1

Sri Chaitanya IIT- JEE Academy

CHEMISTRY ASSIGNMENT
[Dilute Solution & Colligative Properties
J.IIT
***************************************************************************************
1. An azeotropic mixture of two liuid! "oil! at a lower temperature than either of them
when
1# it i! !aturated $# it doe! not de%iate from &aoult'! law
(# it !how! ne)ati%e de%iation from &aoult'! law
*# it !how! po!iti%e de%iation from &aoult'! law
$. A !olution of a !u"!tance containin) 1.+,) per 1++ml wa! found to "e i!otonic with (-
)luco!e !olution. The molecular wei)ht of the !u"!tance i!
1# .( $# .(+ (# ..( *# (1.,
(. In cold countrie!/ enthylene )lycol i! added to water in the radiator! of car! durin)
winter!. It re!ult! in
1# lowerin) "oilin) point $# reducin) %i!co!ity
(# reducin) !pecific heat *# lowerin) freezin) point
*. 0ec1mann thermometer mea!ure!
1# "oilin) point of the !olution $# freezin) point of the !olution (# any temperature
*# ele%ation in "oilin) point or depre!!ion in freezin) point
,. 2hen 3)I
$
i! mixed with aueou! !olution of 4I/ then
1# freezin) point decrea!e $# freezin) point doe! not chan)e
(# freezin) point increa!e *# "oilin) point remain! unchan)e!
.. The freezin) point of +.+, molal !olution of a non-electrolyte in water i! 555555 . 4
f
6
1.7. 1 1) mol
-1
.
1# 81.7.
+
C $# 8 +.9(
+
C (# 8 +.+9(
+
C *# +.9(
+
C
:. 2hich of the followin) +.1 ; aueou! !olution! will ha%e the lowe!t freezin) point
1# pota!!ium !ulphate $# !odium chloride (# urea *# )luco!e
7. The <.=. of a dilute !olution of a non-%olatile !olute i! = and the <.=. of pure !ol%ent i!
=
+
/ the lowerin) of the <.=. i!
1# > <e $# 8 <e (#
0
P P *#
0
P P
$
9. The <ant 3off factor ?aCl a!!umin) 1++- di!!ociation i!
1# 1 2 $# $ (# 1 *# (
1+. The !olution in which the "lood cell! retain their normal form are with re)ard to the
another
1# I!otonic $# 3ypertonic (# 3ypotonic *# none
11. Two !olution! A and 0 are !eparated throu)h a S=;. A ha! hi)h @.= then 0. The
o!mo!i! will occur from
1# A to 0 $# 0 to A (# 0oth *# none
1$. 2hen an ideal "inary !olution i! in euili"rium with it! %apour/ molar ratio of the two
component! in the !olution and in the %apour pha!e i!
1# !ame $# different
(# may or may not "e !ame dependin) upon %olatile nature of the two component!
1(. The lowerin) of %apour pre!!ure of +.1 ; aueou! !olution of ?aCl/ CuS@
*
and 4
$
S@
*
are
1# all eual $# in the ratio 1 A 1 A 1.,
(# in the ratio ( A $ A 1 *# in the ratio 1., A 1 A $.,
1*. The "oilin) point of C
.
3
.
/ C
.
3
,
8 ?3
$
/ C3
(
@3 and C
.
3
,
?@
$
/ are 7+
+
C/ 17*
+
C/ .,
+
C and
$1$
+
C re!pecti%ely. 2hich ha! hi)her %apour pre!!ure at room temperature
1# C
.
3
.
$# C3
(
@3 (# C
.
3
,
?3
$
*# C
.
3
,
?@
$
1,. The correct relation!hip "etween the ".pt of %ery dilute !olution of AlCl
(
( )
1
t and CaCl
$
( )
2
t ha%in) !ame molar concentration i!
1#
1 2
t > t $#
2 1
t > t (#
1 2
t = t *# none
1.. The freezin) point of euimolal aueou! !olution! will "e hi)he!t for
1# C
.
3
,
?3
(
Cl $# CaB?@
(
#
$
(# CaB?@
(
#
(
*# C
.
3
1$
@
.
1:. The relation!hip "etween o!motic pre!!ure at $:( 4 when 1+ )m )luco!e ( )
1
P 1+) urea
( )
2
P and 1+) !ucro!e ( )
3
P are di!!ol%ed in $,+ml of water i!
1# =
1
D =
$
D =
(
$# =
(
D =
1
D =
$
(# =
$
D =
1
D =
(
*# =
$
D =
(
D =
1
17. In dilute !olution the depre!!ion in f.pt. i! directly proportional to
1# normality $# molality (# molarity *# mole fraction
19. A maxima or minima o"tained in the temperature compo!ition cur%e of a mixture of
two liuid! indicate!E
(
1# An azeotropic mixture $# a eutectic formation
(# that the liuid! are immi!ci"le with one another
*# that the liuid! are partially mi!ci"le at the maximum or minimum
$+. Two !ol%ent! A and 0 ha%e
f
K %alue! 1.7. and $.:9 4 mole
-1
1) re!pecti%ely. A )i%en
amount of a !u"!tance when di!!ol%ed in ,++) of A/ it completely dimerize! and when
!ame amount of !u"!tance i! di!!ol%ed in ,++) of 0/ the !olute under)oe!
trimerization. 2hat will "e the ratio of o"!er%ed lowerin) of freezin) point in two ca!e!
for A and 0.
1# ( A $ $# 1 A 1 (# $ A ( *# ( A *
$1. 2hich inor)anic precipitate! act a! !emipermea"le mem"rane
1# calcium pho!phate $# "arium oxalate
(# nic1el pho!phate *# copper ferrocyanide
$$. 0y addin) water to the !olution of ionic compound it!E
1# Concentration remain! !ame $# Concentration increa!e!
(# Ioni!ation may increa!e! *# Concentration decrea!e!
$(. The proce!! of )ettin) fre!h water from !ea water i! 1nown a!
1# @!mo!i! $# Filtration (# Ge!altation *# &e%er!e o!mo!i!
$*. 2hich of the followin) plot! doe! not repre!ent the "eha%iour of an ideal "inary liuid
!olutionE
1# =lot of =
A
%er!u! H
A
Bmole fraction A in liuid pha!e# i! linear
$# =lot of =
0
%er!u! H
0
i! linear
(# =lot of =
total
%er!u! H
A
Bor H
0
# i! linear
*# =lot of =
total
%er!u! H
A
i! non linear
$,. 2hich of the followin) plot! correctly repre!ent! the "eha%iour of an ideal "inary liuid
!olutionE
1# =lot of H
A
Bmole fraction of A in liuid pha!e# %er!u! I
A
Bmole fraction of A in %apour
pha!e# i! linear
$# =lot of H
A
%er!u! I
0
i! linear
(# =lot of
A
1 X %er!u!
A
1 Y i! linear *# =lot of
A
1 X %er!u!
B
1 Y i! linear
$.. For an ideal "inary liuid !olution with
0 0
A B
P > P / which of the followin) relation! "etween
H
A
Bmole fraction of A in liuid pha!e# and I
A
Bmole fraction A in %apour pha!e# i!
correctly repre!entedE
1# H
A
6 I
0
$# H
A
D I
A
(# H
A
J I
A
*
*# H
A
and I
A
cannot "e correlated with each other
$:. A "inary liuid !olution of chloroform and acetone i! prepared. 2hich of the followin)
!tatement! correctly repre!ent! the "eha%iour of thi! liuid !olutionE
1# The !olution formed i! an ideal !olution
$# The !olution formed i! non ideal !olution with po!iti%e de%iation! from &aoult'! law
(# The !olution formed i! non ideal !olution with ne)ati%e de%iation! from &aoult! law
*# Chloroform exhi"it! po!iti%e de%iation wherea! acetone exhi"it! ne)ati%e de%iation
from &aoult'! law
$7. A !emi permea"le mem"rane u!ed in the mea!urement of o!motic pre!!ure of a
!olution allow! the pa!!a)e of
1# !ol%ent molecule! throu)h it $# !olute molecule! throu)h it
(# "oth !ol%ent and !olute molecule! throu)h it
*# either !ol%ent or !olute and not "oth throu)h it
$9. In which mode of expre!!ion the concentration of !olution remain! independent of
temperature
1# ;olarity $# ?ormality (# Formality *# ;olality
(+. If +.,+ mole of 0aCl
$
i! mixed with +.$+ mole of ?a
(
=@
*
/ the maximum num"er of
mole! of 0a
(
B=@
*
#
$
that can "e formed i!
