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SOLUTION

Board Support Question

1. Calculate the freezing point of solution when 1.9 g of MgCl2 (M = 95 g mol–1) was dissolved in 50 g of water,
assuming MgCl2 undergoes complete ionisation. (Kf (H2O) = 1.86 K kg mol–1).
2. Out of 1 (M) glucose and 2 (M) glucose, which one has a higher boiling point and why ?
3. What happens when external pressure is applied became more than osmotic pressure of solution ?
4. When 2.56 g of sulphur was dissolved in 100 g of CS2, the freezing point lowered by 0.383 K. Calculate the
formula of sulphur (Sx).(Kf(CS2) = 3.83 K kg mol–1, atomic mass of sulphur = 32 g g mol–1)
5. Blood cells are isotonic with 0.9% NaCl solution. What happens if we place blood cells in a solution containing
(i) 1.2% NaCl solution ?
(ii) 0.4% NaCl solution ?
6. (i) Define molar elevation boiling point constant (Kb) with unit.
(ii) Define molal freezing point depression constant (Kf) with unit.
7. A solution containing 15 g urea (molar mass = 60 g mol–1) per litre of solution in water has the same osmotic
pressure (isotonic) as a solution of glucose (molar mass = 180 g mol–1) in water. Calculate the mass of glucose
present in 1 litre of its solution.
8. What type of deviation in shown by a mixture of ethanol and acetone ? Give reason.
9. 0.5 g of KCl was dissolved in 100 g of water and the solution originally at 20ºC, froze at –0.24ºC. Calculate the
percentage dissociation of the salt. (Given, Kf (H2O) = 1.86 K kg/mol, atomic mass of K = 39 u, Cl = 35.5 u)
10. What is meant by positive deviation from Raoult’s law ? Give an example. What is the sign of Hmix for (+ve)
deviation ?
11. Define azoeotropes. What type of azeotrope is formed by positive deviation from Raout’s law ? Give an example.
12. Some ethylene glycol ((CH2OH)2), is added to your car’s colling system along with 5 kg of water. If the freezing
point of water-glycol solution is –15ºC, what is the b.pt. of the solution ?

( K b(H = 0.52 K kg mol–1, K f(H = 1.86 K kg mol–1)

2O) 2O)

13. An electrolyte is 50% ionised in aqueous solution. Caltulate the freezing point of 1 molal aqueous solution.
14. What type of non-idealities are exhibited by cyclohexan-ethenol and aecetone-chloroform mixture ? Give reasons.
15. What is osmotic pressure ? Define reverse osmosis.
16. How is the vapour pressure of a solvent affected when a non-volatile solute is dissolved in it ?
17. (i) For which of the following the van’t Hoff factor cannot be greater than unity ?
K4[Fe(CN)6], AlCl3, NH2CONH2, KNO3.
(ii) Why is osmotic pressure of 1 (M) NaCl is higher than 1 (M) glucose solution ?
(iii) Can we separte azeotropes by fractional distillation ? Give reason.
CHEMISTRY SOLUTION

(iv) What type of interaction exist between alcohol and water ?

