Solutions Slot – 1 (Chemistry) Page # 1

STOICHIOMETRY-1

EXERCISE – I SINGLE CORRECT (OBJECTIVE QUESTIONS)

5 Sol.8 Both have equal volume = V
Sol.1 1 moles of x will give = = 2.5 mol
2
 v × 10  × d
1.25   HCl
But yield = × 100 = 50% HCl =  100  mole
2.5 36.5
XB
Sol.2 Molality = X × M × 1000  v × 10  × 1.5 d
A A
  HCl
NaOH =  100  mole
mB = 75 m
40
M × 1000
m= NaOH mole > HCl mole
d × 1000 − M × M.
M = 30 Basic Solution

8
125ml × 1 ×  y y
Sol.3 NaOH = 100 mole Sol.9 CxHy +  x + 4  O2 → XCO2 + H2O (g)
40   2

10 (g) (g)
125 ×
HCl = 100 = 0.34 mole
36.5  y
1 + x + 
HCl > NaOH  4  600
=
Acidic  y 700
x + 
 2 

Sol.4 0.86
5y
x+7=
Sol.5 Let mole of B = x 4
V.D = 25 mole of a = 100 x by option (A)
Mol. mass = 50
80x + 40(100 − x) Sol.10 B
⇒ 250 =
100 wsalt = 1 gm
100 wHg = 0.5934 gm
x= = 25
4 Let wt. % of H = x
Let wt. % of C = 8x
Sol.6 Limiting reactant is A Let wt. % of O = 16x
Ideally with 2 moles of A, D formed = 3 moles
Since its dibasic acid
But yield = 25%
So, moles of D formed ∴ 1 mole salt = 2 moles Ag
= 3 × 0.25 = 0.75 mol 0.5934
Moles of Ag =
108
mole
Sol.7 m = 0.0125 = × 1000
250 0.5934 1
∴ moles of salt /acid = ×
0.0125 108 2
Na2CO3 mole =
4 Given wt of salt = 1 gm
= 0.33 g
1
0.0125 / 4 So, Molecular wt. of salt = × 108 × 2
XNa CO = 0.5934
a 3 0.0125 250
+
4 18 = 364 gm/mol
= 2.25 × 10–4 Now x + 8x + 16 x = 364

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 Page # 2 Solutions Slot – 1 (Chemistry)

x = 14.5 gm Sol.14 A
wt. of H present = 14.5 gm P4O10 + 6 H2O → 4H3 PO4
Moles of H present = 14.5 284 gm 108gm 392 gm
wt. of C present = 8 × 14.5 108 gm water reacts with P4O10 = 284 gm
8 × 14.5 284
Moles of C present = = 9.7 27 gm water will react with P4O10 = × 27
2 108
wt. of O present = 16 × 14.5 = 71 gm
16 × 14.5
Moles of O present = = 14.5 Sol.15 C = 84/12 = 7 mole
16
Hence H and O are present in same ratio. H2 = 12 g = 6 mole
These for option (B) satisfy this critaria. O2 = 56/22.4 = 5/2 mole
12C + 11H2 + 11/2 O2 → C12H22O11
Sol.11 L.R. = O2
CH4 + 2O2 → CO2 + 2H2O 11/2 mole O2 produce 1 mole source
Max. Heat obtained when reactants are 5/2 mole O2 will for 5/11 mole source
present in their stochiometric ratio. mass of scross = 5/11 × (mol. mass)
For 1 mole CH4 O2 required = 2 moles = 5/11 × 342
0.2 moles O2 is in air = 1 mole = 155.45 g

1
2 mole O2 will be in air = × 2 = 10 mol Sol.16 118 % ⇒ 100 g used 18 g water
2
⇒ 50 g need 8 g water
Total no. of moles = nO2 + nN2 + nCH4 (50 g + 18 g water)
=2+8+1 ⇒ 59 g H2SO4 + 9 g water
= 11

2 PV
Mole fraction O2 = Sol.17 Mole of N2 =
11 RT
P = 860 – 24 = 836 mm Hg
8
Mole fraction N2 =
11
 836  ×  100 
   
Mole of N2 =  760   11 × 1000 
1
Mole fraction CH4 = 0.08 × 250
11
= 5 × 10–4 mole
Sol.12 C6H5OH + 7O2 → 6CO2 + 3H2O(
) mass of N2 = 0.014 g
30 ml 0.014 10
% of N = × 100 = %
180 ml produced 0.42 3
Volume used initially
= 30 + 210 = 240
Sol.18 B
for C6H5OH for O2
M2(CO3)n + 2HCl → nCO2 + 2MCln + H2O
Volume formed = 180 ml
balancing O atom
Change in v % = 240 + 80 = 60 ml
3n = 2n + 1
n=1
Sol.13 NxOy + y H2 → yH2O (
) + x/2 N2(g)
10 ml
Sol.19 A
H2 = 10 y ml = 30 ml
N2 = 10 ml = 10 x/2 ml 46x + 30(100–x) = 34 × 100
x=2 Let % by mole of NO2 be x.