1# +.1 $# +.$ (# +., *# +.:
(1. (+ ml of !olution i! neutralized "y 1,ml of +.$? "a!e. The !tren)th of the acid !olution
i!
1# +.1 ? $# +.1, ? (# +.( ? *# +.* ?
($. A ,++) tooth pa!te !ample ha! +.$) fluoride concentration. 2hat i! the concentration
of F in term! of ppm le%elE
1# $,+ $# $++ (# *++ *# 1+++
((. Increa!in) the temperature of an aueou! !olution will cau!e
1# decrea!e in molality $# decrea!e in molarity
(# decrea!e in mole fraction *# decrea!e in - 2K2
(*. 2hich of the followin) !olution! ha! the hi)he!t normality
1# 1.7) of 4@3K1 lit. $# ?-=ho!phoric acid (# .) of ?a@3K1++ ml*# +.,m
3
$
S@
*
(,. 3ydrochloric acid !olution! A and 0 ha%e concentration! of +., ? and +.1 ?
re!pecti%ely. The %olume! of !olution! A and 0 reuired to ma1e $ litre! of +.$ ?3Cl
are
,
1# +.,lit of A>1.,lit of 0 $# 1.,lit of A>+.,lit of 0
(# 1.+lit of A>1.+lit of 0 *# +.:,lit of A>1.$,lit of 0
(.. The molarity of pure water i!
1# ,,.. $# ,+ (# 1++ *# 17
(:. The mole fraction of water in $+- aueou! !olution of 3
$
@
$
i!
1# 77 68 $# 68 77 (# 20 80 *# 80 20
(7. <olume of +.1; 4
$
Cr
$
@
:
reuired to oxidi!e! (,ml of +.,; FeS@
*
!olution i!
1# $9 ml $# 7: ml (# 1:, ml *# 1*, ml
(9. 2hich one i! a colli)ati%e propertyE
1# 0oilin) point $# <apour pre!!ure (# @!motic pre!!ure *# Freezin) point
*+. 2hich of the followin) i! not a colli)ati%e propertyE
1# @!motic pre!!ure $# Ele%ation of ".p. (# <apour pre!!ure *# Gepre!!ion of f.p.
*1. 1++ml of a liuid A wa! mixed with $,ml of a liuid 0 to )i%e a non-ideal !olution of A-0
mixture. The %olume of thi! mixture would "e
1# :, ml $# 1$, ml (# Lu!t more than 1$, ml
*# clo!e to 1$,ml "ut not exceedin) 1$,ml
*$. 2hich of the followin) pair! !how! a po!iti%e de%iation from &aoult'! lawE
1# 2ater-hydrochloric acid $# 2ater-nitric acid
(# Acetone-Chloroform *# 0enzene-methanol
*(. 2hich one of the followin) !olution! would produce maximum ele%ation in 0.=.
1# +.1 ; )luco!e $# +.$ ; !ucro!e (# +.1 ; 0aCl
$
*# +.1 ; ;)S@
*
**. Ele%ation in "oilin) point wa! +.,$
+
C when .)m of a compound H wa! di!!ol%ed in
1++)m of water. ;olecular wei)ht of H i! B4
"
of water i! ,.$4 per 1++) of water#
1# 1$+ $# .+ (# .++ *# 17+
*,. The latent heat of %apouri!ation of water i! 9:++ calKmole and if the ".p. i! 1++
+
C the
e"ullio!copic con!tant of water i!
1# +.,1(4 $# 1.+$.4 (# 1+.$.4 *# 1.7($4
*.. The molal freezin) point con!tant for water i! 1.7.4 4)Kmole. If (*$)m of cane !u)ar
BC
1$
3
$$
@
11
# i! di!!ol%ed in 1+++) of water/ the !olution will freeze at
1# 81.7.
+
C $# 1.7.
+
C (# 8(.9$
+
C *# $.*$
+
C
*:. 2hich ha! the minimum freezin) point
.
1# one molal ?aCl !olution $# one molal 4Cl !olution
(# one molal CaCl
$
!olution *# one molal urea !olution
*7. The freezin) point of 1 molal ?aCl !olution a!!umin) ?aCl to "e 1++- di!!ociated in
water i! 4
f
6 1.7. 43@ mol
-1
.
1# 81.7.
+
C $# 8(.:$
+
C (# >1.7.
+
C *# >(.:$
+
C
*9. +.+1; !olution each of urea/ common !alt and ?a
$
S@
*
are ta1en/ the ratio of
depre!!ion of freezin) point i!
1# 1 A 1 A 1 $# 1 A $ A 1 (# 1 A $ A ( *# $ A $ A (
,+. 2hat i! the molality of a !olution of a certain !olute in a !ol%ent if there i! a freezin)
point depre!!ion of +.17*
+
C and the freezin) point con!tant i! 17.*.
1# +.+1 $# 1 (# +.++1 *# 1++
,1. The %apour pre!!ure of a liuid in a clo!ed container depend! upon
1# amount of liuid $# !urface area of the container
(# temperature *# none of the a"o%e
,$. The temperature at which the %apour pre!!ure i! eual to the external pre!!ure i!
called the
1# critical temperature $# "oilin) point
(# normal point *# !aturation point
,(. 2hat would happen if a thin !lice of !u)ar "eet i! placed in a concentrated !olution of
?aCl
1# Su)ar "eet will lo!e water from it! cell!
$# Su)ar "eet will a"!or" water from !olution
(# Su)ar "eet will neither a"!or" nor lo!e water
*# Su)ar "eet will di!!ol%e in !olution
,*. The freezin) point of the water i! depre!!ed "y +.+(:
+
C in a +.+1 mole! ?aCl !olution.
The freezin) point of a +.+$ mol !olution of !ucro!e in
+
C i!
1# 8+.+(:+ $# 8+.+17, (# 8+.+:*+ *# 8+.17,+
,,. The o!motic pre!!ure of !olution increa!e! if
1# Temperature i! decrea!ed $# Solution con!tant i! increa!ed
(# ?um"er of !olute molecule! i! increa!ed *# <olume i! increa!ed
,.. @!motic pre!!ure of !u)ar !olution at $*
+
C i! $., atmo!phere. The concentration of the
!olution in )m mole per litre i!
1# 1+.$, $# 1.+$, (# 1+$., *# +.1+$,
:
,:. Solution! with !ame o!motic pre!!ure are called
1# 3ypertonic $# 3ypotonic (# I!otonic *# ?ormal
,7. 2hich of the followin) correctly expre!!e! the <an't 3off factorE
1# Calculated o!motic pre!!ure K @"!er%ed o!motic pre!!ure
$# @"!er%ed molecular wei)ht K Calculated molecular wei)ht
(# Calculated "oilin) point K @"!er%ed "oilin) point
*# @"!er%ed colli)ati%e property K Calculated colli)ati%e property
,9. <an't 3off factor for an electrolyte i!
1# D 1 $# J 1 (# 6 1 *# none of the a"o%e
.+. Acetic acid di!!ol%ed in "enzene !how! a molecular ma!! of
1# (+ $# .+ (# 1$+ *# 17+
.1. The ratio of the %alue of any colli)ati%e property for 4CC !olution to that of !u)ar
!olution i! nearly
1# 1 $# +., (# $ *# $.,
.$. The <an't 3off factor for +.1; 0aB?@
(
#
$
!olution i! $.:*. The de)ree of di!!ociation i!
