TAXSILA PUBLIC SCHOOL

CHAPTER – 1 (SOLUTION)
CHEMISTRY ASSIGNMENT

CBSE SYLLABUS OF UNIT

Board Weightage: 7 Marks
Types of solutions, expression of concentration of solutions of solids in liquids, solubility of gases in
liquids, solid solutions, Raoult's law, colligative properties - relative lowering of vapour pressure,
elevation of boiling point, depression of freezing point, osmotic pressure, determination of molecular
masses using colligative properties, abnormal molecular mass, Van't Hoff factor.
General information
 The assignment has three sections i.e., A, B & C.
 The section A has Various theoretical questions completing the whole syllabus of the unit these
questions are to be revised from the class notes / text book for a better understanding of chapters.
 Section B has various questions as per the taxonomy of unit completing the questions from
knowledge level, understanding level, application level, analyzing level, synthesis level, evaluation
level & other forms of questions like case study, art integrated problems etc. These questions are
to be Solved in the assignment notebook.
 In section C the questions have been given for the practice purpose. Students can solve these
questions in the practice copy for better understanding of the syllabus.

SECTION -A
( To be revised from the notes notebook / text book, not to be written in assignment copy )
A1: Write the difference between Molarity & Molality.
A2: Give factors affecting the concentration of the solution.
A3: What is solubility? Write the various factor affecting of solubility in different types of solution.
A4: Compare Henry’s law with Raoults law with suitable examples.
A5: Define different type of colligative properties and apply various type of formulation on it.
A6: What is Vant hoff factor? Where the vant’s hoff apply discuss with suitable formulation?
A7: Prepare a tabulation of all formula, unit and factor affecting, used in this chapter.
SECTION B (To be solved in the assignment copy)
NCERT & EXAMPLER PROBLEM OF THIS CHAPTER.
B1-If 𝐍𝟐 gas is bubbled through water at 293k. How many millimoles of 𝐍𝟐 gas would dissolve in 1 litre of
water? Assume that 𝐍𝟐 exerts a partial pressure of 0.987 bars. Given that Henry’s law constant for 𝐍𝟐 at
293K is 76.48 Kbar. [Ans: 0.716 millimoles]
B2: Henry’s law constant for 𝐂𝐎𝟐 in water is 1.67 × 𝟏𝟎𝟖 pa at 298 K. Calculate the quantity of 𝐂𝐎𝟐 in 500
ml of soda water. When packed under 2.5 atm 𝐂𝐎𝟐 pressure at 298 k. [Ans : 42.14 millimoles]
B3: The vapour pressure of pure liquid A and B are 450 and 700 mm of Hg at 350 K respectively. Find out
the composition of the liquid mixture if total vapour pressure is 600 mm of Hg. Also find the composition of
the vapour phase. [Ans: 𝐗 𝐀 = 0.4, 𝐗 𝐁 =0.6 ( in liquid phase), 𝐗 𝐀 = 0.3, 𝐗 𝐁 =0.7 ( in Vapour phase)]

B4: Heptanes & octane foam an ideal solution. At 373K the vapour pressures of the two liquid components
are 105.2Kpa and 46.8Kpa respectively. What will be the vapour pressure of a mixture of 26.0 g of Heptane
and 35.0 g 0f Octane? [ Ans : 73.87Kpa.]
DEPARTMENT OF CHEMISTRY, TAXSILA PUBLIC SCHOOL.
B5: The vapour pressure of water is 12.3 kpa at 300k. Calculate vapour pressure of 1 molal solution of a
nonvolatile solute in it. [ Ans: 12.0825 kpa.]
B6: A solution containing 30 g of nonvolatile solute exactly in 90 g of water has a vapour pressure of 2.8 kpa
at 298K. Further 18 g of water in then added to the solution and the new vapour pressure becomes 2.9Kpa
at 298K. Calculate (i) molar mass of the solute (ii) vapour pressure of water at 298K. [Ans: 35.30pa]
B7: Boiling point of water at 750 mm Hg is 99.63°𝑪.How much sucrose is to be added to 500g of water
such that it boils at 100°𝑪? Given 𝐊 𝐛 For water = 0.52. [Ans : 121.67g]
B8: Calculate the mass of ascorbic acid (vitamin C),𝐂𝟔 𝐇𝟖 𝐎𝟔 to be dissolved in 75g of acetic acid to lower its
melting point by 1.5℃. (𝐊 𝐟 = 3.9 k kg/mol). [Ans : 5.076g]
B9: A 5% solution (by mass) of cane sugar in water has freezing point of 271K. Calculate the freezing point
of 5% glucose in water if freezing point of pure water is 273.15K. [Ans: 269.065k]
B10:19.5g of CH2 FCOOH is dissolved in 500g of water. The depression in the freezing point of water
observed is 1.0℃. Calculate the vant,s Hoff factor and dissociation constant of fluroacetic acid .
[Ans: ∝= 0.0753, 𝐊 𝐚 = 3.06 × 𝟏𝟎−𝟑 ]
B11: Calculate the osmotic pressure in Pascal’s exerted by a solution prepared by dissolving 1.0g of polymer
of molar mass 185,000 in 450 ml of water at 37℃. [Ans: 30.95pa]
B12: Determine the Osmotic pressure of a solution prepared by dissolving 25mg of K 2 SO4 in 2 liters of
water at 25℃.Assuming that it is completely dissociated. [Ans : 5.27 x 𝟏𝟎−𝟑 atm]
B13: A solution 0.1 M of Na2SO4 is dissolved to the extent of 95%. What would be its osmotic pressure at
27oC ? ( R = 0.0821 L atm/k mol). [Ans = 7.413atm]
-3
B14: The partial pressure of ethane over a solution containing 6.56 x 10 g of ethane is 1 bar. If the solution
contains 5.00 x 10-2 g of ethane then what shall be the partial pressure of the gas? [Ans : 7.621 bar]
B15: A solution is prepared by dissolving 5 g of non-volatile solute in 95 g of water. It has a vapor pressure
of 23.375 mm Hg at 25 oC. Calculate the molar mass of the solute (vapour pressure of pure water at 25 oC is
23.75 mmHg). [Ans : 60 gm]
SECTION-C
(All the questions coming in the previous years from the unit in board exams)
(Questions to be practiced in the practice notebook)