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 Solutions Slot – 1 (Chemistry) Page # 3

Sol.20 A
132
5A2 + 2 B4 → 2AB2 + 4 A 2B Sol.24 CO2 = 132 g = mole = 3 mole
44
5 × 20 2 × 480 2 × 250 4 × 140
54
500 gm 560 gm H2O = 54 g = mole = 3 mole
18
Here limiting product is AB2 = 500 gm
⇒ C atoms = 3 mole
1000 H atoms = 6 mole
Mol. req. = =4 by option C
250
So, A2 needed = 10 × 20 = 200 gm
Sol.25 C4H10 = 80 ml
B2 needed = 480 × 4 = 1920 gm CH4 = xml CO = y ml
Total mass of mixture = 2120 gm x + y = 120 ml
C4H10 → 4 CO2 ,
Sol.21 C2H4O2 + 2O2 → 2CO2 + 2H2O 80 ml 320 ml,
n mole 2n mole for max. energy
CO → CO2
y ml y ml
60 n gram 2n × 32 gram
CH4 → CO2
⇒ 60 n gram 64 n gram
x ml x ml
⇒ 60 n + 64 n = 620 ⇒ n = 5 total CO2 volume
produced CO2 = 2n = 10 mole = 320 + x + y ml
CO2 mass produced = 10 × 44 = 440 gram = 320 + 120
= 440 ml

Sol.22 B
Sol.26 V1 ml 0.2 M NaOH, V2 ml 0.1 M CaCl2
2NaCl + Ag2SO4 → 2AgCl + Na2SO4
(+ve ion) = 0.2 V1 = 0.1 V2 mole
Initially (–ve ion) = 0.2 V1 + 0.1 ×2V2
No. of moles of Ag2SO4 = 2 × 2 = 4 = 0.2V1 + 0.2 V2 mole
No. of moles of NaCl = 4 × 1 by equation
AgCl formed = 4 moles 40
(+ve) = (–ve) – (–ve) ×
No. of moles of Ag2+ left = 4 × 2 – 4 = 4 100
No. of moles of Cl– left = 0
60
No. of moles of Na+ = 4 = (–ve) ×
100
No. of moles of SO4–2 = 4
6
⇒ 0.2 V1 + 0.1 V2 = 0.2 (V1 + V2) ×
12 10
Sum of molar conc. = =2M
6 ⇒ 2V1 + V2 = 1.2 V1 + 1.2 V2
⇒ 0.8 V1 = 0.2 V2 ⇒ 4V1 = V2
Sol.23 A V1 = 200 ml, V2 = 800 ml
100 gm oleum gives H2SO4 = 112 gm
Sol.27 C
112
12.5 gm will give H2SO4 = × 12.5 = 14 gm 3 × 0.5
100 NaI mass = = 0.015 gm
100
14 0.015
No. of moles of H2SO4 = No. of moles of = = 1 × 10–4
98 150
14
×2 No. of I– ions = 10–4 × 6.023 × 1023
Conc. of H+ ions = 98 = 2.85 × 10–3 M = 6.023 × 1019
100

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 Page # 4 Solutions Slot – 1 (Chemistry)

Sol.28 Same emprical formula Sol.35 First of all balance reaction and than check
⇒ same compostion by mass the option

Sol.29 CO = x ml ; CO2 = y ml, N2 = z ml Sol.36 (A) 100 g containt → 80 g NaOH

x + y + z = 200 ....(i) 50 g will containt → 40 g NaOH
CO + 1/2 O2 = CO2 (B)100 ml of 120 g solution has 80 g NaOH
50 g solution will be having 100/3 g NaOH
x o Contraction = x/2
Check all the option like above
o x
CO2 No reaction ; N2 + O2 → no reaction
Sol.37 (A) Molality of MgCl2
change in volume = x/2 = 40
x = 80 ml 2 × 1000
=
1000 × 1.09 − 2 × 95
50
x + y = 200 × = 100 ...(ii) = 2.22
100
y = 20 ml ; z = 100 ml XMgCl
(B)m = (1 − X
2
× 1000
MgCl
)MSolvent
2

Mgas (C) MgCl2 = 2 mole /lt.

Sol.30 1.17 = M = 190 g/lt. or 19g /100 ml
air

mass of solute
Mgas (D) ppm = mass of solvent × 106
1.17 =
29
20 / 9 × 95
M gas = 29 × 1.17 = 33.9 = × 106
1000
Sol.38 Check of all the option
Sol.31 No volume change
C3H8 + 5 O2 → 3CO2 + 4H2O
⇒ a+b=x+d
10 ml 110 ml
(1) Total mole remain same
0 60ml 30 ml
(2) ⇒ Mgas remain same Contraction = 30 ml or 30/120 × 100
(3) ⇒ V.D. remain same = 25%
(A) & (C)
56
Sol.32 Check each and every of option carfully Sol.39 M = =5
11.2
g/
= 5 × 34 = 170 g/

Sol.33 Let volume of solution = 1000 ml
⇒ % w/v = 17
[Ba2+] = 5 M ; [Cl–] = 10 M
1000 ml has 170 g H2O2
[Na+] = 10 M
or 530 g solution has 170 g H2O2
[Cl–] = 10 M
1000 ml solution = 1949 g solution moles
m = mass of solvent ×1000
solute ⇒ BaCl2, NaCl & Na2X
BaCl2 = 5 mole = 1040 g = (5/360) × 1000
NaCl = 588 g ; Na2X = mole of Na2X × 142 1000
=
Solvent = 1949 – (1040 + 588 + 142nNa X) 72
2
= 321 – 142 n Na2X
Sol.40 Check all the option one by one
nNa
2X
mNa = 321 − 142n × 1000 = 2
2X Na X
Sol.41 BaSO4 is insoluble in water
2
⇒ molarity of BaSO4 can’t be calculated.
nNa = 0.5 (2v × 1) × 2 4
2X [Na+] = =
2v + v 3
(2 × v) × 2 4
Sol.34 Check of all the option [NO3–] = =
2v + v 3