1# 91.(- $# 7:- (# 1++- *# :*-
.(. The molecular wei)ht of "enzoic acid in "enzene a! determined "y depre!!ion in
freezin) point method corre!pond! to
1# Ioni!ation of "enzoic acid $# Gimeri!ation of "enzoic acid
(# Trimerization of "enzoic acid *# Sol%ation of "enzoic acid
.*. 0enzoic acid under)oe! dimeri!ation in "enzene !olution/ the <an't 3off factor Mi' i!
related to the de)ree of a!!ociation Mx' of the acid i!
1# i 6 B1- x# $# i 6 B1>x# (# ( ) i = 1 - x 2 *# ( ) i = 1 + x 2
.,. 2hich of the followin) !olution ha! o!motic pre!!ure nearer to that euimolar !olution
of [ ]
4 6
K Fe(CH)
1# ?a
$
S@
*
$# 0aCl
$
(# Al
$
BS@
*
#
(
*# C
1$
3
$$
@
11
... The aueou! !olution with the lowe!t freezin) point of the followin) )roup i!
1# +.+1 ; ;)S@
*
$# +.+1 ; ?aCl (# +.+1 ; C
$
3
,
@3 *# +.++7 ; ;)Cl
$
.:. 2hen two !olution! are !eparated "y a !emi permea"le mem"rane and there i! no flow
of the !ol%ent acro!! the mem"rane/ the !olution! are !aid to "e
1# hypertonic $# hypotonic (# i!otonic *# none
7
.7. If =
A
i! the %apour pre!!ure of a pure liuid A and the mole fraction of A in the mixture
of two liuid! A and 0 i! x the partical %apour pre!!ure of A i!
1# B1 8 x#=
A
$# x =
A
(#
A
x (1- x)P *# ( )
A
1- x x P
.9. The freezin) point depre!!ion con!tant 4
f
depend! on
1# propertie! of pure !ol%ent $# propertie! of pure !olute
(# propertie! of !olute and !ol%ent *# alway! con!tant for all !olute! and
!ol%ent!
:+. The mo!t li1ely of the followin) mixture! to "e an ideal !olution i!
1# ?aCl 8 3
$
@ $# C
$
3
,
- @3 8 C
.
3
.
(# C
:
3
1.
Bl# 8 3
$
@ *# C
:
3
1.
Bl# C
7
3
17
Bl#
:1. For [ ]
3 3
CrCl x!H / ele%ation in 0= of one molal !olution i! dou"le of one molal urea
!olution/ hence x i! Bcomplex i! 1++- ionized#
1# * $# , (# . *# none of the!e
:$. N&elati%e lowerin) in %apour pre!!ureO of a !olution containin) one mol. 4
$
S@
*
in ,*)m
3
$
@ i! B4
$
S@
*
in 1++- ionized#
1# 1 "" $# 3 "8 (# 3 4 *# 1 2
:(. <an't 3off'! factor for [ ]
3 6
K Fe(C!) Bionization ,+-# will "e
1# 1 $# ,., (# $., *# none
:*. @!mo!i! of A into !olution 0 will ta1e place if
1# A i! hyper tonic $# A i! hypotonic (# "oth 1 and $ *# none
:,. ;olal ele%ation con!tant ha! unit
1# mol 1)
-1
4 $# 1) mol
-1
4 (# 4 *# none
:.. 1; Pluco!e !olution at T4 will ha%e o!motic pre!!ure BS 6 !olution con!tant#
1# 10#$ 4 $# ( ST (# * ST *# ST
::. ;ixture of %olatile component to A and 0 ha! total <.=/ = 6 $,* 8 119x
Bx 6 mo. Fraction of 0# 3ence
0 0
A B
P %&' P are
1# 1(,/ $,* $# 119/ $,* (# $,*/ 1(, *# 1(,/ 119
:7. $.,. )m of !ulphur in 1++)m of CS
$
ha! depre!!ion in F.=. of +.+1+
+
4
f
6 +.1
+
Bmolal#.
3ence atomcity of !ulphur in CS
$
i!
1# $ $# * (# . *# 7
:9. An ideal "inary liuid !olution/ the plot of =
total
%er!u! H
A
Bmole fraction of liuid A# i!
linear with !lope and intercept eual to
9
1#
0 0 0
A B A
P - P ( P $#
0 0 0
A B B
P - P ( P (#
0 0 0
B A A
P - P ( P *#
0 0 0
B A B
P - P ( P
7+. ;ole fraction of A %apour! a"o%e !olution in mix of A and 0 ( )
A
X = 04 will "e
0 0
A B
P 100))( P 200)) 1
]
1# +.* $# +.7 (# +.$, *# none
71. If relati%e decrea!e in <.= i! +.* for a !olution containin) 1 mol. ?aCl in ( mol. 3
$
@/
?aCl i! Q.. - ioni!ed
1# .+- $# ,+- (# 1++- *# *+-
7$. 1 mol A> ( mol 0 B%olatile liuid!# ( )
0 0
A B
P = 300))( P =100)) / mol fraction of 0 in %apour
!tate a"o%e !olution i!
1# +.:, $# +.$, (# +.,+ *# +...
7(. 2hich i! true a"out ideal !olution!
1# the chan)e in %olume of mixin) i! zero $# the chan)e enthalpy of mixin) i! zero
(# "oth 1 and $ *# none of the!e
7*. <apour pre!!ure of A i! 1++mm and that of 0 i! $++mm/ mol. fraction of A in %apour
!tate in the mixture of ( mol of A and 1 mol of 0 i!
1# +.* $# +.. (# 1.+ *# +.7
7,. <apour pre!!ure of mixture of a"o%e ue!tion i!
1# 1$, mm $# ,+ mm (# $++ mm *# (++ mm
7.. $, ml of an aueou! !olution of 4Cl wa! found to reuire $+ ml of 1 ; A)?@
(
!olution
when titrated u!in) a 4
$
Cr@
*
a! indicator.. Gepre!!ion in freezin) point of 4Cl !olution
with 1++- ionization will "e B4
f
6 $ for mol
81
4) and molarity 6 molality#
1# +.* $# +.7 (# 1.. *# (.$
7:. 1$.$)m of "enzoic acid B;61$$# in 1++)m 3
$
@ ha! ele%ation of "oilin) point of +.$:
+
.
4
"
6 +.,*
+
1)Kmol. If there i! 1++- polymerization no. of molecule! of "enzoic acid in
a!!ociated !tate i!
1# 1 $# $ (# ( *# *
77. 0a!ed on the )i%en dia)ram/ which of the followin) !tatement! re)ardin) the !olution!
of two mi!ci"le %olatile liuid! are correctE
B1# =lot! AG and 0C !how that &aoult'! law i!
o"eyed for the !olution in which 0 i! a !ol%ent
and A i! the !olute and a! well a! for that in
which A i! !ol%ent and 0 i! !olute
1+
B$# =lot CG !how! that Galton! law of partial pre!!ure! i! o"!er%ed "y the "inary
!olution! of component! A and 0
B(# EF>0P6P3/ and AC and 0G corre!pond to the %apour pre!!ure! of the pure
!ol%ent! A and 0 re!pecti%ely. Select the correct an!wer u!in) the code! )i%en
"elow
1# 1 and $ $# $ and ( (# 1 and ( *# 1/ $ and (
79. An ideal liuid !olution/ the plot of
A A
1 X *er+,+ 1 Y Bwhere
A
X and
A
Y are the mole
fraction! of A in liuid and %apour pha!e# i! linear with !lope and intercept eual to
1#
0 0 0
B A A
0 0
B B
P - P P
(
P P
$#
0 0 0
B A B
0 0
B A
P - P P
(
P P
(#
0 0 0
A B A
0 0
B B
P P - P
(
P P
*#
0 0 0
B B A
0 0
A B
P P - P
(
P P
PART A
1. The %apour pre!!ure of liuid! A and 0 at 1++
+
C are (++
+
mm and 1++ mm of 3)
re!pecti%ely. A mixture of two liuid! formin) ideal !olution at 1++
+
C exert! a %apour
pre!!ure in )a!eou! pha!e in which A and 0 are one mole each in %apour pha!e.
Calculate the %apour pre!!ure of mixture and the mole fraction of liuid mixture in
which two liuid! are mixed.
