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CBSE, Imp Questions Unit Amines and Diazonium Salts
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CBSE, Imp Questions Unit Amines and Diazonium Salts
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CBSE ASSignmene (h solved) amines & ON ae —— ey Amines & DIE a: 5 Teast fy whet aun the paoduele Exhaushve. ammonclyss of ateye Aanae ee deg mite of Fert Secndang . deiong quaternary amine Sal. noe cat Oa chy, (cose 200) he 2,N- Dimethylprepaarl eating = #8) Give Supac name of, OCHA GES Y i nav’) kya Direfgtbutaaemide,, i? N-Pheny lethanami de ) Git Supa mane fv a i (4, NEM, ccaszel?) ye 4st gu Sloomobergenatine i NEL mY Letina ce aot ye Steele of Compoundt A gec in the ing weachion (BEE a) @ CHC tOAKEH ©) oo 9% 1) Gn cook nis]a 58 Br, | OM ee ) Gage nel Be + @ ascooy® iV i wae fen) Nucor, (Case 2016) % iy det @ cxconm © Marr (87 smambromerite 2D 6 aes OC | rans O61 'h meighicoeyenide COCH: » ® Giisre @ gus © GNI ed Nile bogene Aniline ne Prenglemanam” . 99) Give besser. = «) acetijlatin ef aniline Reduces yx achveten 6 ) cace a, Gi) grt, is Ma" Goste tne hens i) although Moe elm itpalicn givessipnifiant anibiant mn Wif Aline i ile, ain hi rN Arad) Upon acelylatenAriline Cnvab ints -phenglerhanen ide, mo oer elections on ilgea oe snvelvect in Pesgmance with aepl garep, So 87 © aetivasGd gs Ompared fe anilige + Bye emeoe a at one Ene Dnteraneette aoe of eleclione on Niliager on miter o di) Due te cr of me roup, Pere eae a ee oe winich Lone podrop elec lens ane eosit 4 involved eee eee CHA it ish
Ci NitgoH” = cH, Nig + On Feclg + 30H —? Fecon, + 3C1 Prt of Fesnic WU pronide [eet22 58) decreas Ee Wiaage tn Oroler 4 Ph, Value wilh 708 4) fine, Pewibvariine 4. pe toluialines 3} case 2014) BC HsNM ,CGHSIAH, CGHSDQN (in gaseous I ne na ° fro-8)a) pk Value ~ dae siengst® o e < a < & He Eveclimatonating oer" Electron "aitnctrasicg basic si tn Gh No. dee 4) Gren < LGHsynn & room, [ep rata taststengn _ eras Bae step, a ae oe Fy Value in vensea teu HT efpech 5 clecneases, 2 Boric Biss Grhecers phy value incheasch ae oy : cy We Wengen? 2 i Gg ley yoor 20 AY, caflomplete the foumong = CS ~prraine ; a ge 4) Give a somple bt & olrshrguish berseen Aniline 4 Ni tiylan wile Acackone wnvolved un the follavi ; / / on Hehoann byomamide aepocaics w ‘Masohisatan Ci )Gabwe! | phtnaLion ce. xn NHeOCH; Aad i iy) Bb Pay 3) GD + crgcoon cid Chet egy a Erbe ones wphenplettanemds 4) Banaene upon 2 yw nine rebengene-Cutpho [4 Pract Chleride Non Dimetigt Sed OD y+ eyeto rm tres Seuzene 2 Foce os © Azoaye tati- Aniline upon theatinent wits ice Cooled Wallon f Qoctiom nite. kdb He! (Nano, taut HeI)er 272 278K, follaved by Theatinen with Cold Obkaline telation of Amepirel Bich Orange e ther —> “Hon$ # Nat Shing t Hemet ME 9) ane Aniline on Beugene oiatonium Chlrvide Cnienel + CY nenOe A Gres, Prnephthe! orange oye Mile nN Dinetay Cariline clo net pve Phi Teale 22 Hog mann bromaumide AencTon I palit or ahemeliz 227d hn trend ent (eit quenes or eMhanalicLddation of Pieasiam Fadrrite € beomine. gives Fomine Gnpainirg 1 on leas thas the amide cigconm. + Br, cor cate) > CN + ky Cos + 2k br + Bo Ethanamide Famine (® Diasorsaton- Grvesion 4 Tatometze amine #2 Haronium sare by Diaror sate dpeatmente with 3te Covled Sulton 4 Sodium nitwile NAL Nano, + Hel —> H. GC + HoNwot+ Hes 223-298 Aniline din Cabriet phrrchimide Aeathen Beuzene dtadonium Chleride. Phthatimide Upon Treatment with etranolic KM Tvee Prpessium pttalimide which up year ment with CUart halite fotleared byhyelro lysis pres“Veliphale, amine ° . 