Chemistry Reviewer
Chemistry Reviewer
DIFFRACTION OF LIGHT
PLANK’S QUANTUM THEORY AND PHOTONS
1900-Max Planck (1858-1947), a German Physicist explained why a piece of iron
changes color as it is heated.
He suggested that the energy absorbed by the iron or any body is absorbed (or
released) only in fixed amounts which he called quanta.
In 1905, Albert Einstein (1875-1955) realized that a tiny packet of energy behaves like a
tiny particle of light and used this to explain the photoelectric effect
PHOTOELECTRIC EFFECT
The photoelectric effect causes electrons to be ejected from the surface of a metal
when light of high frequency/energy(photon) hits the metal surface. This phenomenon
is used in electric-eye openers, photovoltaic cells, and light meters.
ATOMIC SPECTRA
Atomic Spectra/Line Spectra - produced by some gaseous substances that consist of
only limited number of colored lines with dark spaces between them.
Each element has its own disticnt line spectrum, a kind of finger print. Atomic Spectra
can be used to identify an element.
SPECTROSCOPY
The study of spectral lines,was developed by Robert Bunsen and Gustav
Kirchhoff.
Early work in spectroscopy was done using gas burner, now called the Bunsen
burner. Atoms heated (excited) in a Bunsen flame emit characteristic bright
colors. Through the spectroscope, the bright colors appear as bright lines called
emission spectra.
An atomic spectrum shows lines that proves the existence of electrons in atoms
in quantized energy states.
ATOMS are excited when they are heated in a flame or by using an electrical
discharge (current) as in “neon” signs or in the bright light of fireworks. These
are common sources of bright line spectra.
In 1913, using the line spectrum of hydrogen, Neils Bohr postulated the following:
1. Electrons move in circular orbits around the nucleus. Adapting Einstein’s idea that
slight particles are quantized, he proposed that each orbit corresponds to a definite
energy level which increases as its distance from the nucleus increases.
Each orbit contains a definite number of electrons. As long as the elctrons stay in their
given orbits, no absorption or emission of energy occurs. The electron energy is fixed.
2. The lone electron of hydrogen could transfer from one energy level to another when
it absorbs or emits energy.
Each energy level is designated a positive integer, n, called the principal number or
energy level. This indicates the position of the electrons with respect to the nucleus.
When the electron is n=1, it is the ground state or ground level. This is the lowest
energy state of the electrons - the most stable.
Bohr’s model was important because it introduced the idea of quantized energy levels
for electrons in atoms.
WAVE PARTICLE DUALITY
Planck, Einstein, and Bohr suggested that light possesses both particle (photon)
and wave properties.
Louis de Boglie in 1924 -suggested that electrons or small particles at times
display properties of waves.
Davisson and Germer in 1927 - observed that when beams of electrons were
bombarded on metal surfaces, patterns of diffractions and reflections were
produced.
The dual characteristic of matter and energy is known as the wave-particle
duality. De Broglie used the term matter waves to describe the wave
characteristics of material particles.
QUANTUM NUMBER
1. The principal quantum number (n) or shell can have values 1, 2, 3, and so on. It
indicates the size of the orbital and the relative distance from the nucleus. This
quantum number also specifies the energy level of electrons. The higher the n value,
the higher the energy level.
3. Magnetic quantum numbers (ml ) has values of -l to 0 to +l. This quantum number
describes the orientation of the orbital in space. If l = 0, ml = 0. If l = 1, ml will have the
values of -1,0,+1. If l = 2, ml will have the values of -2,-1,0,+1,+2.
4. The fourth quantum number used to describe electrons is the electron spin (m s).
George Uhlenbeck and Samuel Goudsmit proposed that an electron spins in an axis as
the Earth spins in its axis.