[ ]
A&+- 1 4( 3 4( 1"0 ))
$. A mixture of ethyl alcohol and propyl alcohol ha! a <.= of $9+ mm at $:
+
C. If mole
fraction of ethyl alcohol i! +..,. Calculate the %apour pre!!ure of ethyl alcohol/ if
%apour pre!!ure of propyl alcohol i! $1+ mm.
[ ] A&+- 333 ))
(. Calculate %apour pre!!ure of a !olution at 1++
+
C ha%in) (.*$) of cane !u)ar in 17+)
water.
[ ]
A&+- 7".2 ))
*. 2hat wei)ht of non %olatile !olute Burea# ?3
$
C@?3
$
need! to "e di!!ol%ed in 1++) of
water in order to decrea!e the %apour pre!!ure of water "y $,-. 2hat will "e the
molality of !olutionE
[ ]
A&+- 18"2 )
,. An aueou! !olution of )luco!e containin) 1$) in 1++) of water wa! found to "oil at
1++.(*
+
C. Calculate 4
"
for water in 4 mole
-1
4).
[ ]
A&+- 0"1
.. At +
+
C/ $(.,* ml of ?
$
at a partial pre!!ure of 1 atm will di!!ol%e per litre of water.
Rnder the !ame condition!/ *7.79ml of @
$
will di!!ol%e. Calculate the amount "y which
the freezin) point of air free water i! lowered "y "ein) !aturated with air. Bcompo!ition
of air i! :9 %ol - of ?
$
and $1 %ol - of @
$
#
11
4
f
6 1.7.4 1) mol
-1

0
A&+- 00024 C 1
]
:. 3ow much ice will !eparate if a !olution containin) 1+) of ethylene )lycol in 1++) of
water i! cooled to 81+
+
CE 4
f
for 3
$
@61.7. 4 mole
-1
1).
[ ]
A&+- 7000 /
7. At +
+
C %apour pre!!ure of 3
$
@ and it! !olution of 7.*9) ?a?@
(
in 1++) water are *..$
and *.*7(mm re!pecti%ely. Calculate de)ree of ionization of ?a?@
(
.
[ ]
A&+- 6.80
9. A !olution of +..*() of an or)anic compound in ,+ml of "enzene Bden!ity +.7:9 )Kml#
lowered it! freezin) point from ,.,1
+
C to ,.+(
+
C. Calculate the molecular wei)ht of
!olid. 4
f
for "enzene i! ,.1$ 4 mole
-1
1)..
[ ]
A&+- 1"606
1+. Calculate the freezin) point of an aueou! !olution of a non electrolyte ha%in) an
o!motic pre!!ure $.+ atm at (++ 4. 4
f
6 1.7. 4 mole
-1
1) and & 6 +.+7$1 litre atm 4
-1
mol
-1
.
0
A&+- - 01"1 C 1
]
11. A 1- 4Cl !olution i! ionized to the extent of 7$-. 2hat would "e it! o!motic pre!!ure
17
+
C.
[ ]
A&+- "836 %t)
1$. A ,- !olution of )luco!e i! i!otonic with 1.1- !olution of 4Cl at (+
+
C. Calculate de)ree
of ionization of 4Cl.
[ ] A&+- 882.0
1(. The %apour pre!!ure of a !olution containin) $) of an electrolyte 0A in 1++) water
which di!!ociate! in one 0
>
and one A
8
ion in water i! :,1 mm at 1++
+
C. Calculate
de)ree of ionization of 0A if it! mol.wt. i! ,..
[ ]
A&+- 8641
1*. A !olution containin) $7) pho!phorou! in (1,) CS
$
B".p. *..(
+
C# "oil! at *:.97
+
C.4
1
" for
CS
$
i! $.(* 4 mole
-1
1). Calculate m.wt. of pho!phorou! and deduce it! molecular
formula. A!!ume it! complete a!!ociation
[ ]
4
A&+- P
1,. The freezin) point of a !olution containin) +.$) of acetic acid in $+.+) "enzene i!
lowered "y +.*,
+
C. Calculate the de)ree of a!!ociation of acetic acid in "enzene.
A!!ume acetic acid dimerize! in "enzene. 4
f
for "enzene 6 ,.1$ 4 mole
-1
1)
1$
[ ]
A&+- .4"
1.. Calculate the molal lowerin) of %apour pre!!ure for 3
$
@ at 1++
+
C.
[ ]
A&+- 1368 ))
1:. Calculate the amount of urea in 1++ml of a !olution at $,
+
C/ who!e o!motic pre!!ure i!
$+.* atm
[ ]
A&+- "002.
17. Gry air wa! !ucce!!i%ely pa!!ed throu)h a !olution of ,) !olute in 7+) water and then
throu)h pure water. The lo!! in wei)ht of !olution wa! $.,) and that of pure water wa!
+.+*). 2hat i! mol.wt. of !oluteE
[ ]
A&+- 7031
19. Calculate the Ba# molar concentration and B"# molality of a !ulphuric acid !olution of
den!ity 1.1) cm
-(
/ containin) $: ma!! percent of !ulphuric acid. For what
%olume !hould 1++ml of thi! acid "e diluted to prepared 1.,? !olution
[ ]
A&+- 1 = 404. )l
$+. A current of dry air wa! pa!!ed throu)h a !erie! of "ul"! containin) 1.$,) of a !olute
A
$
0 in ,+) of water and then throu)h pure water. The lo!! in wei)ht of the former
!erie! of "ul"! wa! +.97) and in the later !erie! +.+1). If the molecular wei)ht of A
$
0 i!
7+/ calculate de)ree of di!!ociation of A
$
0.
SAn!A*+.: -T
$1. Two element! A and 0 form compound! ha%in) molecular formula A0
$
and A0
*
. 2hen
di!!ol%ed in $+) of "enzene. 1.+) of A0
$
lower! of freezin) point "y $.(
+
C. 2here a!
1.+)m of A0
*
lower! the freezin) point "y 1.(
+
C. Calculate the molar ma!!e! of A and
0. Pi%en A 4
f
B"enzene# 6 ,.1 1) mol
-1
.
[ ]
A&+- 2"6( 426"
$$. 7.+,:,1+
-$
1) of Plau"er'! !alt i! di!!ol%ed in water to o"tain 1 dm
(
of a !olution of
den!ity 1+::.$ 1)m
-(
. Calculate the molarity/ molality and mole fraction of ?a
$
S@
*
in
the !olution.
[ ]
A&+- 02")( 024)( 00043
$(. Getermine the %olume of dilute nitric acid Bden!ity 1.11) cm
-1
19 ma!! - 3?@
(
#. That
can "e prepared "y dilutin) ,+.+ cm
(
of concentrated acid Bden!ity 1.*$) cm ) cm
-(
/
.9.7 ma!! - 3?@
(
#. Calculate the molaritie! and molalitie! of concentrated and dilute
acid!.
[ ]
A&+- 1"73)( 3667)( 33")( 372)( *=2348)
1(
$*. The freezin) point of +.+$ mole fraction !olution of acetic acid in "enzene i! $::.*4.
A!!umin) molality eual to molarity/ calculate 4
c
for the euili"rium reaction
( )
-1
f f
$ = 2784 K( K "K 2/ )3le
[ ]
A&+- 321".
$,. An aueou! !olution containin) ,- "y wei)ht of urea and 1+- "y wei)ht of )luco!e.
2hat will "e it! freezin) pointE 4
f
for 3
$
@ i! 1.7. 4 mole
-1
1).
0
A&+- - 304 C 1
]
$.. Concentrated 3?@
(
ha! a !pecific )ra%ity of 1.*$ and i! .9 ma!! - in 3?@
(
/ what ma!!
of 3?@
(
i! contained in (++ mC of thi! ren)entE 2hat %olume of thi! concentrated
3?@
(
"e diluted to o"tain 7++ mC of +.$+ ; 3?@
(
E
[ ]
A&+- 2.3.4/)
$:. If "oilin) point of an aueou! !olution i! 1++.1
+
C. 2hat i! it! freezin) pointE Pi%en
latent heat of fu!ion and %aporization of water are 7+ cal )
-1
and ,*+ cal )
-1
re!pecti%ely.