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 Solutions Slot – 1 (Chemistry) Page # 5

42. A-R, B-P,C-Q

 63.5 × 2.235  +  63.5 × 2.69 
mole wt. (89 × 3) + (27 × 5) + (16 × 12)    
= 594  223.5   134.5 
= 1.905 g
89 × 3 267
y= × 100 = × 100 In ppt.
594 594
AgBr = 0.02 mole
= 44.95 %
AgCl = 2.87/143.5 = 0.02 mole
27 × 5
Al = × 100 = 22.73 %
594 48. A-B, B-C, C-B
First of all balance the reaction then check all
16 × 12
O= × 100 = 32.32 % options one by one like
594
mole of NaBr = 2.06 × 103 kg
43. A-R, B-Q, C-P 2.06 × 106
= = 2 ×104 mole
C6H8O6 = 72 + 8 + 96 = 176 mol. wt. 103
−3
17.6 × 10 3
mole of C6H8O6 = = 10–4 mole Fe required = × 2 × 104 ×56 g
176 8
(A) O → 10–4 × NA ×6 atoms = 420 kg
176 g vitamin C → 1 mole
49. A-B, B-C, C-B
1
(B)1 g vitamin C = mole 27 g N2O5 = 0.25 mole
176
water required = 0.25 mole = 4.5 g in 50 g of
sample
44. A-Q, B-P, C-S, D-R
1000 ml solution has 10 × 40 g solute ⇒ % labaling (109 %)
1200 g solution has 400 g solute
50. (a)-A, (b) -A
⇒ 800 g solvent has 400 g soute
as degree of dissociation increases the value
400 of total number of mole increases
⇒ 100 g solvent has × 100
800 Pv = nRT
= 50 g solute P
denotes the slope of given graph
T
45. A-R, B-S, C-P, D-Q
Check all the option one by one
51. (a)-D, (b) -B, (c)-C, (d)-A
(a)N2 + O2 = no reaction
46. A-R, B-Q, C-S, D-P
alkane + O2 → CO2 (g) + H2O(
)
By the given equation
when H2 will be added the only possible ren is
1 N2 + 3H2 → 2 NH3
Br2 + O → Br2O
2 2 (b)CO2 produced is 2 ml
Br2O + O2 → Br2O3 water absorbes NH3 gas
check of the option by above equation NH3 produced = 8 ml
volume of N2 = 4 ml
47. A-C, B-A, C-B, D-A CxHy + (x + y/4) O2 → xCO2 + y/2 H2O
AgBr formed & get precipitated p ml q ml 2 ml
Resulting solid will have AgBr & AgCl only one gas was present means alkene & O2
react completely
x
AgCl = xg = mole
143.5 p 1
=
AgBr = 6.63 – x g q  y
x + 
6.63 − x  4
mole
188
p 1
= &p+q=6
x 6.63 − x 5.74 2 x
[Ag+] = + =
143.5 188 143.5 for alkane y = 2x + 2
x = 2.87 g ; AgBr = 0.02 mole after solving the equations will get answer
CuBr2 = 0.01 mole = 2.235 g
total Cu ;

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 Page # 6 Solutions Slot – 1 (Chemistry)

EXERCISE – II MULTIPLE CORRECT (OBJECTIVE QUESTIONS)

Sol.1 Molar mass = NA× 3.257 × 10–22 gm Sol.6 C12 Hn Cl 10–m

Sol.2 Volume of virus 35.5(10 − m ) × 100

% by wt.Cl =
= π(75 × 10–10)2(5 × 10–)m3 12 × 12 + 1× m + 35.5(10 − m)
Volume of virus m~4
mass (in gm ) = −6
0.75 × 10
molecular wt. = mass × NA Sol.7 (a) E. F. = CH2
M. wt = 84
E. F. M . = 12 + 2 = 14
160
Sol.3 160 amu ⇒ = 2 molecular → 4N atom 84
80 n= =6
14
490000
490000 g ⇒ M. F . = 6(CH2) C6H12
98
(b) E. F. = CH2O
= 5000 mole → 5000 mole 5 atom
M.wt = 150
32 amu of S ⇒ 1 atom of S
E. F. M. = 12 + 2 + 16 = 30
1
⇒ molecule of Al2(SO4)3 150
3 n= =5
NA molecules = 342 g 30
M. F. = S(CH2O) = C5H10O5
1 342 1
molecules = N × 3 (c) E. F. = HO
3 A M.wt = 34
E. F. M. = 17
Sol.4 C12H4Cl4O2 → molecular wt. = 322 n=2
mole = 8.78 × 10–8 M. F. = 2(HO) = H2O2
weight = 8.78 × 10–8 × 322 (d) E. F. = HgCl
−8 M.wt = 472
8.78 × 10 × 322
%= ×100 E. F. M. = 200.8 + 35.5 = 236
28.3
n=2
= 10–4
M. F. = Hg2Cl2
(e) E. F. = HF
Sol.5 N = 30% P2O5 = 10% K2O = 10%
Total = X gm M.wt = 80
E. F. M. = 1 + 19 = 20
0.3X 0.1X 0.1X n=4
N= mole , P2O5 = , K2 O =
14 142 94 M. F. = H4F4
 0.1X 0.1X 
⇒ O=  ×5 + , Sol.8 CO2 = C
 142 94 
44 gm 12 gm
30 0.9428 gm ?
Hence No. of moles of N =
14
0.9428
× 12 = 0.2586 gm
10 44
No. of moles of P = ×2
31× 2 + 16 × 5
0.2586
% by mas so C = × 100 = 92.32%
10 0.2801
No. of moles of K = ×2
39 × 2 + 16 × 5 H2O = 2H
18 – 2
This comes out to be : 2.143 : 0.141 : 0213 0.1939 – ?
on dividing throught by 0.213.
= 0.0219 gm
% mass of H = 7.68%

