Safety Data Sheet (SDS)

Laguna Clay Co. GHS - United States

Section 1 - Identification

Product Name WC641 MEXO-WHITE AIR HARDENING MOIST CLAY

Common Names Pottery Clay, Dry Clay, Moist Clay

Company / Laguna Clay Co.

Manufacturer 14400 Lomitas Ave.
City of Industry, CA 91746
(626) 330-0631 fax (626) 333-7694
info@lagunaclay.com

Emergency Number 911

Product Use Non-exhaustive list: pottery, artware, ceramic building materials

Restrictions on Use None applicable

Section 2 - Hazardous Identification

Contains Crystalline Silica ≥1% Respirable

GHS label elements / Signal Word:

Hazard pictograms Danger

OSHA/HCS status Clay mixture in dry form is considered hazardous by the OSHA Hazard
Communication Standard (29 CFR 1910.1200)

Classification of the Carcinogenicity (inhalation) - Category 1A and Specific organ toxicity

substance or (Repeated Exposure) (Respiratory tract through inhalation) - Category 1
mixture

Hazard Statement (H350) Cancer Hazard. Contains quartz (crystalline silica) which may
cause cancer. Risk of cancer depends upon duration and level of exposure
to the dust. Not an acute hazard.
(H332) Prolonged inhalation of dust may cause lung injury. Inhalation of
high concentrations of dust may cause mechanical irritation and
discomfort of the respiratory tract. Repeated exposure may have chronic
effects.
(H316 + H320 + H335) Can cause skin, respiratory, and eye irritation.

Precautionary (P261) Avoid breathing dust.

Statements (P280) Wear protective gloves, eye, and respiratory protection.

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Safety Data Sheet (SDS) GHS - United States

Section 3 - Composition / Information on Ingredients

Substances/Mixtures Mixture - A trade secret claim is made for this item.

Component CAS # Approx % by Wt.

Kaolin 1332-58-7 >65%

4,4'-Bis(dimethylamino)benzophenone 9004-53-9 5-10%
Bentonite 1302-78-9 <5%
Titanium Dioxide 13463-67-7 <2%
Crystaline Silica - quartz 14808-60-7 <2%
Mica group 12001-26-2 <2%

Section 4 - First Aid Measures

First-Aid Measures

Eye Contact If eye contact occurs, rinse immediately with plenty of water. If irritation persists, seek
medical attention.

Skin Contact If irritation occurs, wash thoroughly with water. If it persists, seek medical attention.

Inhalation Move victim to fresh air in well ventilated area. If coughing or irritation persists, seek
medical attention.

Ingestion Consult physician and/or obtain competent medical assistance.

Symptoms and Effects, both Acute and Delayed

Eye Contact Prolonged contact with large amounts of dust may cause mechanical irritation.

Skin Contact Prolonged contact with large amounts of dust may cause mechanical irritation.

Inhalation Inhalation of high concentrations of dry clay dust may cause mechanical irritation and
discomfort. Long term exposure may cause chronic effects (see section 11).

Ingestion Large quantities ingested may cause gastrointestinal irritation.

Chronic Symptons Repeated or prolonged exposure to respirable crystalline silica dust may cause lung
damage in the form of silicosis. Symptons will include shortness of breath, fever fatigue,
loss of appetite, chest pain, dry non-productive cough.

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Safety Data Sheet (SDS) GHS - United States

Section 5 - Fire Fighting Measures

General Fire Hazards Clay mixture in dry or moist form is not flammable and does not support fire. The
paper bags or plastic bags and cardboard boxes containing the mixture are
flammable.

Extinguishing Media Use appropriate extinguishing media for surrounding fire.

Chemical hazards Clay mixture does not contain hazardous decomposition products.
from fire

Protective actions Clay mixture and packaging can become slippery when wet. Fire-fighters should
and equipment for wear appropriate protective equipment.
fire-fighters

Section 6 - Accidental Release Measures

Clean-up Methods If appropriate, use gentle water spray to wet down and minimize dust generation.

Personal Precautions Wear appropriate protective equipment and clothing during clean-up. When dry
and Personal sweeping use NIOSH approved respirators when dust levels exceed exposure
Protective Equipment limits.

Environmental Clay is a natural mineral product mixture and will not cause adverse effects to the
Precautions water system other than turbidity from suspended particles.