0
A&+- - 0361 C 1
]
$7. A certain ma!! of a !u"!tance when di!!ol%ed in 1++) C
.
3
.
lower! the freezin) point "y
1.$7
+
C. The !ame ma!! of !olute di!!ol%ed in 1++) of water lower! the freezin) point
"y 1.*+
+
C. If the !u"!tance ha! normal molecular wei)ht in "enzene and i! completely
di!!ociated in water/ into how many ion! doe! it di!!ociate in waterE 4
f
for 3
$
@ and
C
.
3
.
are 1.7. and ,.1$ 4 mole
-1
1) re!pecti%ely.
[ ]
A&+- 3
$9. 1) of mono "a!ic acid in 1++) of water lower! the freezin) point "y +.1.7
+
. If +.$) of
!ame acid reuire! 1,.1ml of ?K1+ al1ali for complete neutralization/ calculate de)ree
of di!!ociation of acid. 4
f
for 3
$
@ i! 1.7. 4 mole
-1
1).
[ ]
A&+- 4 = 1.60
(+. To ,++ cm
(
of water/ (1+
-(
1) of acetic acid i! added. If $(- of acetic acid i!
di!!ociated. 2hat will "e the expre!!ion in freezin) pointE 461.7. 4 1)
>1
mole
-1
and
d6+.99: )Kcm
(
.
[ ]
A&+- 022.
(1. A tu"e of uniform cro!!-!ectional area 1 cm
$
i! clo!ed at one end with !emi permea"le
mem"rane. A !olution of ,)m )luco!e per 1++ml i! placed in!ide the tu"e and i!
dipped in pure water at $:
+
C. 2hen euili"rium i! e!ta"li!hed calculated
1# o!motic pre!!ure of !olution
$# hei)ht de%eloped in %ertical column. A!!ume den!ity of )luco!e !olution 1 )mKml.
1*
[ ]
A&+- 6841 %t)+( 7043 )
($. The molar %olume of liuid "enzene Bd6+.7:: )Kml# increa!e! "y a factor of $:,+ a! it
%aporize! at $+
+
C and that of liuid toluene Bd6+.7.: )Kml# increa!e! "y a factor of
::$+ at $+
+
C. A !olution of "enzene and toluene at $+
+
C ha! a %apour pre!!ure of *./
Torr. Find the mole fraction of "enzene with %apour a"o%e the !olution.
[ ]
A&+- 073
((. A 1.$- !olution BwtK%olume# of ?aCl i! i!otonic with :.$- !olution BwtK%olume# of
)luco!e. Calculate de)ree of ionization and <ant 3off factor of ?aCl.
[ ]
A&+- 4 = 0."( i = 1."
(*. 2hat i! the ratio "y wei)ht of ?aF and ?aI which when di!!ol%ed in water produce! the
!ame o!motic effect! a! +.1 molar !olution of urea in waterE The wei)ht of re!idue
o"tained on e%aporation of the !alt !olution i! +.*7 )m per 1++ ml of !olution
e%aporated. A!!ume complete di!!ociation of the !alt! SAn!A+.$7T
(,. 1++)m of !ucro!e !olution in water i! cooled to 8+.,
+
C. 2hat wei)ht of ice would "e
!eparated out at thi! temperature of !olution !tarted to freeze! at 8+.(7
+
CE 4
f
for 3
$
@
6 1.7. 4 mole
-1
1).
[ ]
A&+- 2242 /)
(.. <apour pre!!ure of C
.
3
.
and C
:
3
7
mixture at ,+
+
C i! )i%en "y =Bmm 3)#617+ H
0
>9+/
where H
"
i! the mole fraction of C
.
3
.
. A !olution i! prepared "y mixin) 9(.) "enzene
and :7.) toluene and if the %apour! o%er thi! !olution i! remo%ed and cooled.
Calculate the mole fraction in %apour !tate a"o%e the !olution
[ ]
A&+- 0.3
(:. A !olution compri!in) +.1mol of naphthalene and +.9mol of "enzene i! cooled until
!ome "enzene freeze! out. The !olution i! then decanted off from the !olid and
warmed to (,( 4. 2here it! %apour pre!!ure i! found to "e .:+ torr. The freezin) and
normal "oilin) point of "enzene are $:7., 4 and (,( 4/ re!pecti%ely and it! enthalpy of
fu!ion i! 1+..: 1J mol
-1
. Calculate the temperature to which the !olution wa! cooled
ori)inally and the amount of "enzene that mu!t ha%e freezen out. A!!ume condition!
of ideal !olution.
[ ]
A&+- 2703. K
(7. The %apour pre!!ure! of two pure liuid! A and 0 that form an ideal !olution are (++
and 7++ torr/ re!pecti%ely/ at temperature T. A mixture of the %apour! of A and 0 for
which the mole-fraction of A i! +.$, i! !lowly compre!!ed at temperature T. Calculate
Ba# the compo!ition of the fir!t drop of the conden!ate
B"# the total pre!!ure when thi! drop i! formed
Bc# the compo!ition of the !olution who!e normal "oilin) point i! T.
1,
Bd# the pre!!ure when only the la!t "u""le of %apour remain!
Be# compo!ition of the la!t "u""le
[ ]
A A A
A&+- (%) X 047 (5) "6" $3rr (6) X 008 (') 67" $3rr (e) X 011
(9. The den!ity of a ( molal !odium thio!ulphate !olution i! 1.$,) cm
-(
. Calculate the
percenta)e "y ma!! of !odium thio!ulphate/ Bii# the mole fraction of !odium
thio!ulphate/ and Biii# molaritie! of ?a
>
and
2 -
2 3
# 7 ion!
1# *$.:1 $# +.+,1 (# *.( *# $.1,
*+. The freezin) point of an aueou! !olution of 4C? containin) +.179$ mol 1)
-1
wa! 8
+.:+*
+
C. @n addin) +.+9, mol. of 3) BC?#
$
/ the freezin) point of the !olution wa! 8
+.,(7
+
C. A!!umin) that the complex i! formed accordin) to the euation.
- ) -
2 )+2
H/(C!) +)C! H/(C!) . Find the formula of the complex. B4
f
6 1.7. 4 1) mol
-1
#
[ ]
2
4
A&+- H/(C!)

PART !
1. At $:
+
C two !olution! of )luco!e in water of concentration +.+1; and +.++1; are
!eparated "y !emipermea"le mem"rane with re!pect to water. @n what !olution/
pre!!ure need "e applied to pre%ent o!mo!i!E Calculate ma)nitude of thi! applied
pre!!ure.
[ ]
A&+- 02217 %t)
$. An aueou! !olution of )luco!e "oil! at 1++.+1
+
C. The molal ele%ation con!tant for
water i! +., 4 1) mole
-1
. 2hat i! the num"er of )luco!e molecule in the !olution
containin) 1++) water.
21
A&+- 12 10 1
]
(. +.*7) of a !u"!tance wa! di!!ol%ed in 1+..) C
.
3
.
. The freezin) point of "enzene wa!
lowered "y 1.7
+
C. Calculate m.2t. of !u"!tance. ;olecular depre!!ion con!tant for
"enzene i! ,+ 4 mole
-1
1++).
[ ]
A&+- 12"7.
*. A ,- "y wei)ht !olution of cane !u)ar in water ha! freezin) point of 8$
+
C calculate the
f.pt. of ,- "y wei)ht !olution of )luco!e in water if freezin) point of pure water i! +
+
C.
0
A&+- - 38 C 1
]
,. The %apour pre!!ure of an aueou! !olution of )luco!e i! :,+mm of 3) at (:( 4.
Calculate molality and mole fraction of !olute.
[ ]
A&+- 0741
1.
