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Olympiad Chemistry

(1) Hydrogen fluoride (HF) has a higher boiling point than other hydrogen halides due to the strong bonding between hydrogen and fluorine atoms. Fluorine is much more electronegative than other halogen elements, polarizing and strengthening the HF bond. (2) The H-F bond is polar, with the hydrogen partially positive and fluorine partially negative. This leads to strong electrostatic attractions between HF molecules. (3) In contrast, hydrogen chloride and other hydrogen halides have weaker, less polar bonds between hydrogen and the other halogen elements.

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98 views1 page

Olympiad Chemistry

(1) Hydrogen fluoride (HF) has a higher boiling point than other hydrogen halides due to the strong bonding between hydrogen and fluorine atoms. Fluorine is much more electronegative than other halogen elements, polarizing and strengthening the HF bond. (2) The H-F bond is polar, with the hydrogen partially positive and fluorine partially negative. This leads to strong electrostatic attractions between HF molecules. (3) In contrast, hydrogen chloride and other hydrogen halides have weaker, less polar bonds between hydrogen and the other halogen elements.

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JUBI
Copyright
© © All Rights Reserved
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Pre-Medical reduced

nuclear shieldingismuch
(2) The effect of molecule
the HF
polarises
fluorine which is much
higher
in eectronegativity
of fluorine

52. The correct bonl order in the folkwing specdesis (3)The in the group.
elements
than for other b e t w e e n HF
bonding
(1) o 0, 0 (2) O <O, <0} (4) There is strong
hydrogen

(3) 0,0 0 (4) o <0; <0, molecules

53. Which of the folkwirng pairs of ons are isoelectronic respectively are

61 SF, XeF, shape


&
and isostructural distorted
tetrahedral
(1) Linear and
(1) CIO,.co (2) SO.NO, 2 1 See-saw and linear
trigonal bipyramidal
(3) CIO,SO (4) Co .Sof (3) T-shape and
Tetrahedral and
linear
the (4)
54. Which of the following options represents
correct bond order In ClIF, lone pair are present at approx
62. (4) 60°
(1) 180° (2) 120 3)90°
O 0, 0; (2) O, >O, <0;
it consists of
(4) O, >0, >0; 63 In solid phase of XeFs,
(3) O, <0, >0; (1)XeF +F (2) XeF, +F2
in (4) XeF2 + 2F,
55. Solubility of the alkaline earth's metal sulphates (3) XeF + XeF2
water decreases in the sequence
> Ba
Correct order of bond length
(1) Ca > Sr > Ba > Mg (2) Sr > Ca Mg
>
64
Ca (4) Mg> Ca > Sr > Ba
(3)Ba> Mg > Sr >
(1) CO O >CO,
at nitrogen is present in
56. Maximum bond angle >CO
which of the following:
(2) co co
(1) NO, (2) NO (3) CO<cO, < COg
(4) NO (4) CO <CO, <CO
(3) NO
Correct order of bond energy
GREAPE2015 65 (2) Br F > F-F
57. On heating which of the following releases CO% (1)HCl< (4) F-F < CHCI
(3) Br - F <I- I
most easily
(1) MgCOP, (2) CaCOa
(3) KCO 4Na,CO 66. Consider the molecules CH4. NHg and HO. Which
and
58. Decreasing order of stability of O2, O, O of the given statements is false ?
O2is (1) The H-CH bond angle in CH4, the H-N-H

(1)O2> O2 > 0g > O bond angle in NH3. and the H-O-H bond angle

(2) O>0 > 0> O, in HO are all greater than 90°

(3) O > O2> O» Oz (2) The H-0-H bond angle in H2O is larger than
the H-C-H bond
(4)O> O> O,> O;
angle in
CH4
(3) The H-0-H bond angle in H2O is smaller than
59. In which of the following pairs, both the species
are not isostructural
the H-N-H bond angle in NH3
(1) NH3, PH3 (4) The H-C-H bond angle in CH4 is larger than
(2) XeF. XeQ the H-N-H bond angle in NH3
3) SiCl. PCI 67. Which one of the following orders is correct for
(4) Diamond, silicon carbide
60. The variation of the boiling points of the hydrogen
the bond dissociation enthalpy of halogen
molecules?
halides is in the order HF > HIl> HBr > HCI
What explains the higher boiling point of hydrogen (1) l>Br2> Cl2> F2
fluoride?
(1) The bond energy of HF molecules is greater than
(2) Clh>Bra> Fz>2
(3) Br2> l2 > F2> Ce
in other hydrogen halides
4> Ch > Brz > l2
60 E

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