Class 11th JEE

MRJM/11 Milestone Test-03 Phase-1

DATE: 07/07/2024

ANSWER KEY

PHYSICS CHEMISTRY MATHEMATICS

1. (2) 31. (3) 61. (2)
2. (1) 32. (3) 62. (4)
3. (2) 33. (4) 63. (1)
4. (3) 34. (2) 64. (3)
5. (3) 35. (4) 65. (2)
6. (1) 36. (1) 66. (1)
7. (1) 37. (1) 67. (4)
8. (1) 38. (2) 68. (4)
9. (3) 39. (4) 69. (2)
10. (2) 40. (1) 70. (1)
11. (4) 41. (3) 71. (3)
12. (3) 42. (3) 72. (1)
13. (3) 43. (4) 73. (3)
14. (2) 44. (4) 74. (1)
15. (2) 45. (2) 75. (1)
16. (1) 46. (4) 76. (2)
17. (3) 47. (1) 77. (4)
18. (4) 48. (1) 78. (3)
19. (1) 49. (2) 79. (1)
20. (3) 50. (2) 80. (1)
21. (26) 51. (1) 81. (0)
22. (10) 52. (32) 82. (20)
23. (45) 53. (110) 83. (1)
24. (40) 54. (72) 84. (19)
25. (5) 55. (18) 85. (26)
26. (8) 56. (3) 86. (2)
27. (100) 57. (10) 87. (1)
28. (5) 58. (4) 88. (3)
29. (750) 59. (55) 89. (7)
30. (6) 60. (4) 90. (4)
 SECTION-I (PHYSICS)
1. (2) 7. (1)
6
6 6
t  55 1 2
( )
2
5 2 From S= ut +
∆
=s ∫ vdt
5
= ∫ 5t =
dt
5
5 = 
 2 5 2
6 − 52 =
2
m
2
at

1 1
=
S1 a ( p − 1) 2 and S2 = ap 2 [As u = 0]
2. (1) 2 2
displacement a
From Sn = u + (2n − 1)
1 1 2
= × 7 × 6 + × 3(−6) = 21 – 9 = 12 m
2 2 a
S 2 = 2( p 2 − p + 1) − 1
Distance ( p − p +1) th 2 
1  1 a 2
=  × 7 × 6  + × 3 × ( −6) = 21 + 9 = 30 m = 2 p − 2 p + 1
2  2 2 
th= S1 + S 2
30 5 It is clear that S 2
Ratio = = = 2.5 ( p − p +1)
12 2
8. (1)
3. (2) Let initial (t = 0) velocity of particle = u For first 5
v= t 2 − t sec motion s5 = 10 metre
v = 0 at t = 1, 0 sec 1 1
Hence, s = ut + at 2 ⇒ 10 = 5u + a (5) 2
2 2
1 2 1 2

∫ ∫ ∫ ∫ (t
=S vdt + vdt = (t 2 − t ) dt + 2
− t ) dt 2u + 5a = 4 …(i)
0 1 0 1 For first 8 sec of motion s5 = 20 metre
1
20 = 8u + a (8) 2 ⇒ 2u + 8a = 5
1 2
 t3 t2   t3 t2 
=  −  + −  2
 3 2  0  3 2 1 7 1
By solving u = m/s and a = m/s 2 …(ii)
1 1 8  1 1 6 3
= − +  − 2 −  −  =1 m Now distance travelled by particle in total 10 sec
3 2 3  3 2
1
s10 =u × 10 + a (10) 2
2
4. (3) By substituting the value of u and a we will get
From the graph, we can write s10 = 28.3 m
So the distance in last 2 sec = s10 – s8
= 28.33 –20 = 8.33 m

9. (3)
v = –x + 2 Let man will catch the bus after ‘t’ sec. So he will
dv dx cover distance ut.
a= = − = −v = – (–x + 2) = x – 2 Similarly distance travelled by the bus will be
dt dt
1 2
at . For the given condition
5. (3) 2
1 1 1
a × 12 = 20 + 30 × 1 ut = 45 + at 2 = 45 + 2.5t 2 [As a = 2.5 m/s2]
2 2 2
a = 100 m/sec2 45
⇒ = u + 1.25 t
t
6. (1) To find the minimum value of u
v2 = x + 10 du
vdv 1 = 0 , so we get t = 6 sec. then
= dt
dx 2 45
1 u= + 1.25 × 6 = 7.5 + 7.5 = 15 m/s
a = m/sec2 6
2
 10. (2)
Let car B catches, car A after ‘t’ sec, then
1
60t + 2.5= 70t − × 20 × t 2
2
⇒ 10t – 10t + + 2.5 = 0
2