.. Calculate the relati%e lowerin) in <.=. of 1+) of a !olute Bm.wt.1++# i! di!!ol%ed in 17+)
water
:. 2hat will "e "oilin) point of "romine when 1:*.,m) of octa atomic !ulphur i! added to
:7) of 0romine. 4
"
for 0r
$
i! ,.$ 4 mole
-1
1) and ".pt of 0r
$
6 (($.1, 4
0
A&+- 3321." K 1
]
7. A mixture which contain! +.,,) of camphor and +.+9+) of an or)anic !olute melt! at
1.1
+
C. The !olute contain! 9(.:,-C and ..$,-3 "y wei)ht. 2hat i! the molecular
formula of compound
1
f
K for camphor i! (:.,
+
mole
-1
1)E The m.pt. of camphor i!
$+9
+
C.
[ ]
10 8
A&+- C H
9. Calculate the o!motic pre!!ure of $+- anhydrou! CaCl
$
!olution at +
+
C a!!umin) 1++-
ionization.
[ ]
A&+- 1211" %t)
1+. 2hen 11.:) of ?aCl are di!!ol%ed in $++) of water the depre!!ion in freezin) point i!
dou"led than the depre!!ion cau!ed "y (*$) of cane !u)ar in 1+++) of water. From
thi! information what do you infer a"out the nature of !olute particle! of ?aCl in
!olution.
[ ]
A&+- 1000
11. $) of "enzoic acid di!!ol%ed in $,) of C
.
3
.
!how! a depre!!ion in freezin) point eual
to 1..$ 4.;olal depre!!ion con!tant of C
.
3
.
i! *.9 4 1) mole
-1
. 2hat i! the percenta)e
a!!ociation of acid if it form! dou"le molecule! in !olutionE
[ ]
A&+- ..20
1$. A !u)ar !yrup of ma!! $1*.$) contain! (*.$) of !u)ar ( )
12 22 11
C H 7 . Calculate molality/
and Bii# mole fraction of !u)ar in the !yrup.
[ ]
A&+- 0""6
1(. The %apour pre!!ure of pure "enzene at a certain temperature i! .*+mm 3). A non
%olatile !olid wei)hin) $.1:,) i! added to (9.+) of "enzene. The %apour pre!!ure of
the !olution i! .++mm 3). 2hat i! the molar ma!! of the !olid !u"!tanceE
[ ]
A&+- 6.6
1*. A +.1 molar !olution of ?aCl i! found to "e i!otonic with 1- urea !olution. Calculate Ba#
<an't 3off factor/ and B"# de)ree of di!!ociation of !odium chloride. A!!ume den!ity of
1- urea eual to 1) cm
-(
.
[ ]
A&+- 1667
1:
1,. A !olution i! prepared from $..:) of an un1nown compound and 11..+) of acetone at
(1(4. The %apour pre!!ure of pure acetone at thi! temperature i! +.,$. atm and that
of the acetone a"o%e the !olution i! +.,+1 atm. Calculate the molar ma!! of the
un1nown compound.
[ ]
A&+- 2677
1.. 2hen $) of a non%olatile hydrocar"on containin) 9*.* percent car"on i! di!!ol%ed in
1++) "enzene/ the %apour pre!!ure of "enzene i! lowered from :*... Torr to :*.+1
Torr. Getermine the molecular formula of the hydrocar"on.
[ ]
14 10
A&+- C H
1:. The den!ity of a ( molal !odium thio!ulphate !olution i! 1.$,) cm
-(
. Calculate the
percenta)e "y ma!! of !odium thio!ulphate/ Bii# the mole fraction of !odium
thio!ulphate/ and Biii# molaritie! of ?a
>
and
2 -
2 3
# 7 ion!
1# *$.:1 $# +.+,1 (# *.( *# $.1,
17. 2hat %olume of 1.+ ;3Cl mu!t "e added to ,+.+ mC of +.,+; 3Cl to )i%e a !olution
who!e concentration i! +.. ;E
[ ]
A&+- 12"
19. At 1++
+
C/ "enzene and toluene ha%e %apour pre!!ure! of 1(,: and ,,7 Torr/
re!pecti%ely. A!!umin) the!e two form an ideal "inary !olution. Calculate the
compo!ition of the !olution that "oil! at 1 atm and 1++
+
C. 2hat i! the compo!ition of
%apour i!!uin) at the!e condition!E
1# H
0
6 +.$*: $#
1
B
X 0447 (#
$
X 07"3 *# H
T
6 +.,,(
$+. Calculate o!motic pre!!ure of a !olution containin) 1++ml of (.*- !olution B"y %olume#
of urea Bm.wt..+# and ,+ ml of 1..- !olution B"y %olume# of cane !u)ar Bm.wt.(*$# at
$:
+
C.
[ ]
A&+- .704
$1. The molarity of ?3
(
in an aueou! !olution i! 11.7 mol dm
-(
. The den!ity of the !olution
i! +.91.) cm
-(
. Getermine 1# molality $# ma!! percent and (# mole fraction of ?3
(
[ ]
A&+- 16" )3l82/
$$. 2hat i! the mole fraction of "enzene in a "enzene-toluene !olution that i! in-
euili"rium with a %apour pha!e containin) .+.+ mol - C
.
3
.
E Pi%en = B"enzene#69,.1
mm 3) and =Btoluene#6$7.* mm 3).
[ ]
A&+- 031
17
$(. The den!ity of a (.:*$; !olution of )lycerol ( )
3 8 3
C H 7 in water at $97 4 i! 1.+::) cm
-(
.
The %apour pre!!ure of pure water at thi! temperature i! $(.:. Torr. Calculate the
%apour pre!!ure of water a"o%e the !olution.
[ ]
A&+- 21 $3rr
$*. Chloro acetic acid ha! 461.9(1+
-(
;. Calculate the freezin) point of +.1; !olution of
thi! acid. A!!ume that molarity and molality ha%e identical %alue!. 4
f
Bwater#61.7. 4
1) mol
-1
.
0
A&+- - 021 C 1
]
$,. Two liuid! A and 0 form ideal !olution at (++4. The %apour pre!!ure of a !olution
containin) one mole of A and four mole! of 0 i! ,.+mm of 3). At the !ame
temperature. If one mole of 0 i! ta1en out from the !olution/ the %apour pre!!ure of
!olution decrea!e! "y 1+mm of 3). Calculate %apour pre!!ure! of A and 0 in pure
!tate.
[ ]
A&+- 400( 600 ))
$.. 3ow much ice will !eparate if a !olution containin) $,) of ethylene )lycol in 1++) of
water i! cooled to 81+
+
CE 4
f
for 3
$
@ 6 1.7. 4 mole
-1
1).
[ ]
A&+- 2"00 /
$:. At +
+
C %apour pre!!ure of 3
$
@ and it! !olution of 7.*9) ?a?@
(
in 1++) water are *..$
and *.*7( mm re!pecti%ely. Calculate de)ree of ioni!ation of ?a?@
(
.
[ ]
A&+- 6.80
$7. 3ow much of concentrated 3
$
S@
*
of den!ity 1.7*) cm
-(
and containin) 97 ma!! percent
of 3
$
S@
*
mu!t "e diluted to prepare 1++ cm
(
of the $+ ma!! percent 3
$
S@
*
of den!ity
1.1*) cm
-(
E
[ ]
A&+- 1264)
$9. A !olution containin) (+) of non%olatile !olute in exactly 9+) water ha! a %apour
pre!!ure of $1.7, mm 3) at $,
+
C. Further 17) of water i! then added to the !olution.
The re!ultin) !olution ha! %apour pre!!ure of $$.17 mm 3) at $,
+
C. Calculate Ba#
molar ma!! of the !olute and B"# %apour pre!!ure of water at $,
+
C.
[ ]
A&+- 23..)) H/
(+. A !olution contain! (.$$) of 3cl@
$
in *:.+) of water. The freezin) point of the !olution
i! $:1.1+ 4. Calculate the fraction of 3cl@
$
that under)oe! di!!ociation to 3
>
and
-
2
Cl7 .
Pi%enA 4
f
Bwater# 6 1.7. 4 1) mol
-1
.