(v) What is the value of ‘i’ for Na2SO4  10 H2O ?
18. What is colligative property ?
19. Calculate the freezing point (f. pt.) of a solution containing 0.1 g of K3[Fe(CN)6] (M. wt. = 392) in 100 g of H2O
if it is 50% ionised. [Kf(H2O) = 1.86 k/m, normal f. pt. of H2O = 273.15 K]
20. (i) Why boiling point of water less than 100ºC at hill station ?
(ii) Why are aquatic species more comfortable in cold water than hot water ?
21. A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298
K. Further, 18 g of H2O is the added to the solution and new vapour pressure becomes 2.9 kPa at 298 K.
Calculate
(i) Molar mass of the tolute
(ii) Vapour pressure of H2O at 298 K.
22. Measurement of which colligative property is preferred for determination of molar mass ?
23. State Raoult’s law for a solution containing volatile component.
24. Define ‘mole fraction’ of a substance in a solution.
25. State the main advantage of molality over molarity as the unit of concentration.
26. State Henry’s law and mention its two important applications.
27. Heptane and octane form ideal solution. At 373 K, the vapour pressure of the two liquid components are 105.2
kPa and 46.8 kPa respectively. What will be the vapour pressure of a mixture of 26.0 g of heptane and 35.0 g of
octane ?
28. Vapour pressure (V.P.) of chloroform (CHCl3) and dichloromethane (CH2Cl2) at 289 K are 200 mm Hg and 415
mm Hg respectively
(i) Calculate the V.P. of the solution prepared by mixing 25.5 g CHCl3 and 40 g CH2Cl2 at 298 K and
(ii) Mole fraction of each component in vapour phase.
29. The osmotic pressure of 0.01 molar solution of an electrolyte is 0.65 atm at 27ºC. Calculate the van’t Hoff factor.
Mention conclusion regarding the molecular state of the solute in the solution.
30. Calculate the freezing point of an aqueous solution of urea whose boiling point is 100.18ºC
(Kf (H2O) = 1.86 K kg mol–1 ; Kb (H2O) = 0.512 K kg mol–1)
31. A solution of sucrose (M. wt. = 342) is prepared by dissolving 1.71 g of it in 500 ml of water at 300 K. What will
be the osmotic pressure ?
32. A 10% aqueous solution of cane sugar (M. wt. = 342) is isotonic with 1.754% aqueous solution of urea. Find the
molecular mass of urea.
33. What is van’t Hoff factor ?
34. The vapour pressure (V.P.) of pure H2O is 17.24 mm Hg at 20ºC. When 20 g of non-electrolyte solute is added to
100 g of H2O, V.P. lowers by 0.30 mm Hg. Calculate molecular weight of solute.
35. Find out the boiling point of 5% (W/W) sucrose solution. (Kb(H2O) = 0.52 K kg mol–1)
36. (i) When the value of Van’t Hoff factor becomes greater and less than one ?
(ii) Same molar solution of NaCl and BaCl2 are prepared. If the freezing point of NaCl solution is –2ºC, what
will be the f. pt. valueof BaCl2 solution ?
37. Explain the molal elevation of boiling point of benzene is 2.5 degree molality.
38. 100 of liquid A(MM = 140) was dissolved in 1000 g of another liquid B(MM = 180). The vapour pressure (V.P.)
of pure B is 500 torr. Calculate the V.P. of pure A, if the total pressure of the solution in 475 torr.
39. Why vapour pressure (V.P.) of solution increases when HgI2 is added to the aqueous solution of KI ?

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CHEMISTRY SOLUTION

40. What will be the osmotic pressure of 0.02 molar aqeuous solution of urea at 27ºC ?
(R = 0.082 L atm K–1 mol–1)
41. (i) State Raoult’s law of relative lowering of vapur pressure.
(ii) Write two differences between ideal and non-ideal solution.
42. What is the freezing point of aqueous solution of 0.1(M) urea ? (Kf(H2O) = 1.86 K kg mol–1)
43. 0.5 (M) aqueous solution of KBr dissociates 80%. Calculate the vant’ Hoff factor.
44. What is relative lowering of vapour pressure (V.P.) ? On which factor it depends according to Raoul’s law.
45. Why 0.84% NaCl solution is used as normal saline ?
46. (i) Why we get abnormal molecular masses of substance using colligative property of solution only some times
? What are the nature of these abnormalities ?
(ii) What do you mean by isotonic solution ?
47. What will be the vapour pressure of the solution at 100ºC containing 18 g of glucose in 178.2 g of water?
48. When 1.4 g of acetone is dissolved in 100 g of benzene freezing point of the solution becomes 277.12 K. Again in
the same amount of benzene an unknown solute of 2.8 g is added then the freezing point of the slution becomes
277.76 K. If pure benzene (C6H6) has the freezing point (f. pt.) of 278.4 K, then calculate the molecular weight
of unknown solute.
49. State Raoult’s law for elevation of boiling point.
50. State Raoult’s law for depression of freezing point.
51. State Van’t Hoff law of osmotic pressure.
52. Define hypertonic and hypotonic solution.

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