⇒ t2 – t + 0.25 = 0
for path AB: v2 = 0 + 2gh …(i)
1 ± 1 − 4 × (0.25)
=∴ t = 1 hr for path AC: (2v)2 = 0 + 2gx
2 2
4v2 = 2gx …(ii)
Solving (i) and (ii) x = 4h
11. (4)
As v2 = u2 + 2as ⇒ (2u)2 = u2 + 2as ⇒ 2as = 3u2 15. (2)
Now, after covering an additional distance s, if v (3 sec) = 200 – 10 ×3 = 170 m/sec
velocity becomes v, then v (5 sec) = 200 – 10 × 5= 150 m/sec
v2 = u2 + 2a(2s) = u2 + 4as = u2 + 6u2 = 7u2 170 17
Ratio = =
∴ v = 7u 150 15

12. (3) 16. (1)

Since direction of v is opposite to the direction of g When two particles moves towards each other then
and h so from equation of motion v 1 + v2 = 6
1 When these particles moves in the same direction
h= −vt + gt 2 then
2
v 1 – v2 = 4
⇒ gt – 2vt – 2h = 0
2
By solving v1 = 5 and v2 = 1 m/s
2v ± 4v 2 + 8 gh
⇒ t=
2g 17. (3)
v 2 gh  =
(20) 2 1
+ × 10 ×=
12 25 m
⇒ t= 1 + 1 + 2 
distance
2 × 10 2
g v 

18. (4)
13. (3) Car comes to rest in 2 s
Let both balls meet at point P after time t.
20 × 20
Hence displacement = = 20 m
2 × 10

19. (1)
Displacement = Summation of all the areas with
sign = (A1) + (–A2) + (A3)
= (2 × 4) + (–2 × 2) + (2 × 2)
1
The distance travelled by ball A, h1 = gt 2
2
1
The distance travelled by ball B, h2= ut − gt 2
2
h1 + h2 = 400 m ⇒ ut = 400,
t = 400/50 = 8 sec
∴ h1 = 320 m and h2 = 80 m ∴ Displacement = 8 m
Distance = Summation of all the areas without sign
14. (2) = |A1| + |–A2| + |A3|
Let at point A initial velocity of body is equal to zero = |8| + |–4| + |4| = 8 + 4 + 4
∴ Distance = 16 m
20. (3) So, vrel. = vC – (–30) = (vC + 30) km/hr.
For upward motion So, the time taken by it to cross the cars A and B
Effective acceleration = –(g + a) d 4 5
t= ⇒ =
and for downward motion vrel 60 vC + 30
Effective acceleration = (g – a) ⇒ vC = 45 km/hr
But both are constants. So the slope of speed-time
graph will be constant. ' 24. (40)
1
21. (26) 5= × at 2
2
u = +8 m/s, a = –4 m/s2 1
v=0 S ' = a (3t ) 2
2
⇒ 0 = 8 – 4t or t = 2 sec
1 
Displacement in first 2 sec S ' = 9  at 2 
2 
1
S1 = 8 × 2 + ⋅ (−4) ⋅ 22 = 8 m = 9 × 5 = 45 m
2 So, in next 2t sec = 45 – 5 = 40 m
Displacement in next 3 sec
1
S2 =0 × 3 + ⋅ (−4) ⋅ 32 =−18 m 25. (5)
2 1
Distance travelled = |S1| + |S2| = 26 m – 25 = 20 t − × 10 × t 2
2
t = 5 sec
22. (10)
Relative velocity of one train w.r.t. other 26. (8)
= 10 + 10 = 20 m/s v = (180 – 16x)1/2
Relative acceleration = 0.3 + 0.2 = 0.5 m/s2 dv dv dx
1 As = a = ⋅
If trains cross each other than from =
s ut + at 2 dt dx dt
2
∴= 1  dx 
As, s = s1 + s2 = 100 + 125 = 225 a (180 − 16 x) −1/2 × ( −16)  
2  dt 
1
⇒ 225 = 20t + × 0.5 × t2 = –8(180 – 16x)–1/2 × v
2
= –8(180 – 16x)–1/2 × (180 – 16x)1/2 = –8 m/s2
⇒ 0.5t2 + 40t – 450 = 0
−40 ± 1600 + 4 × (0.5) × 450
⇒ t= =−40 ± 50 27. (100)
1 The relative velocity of policeman w.r.t. thief
∴ t = 10 sec (Taking +ve value) = 10 – 9 = 1
Time taken by police to catch the thief
23. (45) 100
The two car (say A and B) are moving with same = 100 sec
1
velocity, the relative velocity of one (say B) with
respect to the other A. 28. (5)
  
