF ADDING A
NON-VOLATILE SOLUTE TO A SOLVENT.
2.3 0.6

5.32 1.0

8.23 1.1

10 1.5
DERIVATION OF
FREEZING POINT
DEPRESSION FORMULA
Proportionality
constant, is called
the molal freezing-
point depression
constant .
Wher
e:

Freezing-Point Depression Formula


•COLLIGATIVE PROPERTIES OF
SOLUTIONS DEPEND ONLY ON THE
NUMBER OF MOLECULES OF SOLUTE
IN THEM, THUS, THIS METHOD IS
ESPECIALLY USED FOR DETERMINING
THE MOLAR MASSES OF COMPLEX
MOLECULES, PROTEINS,
MACROMOLECULES, AND POLYMERS.
Post -
Test
A. NUMBER OF COVALENT
Q1. A
BONDS COLLIGATIVE PROPERTY
DEPEND ON
B. NUMBER OF HYDROGEN
BONDS
C. NUMBER OF DIPOLE-DIPOLE
INTERACTIONS
D. NUMBER OF SOLUTE
PARTICLES
Q2. FOR A LIQUID SOLVENT,
ADDING SOLUTE PARTICLES WILL
__________ THE FREEZING
TEMPERATURE.
A. INCREASE
B. DECREASE
C. NOT AFFECT
CONSTANT
Q3. KF STANDS FOR
B. FREEZING POINT ELEVATION
CONSTANT
C. MOLAR FREEZING POINT
CONSTANT
D. MICRO FREEZING POINT
CONSTANT
Q4. WHAT IS THE FREEZING POINT
A. THE DEPRESSION PEOPLE TEND TO
DEPRESSION?
FEEL AS THEY BEGIN TO FREEZE
B. WHERE THE FREEZING POINT OF A
LIQUID DECREASES AS SOLUTES ARE
ADDED
C. A CHART SHOWING DIFFERENT
FREEZING POINTS OF LIQUIDS
D. A PHENOMENA WHERE A LIQUID WILL
RANDOMLY DECREASE ITS FREEZING
POINT
Q5. THE FREEZING POINT OF A
A. INCREASING
SOLUTION THE NUMBER
IS LOWERED BY OF
SOLUTE PARTICLES
B. INCREASING THE KINETIC
ENERGY
C. DECREASING THE NUMBER OF
SOLUTE PARTICLES
D. INCREASING THE PRESSURE ON
THE SOLUTION
ANSWER KEY
ASSIGNMENT:
GRASP the following problems.
1. What is the freezing point depression when 155
g of iodine (I₂) crystal is added to 1200 g of
Benzene (C6H6)? MW (I₂) = 253.8g/mol
Kf (C6H6) = 5.12 °C/m, FP (C6H6) = 5.51°C

2. A solution of 4.00 g of a nonelectrolyte solute is


dissolved in 55.0 g of benzene is found to freeze at
2.32 °C. What is the molar mass of this compound?
ASSIGNMENT:
GRASP the following problems.
1. What is the freezing point of a solution
prepared by adding 140. g trichothecin
(C19H24O5) to 0.746 kg of benzene? The freezing
point of pure benzene is 5.5 °C. The freezing
point constant for benzene is 5.12 °C/m.
2. What is the freezing point of a solution
prepared by adding 239.0 g of copper(II) sulfate
pentahydrate to 4.00 liters of water? The freezing
point depression of water is 1.86 °C/m.
ASSIGNMENT:
GRASP the following problems.
3. A solution that contain 55.0 g of ascorbic acid
(vitamin C) in 250. g of water freezes at −2.34
°C. Calculate the molar mass (in g/mol) of the
solute.
4. When 1.150 grams of an unknown non-
electrolyte dissolves in 10.0 grams of water, the
solution freezes at −2.16 °C. What is the
molecular weight of the unknown compound? Kf
for water = 1.86 °C/ m.

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