CLASS : XIth SUBJECT : CHEMISTRY

DATE : 20/08/24 DPP No. : 4 and 5

Topic :-SOLUTIONS
1. The lubricating action of an oil is more if it possess :
a) High vapour pressure
b) Low vapour pressure
c) High surface tension
d) High density

2. Maximum lowering of vapour pressure is observed in the case of

a) 0.1 M glucose b) 0.1 M Bacl2 c) 0.1 M MgSO4 d) 0.1 NaCl

3. The solubility of a gas in liquid at a temperature is directly proportional to its :

a) Density b) Melting point c) Boiling point d) Pressure

4. A solution of sucrose (Molar mass = 342 g/mol) is prepared by dissolving 68.4 g of it per litre
of solution, what is its osmotic pressure (R=0.082 L atmK −1 mol−1 ) at 273 K?
a) 3.92 atm b) 4.48 atm c) 5.92 atm d) 29.4 atm

5. Which of the following concentration factors is affected by change in temperature?

a) Molarity b) Molality c) Mole fraction d) Weight fraction

6. Which of the following mixture does not show positive deviation from the Raoult’s law?
a) Benzene + acetone b) Acetone + ethanol
c) Acetone + chloroform d) Water + ethanol

7. The ratio of vapour pressure over solution phase on mixing two immiscible liquids is equal to :
a) Ratio of their weights in mixture
b) Ratio of their mol. weights
c) Ratio of their moles in liquid phase
d) Ration of their moles in vapour phase

8. The vapour pressure of benzene at 80 ͦC is lowered by 10 mm by dissolving 2g of a non-volatile

substance in 78 g of benzene. The vapour pressure of pure benzene at 80 ͦC is 750 mm. The
molecular weight of the substance will be :
a) 15 b) 150 c) 1500 d) 148
9. I2 is added to a system of H2 O and CS2. The concentration of I2 in water and CS2 is found to be
𝑐1 and 𝑐2 respectively. The ratio of 𝑐1 /𝑐2 will be constant only if :
a) The solutions are dilute
b) The temperature remains constant
c) The solute neither changing the immiscibility of solvents nor itself changing in molecular
state
d) All of the above

10. The boiling point of an aqueous solution of a non-volatile solute is 100.15 ͦC. What is the
freezing point of an aqueous solution obtained by diluting the above solution with an equal
volume of water? The values of 𝐾𝑏 and 𝐾𝑓 for water are 0.512 ͦC and 1.86 ͦC K molality −1
a) −0.544 ͦC b) −0.512 ͦC c) −0.272 ͦC d) −0.1.86 ͦC

11. A solution has an osmotic pressure of 0.821 atom at 300 K. its concentration would be :
a) 0.066 𝑀 b) 0.66 𝑀 c) 0.033 𝑀 d) 0.33 M

12. Density of a 2.05 M solution of acetic acid in water is 1.02 g/mL. The molality of the solution is
a) 9 L b) 1.8 L c) 8 L d) 0.9 L

13. On adding 1 g arsenic to 80 g benzene, the freezing point of benzene is lowered by 0.19℃ . The
formula of arsenic is
a) As b) 𝐴𝑠2 c) 𝐴𝑠3 d) 𝐴𝑠4

14. The process of getting fresh water from sea water is known as :
a) Osmosis
b) Filtration
c) Diffusion
d) Reverse osmosis

15. The statement “the relative lowering of the vapour pressure is equal to th ratio ot moles of the
solute to the total number of the moles in the solution” refers to
a) Decrease the freezing point of water in the winter and increase the boiling point of water in
the summer
b) Only decrease the freezing point of water
c) Only increase the boiling point of water
d) Be used for cleaning the radiator in a car

16. X is dissolved in water. Maximum boiling point is observed when X is ….(0.1 M each)
a) 𝐶𝑎𝑆𝑂4 b) 𝐵𝑎𝐶𝑙2 c) NaCl d) Urea

17. What is molarity of 𝐾 + in aqueous solution that contains 17.4 ppm of 𝐾2 𝑆𝑂4 (174 𝑔 𝑚𝑜𝑙 −1)?
a) 2 × 10−2 𝑀 b) 2 × 10−3 𝑀 c) 4 × 10−4 𝑀 d) 2 × 10−4 𝑀
18. Which of the following statement is true?
a) The relative lowering of vapour pressure of a solution is equal to the mole fraction of the
solute present in the solution.
b) Passage of solute molecules towards solution side through semipermeable membrane is
osmosis.
c) The boiling point of solution is always lower than the solvent.
d) The boiling point of a liquid is the temperature at which its vapour pressure becomes equal
to 260 mm.