A ⋅ vBA = vB − v A = v − v = 0 The distance travelled in last second.
so the relative separation between them (= 5 km) g 1
always remains the same. SLast = u + (2t − 1) = × 10(2t − 1) = 5(2t − 1)
2 2
Now if the velocity of car (say C) moving in And distance travelled in first three second,

opposite direction to A and B, is vC relative to 1
SThree = 0 + × 10 × 9 = 45 m
ground then the velocity of car C relative to A and 2
  
= vC − v
B will be vrel. According to problem SLast = SThree

But as v is opposite to vC ⇒ 5(2t – 1) = 45 ⇒ 2t –1 = 9 ⇒ t = 5 sec
29. (750) 30. (6)
Velocity acquired by body in 10 sec dv bt 2
= bt ⇒ dv = bt dt ⇒ v = + K1
v = 0 + 2 × 10 = 20 m/s dt 2
and distance travelled by it in 10 sec At t = 0, v = v0 ⇒ K1 = v0
1 1 2
S1 = × 2 × (10) 2 = 100 m We get= v bt + v0
2 2
Then it moves with constant velocity (20 m/s) for dx 1 2
30 sec Again= bt + v0
dt 2
S2 = 20 × 30 = 600 m 1 bt 2
After that due to retardation (4 m/s2) it stops ⇒ x= + v0t + K 2
2 3
v 2 (20) 2 At t = 0, x = 0 ⇒ K2 = 0
S=
3 = = 50 m
2a 2 × 4 1 3
Total distance travelled S1 + S2 + S3 = 750 m ∴= x bt + v0t
6

SECTION-II (CHEMISTRY)
31. (3) (i.e., group 1)
Electron affinity order for halogens is Cl > F > Br > I.  Element C is a noble gas.
∴ Element B must be a halogen i.e., have
32. (3)
highest electron affinity and element D must be an
Anion (O–) repels the test electron because of
alkali metal and exist in +1 oxidation state.
same charge.
39. (4)
33. (4)
Statement I is incorrect as in any period, the radius
The correct order of ionic radii of these ions is
of the noble gas is largest and not the lowest.
S2− > Cl– > Ca2+ > Sc3+.
Statement II is correct.
34. (2)
40. (1)
Sulphur valence shell is less dense than oxygen.
20Ca, 22Ti, 82Pb, 64Gd

35. (4)
41. (3)
d and f- electrons have a poor shielding effect
In order to belong with the same family, the outer
compared to s and p- electrons.
configuration must be the same
42. (3)
36. (1)
From top to bottom electron affinity decreases.
s-block elements and p-block elements (group 13-
18) are representative elements.
43. (4)
Non-metals are more than metals is the wrong
37. (1)
statement.
As2O3 can react with acid and base both
44. (4)
38. (2) B and Si shows the diagonal relationship.
Given,
Atomic number of element C = Z + 1 45. (2)
(∵ Noble gas belongs to 18 group) Na belongs to IA group and Mg belongs to IIA
Atomic number of element A = Z – 2 group. On moving from left to right in a period,
(i.e., group 16) first ionisation energy increases, thus, IE of Mg is
Atomic number of element B = Z greater than the IE of Na.
(i.e., group 17) IE order
Atomic number of element D = Z + 2 Mg > Na
46. (4) The difference in electronegativity is 2.8,
Group-14 contains metals (Sn, Pb), non-metals therefore, percentage ionic character due to EN
(C) and metalloids (Si, Ge). difference of 2.8 is
= 16 |∆E| + 3.5 |∆E|2 = 72.24%
47. (1)
Antimony is an example of a metalloid. 55. (18)
Electronic configuration of element with atomic
48. (1) number 36, will be
Metals are electropositive in nature. 2 2 6 2 6 10 2 6
= 1s ,2s 2p ,3s 3p 3d ,4s 4p (noble gas)

49. (2) As the last electron is present in p-subshell, hence

The element with atomic no. 105 is Dubnium. In the element will be placed in p-block, 18th group.
IUPAC nomenclature, it is known as Un-nil-
pentium. 56. (3)
Since, the IV th IE is very high, ie, electron is to
50. (2) be removed from stable configuration, thus it has
The physical and chemical properties of elements 3 valence electrons
are periodic functions of their atomic number.
This is the correct statement. 57. (10)
IE + EA
XF = (in eV)
51. (1) 2
Total energy required for the conversion of one 17 + 3
= = 10
Mg atom into Mg 2+
is = IE1 + IE2 2
= 7.646 + 15.035 eV
= 22.681 eV = 2188.6 kJ mol–1 58. (4)
−3 1s 2 , 2s 2 2p6 , 3s 2 3p6 , 4s 2 .
Moles of Mg = 12 × 10
Principal quantum
= 0.5 × 10–3
24 number is 4, so it belongs to 4 period th