C1: Calculate the B.P of elevation for a solution prepared by adding 10 g CaCl2 to 200 g of H2O, assuming
that CaCl2 is completely dissociated. [Kb for H2O = 0.512 Kkg/mol, MBCaCl2 = 111g/mol] [Ans: 373.69]
[CBSE – 2016]
C2: A 1.00 molar aqueous solution of trichloroacetic acid (CCl3COOH) is heated to its boiling point. The
solution has the boiling point of 100.18 oC. Determine the van’t Hoff factor for trichloroacetic acid. (Kb
water=0.512Kkg /mol). [Ans: i = 0.35] [CBSE- 2017]
C3: Calculate the freezing point of a solution 60 g of glucose (molar mass = 180g/mol) in 250 g of water. (Kf
of water = 1.86 K kg/mol) [Ans: 270.67K or -2.480C] [CBSE- 2017]
C4: A 10% solution (By mass) of sucrose in water has freezing point of 269.15 K. Calculate the freezing point
of 10% glucose in water, if freezing point of pure water is 273.15 K. (Molar mass of sucrose =342 g/mol,
molar mass of glucose = 180g/mol).[Ans: 265.55 K] [CBSE- 2018]
C5: A 4 % solution (w/w) of sucrose (M = 342g/mol) in water has a freezing point of 271.15 K. Calculate the
freezing point of 5% glucose (M = 180g/mol) in water. (Freezing point of pure water = 273.15K)
[Ans: 268.35K] [CBSE- 2018]

DEPARTMENT OF CHEMISTRY, TAXSILA PUBLIC SCHOOL.

C6: 30 g of urea (M = 60g/mol) is dissolved in 846 g of water. Calculate the vapour pressure of water for this
solution if vapour pressure of pure water at 298K is 23.8 mm Hg. [Ans: 23.54 mm of Hg] [CBSE- 2019]
C7: Henry’s law constant for the solution of methane in benzene at 298K is 4.27 x 105 mm Hg. Calculate the
solubility of methane in benzene at 298K under 760 mm Hg. [Ans: 0.0228 moles] [CBSE-2021]
C8: The vapour pressure of pure liquid X and pure liquid Y at 25 0C are 120 mm Hg and 160 mm Hg
respectively. If equal moles of X and Y are mixed to form an ideal solution. calculate the vapour pressure of
the solution. [Ans: 140 mm of Hg ] [CBSE – 2022-23]
C9: When 19.5 g of F-CH2-COOH (Molar mass = 78g/mol), is dissolved in 500g of water, the depression in
freezing point is observed to be 10C. Calculate the degree of dissociation of F-CH2-COOH. (Given: Kf for
water = 1.86 K Kg/mol) [Ans: I = 1.0753, 𝜶 = 0.075] [CBSE – 2022-23]
C10: Assertion Reason Type Questions
(A) Both A & R are true & R is correct explanation of A.
(B) Both A & R are true & R is not correct explanation of A.
(C) A is true, but R is false.
(D) A is false, but R is true.
(i) : Assertion : osmotic pressure is a colligative property. (CBSE 2022-23)
Reason: Osmotic pressure is proportional to the molarity.
(ii): Assertion: The enthalpy of mixing ∆mixH is equal to zero for an ideal solution.
Reason: For an ideal solution the interaction between solute and solvent molecules is stronger than the
interaction between solute-solute or solvent–solvent molecules. (CBSE- 2022-23)
(iii):Assertion : Elevation in boiling point is a colligative property.
Reason: The lowering of vapour pressure of solution causes elevation in boiling point. (CBSE- 2022-23).
(iv): Assertion: The boiling point of 0.1M urea solution is less than that of 0.1 M KCl solution. (CBSE- 20-21)
Reason: Elevation of boiling point is directly proportional to the number of species present in the solution.
(v): Assertion : When methyl alcohol is added to water, boiling point of water increases. (CBSE- 2019-20)
Reason: When a volatile solute is added to a volatile solvent elevation in B.P is observed.
C11: (a) How can you remove the hard Calcium Carbonate layer of the egg without damaging its
semipermeable?
(b) Can this egg be inserted into a bottle with a narrow neck without distorting its shape? Explain the
process involved. (EXAMPLER- 2017)
C12: A person suffering from high blood pressure is advised by a doctor to take minimum quantity of
common salt. Explain (CBSE 2015)
C13: Measurement of osmotic pressure method is preferred for the determination of molar masses of
macromolecules such as proteins and polymers. (CBSE 2017)
C14: Consider the figure and mark the correct option. [Exampler]