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 Solutions Slot – 1 (Chemistry) Page # 7

Sol.11 x + y = w
Element % by wt. Mole S. R.
x y w
C 92.32 12.32/12 = 7.69 1 × 56 + × 40 =
100 84 2
H 7.68 7.68/1 =7.68 1
CaCO3 CaO + CO2
E.F. = CH MgCO3 MgO + CO2

Sol.9 N = 1.4 gm 14 x + 10 y = w
25 21 2
C = 3.6 gm
H = 0.5 gm 588 x + 500 y = 525 w
M. M = 55 –588 + 588 y = – 588 w
__________________________
1. 4 –88y = – 63 w
% by mass of N = × 100 = 25.45%
5. 5
63
y= w x + 0.715 w = w
3. 6 88
% mass of C = × 100 = 65.45%
5. 5 x = w – 0.715 w
x = 0.284 w
0. 5
% mass of H = × 100 = 9.09% y = 0.715 w
5. 5
0.284
% wt of CaCO3 = × 100 28.4 %
Element % by wt. Mole S. R. 100

C 5.45 5.4 3 0.715 w

% wt. of MgCO3 = × 100 = 71.5 %
w
N 25.35 1.8 1

H 9.09 9.09 5 Sol.12 Na2CO3 = xg NaHCO3 = 2 – xg

Na2CO3 shows not heating effect only NaHCO3
E. F. = C3H5N1 will decomposs on heating
55 2NaHCO3(s) →
n= =1 Na2CO3(s) + H2O(g) + CO2(g)
55
wt. in loss is due to H2O & CO2
M. F. = C3H5N1

Sol.10 x + y =1 ........(1) Sol.13 CaCl2 – x gm

Al + 3HCl → AlCl3 + 3/2 H2 NaCl – y gm x + y = 10
x/27 CaCl2 + Na2CO3 → CaCO3 + 2Na
Mg + 2HCl → MgCl2 + H2 CaCO3 CaO + CO2
y/24 let a be wt of CaCO3
Total H2 produced CaO = 1.12
1.12
n= a
22.4 × 56 = 112
100
y/27
a = 2 gm
x
mol H2
18 x
× 100 = 2gm
111
y
mol H2 x = 2.22 gm
24
y = 7.78
x y 1
Total no. of H2 = + = 7.78
18 24 20 ∴ % by wt. of NaCl = × 100
10
y = 0.4 gm
x = 60 % y = 60 % = 77.8 %

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 Page # 8 Solutions Slot – 1 (Chemistry)

Sol.14 (i) Fe2O3 + 2Al → Al2O3 + 2Fe Sol.18 P4S3 + 8 O2 → P4O10 + 3SO2
(ii) Mass of Fe2O3 = 160 gm 1 1
Mass of Al = 54 gm 284 64
160 80 Every mole of P4S3 (220 gm) produces 284
Ratio = = gm P4O10 and 192 gm SO2.
54 27
(iii) 16 kg of Fe2O3 will require 5.4 Kg Al Sol.19 Let no. of moles of CO formed are a moles
Hence, Al is limiting reactant and no. of moles of CO2 formed be b moles.
∴ 54 gm of Al releases energy = 200 unit we will balance moles of C and O separately
to form 2 equations and 2 variable
200 Hence,
2700 gm will release = × 2700
54 a + b = 1 (no. of moles of C = 1 )
4
= 10 units 20
a + 2b = × 2 (no. of atoms)
32
Sol.15 solving we get
a = 75 % , b = 25 %
Limiting Reactant
Now this is the ratio of no. of moles of CO and
Reactant Required Available CO2 formed.
TiO2 240 gm 4.32 gm To find out ratio we will multiply with their
TiO2 48 gm 5.76 gm molecular masses.
TiO2 426 gm 6.82 gm So,

On comparing we clearly found out that Cl2 is 75 × 28 21

Ratio of mass of CO : CO2 = =
the limiting reagent. 25 × 44 11
So, 426 gm of Cl2 gives 570 gm of TiCl4 Sol.20 2ZnS + 3O2  75%
→ 2ZnO + 2SO2
∴ 6.82 gm of Cl2 will give
ZnO + H2SO4  100%
→ ZnSO4 + H2O
6.82
⇒ × 570 = 9.12 gm of TiCl4 2ZnSO4 + 2H2O  80%
436 → 2Zn + 2H2SO4 + O2

291 × 103
Mole of ZnS = = 2987.7 mole
Sol.16 Clearly the limiting rectant is BF3 97.4