∴ –3
The energy required to convert 0.5 × 10 mol
Mg into Mg2+ = 0.5 × 10–3 × 2188.6 59. (55)
= 1.09 ≈ 1 kJ Caesium is the most electropositive element in the
periodic table. Francium is not considered because
52. (32) its half life is very very small.
The sixth period is from Caesium (55) to Radon
(86). Therefore, the sixth period has 32 elements. 60. (4)
The ionisation energy values for valence electrons
53. (110) are comparable to remove electrons from inner
Atomic number of Uun = 110 shell very high amount of energy is needed. In the
given values there is a biggest jump between IE4
54. (72) and IE5. Hence, there are four valence electrons
for the atom X.
 SECTION-III (MATHEMATICS)
61. (2) 1  5 − 1  5 + 1  5
= 1 − 1 +
  =
A
1 + sin A = sin + cos
A 4  4  4   16
2 2
 A A
1 − sin A =  sin − cos  69. (2)
 2 2 m 1
+
A (m + 1) (2m + 1)
1 + sin A + 1 − sin A =
2cos =
tan(α + β) = 1
2  m  1 
1−   
 m + 1  2m + 1 
62. (4)
 87 π   87 π  70. (1)
tan   + cot  
 4   4  Convert to sin and cos and simplify
π π
= − tan − cot =−1 − 1 =−2
4 4 71.
(3)
sin (A + B) = sin A cos B + cos A sin B
63. (1)  3  −12   −4  5  −56
=    +    =
cos(502π) = 1  5  13   5  13  65

64. (3) 72. (1)

− a + b ≤ a sin θ + b cos θ ≤ a + b
2 2 2 2 sin ( 47° ) + cos 77
= 2sin 30° cos17°
65. (2) = cos 17°
sin 3θ
sin θ sin(60° − θ)sin(60° + θ) =
4 73. (3)
cos3θ tan θ + sec θ =
5
cos θ cos(60° − θ) cos(60° + θ) =
4 3
tan θ tan(60° − θ) tan(60° +=
θ) tan 3θ 3
sec θ − tan θ =
5
66. (1) 17 15
⸫ sec θ = , cos θ =
K>0 15 17
2
 15  8
67. (4) ⇒ sin θ= 1−   =
 17  17
 16π 
sin   23
 5  = −1 sin θ + cos θ =
 π  16 17
16sin  
5 74. (1)
We know that
68. (4)  sin (A + B) = sin A cos B + cos A sin B
sin 36° sin 72° sin108° sin144° = sin {(45° + A) + (45° – B)}
= sin 2 36° sin 2 72° = sin (90° + (A – B))

( )( )
1 = cos (A – B)
= 2sin 2 36° 2sin 2 72° 
4  
75. (1)
1
= (1 − cos 72° )(1 − cos144° )  1 3
4 =
tan α =, tan 2 B
7 4
1
= (1 − sin18° )(1 + cos36° )  4 + 21
4 tan(α=
+ β) = 1
28 − 3
76. (2) 82.
(20)
2sin A 1 + sin A − cot A sin ( B − C ) sin B cos C − cos B sin C
= = K =
1 + sin A + cos A 1 + sin A cos B cos C cos B cos C
sin B sin C
= − = tanB – tanC
77.
(4) cos B cos C
1 3  sin ( C − A )
2  sin 80° − cos80° Similarly, = tan C − tan A
2 2  = 4 sin ( 80° − 60° )  cos C cos A
sin 80° cos80° 2sin 80° cos80° sin ( A − B )
And = tan A − tan B
4sin 20° 4sin 20° cos A cos B
== = 4
sin160° sin (180° − 20° ) sin ( B − C ) sin ( C − A ) sin ( A − B )
⸫ + +
cos A cos C cos C cos A cos A cos B
78. (3) = 10(tanB – tanC + tanC – tanA + tanA – tanB)+20
= 20
2 tan θ
sin 2θ =
1 + tan 2 θ 83. (1)
1 − tan θ 2 sin2θ + cos2θ = 1
and cos 2θ =
1 + tan 2 θ
84. (19)
sin25° + sin210° + … sin245° + … sin285° + sin290°
79. (1)
L.H.S. = cos 18° – sin 18° = (sin 2 5° + sin 2 85°) + ...... + (sin 2 ( 40°) + sin 2 50°)
= 2
 1
 2
cos18° –
1
2

sin18° 

= (sin 2 5° + cos2 5°) + ...... + (sin 2 40°) +
2
2 ( sin 45° cos18° − cos 45° sin18° )  1 
 + (1)
= + cos 40° + 
2 2
 2
= 2 ( sin ( 45° − 18° ) )
1 19
= 2 sin 27° = 1
+ 1 + ...... + 1 + + 1 =
8 times 2 2