𝟏 𝟏
There are two possibilities for electron spins-a value of + 𝟐 ( denoted by ) or − 𝟐 (
denoted by )
ATOMIC ORBITALS
Orbitals with the same value of n are reffered to as a shell. One or more orbitals with
the same n and l values are called subshell. The total number of orbitals is n 2. The
total number of electron in a shell is 2n2. Electron capacity of Subshell is 4l + 2.
s ORBITALS – SPHERICAL
p ORBITALS - pair of lobes/dumbbell shape
d ORBITALS - four leaf clover shape
f ORBITALS -eight lobes-more complex
Angular momentum quantum number (l) – defines the 3D shape of an orbital. It has
integral value of 0 to n – 1. This is referred to by letter rather than by number.
Quantum number (l): 0, 1, 2, 3, 4, …
Subshell notation: s, p, d, f, g, …
Magnetic quantum number (ml ) – defines the spatial orientation of the orbital along
standard set of coordinate axes. It has integral value from –l to +l.
Electron spin (ms ) – describes the clockwise or counter clockwise spins of electrons.
A value of +½ or –½ is used to describe the spin.
What is the maximum number of electrons in the fifth principal energy level?
Using 2n2
= 2(5)2
= 50 electrons
Arrange the following orbitals from the lowest to highest energy level?
4p, 3p, 3d, 4f, 6s, 5p
Answers
4s, 3d, 4p, 5p, 6s, 4f
4, 5, 5, 6, 6, 7
4s<3d<4p<5p<6s<4f
NOTE: if n+l is the same for 3d and 4p, then we need to compare the values of n, the n that has
a lower value has the lower enegry level. The same goes for 5p and 6s... and other orbitals
later on with same n+l value. Remember that the higher the value of n, the higher the energy
level.
QUANTUM MECHANICS
is a Science that deals with the process that affect the behavior of matter and light in
atomic and sub atomic scales.
PLANK - light and electromagnetic waves are emitted in discrete packets of energy -
quanta
EINSTEIN - photoelectric effect - light can eject electrons in a metal since it can also
behave as a particle
SCHRODINGER - wave mechanics - explain the properties of an atom, electron’s
wave-like characteristics, suggested the existence of orbitals
HEISENBERG - uncertainty principle
ELECTRONIC CONFIGURATION
Electrons are arranged and distributed in orbital shells and subshells
SHELLS
Energy levels (also called electron shells) are fixed distances from the nucleus of an
atom where electrons may be found. Electrons are tiny, negatively charged particles in
an atom.
SUBSHELLS
• Subshells increase in energy as follows:
s<p<d<f
• Therefore, electrons in 3d subshell have more energy than electrons in the 3p
subshell.
• Note: when giving a subshell, also give the principal energy level with it. 1s, 2s,
2p...
Electron Subshells
• A region of space within an electron shell that contains electrons that have the
same energy.
ORBITALS
Orbital - a specific region of a subshell containing a maximum of two electrons.
• The two electrons in the orbital spin is in opposite directions.
• When the orbital contains two electrons, the electrons are said to be paired.
Electron Orbitals
• The orbits are also identified using
“quantum numbers”
– n = 1, 2, 3, …
– When the electron relaxes, the energy
released is observed as a single
wavelength of light.
AUFBAU PRINCIPLE
ELECTRONS FILL ORBITALS STARTING FROM THE LOWEST ENERGY ORBITAL (FIRST
PRINCIPAL ENERGY LEVEL), THEN PROCEED TO FILLING EACH LOWER ENERGY
ORBITAL, ONE ELECTRON AT A TIME, BEFORE FILLING A HIGHER ENERGY LEVEL.
Electron Configuration and the Aufbau Principle
• Electron Configuration - the arrangement of electrons in atomic orbitals.
• Aufbau Principle - or building up principle helps determine the electron
configuration
• Electrons fill the lowest-energy orbital that is available first
• Remember s<p<d<f in energy
EXCEPTION:
Some elements are more stable if the subshells are half-filled or fully filled. Hence, d-
orbitals are more stable with 5 and 10 electrons, while f orbitals are more stable with 7
and 14 electrons.
Electronic Configurations
• A statement of how many electrons an atom has in each of its electron
subshells.
• Aufbau Principle, Pauli Exclusion Principle and Hund’s Rule
• An oxygen atom as an electron arrangement of two electrons in the 1 s subshell,
two electrons in the 2s subshell, and four electrons in the 2p subshell.