2 1 75 80
for LiH = = Mole of Zn produced = 2987.7 × ×
6 3 100 100
mass of Zn produced = 1792.62 × 65.4 g
2 1
For BF3 = = 1792.62
8 4 O2 produce = mole
2
Now, 8 moles of BF3 gives B2H6 = 1 moles
So, 2 moles of BF3 will give B2H6 Sol.21 2[NaH2PO4 + NH4+ Mg2+ + 6H2O
→ 2Mg(NH4)PO4. 6H2O + 2H+ + Na+]
1 120.5 = M
⇒ × 2 = 0.25 moles of B2H6
8
2Mg(NH4)PO4.6H2O →∆ Mg2P2O7 + .......
w = 1.054 gm
Sol.17 C + 2Cl2 → CCl4
n = 222
Req. wt. 12 142 154 (120.5 × 2)241 gm of NaH2PO4 gives Mg2P2O7
Given wt 36 142 154 (calculated) = 222 gm
Left 24 0 – So, NaH2PO4 required to get Mg2P2O7 is
Thus wt. left of C is 24 gm and CCl4 prodced is 241
154 gm. = × 1.054 = 1.14 gm
222

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 Solutions Slot – 1 (Chemistry) Page # 9

Sol.22 N2 + 3H2 → 2NH3 Sol.24 M(CH3)2SiCl2 = 129 gm

M = 28 M = 2 M = 17 M(CH3)2SiO = 74 gm
Let, the mass of gas be wg and molecular Volume of layer req.
mass Mg. = 100 × 300 ×(10–10 × 6) × 102
dRT mass req. = V × 1gm/cm3 (given d = 1gm /
So, P = cm3)
Mg
Mass req. = 5.4 × 10–1 gm
Mg = 0.497 × 0.0821 × 298
Mg = 12.16 gm/mol So,
Now, 0.54
No. of moles of (CH3)2SiO = × 129
wg 74
PV = RT
Mg = 0.9413 gm

wg
1 × 22.4 = × 0.821 × 273 4 / 40
12.16 Sol.25 (a) M = × 1000 = 0.5 M
290
wg = 12.15 gm
5.3 / 106
Sol.23 2KClO3 → 2KCl + 3O2 ↑ ............(1) (b) M = × 1000 = 0.5 M
100
245 gm 149 gm 96 gm
4KClO3 → 3KClO4 + 1KCl ............(2) 0.365 / 36.5
415.5 gm 74.5 gm (c) M = × 1000 = 0.2 M
50
112 ml
O2 evolved = = 0.005 mole
22400 Sol.26 d = 1.09 gm/ml
= 0.16 gm 13% by mass H2SO4
96 gm O2 is evolved when KClO3 reacted
= 245 gm NH2SO 4
M= × 1000
0.16 gm O2 is evolved when –––––––––––– V (ml)

246 13 / 98
= × 16 = × 1000
96 100 / 1.09
= 0.400 gm = 1.446 M
Hence in reaction (1) 0.408 gm of KClO3 is
reacted, so, in reaction (2) KClO3 reacted =
= 1 – 0.408 gm 40 / 36.5
Sol.27 M = × 1000 = 13.15 M
= 0.592 gm 100 / 1.20
Residue consist of KCl and KClO4 only KCl
246 Sol.28 Mass of 100 ml solution
formed in reaction (1) = × 0.408 = 0.284
245 = 100 × 0.9 = 90 gm
gm Mass of solvent = 90 – 15 = 75 gm
KCl formed in reaction (2)
15
% by mass CH3OH = × 100 = 16.67 %
74.5 90
= × 0592 = 0.090 gm
490
Sol.29 1.9 gm of Li+ ions is present in 106 gm
415.5
KClO4 formed = × 0.592 = 0.502 gm water.
490
Hence wt % of KClO4 is redidue. 1.9 103
Molality (m) = ×
0.502 106 7
= × 100 = 59.76 %
0.502 + 0.248 + 0.090 = 2.7 × 10–4

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 Page # 10 Solutions Slot – 1 (Chemistry)

Sol.34 Ca2+ = 2M
Mass of solution
Sol.30 d = NO3– = 4 M
Volume of solution
1 L of solution contains KOH = 386.4 gm 1000 × 2
m= =2
1328 − 2 × 164
1000 gm solution contains KOH = 300 gm
Mass of solvent = 1000–300 = 700 gm m × mol. wt. solvent
when 300 gm of solute is present Xsolute = 1000 + m × mol. wt. solvent
solvent = 700 gm
So 386.4 gm of solute is present in
1000 × 2
386.4 × 700 Sol.35 m =
= = 910.6 3107 − 53.5 × 2
300
2000 2
Mass of solute + mass of salvent m= =
d= 3000 3
valume of solution
2
mCl =
386.4 + 901.6 3
d= = 1.288 gm/ml
1000
2
NH4+ = m
3
100
Sol.31 Let 100 g solution = ml
1.6 Sol.36 M1V1 + M2V2 = M3(V1 + V2) ( in ideal case)
wt. of solute = 67 g 2 × 500 + 2 × 200 = M3 (500 + 200)
Lets add xg or x ml H2O in 100 g solution M3 = 2
100 + x Volume of solution = 700 ml
1.2 = 100 + x
1.6 Sol.37 66.67 %
⇒ x = 125 ml or 125 g
Sol.38 35 %