7 ; nu u Meow + Ko, SCN. 4k ° ne? Hay) Croat is a MoyHt 3 x “KE NG HS > Gren, imide. Porasssioy Phthalemicle : Famine } w-ehnglphitalimicle Eranamine 4 be) Give Bane * CMC, WH ie ene base Ahaus (CMAN Im agent Sor) > LOM Gi) Aromatic HMaroniun (alG are mne stab! 2 a © than abiphalie hiadonium s. sar iin Addanye in intresting oycles of their pk, vatues Case 201) GMS, GEN, Etcnnety —— fa lo ey) In ore Adtuslen Bosic SGrengtn Gomines epends pen > : Sabilily @ emmeniven Copier Reitig HHA ee Blabilily th this arrmonum Calin olependt upen ven o Helfer of aug groop cB) Hydorgen Seroling Cr SHEE Gee | Duet Combined effecr these Jaclos 2° amire cx moe basic then | * oemine. diy Refer Avouer Fa Page 4 Gren. < GHgnhety < Gos delocaiteat die Aeetyech of abet youp ~ pPefsecha ateyl jmp opposed seormamee: inereases bic SEretgin by Resonance cue bs whith Lome fait of fC int cole loca increases Que Chang deteas ¢ pk, value ne On) 9A walle mujer Plodstle’ they Beugene cadence coleide Asacl ih joNee 29 2) 3,2" (casé 20/9) SN He case ai Gy Salt Co Cuen” Wi? Creer! Wy OHO! hee fy BS ewer cucnyten ob s eats Ey cgena rae! 1 TRE gc enecarbonibrle Benzene s! ld Chloe snd 4) Annonse in order of increasing basic Glew) eae Hr (Hy) wt, “GHeNIa., Gis e city Cig Chypihy & Chg My, < CMe), fod orctlineé "n+ Beech” ECR aunyl grup Increases tofth Increase iM an ites on F bemaye group mabe io ei grmets, 4 thus basic
fas Gite, 2 eangy OP) OCJener > GJ iin eneae slaoméani line Ee 2 Ayricline My 6 TRSzm: chleside NHCOCH: Mange in orclee increasing boilirg Port - + Oncooy & 4 aad N-phengCchhamaniie Gliskm,, Ghtson, (Grts), I (GUS NH 2 GUcNN, < S804 shoeogin G imFeumal yoo bencling increarce, So beilng Point also ines coset Q) Give Chemis teat © okchngecth ays Oe amine ro nt rt 2" amine (CRIN Upon dpeatment= waite Hirsbery's reagent he. gene Curtho: mag heals NWN> or me they Suxp hon aan ele Whack, "S ingsclubie in ken - Suton Be amuse de wi~ Aeaep-Bodies coy ne Saye Ws Opt ie yt Leming spine erophonoria (Cotteete in Any Sen chins in pte, A amine old nh easy. IT Hinghery metrod & amine 4 ore " my Ober ‘ool wi sda deagents Vaminel pred Suaphonactice Solu, in kon kort (a+ ! wR] Ke ne DU gauibe a ot er» Gg -NHa ig Seger peargtieugencsusphonomide eae , Gi tam ge HONE git Hat Cid Pamine Aero peace ‘gy Covert" merryt Chive & Ethylene itt , Aus dy Cgc! BENE en Lininy he ob ne Le @ kou wie ber eins 3 cD Benge Ccgene. dare Cap gene Fetpanemire; cat g oa Patrye —> G+ He vy tamines rg bn Mehgl Chlericle Ethaneniile iy Gi) Cry coon MB» Cyconty— Bl, eat Woe tk by 5 3 ehayale Gtranomide. (aid meBanenine wy Give Slaclies ie A, Bee, Cease 2014) SwbhC) Mante,pne! ; O Groner” Cu hyo ipefHt © 36) Gi Gish —@ —@ 48) es) Gy of ni *NENCT ol wesc) O> & S @ f wXOD © wv Hy Aniline Benzene diate ninn Pomel Benzene Cosbonite!® Ou Oveen Chu: trite é lg Gmp ete 7 the Gotta Gatonihile 8 Ganeccnhy a LG Sac, @ Py BH) Gist By a @ snftey @ ene one kon ) 43% 0B Ygcenn Odussm © Gee a o, Beuziamcce ae wt pheryletanamide. Gy ® Qe ror Blubwobungene Driline I © Phenglssvoyanide gia aticytamine, mae basic fran ashmenio aan amine cue AL efpecra, alert gooep, lone fas on nilte ges ane eaig Qrodable ae donation. RANM_ ps wold CH nny , (Cty Ni, CENYE Phen Gnmonia. y ic inorder incressing Slab é : 12 Geel gee "mb of hyde oy attached! b- Nilkagey of Fimin® Siubitly waleL So meler ts
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