DEPARTMENT OF CHEMISTRY, TAXSILA PUBLIC SCHOOL.

(a) Water will move from side (A) to side (B) if a pressure lower than osmotic pressure is applied on piston
(B).
(b) Water will move from side (B) to side (A) if a pressure greater than osmotic pressure is applied on
piston (B).
(c) Water will move from side (B) to side (A) if a pressure equal to osmotic pressure is applied on piston (B).
(d) Water will move from side (A) to side (B) if pressure equal to osmotic pressure is applied on piston (A).
C15: Two beakers of capacity 500 mL were taken. One of these beakers, labelled “A”, was filled with 400 mL
water whereas’ the beaker labelled “B” was filled with 400 mL of 2 M solution of NaCl. At the same
temperature both the beakers were placed in closed containers of same material and same capacity as
shown in figure. [Exampler]

At a given temperature, which of the following statement is correct about the vapour pressure of pure
water and that of NaCl solution.
(a) Vapour pressure in container (A) is more than that in container (B).
(b) Vapour pressure in container (A) is less than that in container (B).
(c) Vapour pressure is equal in both the containers.
(d) Vapour pressure in container (B) is twice the vapour pressure in container (A).
C16: For a binary ideal liquid solution, the variation in total vapour pressure versus composition of solution it given by
which of the curves? [Exampler]

DEPARTMENT OF CHEMISTRY, TAXSILA PUBLIC SCHOOL.

C17: Which one of the following concentrations is not affected by temperature? [CBSE-2016]
(a) Normality (b) Molarity (c) Molality (d) Formality
C18: The number of moles of NaCl in 3 litres of 3M solution is [CBSE-2016]
(a) 1 (b) 3 (c) 9 (d) 27
C19: The boiling point of a solvent containing a non-volatile solute: [CBSE-2016]
(a) is depressed (b) is elevated (c) does not change (d) none of them
C20: What are azeotropes? Give an example. [CBSE-2016]
C21: Define ebullioscopic constant or molal elevation constant. [CBSE-2017]
C22: Why is the elevation of boiling point a colligative property? [CBSE-2017]
C23: What would happen when red blood cells are placed in saline water (Hypertonic solution)
[CBSE-2017]
C24: Give reason when 30 ml of ethyl alcohol and 30 ml of water are mixed, the volume of resulting solution
is more than 60ml.’ [CBSE-2017]
C25: 10 ml of liquid A was mixed with 10 ml of liquid B. The volume of the resulting solution was found to
be 19.9ml. what do you conclude. [CBSE-2017]
C26: Measurement of which colligative property is preferred for determination of molar mass of
macromolecules such as proteins and polymers. [CBSE-2017]
C27: A person suffering from high blood pressure should table less common salt, why? [CBSE-2018]
C28: Why do doctors advise gargles by saline water in case of sore throat? [CBSE-2018]
C29: Of 0.1 molal solutions of glucose and potassium chloride respectively, which one will have a higher
boiling point? [CBSE-2018]
C30: Give an example of a material used for making semipermeable membrane for carrying out reverse
osmosis. [CBSE-2018]
C31: State Raoults law for a solution containing volatile components. How does Raoult’s law become a
special case of Henry’s law? [CBSE-2019]
C32: The molecular masses of polymers are determined by osmotic pressure method and nor by measuring
other colligative properties. Give two reasons. [CBSE-2019]
C33: Aquatic animals are more comfortable in cold water than in warm water. [CBSE-2019]
C34: List any four factors on which the colligative properties of a solution depend. [CBSE-2019]
C35: What is the significance of Henry’s law constant KH? [CBSE-2019]
C36: How does sprinkling of salt help in clearing snow covered roads in hilly areas? Explain the phenomenon
involved in the process. [CBSE-2021]
C37: What type of deviation is shown by a mixture of ethanol and acetone? [CBSE-2021]
C38: What type of azeotropes is formed by negative deviation from Raoult’s law? [CBSE-2021]
C39: How is it that alcohol and water are miscible in all proportions? [CBSE-2021]
C40: What is the sign of ∆mixH for negative deviation? [CBSE-2021]

DEPARTMENT OF CHEMISTRY, TAXSILA PUBLIC SCHOOL.