Sol.32 No. of moles of H2SO4 in 12.5 L of 2.5 M Sol.39 CH3Cl

H2SO4 solution
⇒ 12.5 × 2.5 = 31.25 moles
1 mole or 98 gm H2SO4 is resent in solution = 1.466
CO2 ×1
44
100 gm
0.4283
H2O ×2
18
1000 Sol.40 O. C.
100 gm solution = = 55.56 ml AgNO3 1.6872
1. 8 170
 PV 0.6872 
For 31.25 mole solution required = 55.56 × N2 2 × 
 RT 0.3178 
1.25
= 1.7362
= 0.0047
Sol.33 100 ml of solution contains HNO3 = 19 gm 0.033
C= =7
69.8 0.0047
wt. of HNO3 in 50 ml solution = gm
2 0.047
Total volume of solution to be 19% w/v H= = 10
0.0047
containing
0.004
69.8 Cl = =1
⇒ gm HClO3 0.0047
2
0.0047
69.8 N= =1
⇒ × 100 = 183.68 ml 0.0047
2

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 Solutions Slot – 1 (Chemistry) Page # 11

Sol.41 Msalt = 595.42 gm/mol. Volume contraction = volume consumed – vol-

ume product
Msalt = 2MB + MH2PtCl6
6.5 = (x + x/2) + (y + 2y) – (x + y)
595.42 = 2 MB + 410 6.5 = x/2 + 2y
MB = 92.7 gm/mol. 13 = x + 4y .................(2)
Also volume contraction after passing through
Sol.42 (RCOO)2Ba salt with KOH will be due to CO2
molecular wt. of salt = 2x + 137 ∴ x+y=7 ...............(3)
x → for RCOO– graph solving we get
(RCOO)2Ba. 2H2O + H2SO4 x = 5 ml y = 2ml z = 3 ml
→ 2RCOOH + BaSO4

 2.562  Sol.47 2O3 → ∆ 3O2

(RCOO)2Ba. 2H2O =  137 + 2x + 36  mole
  20 ml 30 ml
Let volume of O2 present be x and O3 be y ml
 30 
H2SO4 =  1000 × 0.2  mole Turpentine absorb O3
 
⇒ Volume of O3 present = 20 ml
30 2.562 volume of O2 present = 80 ml
× 0.2 = ⇒ x = 127 20 ml of O3 produces O2 = 30 ml
1000 173 + 2x
Molecular wt. of acid (RCOOH) = x + 1 volume increase = valume formed – volume
= 128 consend
= 30 – 20 = 10 ml
Sol.43 (a) 100 g sample + 9g H2O
Sol.48 N2O + H2 → N2 + H2o
⇒ 109 g H2SO4
x x x x
(b)109 g H2SO4 + 9 g water
NO + H2 → 1/2N2 + H2O
(c)109 g H2SO4 + 111 g water
y y y/2 x
x + y = 60
44.8 x + y/2 = 38
Sol.44 M = =4
11.2 solving we get
x = 16 ml , y = 44 ml
1000 × 4
m=
1136 − 4 × 34
Sol.49 X O2 → 2Ox
4000 ax 2a
= =4
1000 Volume concentration = 4
x xa – 2a .............(1)
m = (1 − x ) × 18 × 1000 Turpentine absorbs Ox
2a = 8 ..............(2)
a=4
72 Putting in (1) we get
X=
1072 x = 3 Hence Ox = O3

Sol.45 (i) 20 gm H2SO4, (ii) 35.4 gm H2SO4, Sol.50 Nx Hy → x/2 N2 + y/2 H2

(iii) H2SO4 = 35.4 gm, H2O = 34.6 gm 10 ml 5x ml 5y ml
Given after Ist step final volume = 20 ml
1
Sol.46 CO + O → CO2 5x + 5y = 20
2 2 x + y = 4 ............(1)
x x/2 x Also Given V. D. = 8.5
CH4 + 2O2 → CO2 + 2H2O (
) Molecular wt. = 8.5 × 2 = 17
y 2y y x 14 x + y = 17 .......(2)
N2 → N2 Solving we get
z z x = 1,y = 3 Hence formal is NH3
x + y + z = 10 .................(1)

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 Page # 12 Solutions Slot – 1 (Chemistry)

EXERCISE – III SUBJECTIVE QUESTIONS

Sol.1 From reaction (1) & (2) 5 × 10.4
= V mole AgNO3
A2B4 + 1/2 A2 → A3B4 ....(3) 170
solve question by reaction (1) and (3) = 0.305 V mole AgNO3
for precipitation
Sol.2 Al 2(SO4 )3 + 3Ca(NO3 )2 → 2Al(NO3)3 + Mole of AgNO3 = Mole of Cl– ion

136 x
x g NaCl → mole Cl–
3CaSO 4 58.5

213 ×2 = 426 /136×3 =408 y

y g KCl → mole Cl–
Here limiting product is CaSO4. 74.5
1 mole Al2(SO4)3 produces CaSO4 = 408 z
For 1 gm CaSO4 will need. Al2(SO4)3 moles z g NH4Cl → mole Cl–
53.5
1 ⇒ fir max. mole of Cl– → less mol. wt. of
=
408 species
⇒ pure NH4Cl ⇒ z = 0.3
1
∴ M1V1 = ⇒ 0.305 V = 03./53.5 ⇒ V = 0.01838 L
408
= 18.38 ml.
1
0.1 × V1 = Sol.5 1000 ml of Solution weights = 1035 gm
408
V1 ⇒ 0.02451 L = 24.5 ml 100 ml is fat in this solution which weights
= 0.875 × 100 = 87.5 gm
Sol.3 H2SO4 + 2NaOH → Na2SO4 + 2H2O Density of fat free skimed milk
x/98 1035 − 87.5
SO3 + 2NaOH → Na2SO4 + H2O = = 1.0527 gm/ml
900
1/86
SO2 + 2NaOH → Na2SO3 + H2O
According to problem  y z y
Sol.6 CxHyOz +  x + 4 − 2  O2 → xCO2+ H2O
Total mass balance x + y + 2 = 1   2