Oxygen: 1s22s22p4
1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p67s25f146d107p6 8s2
Orbital Diagrams
• A notation that shows how many electrons an atom has in each of its occupied
electron orbitals.
8 Oxygen: 1s22s22p4
Oxygen: 1s 2s 2p
HUND’S RULE
DEGENERATE ORBITALS ARE FILLED SINGLY BEFORE PAIRING UP.
The most stable arrangement of electrons in subshells is the one with the greatest
number of parallel spins (Hund’s rule).
The Pauli Exclusion Principle and Hund’s Rule in Electron Configurations
Ferromagnetism is the permanent magnetism that we encounter in our daily lives. It
only occurs with three elements: iron (Fe), nickel (Ni), and cobalt (Co
Property of substance to be slightly attracted to a magnetic field
with unpaired electrons
Elements can be classified into four different categories according to their electron
configuration
1. Noble gases (Group 8A)
They have filled outer s and p orbitals, their structures represented as ns2np6, where n
is the outermost energy level.
2. The representative elements are usually called the Group A elements. Outermost s
or p sublevels are only partially filled. For any representative element, its group
number is equal to the number of electrons in the outermost energy level or valence
electrons, Group 1A has 1 valence electron and so on...
3. The transition metals are called the Group B elements. They are the elements whose
outermost s sublevels are filled and electrons are added to the d orbitals. They are
considered as transitions between the alkaline elements and the nonmetals on the
right.
4. The inner transition metals are sometimes known as f transition elements. They are
the elements whose electrons are being added to f orbitals. They are loacted between
Groups 3B and 4B in the periodic table. Elements where 4f subshells are being filled
are also called lanthanide series (Ce through Lu) while elements whose 5f subshells
are being filled are called actinide series (Th through Lr). Elements beyond Uranium
are the transuranic or synthetic elements-created in laboratory.
• Atomic size
• Ion size
• Ionization energy
• Electron affinity
From left to right across a period of elements, the atomic radius decreases.
As you move down a group, atomic radii increase as electrons are added to
successively higher energy levels.
Nuclear charge is the attraction exerted by the nucleus on electrons due to the
positive charge of the protons and negative charge of the electron
• Atomic size
• - Atomic size of the elements depend on the size of the atoms. The size of the
atoms decreases because the nucleus pulls electron closer.
• That is why . . . the atomic size of the elements ;
• Atomic / Ionic size
Cations are always smaller than their parent atom.
This is due to more protons than electrons. The extra protons pulls the remaining
electrons closer
Which would be smaller, Fe2+ or Fe3+?Fe3+
This size trend is also due to the fact that it is the outer shell that is lost.
Ionization Energy
- Ionization energy or ionization potential is the energy required to remove a
valence electron from a neutral atom.
• The lower the ionization energy, the easier to form a cation.
An increase in attractive force of the nucleus for the valence electron is due to an
increase in nuclear charge.
• Electron Affinity
Electron affinity is defined as the energy releasedwhen an atom gains one
electron.
Electron affinity is high for non-metals but low for metals.
-Large electron affinity indicates an atom becomes more stable as it forms an
anion.
Electronegativity
Electronegativity of an element is the ability of an atom in a compound to attract
electrons to itself. The larger the electronagativity value, the greater the
tendency of the atom to attract electrons. For representative elements,
electronegativity increases from left to right across periods and decrease from
top to bottom with in groups.
-Electronegativity is the ability of an atom to attract electrons in a
covalent bond.
like Electron affinity it increases from left to right in a period and bottom
to top within a group
Electronegativity: a measure an atom’s attraction for the electrons it
shares in a chemical bond with another atom.
on the Pauling scale, fluorine, the most electronegative element is
assigned a value of 4.0, and all other elements are assigned values
relative to fluorine.
Metallic Property
Elements are divided into: Metals, Non-Metals and Metalloids
GENERAL TREND
• Ionization Energy
• Electron Affinity
Electronegativity
• Atomic Number
Iodine - iodized salt with KI and NaI, used to make tincture of iodine for treat minor
cuts and scratches.