1 Formation of Steam
1 Formation of Steam
22.1 Introduction
Steam, which is gaseous form of pure water, is an excellent working medium in various
thermodynamic systems because of its following properties:
3) It can be used for heating purposes after its duty as working agent is completed.
In general, steam can be formed by boiling water in a vessel. But to use it effectively as a working
or heating medium, it has to produce in a closed vessel under pressure. Steam formed at a higher
pressure has higher temperature and can be made to flow easily through insulated pipes from steam
generator to point of use. A simple arrangement of formation of steam at constant pressure is
shown in Fig. 22.1.
Consider 1 kg of ice at temperature -100C which is below the freezing point. Let it be heated at
constant pressure P. The temperature of ice starts increasing until it reaches the melting
temperature of ice i.e., 00C and during this course ice absorbs its sensible heat. On further addition
of heat, ice starts melting, its temperature remains constant at 00C and it absorbs latent heat of
fusion and converts completely into water at 00C.
On further addition of heat, the temperature of water starts rising until it reaches the boiling
temperature or saturation temperature corresponding to pressure P. This heat absorbed by water in
sensible heat.
After the boiling temperature is reached, it remains constant with further addition of heat and
vaporization take place. The water absorbs its latent heat and converts into dry saturated steam
remaining at same saturation temperature. The intermediate stage of water and dry saturated steam
is wet steam, which is actually a mixture of steam and water.
If further the heat is added, the temperature of this dry saturated steam starts rising from saturation
temperature and it converts into superheated steam. This heat absorbed is again the sensible heat.
The total rise in temperature of superheated steam above the saturation temperature is called
degree of superheat. We must know here that the saturation temperature, latent heat and other
properties of steam remain same at constant pressure but varies with the variation of pressure.
2) The temperature of superheated steam being higher, it gives a high thermal efficiency in
heat engine.
3) It has high heat content and so high capacity of doing work. Thus it results in an economy
in steam consumption.
To find out the total heat content or enthalpy of any state of water/ steam we have to add all types
of heat added i.e., sensible and latent to convert the water to that state starting from some initial
state or datum which is assumed as a zero enthalpy point or where the heat content is taken as
zero. Generally in engineering calculations the datum is water at 00C where it is considered as
having zero heat content or zero enthalpy. Enthalpy of one kg of water or steam is called as specific
enthalpy.
It is simply the amount of heat required to raise the temperature of one kg of water from 0 ℃ to its
actual temperature which is below its saturation temperature. It can be calculated by multiplying
actual temperature of unsaturated water with its specific heat which is considered equal to 4.187
kJ/ kg/ K. It is denoted as hw.