23.47  x y 2  10 ml 100 ml
Balancing NaOH × 1 = 2 × ×  0 (100 – k) ml 20 ml
1000  98 80 64 
KOH absorb CO2 ⇒ volume of CO2 = 20 ml
Given z = 0.015 volume left after cooling = 90 ml
solving we get
⇒ 100 – k + 20 = 90 ⇒ k = 30
x = 35.36%y = 63.13 %
z = 1.5 % 10 1
⇒ = ⇒ x=2
Free SO3 = 63.13 % 20 x
Combined SO3 is SO3 present in H2SO4 volume of O2 used = k = 30 ml

  0.3536   x + y / 4 − z / 2 30
= ⇒ y – 2z = 4 ..(1)
⇒   98 × 80  ÷ 1 × 100 = 28.89 % x 20
  
mol. of = 2 × V.D.
= 23 × 2 = 46
Sol.4 Let V
volume of AgNO3 solution added Mol. wt. of compound = 12x + y+16 z
100 gm solution has 5 g AgNO3 ⇒ 12x + y + 16 x = 46
100 ⇒ y = 16 z = 22 ....(2)
ml solution has 5 g AgNO3
1.04 from eq. (1) & (2)
V × 1000 ml solution will be having z=1 , y=6
5
⇒ compound will be = C2H6O
× 1.04 × V × 1000 g AgNO3
100

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 Solutions Slot – 1 (Chemistry) Page # 13

Sol.7 3A (g) → C(g) + D (g) Now, a + b + c = 100 ..............(1)

t=0 1 H 2 + O2 → H 2 O2
t = 30 1 – 3x x x x x
mol. wt. of A =2 × V.D = 2 × 60 = 120 N2 + H2 → N2H2
Total mole of mixture y y y
= 1 – 3x + x + x =1 - x Since O2 was lata absorbed by pyragallal this
V.D.mix. = 75 & M.w. of C = 200 means O2 was n excess hence H2 was LR.
⇒ M.ul. 75 × 2 = 150
⇒ 150 Also, in second reaction more H2 was added
to cary forward reaction this means, N2 was
(1 − 3x) × 120 + x × 200 + x × M.w.D in excess and H2 is LR.
=
1−x From both reactions
⇒ 150 (1 – x) = 120 – 360 x Hydrogen balance x + y = a ................(2)
+ 200 x + M.w.D x Also, given in Ist step volume contraction is
⇒ 30 = –10x + M.w.Dx=x(M.w.D – 10)...(1) 60.
Mass conservation (2x + 2y) – (y) = 60
Initially 1 mole A = 120 g 2x + y = 60 ...........(3)
120 = (1 – 3x) 120 + 200 x + M.w.D x Residual oxygen was absorbed by 10 ml
120 = 120 – 360 x + 200 x + M.w.D x pyragallal
⇒ x(–360 + 200 + M.w.D) = 0 C – x = 10 ............(4)
Since all the O2 is observed by pyragallal later
⇒ M.wD = 160
no. more H2O2 will be formed when more H2 is
⇒ fro eq. (1)
added. So only 2nd reaction. will take place
30 = x(160 – 10) ⇒ x = 1/5 now,
⇒ At 30 minutes Remaining volume of N2 = b – y
nA = 1 – 3x = 2/5, nC = 1/5 & nD = 1/5 H2 + N2 → N2H2
b–y b–y b–y
mass (PCl5 ) 417
Sol.8 Now volume contraction = 10 ml
mass (H3PD3 ) = 246
⇒ 2(b – y) – (b – y) = 10
⇒ b – y = 10 ................(5)
mole (PCl5 ) (417 / 208.5) 2
⇒ mole (H PO ) = (246 / 82) = 3 Substituting values of a, b, c will get
3 3 x + y = 40
from reaction Also, from eq. (iii) 2x + y = 60
If PCl5 mole = 2 ⇒ mole of Cl2 = 2 Solving both and putting back values we get
H3PO2 mole = 3 ⇒ H2O mole = 3 × 3 = 9 H2 = a = 40 ml
N2 = b = 30 ml
mole (Cl2 ) 2 O2 = c = 30 ml
ratio of mole (H O) =
2 9
Suppose water is 1000 gm Sol.10 White resisdue is Ag
for the reaction n mole white residue will be
1000 formed
⇒ mole of water
18 0.1 mole of salt form 54 g of residue
2 1000 ⇒ 1 mole of salt will from 540 g of reisdue
In 1000 gm water, mole of Cl2 = ×
9 18 540
⇒ = 5 mole of residue
2 1000 108
⇒ MCl = × mole/kg
2 9 18 ⇒ 5 mole ⇒ n=5
Mol. mass of compound
Sol.9 Let initial composition of = (15 × 2) + (13 × 5) + (80 × 5) = 495
H2 = a ml
N2 = b ml Sol.11 AlCl3 = 33.3 %, NaHCO3 = 50 %,
O2 = c ml KNO3 = 16.67 %
initial composition