80. (1)
85. (26)
sin 3θ − cos3θ
+1 Let A = 25sin 2θ+12cos 2θ
sin θ + cos θ ∴−13 ≤ 5sin 2θ + 12cos 2θ ≤ 13
sin 3θ – cos3θ + sin θ + cos θ
= 2−13 ≤ A ≤ 213
sin θ + cos θ
(3sin θ − 4sin3 θ) − ( 4cos3 θ − 3cos θ) + 1 86. (2)
( sin θ + cos θ ) Expression simplifies to 2

 3θ + θ   3θ – θ   θ + 3θ   3θ – θ 
2sin   ⋅ cos   + 2sin   sin  ⋅ 87. (1)
=  2   2   2   2 
sin θ + cos θ cos 2 A + cos 2 B + cos 2 C
2sin 2θ.cos θ + 2sin 2θ ⋅ sin θ 1 + cos 2 A 1 + cos 2 B
= 2sin 2θ = + + cos 2 C
sin θ + cos θ 2 2
1
= 1 + ( cos 2 A + cos 2 B ) + cos 2 C
81. (0) 2
sin θ + sin ( π + θ) + sin (2π + θ) + sin (3π + θ) + 2
= 1 + cos ( A + B ) cos ( A − B )  + cos 2 C
… + sin (2023π + θ) 2
sin θ + (– sin θ) + (sin θ) + (– sin θ) + ... + ... = 1 + cos C cos ( A − B ) + cos C cos ( A + B )
  
Ist pair IInd pair
=1 + cos C cos ( A − B ) + cos ( A + B ) 
+ (sin θ) + (– sin θ)
 = 1 + 2cos C cos B cos A
⇒ cos 2 A + cos 2 B + cos 2 C
+ 0 + 0 + ... + 0 =
= 0 0
−2cos A cos B cos C = 1
88. (3) ⇒ t 2 + 4t − 1 =0 ⇒ t =−2 + 5
8
tan α + 2 tan 2α + 4 tan 4α +  2 x 
tan 8α =
 t tan 2 > 0 

= tan α + 2 tan 2α + 4 tan 4α +

(
4 1 − tan 2 4α )
tan 4α
90. (4)
 2 tan θ 
 tan 2θ =1 − tan 2 θ 
Given equation can be written as
 π  7 π  3π  5π 
1 + cos 1 + cos 1 + cos 1 + cos 
4 tan 2 4α + 4 − 4 tan 2 4α  8  8  8  8 
= tan α + 2 tan 2α +
tan 4α  π 7π π 7π 
=+
1 cos + cos + cos cos 
= tan α + 2 tan 2α +
(
4 1 − tan 2α 2
)  8 8 8 8 
2 tan 2α  3π 5π 3π 5π 
1 + cos + cos + cos cos 
2 tan 2α + 2 − 2 tan 2 2α
2  8 8 8 8 
= tan α + π π π 7π 
tan 2α 
=+
1 cos − cos + cos cos 

= tan α +
(
2 1 − tan 2 α ) 

8 8
5π
8
5π
8 
3π 5π 
2 tan α 1 − cos + cos + cos cos 
 8 8 8 8 
tan α + 1 − tan 2 α
2
1
= = = cot α  π 7 π  3π 5π 
tan α tan α =
1 + cos cos 1 + cos cos 
 8 8  8 8 
1 π 7 π  3π 5π 
89. (7) = 2 + 2cos cos  2 + 2cos cos 
We have, 4 8 8  8 8 
x 1 3π  π 
=tan cosec x − sin x =  2 + cos + cos π  2 + cos cos π 
2 4 4  4 
x x 1 3π  π
1 + tan 2 2 tan =
x 2− 2 1 + cos 1 + cos 
⇒ tan= 4 4  4
2 x 2 x
2 tan 1 + tan 1 π  π
2 2 =−
1 cos 1 + cos 
x 4 4  4
⇒ 2t (1 + t ) = (1 − t ) , where t = tan 2
2
2 1 2 π 1 1 1
= 1 − cos  = 1 −  =
4 4 4 2 8

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