19. Calculate the molarity of 1 L solution of 93% H2 SO4 (weight/volume). The density of the
solution is 1.84 g/mL
a) 11.05 b) 12.05 c) 13.05 d) 14.05

20. If 0.15 g of a solute dissolved in 15 g of solvent is boiled at a temperature higher by 0.216℃

than that of the pure solvent, the molecular weight of the substance is (molal elevation
constant for the solvent is 2.16℃)
a) 100 b) 102 c) 104 d) 1.02
21. The vapour pressure of a liquid in a closed container depends upon
a) Amount of liquid b) Surface area of the container
c) Temperature d) None of the above

22. The vapour pressure of a solution is proportional to :

a) Mole fraction of solute
b) 1/(mole fraction of solute)
c) Mole fraction of solvent
d) None of the above

23. At 25∘ 𝐶 a 5% aqueous solution of glucose (molecular weight = 180 g 𝑚𝑜𝑙 −1 ) is isotonic with
2% aqueous solution containing an unknown solute. What is the molecular weight of the
unknown solute.
a) 60 b) 80 c) 72 d) 63

24. The spontaneous movement of solute particles from a more concentrated solution to less
concentrated solution is called :
a) Osmosis b) Diffusion c) Plasmolysis d) Fusion

25. How many grams of a sucrose (mol wt. = 342) should be dissolved in 100 g water in order to
produce a solution with a 105.0℃ difference between the freezing point and boiling
temperature? (𝑘𝑓 = 1.86 C/m, 𝑘𝑏 = 0.151℃)
a) 34.2 g b) 72 g c) 342 g d) 460 g

26. A solution of urea (mol. mass 56) boils at 100.18 ͦC at atmospheric pressure. If 𝐾𝑓 and 𝐾𝑏 for
water are 1.86 and 0.512 K molality −1 respectively, the above solution will freeze at :
 a) − 6.54 ͦC b) 6.54 ͦC c) − 0.654 ͦC d) 0. 654 ͦC

27. 19.85 mL of 0.1 N NaOH reacts with 20 mL of HCl solution for complete neutralization. The
molarity of HCl solution is
a) 9.9 b) 0.99 c) 0.099 d) 0.0099
28. The vapour pressure will be lowest of
a) 0.1 M sugar solution b) 0.1 M KCl solution
c) 0.1 M Cu(NO3 )2 solution d) 0.1 M AgNO3 soution

29. Which one is correct?

a) Molality changes with temperature. b) Molality does not change with temperature.
c) Molarity does not change with temperature. d) Normality does not change with
temperature.

30. What is molality of a solution in which

(18 g glucose mol. wt. = 180) is dissolved in 500 g of water?
a) 1 m b) 0.5 m c) 0.2 m d) 2 m

31. Which of the following solution in water possesses the lowest vapour pressure?
a) 0.1 (N) BaCl2 b) 0.1 (M)NaCl c) 0.1 (M) KCl d) None of these

32. A 5.25% solution of a substance is isotonic with a 1.5% solution of urea (molar mass =60
gmol−1) in the same solvent. If the densities of both the solutions are assumed to be equal to
1.0 g cm−3 , molar mass of the substance will be
a) 90.0 g mol−1 b) 115.0 g mol−1 c) 105.0 g mol−1 d) 210.0 g mol−1

33. Which of the following solutions will have highest boiling point
a) 0.1 M FeCl3 b) 0.1 M BaCl2
c) 0.1 M NaCl d) 0.1 M urea (NH2 CONH2 )

34. At25∘ 𝐶 , the highest osmotic pressure is exhibited by 0.1 M solution of

a) Decinormal aluminium sulphate
b) Decinormal barium chloride
c) Decinormal sodium chloride
d) A solution obtained by mixing equal volumes of (b) and (c) and filtering

35. Molarity of 0.2 N H2 SO4 is

a) 0.1 b) 0.2 c) 0.3 d) 0.4

36. The ionic strength of solution containing 0.1 mol/kg of KCl and 0.2 mol/kg of 𝐶𝑢 𝑆𝑂4 is
a) 0.3 b) 0.6 c) 0.9 d) 0.2

37. 25 mL of a solution of barium hydroxide on titration with 0.1 molar solution of hydrochloric
 acid gave a titre value of 35 mL. The molarity of barium hydroxide solution was
a) 0.07 b) 0.14 c) 0.28 d) 0.35

38. The freezing point of equimolal aqueous solution will be highest for
a) C6 H5 NH3 Cl b) La(NO3 )3 c) C6 H12 O6 d) Ca(NO3 )2
39. The normality of a 100 mL solution of sodium hydroxide which contains 4 g of NaOH, is
a) 0.5 b) 1.0 c) 1.5 d) 2.0

40. For determination of molecular weights, Raoult’s law is applicable only to

a) Dilute solutions of electrolytes b) Concentration solution of electrolytes
c) Dilute solutions of non electrolytes d) Concentration solution of non electrolytes