[ ]
A&+- 4 = 002
19
(1. The addition of () of a !u"!tance to 1++) CCl
*
B; 6 1,*) mol
-1
# rai!e! the "oilin) point
of CCl
*
"y +..+
+
C. If 4
"
BCCl
*
# i! ,.+( 4.mol
-1
1)/ calculate Ba# the freezin) point
depre!!ion/ B"# the relati%e lowerin) of %apour pre!!ure/ Bc# the o!motic pre!!ure at
$974 and Bd# the molar ma!! of the !u"!tance. Pi%eA 4
f
BCCl
*
#6(1.7 4 1) mol
-1
and
=B!olution#61..*) cm
-(
.
[ ]
A&+- 466. %t)( )9 2"1
[ ]
A&+- 1127
PASSAGES
I" Consider following law for the solution of a gas in a solvent and answer the
questions at the end of it.
#T$e solu%ilit& o' a gas in a li(ui) is )ire*tl& proportional to t$e pressure o'
t$e gas+"
1. Select correct !tatementA
1# ?3
(
i! !olu"le in water due to hydro)en "ondin) a! well a! due to formation of ion!
$# Pa!e! which can "e liuefied ea!ily are more !olu"le in water than the )a!e! which
cannot "e liuefied
(# 0oth of the a"o%e are incorrect *# 0oth of the a"o%e are correct
$. An ionic compound that attract! atmo!pheric water !o !tron)ly that a hydrate i!
formed i! !aid to "e
1# dilute $# hy)ro!copic (# immi!ci"le *# mi!ci"le
(. The !olu"ility of )a!e! in liuid!
1# increa!e with increa!e in pre!!ure and temperature
$# decrea!e! with increa!e in pre!!ure and temperature
(# increa!e! with increa!e in pre!!ure and decrea!e in temperature
*# decrea!e! with increa!e in pre!!ure and increa!e in temperature
*. The !olu"ility of ?
$
B)# in water expo!ed to the atmo!phere/ when the partial pre!!ure i!
,9( mm i! ,.(1+
- *
;. It !olu"ility at :.+mm and at the !ame temperature i!
1# *.11+
- *
; $# ..71+
- *
; (# 1,++ ; *# $*++ ;
II" Following statement is considered to define colligative properties: Answer
the questions at the end of it.
Properties ,$ose values )epen) onl& on t$e *on*entration o' solute parti*les
in solution an) not on t$e i)entit& o' t$e solute are *alle) *olligative
properties"
1. Acetic acid in "enzene !olution form! dimmer due to intermolecular 3-"ondin). For
thi! ca!e %an't 3off factor i!
$+
1# i 6 1 $# i D 1 (# i J 1 *#
inclu!i%e
$. If p4
a
6 - lo) 4
a
6 */ and 4a 6 Cx
$
then %ant'! 3off factor for wea1 mono"a!ic acid
when C6+.+1 ; i!
1# 1.+1 $# 1.+$ (# 1.1+ *# 1.$+
(. An aueou! !olution of +.+1; C3
(
C@@3 ha! %an't 3off factor of 1.+1. If p3 6 -lo)
+
H 1
]
/ p3 of +.+1; C3
(
C@@3 !olution would "e
1# $ $# ( (# * *# ,
*. In which ca!e %an't 3off factor i! maximumE
1# 4Cl/ ,+- ionized $# 4
$
S@
*
*+- ionized
(# SnCl
*
/ $+- ionized *# FeCl
(
/ (+- ionized
,. A complex containin) 4
>
/ =t BI<# and Cl
8
i! 1++- ionized )i%in) i 6 (. Thu!/ complex i!
1# [ ]
2 4
K PtCl $# [ ]
2 6
K PtCl (# [ ]
3 "
K PtCl *# [ ]
3
K PtCl
III" Consider following figure and answer the questions
at the end of it.
-igure e.plains elevation in %oiling point ,$en a
non/volatile solute is a))e) to a solvent"
0ariation o' vapour pressure ,it$ te1perature an)
s$o,ing elevation in %oiling point
1. Pi%en that T
"
i! the ele%ation in "oilin) point of the !ol%ent in a !olution of molality
Mm' then
5
$
)
_

,
i! eual to
1# 4
"
Bmolal ele%ation con!tant# $# C
%
Blatent heat of %aporization#
(# S Bentropy chan)e# *# x Bmole fraction of !olute#
$. Ele%ation in ".p. of an aueou! urea !olution i! +.,$
+
. ( )
0 -1
5
K 0"2 )3l 2/ . 3ence mole
fraction of urea in thi! !olution i!
1# +.97$ $# +.+,.: (# +.9*( *# +.+17
$1
(. A complex of iron and cyanide ion! i! 1++- ionized at 1m Bmolal#. If it! ele%ation in
".p. i! $.+7
+
( )
0 -1
5
K = 0"2 )3l 2/ then the complex i!
1# [ ]
3 6
K Fe(C!) $#
2
Fe(C!) (# [ ]
4 6
K Fe(C!) *#
4
Fe(C!)
*. Select correct !tatementA
1# 3eat! of %aporization for a pure !ol%ent and for a !olution are !imilar "ecau!e
!imilar intermolecular force! "etween !ol%ent molecule! mu!t "e o%ercome in "oth
ca!e!.
$# Entropy chan)e "etween !olution and %apour i! !maller than the entropy chan)e
"etween pure !ol%ent and %apour
(# 0oilin) point of the !olution i! lar)er than that of the pure !ol%ent
*# All are correct !tatement!
,. Con!ider followin) term!A
BI# m4
"
BII# m4
"
i BIII#
5
$
i

BI<# 4
"
Term! which can "e expre!!ed in de)ree Btemperature# are
1# III/ I< $# I/ II (# I/ II/ III *# I/ III
.. &atio of
5 5
$ K of .- A0
$
and 9- A
$
0 BA0
$
and A
$
0 "oth are non-electrolyte!# i! 1
molK1) in "oth ca!e!. 3ence atomic ma!!e! of A and 0 are re!pecti%ely.
1# .+/ 9+ $# *+/ *+ (# **.,/ 9., *# 1+/ *+
I0" Questions at the end are based on following phase diagram for pure solvent
and solution for depression in freezing point.
-ree2ing point o' a li(ui) is )e'ine) as t$at
te1perature at ,$i*$ it is in e(uili%riu1 ,it$ its
soli) state"
P$ase )iagra1 'or a pure solvent an) solution
'or )epression in 'ree2ing point
1. Freezin) point of the followin) !y!tem i!A
liuid !ol%ent

!olid !ol%ent
$$
1#
H - :
#

$#
H
#

(#
:
#

*#
#
H

$. Freezin) point of a !olution i! !maller than that point of a !ol%ent. It i! due to

1# 3 of !olution and !ol%ent i! almo!t identical !ince intermolecular force! "etween
!ol%ent molecule! are in%ol%ed
$# S of the !olution i! lar)er than that for the !ol%ent
(# S of the !olution i! !maller than that of the !ol%ent
*# 3 of !olution i! much hi)her than of !ol%ent "ut S of !olution i! !maller than that
of the !ol%ent
(. Select correct !tatementA
1# Solution ha! more molecular randomne!! than a pure !ol%ent ha!/ the entropy
chan)e "etween !olution and !olid i! lar)er than the entropy chan)e "etween pure
!ol%ent and !olid
$# 3eat! of fu!ion of !olution and !ol%ent are !imilar !ince !imilar force! of
intermolecular force! are in%ol%ed
(# Su)ar containin) !olution freeze! at a lower temperature than pure water
*# All are correct !tatement!
*. .+) of urea i! di!!ol%ed in 11++) !olution. To 1eep
f
$ K a! 1 molK1)/ water
!eparated in the form of ice i!
1# *+) $# .+) (# 1++) *# $++)
0" Read the following fact and answer the questions at the end of it.
3s1osis4 li5e all *olligative properties4 results 'ro1 an in*rease in entrop& as
pure solvent passes t$roug$ t$e 1e1%rane an) 1i.es ,it$ t$e solution"
1. Ge!alinatin) of !ea water i! now done u!in)
1# re%er!e o!mo!i! $# o!mo!i! (# filtration *# e%aporation
$. &ed "lood cell! are placed in a !olution and neither hemoly!i! nor crenation occur!.
