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Quiz 02

This document contains an inorganic chemistry quiz with multiple choice and numeric questions testing understanding of concepts like molecular geometry, bond angles, hybridization, and relative bond lengths. It includes 4 sections with a total of 25 questions related to properties of compounds containing main group elements and their ions.

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533 views4 pages

Quiz 02

This document contains an inorganic chemistry quiz with multiple choice and numeric questions testing understanding of concepts like molecular geometry, bond angles, hybridization, and relative bond lengths. It includes 4 sections with a total of 25 questions related to properties of compounds containing main group elements and their ions.

Uploaded by

honey1002
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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TM

Path to success KOTA (RAJASTHAN)

INORGANIC CHEMISTRY QUIZ # 02


SECTION–I (i) : (Maximum Marks : 26)
 This section contains 13 questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option(s) is correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 Marking scheme :
+3 If only the bubble(s) corresponding to all the correct option(s) is (are) darkened
0 If none of the bubbles is darkened
–1 In all other cases
1. Consider the following information (X = F or Cl)
Molecule P–X(axial) bond length P–X(equatorial) bond length
PF5 a b
PF4CH3 c d
PF3(CH3)2 e f
PCl5 g h
According to given information choose the incorrect order of bond length
(A) g > a > d > b (B) g > e > f > b (C) f > d > a > b (D) c > f > d > b
2. Select the correct order of H – M – H bond angle
(A) PH3 > PH4+ (B) P2H4 > PH4+ (C) PH3 > NH4+ (D) PH4+ > NH3
3. Compare bond angle x and y in following molecules –

F F
O F
: Cl x : S y
F F
F F

(A) x > y (B) y > x (C) x = y (D) None of these


4. In BClBr I molecule the maximum % s-character provided from the central atom is in bond :
(A) B – I (B) B – Cl (C) B – Br (D) Can not predict
5. What is the percentage of s- character in the orbital occupied by lone pair of NH3
It is given that : cos 107° = –0.292
(A) 22.6% (B) 32.2% (C) 25% (D) None of these
6. Choose the CORRECT statement from following options -
(A) All dC–O in H2CO3 are identical (B) All dSb–Cl in SbCl5 are identical


(C) HCH  (in F CO)
(in H2CO) < FCF (D) All above statements are incorrect
2

INORGANIC CHEM. / QUIZ # 02 E-1 / 4


TM

Path to success KOTA (RAJASTHAN )

7. The maximum number of atoms may lie in one plane of P(CH3)3(CF3)2 is "________" .
(A) 4 (B) 5 (C) 6 (D) 7
8. The maximum % of S-character in N–H bond is observed in
(A) NH3 (B) NH4+ (C) N2H4 (D) N2H2
9. Consider the following statements and select the correct set of codes using T(True) and F(False) in the
given sequence
(i) PI5(s) does not exist due to steric crowding
(ii) All possible angle in BF2Cl are 120º
(iii) In N(SiH3)3 lone pair of N is present in sp3 hybrid oribital.
(iv) 'd' orbital used in hybridization of 'P' in PBr5(s) is d z2
(A) T F T T (B) F T T T (C) F F F F (D) T F T F
10. Maximum seven atoms are present in a plane , Except in-
(A) H2CSF4 (B) P(CF3)2 (CH3)3 (C) N(SiH3)3 (D) B(CH3)3
11. Order of number of planes present in molecule which contain maximum number of atoms of corresponding
molecule.
(A) IF7 > SF6 > CH4 (B) CH4 > SF6 > IF7 (C) SF6 > IF7 > CH4 (D) CH4 > IF7 > SF6
12. In which of the following case C—C bond length will be highest ?
(A) CF3 – CF3 (B) F2CH – CHF2 (C) FCH2 – CH2F (D) CH3–CF3
13. The number of planes in which  4 atoms are present in IF7, is
(A) 6 (B) 5 (C) 4 (D) 7
(ii) : (Maximum Marks : 12)
 This section contains 3 questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is (are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is (are) darkened
0 In all other cases
14. Select molecule(s) in which all P–Cl lengths are identical :
(A) PCl3F2 (B) PCl3 (C) PCl2F3 (D) none of these
15. Which of the set is INCORRECT for the following compound and their bond length ?
(A) dC–Cl:– CH3Cl < CF3Cl (B) dN–N:– N2H4 > N2F4
(C) dO–O:– O2F2 > H2O2 (D) dC–C:– C2F6 < C2H6
16. Select the correct statement -
(A) A molecule which have T.B.P. geometry axial bond length always greater than that of equatorial
bond length
(B) In PCl3F2 molecule equatorial bond length is greater than that of axial bond length.
(C) A molecule which have P.B.P. geometry , axial orbital length of central atom is greater than that
of equatorial orbital length.
(D) A molecule which have P.B.P. geometry, equatorial orbital bond length of central atom is greater
than that of axial orbital length

Inorganic / Quiz # 02 E-2/4


TM

Path to success KOTA (RAJASTHAN )

SECTION–I(iii) : (Maximum Marks : 12)


 This section contains 2 paragraphs.
 Based on each paragraph, there will be 2 questions
 Each question has FOUR options (A), (B), (C) and (D) ONLY ONE of these four option(s) is correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 Marking scheme :
+3 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 In all other cases
Paragraph for Q.17 & Q.18
Follow the structure of two compounds

F F
F F
F F
Se I F
F F F
F F F
(I) (II)
17. Find the ratio of 90º angles in (I) & (II)
(A) 6 : 5 (B) 5 : 2 (C) 8 : 10 (D) 4 : 5
18. Choose the correct statement from the following options-
(A) The number of identical bonds in (I) is equal to that in (II)
(B) The number of identical bonds in (I) is equal to that in S2O72–
(C) All bond length in (II) are identical
(D) Smallest bond angle value is available in (I) among these two structure.
Paragraph for Q.19 & Q.20
According to bent's rule more EN surrounding atom prefer to attach with that hybrid orbital which has
less electronegativity.
19. Select the correct statement for following molecules :
(I) PF2(CH3)3 ; (II) PF2(CF3)3
(A) Both have trigonal bipyramidal structure with respect to P.
(B) P-F bond length is longer in PF2(CH3)3 than in PF2(CF3)3
(C) F-atoms occupy axial position in both
(D) All of these
20. Which one correct for bond angle -
(A) PF3 < PCl3 (B) PF3 < PH3 (C) BF3 < BCl3 (D) All of these

Inorganic / Quiz # 02 E-3/4


TM

Path to success KOTA (RAJASTHAN )

SECTION–IV : (Maximum Marks : 25)


 This section contains 5 questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is (are) darkened
0 If none of the bubbles is darkened
–1 In all other cases

1. In the compound PClk F5–k, possible values of k are 0 to 5 then sum of all possible value of k for the
compounds having zero dipole moment, is :

2. Number of molecules in which all the equitorial M – X at bonds are smaller as compared to axial
M – X bonds (M = Central atom, X = halogen bonded with central atom)

PCl3F2, PCl2F3, PCl5, SeF6, IF7, SOF4 , ClF3

3. Find number of shorter bond(s) in IF7

4. Maximum number of atom(s) in I2Cl6 which is/are in the same plane.

5. Find the number of 90º angles in XeF5 molecules

Inorganic / Quiz # 02 E-4/4

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