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 Page # 14 Solutions Slot – 1 (Chemistry)

Sol.12
50
(b) 2 moles of KMnO4 yield O2 = × 3 × 22.4
 3n + 1  100
CnH2n+2 +   O → nCO2 + (n + 1) H2O (g)
 2  2 = 33.6 ml

 3n + 1  6.74
 a 6.74 L of O2 is yielded with KMnO4 = ×2
a an a(n + 1) 33.6
 2 
= 0.401
 3x 
CxH2x +   O → xCO + x H O (g)
(c) 1 mole H2O2yields KOH =
40
× 2 = 0.8
 2  2 2 2
100
moles
 3x 
b  b bx bx
 2  1
So, 0.2 moles is yielded by H2O2 = × 0.2 =
In this question temp. is given as 127ºC So, 0. 8
H2O will be considered as gas. Let initially moles 0.25
of In second part
CnH2n+2 = a 1 mole H2O2 needs KMnO4 = 2 moles
CxH2x = b So, 0.401 moles KMnO4 is used by H2O2 =
and O2 = C 1
Given that H. C. react complety to form CO2 × 0.401
2
&
= 0.2 molar
H2O So, O2 is increases.
Total no. of H2O2 moles = 0.25 + 0.2 = 0.45
KOH absorbs CO2 : Moles of CO2absorbed
(d) Volume strength of H2O2
132 1 mole H2O2 gives O2 = 0.5 mole
= =3
44 0.5
an + bx = 3 ...(1) 0.45 moles ________ = × 0.45 = 0.225
1
Anhydrous CuSO4 absorbes H2O vapour, so
Volume of O2 = 0.225 × 22.4 = 5.04 L
balancing moles of water.
a(n+1) + bx = 4 .............(2) 5.04
Volume strength of H2O2 = × 1000 = 50.4
Also, given initially total no. of moles are 10 100
so,a + b + c = 10 ...(3) V
Also given initially moles of both H. C. are equal
so y
Sol.14 CxHyO8 + O2 → xCO2 + H2O
a = b .................(4) 2
Also given molecular mass data Since equal volumes of CO2 & H2O were formed.
(12x + 2x) – (12n + 2n + 2) = 12 x = y/2 = n
x – n = 1 .................(5) Again writing eq.
5 eq. with 5 variables
 3n 3 
after solving above equations CnH2nO8 +  −  O → nCO + nH O
a = 1, x = 2  2 2 2 2 2

b =1, c = 8 & n = 1 100 100 n100 n100

(a) CO2, H2O & O2 Given volume of system is not change, as-
(b) CO2 = an + bx = 1 + 2 = 3 moles sume initial volume of CnH2nOz & O2 be: 100
H2O = 1(n + 1) + bx = 2 + 2 = 4 moles ml
(c) Molecular formula are CH4& C2H4 Since initial values
(d) NCH4 = 1 mol NC2H4 = 1 mol 3n 2
⇒ – = 1 .............(1)
2 2
NO2 = 8 moles
Also volume contraction = 0
200 = 200 n = 0
Sol.13 Let x ml be first part and y ml be second ⇒n=1
part from (i) z = 1
1 200 Hence formula of compound = CH2O
(a) Moles of KOH = × 2× = 0.2 moles molecular wt. = 30 gm/mol
2 1000

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 Solutions Slot – 1 (Chemistry) Page # 15

EXERCISE – IV ADVANCED SUBJECTIVE QUESTIONS

Sol.1 148 – 50 = 98 gm of liquid
Sol.6 6 CaO + P4O10 → 2Ca3 (PO4)3
d = 0.98 gm/ml
56 284
98 284 gm P4O10 requires CaO = 336 gm
Volume of glass = = 100 ml 852 gm P4O10 will require
0.98
PV = nRT 336
= × 852
284
760 0.5
⇒ ×1 = × 0.0821 × 300 = 1008 gms
160 M
M = 123 g/mol
Sol.7 No. of moles of N2

Sol.2 Volume occupied by steam = 1000 ml 2.46

⇒ 0.001 × = n × 0.821 × 298
Mass of water molecules in steam = 1000 × 1000
0.006 ⇒ nN2 = 10–7 moles
= 0.6 gm Total no. of sites occusied by N2 molecules

0. 6 20
Volume occupied by water molecules = = 6.023 × 1014 × 1000 ×
1 100
= 0.6 cm3 No. of sites /molecules of N2

 10 −7 × NA 
Sol.3 D  
= Total No. of sites occpied by N molecule 
wt. of 1 e– = 9.108 × 10–31 kg  2 

1 =2
1 kg will contain e–s =
9.108 × 10 −31
No. of moles of e– s = 120
8. Mole of urea = =2
60
1 total mass of solution = 1000 + 120
−31 23
9.108 × 10 × 6.023 × 10 = 1120 g
1120
1 Volume = ml = 973.9 ml
= × 108 1.15
9.108 × 6.023
2
Molarity = × 1000
973.9
1000 = 2.05 M
Sol.4 M = 18 × 1000 = 55.56 M
1000 9. 3Br2 + 3 Na2CO3 →
5NaBr + NaBrO3 + 3CO2
Sol.5 Moles of CH3COOH absorbed = (0.5 – 0.49)
× 0.1
= 0.001 moles
Surface area of 1 gm charcoal = 3.10 × 102
gm
Surface area absorbed by each molecule

3.01× 10 2
=
0.001× 6.023 × 10 23

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