Emergency procedures There are no emergency procedures required for this mixture. Place dry clay dust
& Methods of in a sealed container for re-use or proper disposal.
Containment

Section 7 - Handling & Storage

Precautions for safe Use proper lifting techniques to avoid physical injury.
handling

Recommendations on No special storage considerations. Do not store moist clay mixture

the conditions for safe below freezing point (< 0 °C or<32°F).
storage

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Safety Data Sheet (SDS) GHS - United States

Section 8 - Exposure Counts / Personal Protection

Airborne Exposure Limits

Hazardous Ingredient Wt. % Aprox. CAS# OSHA PEL* / ACGIH TLV*

Kaolin >65% 1332-58-7 5mg/m3 / 2mg/m3 respirable

4,4'-Bis(dimethylamino)benzophenone5-10% 9004-53-9
Bentonite <5% 1302-78-9 5mg/m3 / 3mg/m3 respirable
Titanium Dioxide <2% 13463-67-7 15mg/m3 / 10mg/m3 total dust
Crystaline Silica - quartz <2% 14808-60-7 0.1mg/m3 / 0.025mg/m3 respirable
Mica group <2% 12001-26-2 3mg/m3 / 3mg/m3 respirable
Engineering Measures

Clay mixture in moist form poses no inhalation health risk. Once clay mixture has dried, there may be dust
generated by cleaning and working processes. In the event that dust is generated, use local exhaust ventilation or
other engineering controls as required to maintain exposures below applicable occupational exposure limits (TLV).
Personal Protective Equipment (PPE)

Respiratory Dust is generated when working with dry clay mixture. To minimize exposure to dust and/or
crystalline silica, cutting or sanding dry clay products should be conducted with sufficient
ventilation. Respirable dust and quartz levels should be monitored regularly. Dust and quartz
levels in excess of appropriate exposure limits should be reduced by feasible engineering
controls, including (but not limited to) wet sanding, wet suppression, ventilation, and process
enclosure. When such controls are not feasible, NIOSH/MSHA approved respirators must be
worn in accordance with a respiratory protection program which meets OSHA requirements
as set forth at 29 CFR1910.134 and ANSI Z88.2-1080 "Practices for Respiratory Protection”.
In most cases, a disposable N-95 Particulate Respirator is sufficient.

Eyes Use of NIOSH/OSHA approved safety glasses with side shields is recommended. Face shields
should also be used when dry sawing clay products. Wear tight fitting dust goggles when
excessively (visible) dusty conditions are present or are anticipated. NIOSH recommends that
contact lenses not be worn when working with crystalline silica dust.

Skin and Body Protective Clothing is not essential. Use gloves and/or protective clothing if abrasion or
allergic reactions are experienced.

Section 9 - Physical & Chemical Properties

Appearance Lump/dry powder or Evaporation Rate No data available

moist mud brick Solubility in water at 100 C None
Color White, red, brown Decomposition temperature Not Applicable
Physical state Solid Viscosity Not Applicable
pH 6-8 Flashpoint Not Applicable
Odor Earthy odor Boiling Point Not Applicable
Odor threshold Not Applicable Flammability Not Applicable
Melting Point > 1200 °C (>2150°F) Vapor Pressure (mm HG) Not Applicable
Freezing Point < 0 °C (<32°F) Vapor Density Not Applicable
Relative density/Specific Partition coefficient Not Applicable
Gravity ~2.6 gm/cc Auto-ignition temp Not Applicable

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Safety Data Sheet (SDS) GHS - United States

Section 10 - Stability & Reactivity

Reactivity No dangerous reactions are known under normal conditions of use

Chemical Stability Stable at standard temperature and pressure. No stabilizers

required to maintain chemical stability. Safety issues - Mold may
form in plastic bag (moist clay mixture) after several months of
shelf life.

Possibility of Hazardous Reactions None known

and Conditions to Avoid

Incompatibility / Hazardous None known

decomposition products

Section 11 - Toxicological Information

Primary Route of Exposure: Skin, Eye Contact, Inhalation and Ingestion

Specific Organ Toxicity - Single Exposure

Target organs include ears, skin, respiratory system, and gastrointestinal tract.

Specific Organ Toxicity - Repeated Exposure

Causes damage to eyes, skin, respiratory system, and gastrointestinal tract through prolonged or repeated exposure.

Acute Short-Term Exposure Effects

May cause eye irritation, skin irritation, respiratory tract irritation, and gastrointestinal tract irritation. Inhalation of
high concentrations of dry clay dust may cause mechanical irritation and discomfort. Long term exposure may cause
chronic effects.

Chronic Long Term Exposure Effects

Silica has been classified by OSHA as a human lung carcinogen. Repeated or prolonged exposure of respirable
crystalline silica dust may cause lung damage in the form of silicosis.

Effects of silicosis include bronchitis/chronic obstructive pulmonary disorder, increased susceptibility to tuberculosis,
scleroderma (a desease affecting skin, blood vessels, joints and skeletal muscles), and possible renal disease. Acute
silicosis can be fatal.