Therefore the !olution i!
1# hypertonic $# hypotonic (# i!otonic *# i!otropic
(. The pa!!a)e of a !ol%ent acro!! a !emipermea"le mem"rane "ecau!e of concentration
difference! i! called
1# dialy!i! $# hemoly!i! (# hydration *# o!mo!i!
$(
,. Mat*$ t$e ter1s ,it$ )e'initions
Ter1 De'inition
I A 3emoly!i! A A the !hrin1in) of a red "lood cell when placed in a !olution of
)reater o!molarity than the cell it!elf
II A Crenation 0 A refer! to two !olution! of !ame o!molarity
III A 3y)ro!copic C A refer! to a !olution ha%in) a )reater o!molarity than +.(+
o!mol/ the o!molarity of normal red "lood cell!
I< A 3ypertonic G A an ionic compound which attract! water molecule! from the
atmo!phere
< A I!otonic E A the !wellin) and "ur!tin) of a red "lood cell when placed in a
!olution of lower o!molarity than the cell it!elf
Mat*$ing *o)es are 6
I II III I0 0 I II III I0 0
1# A 0 C G E $# E G C 0 A
(# E G 0 C A *# E A G C 0
0I" Read the following statement and answer the questions at the end of it.
T$e partial vapour pressure o' an& volatile *o1ponent o' an i)eal solution is
e(ual to t$e vapour pressure o' t$e pure *o1ponent 1ultiplie) %& t$e 1ole
'ra*tion o' t$at *o1ponent in t$e solution"
1. At a )i%en temperature/ total %apour pre!!ure in Torr of a mixture of %olatile
component! A and 0 i! )i%en "y =61$+-:, H
0
hence %apour pre!!ure of pure A and 0
re!pecti%ely in Torr.
1# 1$+/ :, $# 1$+/ 19, (# 1$+/ *, *# :,/ *,
$. A mixture contain! 1 mol. %olatile liuid A B
0
A
; 6 1++ mm 3)# and ( mol %olatile liuid
0 B
0
B
; 6 7+ mm 3)#. If !olution "eha%e ideally/ total %apour pre!!ure of the di!tillate i!
approximatelyA
1# 7,mm 3) $# 7.mm 3) (# 9+mm 3) *# 9$mm 3)
(. ;ole! of 4
$
S@
*
to "e di!!ol%ed in 1$ mol. water to lower it! %apour pre!!ure "y 1+mm
3) at a temperature at which %apour pre!!ure of pure water i! ,+mm 3) i!
1# ( mol $# $ mol (# 1 mol *# +., mol
$*
0II" Answer the questions (given below which are
based on the following diagram.
0apour pressure plots o' %en2ene/toluene
1i.tures at 78
8
C" Solutions o' %en2ene an)
toluene are i)eal" Raoult9s la, is valie) 'or %ot$
*o1ponents over t$e entire range o' *on*entration"
1. An ideal !olution con!i!tin) of two component! A and 0 B!uch a! "enzene and toluene#
i! one in what
1# the intermolecular attraction! A/ Q. A/ 0/ Q.. 0 and A Q. 0 are eual
$#
)ix )ix
H = 0( 1 = 0
(# "oth of the a"o%e condition! are followed
*# none of the a"o%e condition! i! followed
$. There i! de%iation from ideal "eha%iour if mixture contain!A
1# n-hexane and n-heptane $# chloro"enzene and "romo"enzene
(# o-xylene and p-xylene *# acetone and chloroform
0III" Answer the questions (given below which are based on the following
diagram.
0apour pressure )iagra1 'or real solutions o' t,o li(ui)s A an) ! t$at e.$i%it
a negative )eviation 'ro1 Raoult9s la," T$e vapour pressure o' %ot$ A an) !
are less t$an pre)i*te) %& Raoult9s la," T$e )as$e) lines represent t$e plots
'or i)eal solutions
1. Solution containin) component! A and 0 !how! thi! type of de%iation from ideal
"eha%iour when
Attraction A Q 0 3
mix
<
mix
".p.
1# lar)er than a%era)e of A .. A/ 0Q 0 >%e >%e lar)er than
expected
attraction
$# a! in Ba# - %e - %e a! in Ba#
$,
(# !maller than a%era)e of A Q A/ 0 Q 0 >%e >%e !maller than expected
attraction
*# a! in Bc# >%e >%e a! in Bc#
$. Thi! type of de%iation i! al!o expected in the followin) mixture
1# ethanol and cyclohexane $# ethyl "romide and ethyl chloride
(# "enzonitrile and ethyl cyanide *# diethyl ether and chloroform
I:" Answer the questions (given below which are based on
the following diagram.
0apour pressure )iagra1 'or real solution o' t,o li(ui)s
A an) ! t$at e.$i%it a positive )eviation 'ro1 Raoult9s
la," T$e vapour pressure o' %ot$ A an) ! are greater
t$an pre)i*te) %& Raoult9s la," T$e )as$e) lines
represente) t$e plots 'or i)eal solutions"
1. Con!ider !ome fact! a"out the a"o%e pha!e dia)ram
BA# Thi! i! o"!er%ed when A Q 0 attraction! are )reater than a%era)e of A Q A and 0 Q
0 attraction
B0#
)ix )ix
AH = +*e( 1 +*e
BC# 0oilin) point i! !maller than expected !uch that %aporization i! increa!ed
BG# It form! azeotropic mixture
Select correct fact! A
1# A/ 0/ C $# 0/ C/ G (# A/ C/ G *# A/ 0/ C/ G
$. Total %apour pre!!ure of mixture of 1 mol. of %olatile component ( )
0
A
A ; = 100 )) H/
and ( mol. %olatile component 0( )
0
B
; = 60 )) H/ i! :,mm. For !uch ca!e
1# there i! po!iti%e de%iation from &aoult'! law
$# "oilin) point ha! "een lowered
(# force of attraction "etween A and 0 i! !maller than that "etween A and A or
"etween 0 and 0
*# all the a"o%e !tatement! are correct
:" Read the following sentence and answer the question at the end of it.
In *ase o' positive an) negative )eviations s$o,n %& 1i.ture o' t,o solvents
t$e %oiling point *o1position *urves $ave 1ini1a or 1a.i1a"
$.
1. Select correct !tatementB!# a"out thi! mixture of !ol%ent!
1# Separation of !uch mixture into their component! can't "e o"tained "y !imple or
fractional di!tillation
$# ;ixture i! called azeotropic mixture
(# ;ixture "oil! at a con!tant temperature and di!till! o%er without under)oin) any
chan)e in the compo!ition
*# Ethanol-water !y!tem !how! po!iti%e de%iation.
:I" Read the following sentence and answer the questions at the end of it.
!en2oi* a*i) )i1erises in %en2ene %ut ioni2es in a(ueous solution
1. Euimolal !olution! of BA# "enzoic acid in "enzene and B0# in aueou! !olution are
ta1en. Thu!
1# %an't 3off factor of BA# D B0# $# %an't 3off factor of BA# J B0#
(# %an't 3off factor of BA# 6 B0# *# dimmer formation or ioni!ation i! not po!!i"le
$. In the followin) euili"rium
2 4 2
! 7 (/) 2!7


?@
$
i! ,+- of the total %olume. 3ence/ de)ree of di!!ociation Bx# and %an't 3off factor
Bi# re!pecti%ely are
1# +.,/ 1., $# +.$,/ 1.$, (# +.((/ 1.(( *# +.../ 1...
(. 2hich ha! maximum freezin) pointE
1# .) urea !olution in 1++) 3
$
@ $# .) acetic acid !olution in 1++) 3
$
@
(# .) !odium chloride in 1++) 3
$
@ *# all ha%e eual freezin) point
*. Aluminium pho!phate i! 1++- ionized in +.+1 mol. aueou! !olution. 3ence
5 5
$ K i!
1# +.+1 $# +.+1, (# +.+1:, *# +.+$