Related Symptoms
Symptons will include shortness of breath, fever, fatigue, loss of appetite, chest pain, dry non-productive cough.

Medical Conditions Aggravated by Exposure:

Individuals with pre-existing allergies, eye disorders, skin disorders, respiratory disorders and/or gastrointestinal
disorders may have increased susceptibility to the effects of exposure.

OSHA, IARC, and NTP Carcinogen Classifications

Chemicals with Carcinogen Potential CAS # OSHA IARC NTP

Titanium Dioxide 13463-67-7 NO YES - 2B NO

Crystaline Silica - quartz 14808-60-7 YES YES - 1 YES

IARC - International Agency for Research on Cancer OSHA - Occupational Safety & Health Administration
1 = Carcinogenic to humans NTP - National Toxicology Program
2A = Probably carcinogenic to humans
2B = Possibly carcinogenic to humans

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Safety Data Sheet (SDS) GHS - United States

Section 12 - Ecological Information (non-mandatory)

Ecotoxicity None Known

Biochemical oxygen demand (BOD5) None Known
Chemical oxygen demand (COD) None Known
Products of Biodegradation None Known
Toxicity of the products of Biodegradation None Known
Bioaccumulation Potential None Known
Potential to move from soil to groundwater None Known
Other adverse effects None Known

Section 13 - Disposal Configurations (non-mandatory)

Personal Protection Refer to section 8 for proper PPE when disposing of waste material.

Appropriate disposal containers Standard waste disposal containers - no special requirements.

Appropriate disposal methods Disposal of this product should comply with the requirements of
environmental protection and waste disposal legislation and any
regional or local authority requirements.

Physical and chemical properties Dry clay dust should be placed in a sealed container or in a manner
that may affect disposal that reduces or eliminates the release of the product. Moist clay has no
special requirements.

Sewage disposal Do not dispose of into sinks or toilets. Never dispose of this product
into a sewer system.

Special precautions for landfills There are no special precautions for disposal in a landfill. This product
or incineration activities is non-combustible and is not suitable for incineration.

Section 14 - Transporation Information (non-mandatory)

Regulatory UN Proper Transport Packing Bulk Transport Special

Information UN Number Shipping Name Hazard Class Group Number Guidance Precautions

DOT Classification Not regulated

TDG Classification Not regulated

ADR/RID Class Not regulated

IMDG Class Not regulated

IATA-DGR Class Not regulated

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Safety Data Sheet (SDS) GHS - United States

Section 15 - Regulatory Information (non-mandatory)

TSCA - Toxic Substances Control Act - EPA

Quartz and other chemicals are listed in the TSCA Chemical Substance Inventory.

California Prop. 65 WARNING

This product contains a chemical known to the State of California to cause cancer. (Prop. 65 - California Health and
Safety Code Section 2549 Et Seq).

SARA/Title III (Emergency Planning & Community Right-to-Know Act

This mixture contains no substances at or above the reporting threshold under section 313, based on available
data.

Section 16 - Other Information (non-mandatory)

Definitions
ACGIH American Conference of Governmental Industrial Hygienists
CAS Chemical Abstract Service
CAL-OSHA California Occupational Safety & Health Administration
IARC International Agency for Research on Cancer
OSHA Occupational Safety & Health Administration
MSHA Mine Safety and Health Administration
NIOSH National Institute of Occupational Safety and Health
NTP National Toxicology Program

HCS Hazardous communication standard

OSHA PEL OSHA permissible exposure limit
STEL Short-term exposure limit
TLV Threshold limit value
TWA Time weighted average

Three types of TLVs for chemical substances as defined by the ACGIH are:

TLV-TWA Time weighted average - average exposure on the basis of an 8h/day,

40h/week work schedule.

TLV-STEL Short-term exposure limit - spot exposure for a duration of 15 minutes,

that cannot be repeated more than 4 times per day, with at least 60
minutes between exposure periods.
TLV-C Ceiling limit - absolute exposure limit that should not be exceeded at
any time.

This SDS is in compliance with The Globally Harmonized System of Classification and Labeling of Chemicals
(GHS), and is subject to revsion at any time without notice. Its current revision date is : 9/9/2020

Information presented herein has been compiled from sources considered to be dependable and is accurate
and reliable to the best of our knowledge and belief but is not guaranteed to be so. Nothing herein is to be
construed as recommending any practice or any product in violation of any patent or in violation of any law or
regulation. It is the user’s responsibility to determine for himself the suitability of any material for a specific
purpose and to adopt such safety precautions as may be necessary. We make no warranty as to the results to
be obtained in using any material and, since conditions of use are not under our control, we must necessarily
disclaim all liability with respect to the use of any material supplied by us.

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