Index Volume % Temp D86 Temp D86 TBP TBP TBP

number, i distilled a b o
C o
F o
R o
F o
C
1 0 0.9167 1.0019 36.5 97.7 517.4 57.4 14.1
2 10 0.5277 1.09 54 129.2 552 92 33.3
3 30 0.7429 1.0425 77 170.6 616.1 156.1 68.9
4 50 0.892 1.0176 101.5 214.7 674.9 214.9 101.6
5 70 0.8705 1.0226 131 267.8 735.3 275.3 135.2
6 90 0.949 1.011 171 339.8 816.9 356.9 180.5
7 95 0.8008 1.0355 186.5 367.7 841.4 381.4 194.1

250

200
f(x) = 1.102873553437E-06 x⁴ − 7.8398876832247E-05 x³ − 0.003228251188843 x² + 1.96633880965716 x
+ 14.0719284716821
R² = 0.99998822367002
150

Column I
Polynomial (Column I)
100

50

0
0 10 20 30 40 50 60 70 80 90 100
 250
Figure 3- x. Conversion of ASTM D86 to TBP

200
f(x) = 0.0000011028735534 x⁴ − 0.0000783988768322 x³ − 0.0032282511888 x² + 1.9663388096572 x
+ 14.071928471682
R² = 0.99998822367002

33880965716 x
150
Temperature, oC

ASTM D86
TBP(API method)
Column I Polynomial (TBP(API method
100
Polynomial (Column I)

50

0
0 10 20 30 40 50 60 70 80 90 100
Volume % distilled
BP

2511888 x² + 1.9663388096572 x

ASTM D86
TBP(API method)
Polynomial (TBP(API method))

90 100
 Index Volume % Temp D86 Temp D86 ΔT ΔT' TBP TBP
number, i distilled Ai Bi o
C o
F o
F o
F o
C
1 0 7.4012 0.6024 36.5 97.7 31.5 59.14 22.42 -5.32
2 10 4.9004 0.7164 54 129.2 41.4 70.57 81.56 27.53
3 30 3.0305 0.8008 77 170.6 44.1 62.86 152.13 66.74
4 50 0.8718 1.0258 101.5 214.7 0 214.99 101.66
5 70 2.5282 0.82 131 267.8 53.1 65.67 280.66 138.14
6 90 3.0419 0.775 171 339.8 72 83.67 364.33 184.63
7 95 0.118 1.6606 186.5 367.7 27.9 29.68 394.01 201.12

Volume average boiling point (VABP)

AVBP= 224.42 oF 106.9 o

C

SL = (T90-T10)/(90-10) 2.6325

ln Δ = -0.94402-0.00865(VABP-32)^0.6667+2.99791SL^0.333

Δ = EXP(-0.94402-0.00865(VABP-32)^0.6667+2.99791SL^0.333)

Δ 18.27523

Mean average boiling point (MeABP)

MeABP 206.1448 oF 96.75 o

C

o
API 62

Specific gravity 0.731

Watson characterization factor K 11.92

100
f(x) = 4.85902825E-09 x⁴ − 0.0000
+ 1.38511964627
90 R² = 0.999762340788044
80

70

60

50

40

30

20

10

0
23.5 73.5 123.5 173.5 223

100
f(x) = 0
R² = 0

80

60
80

60

40

20

0
23.5 73.5
 250

200
f(x) = − 0.000001716191715 x⁴ + 0.000562376991 x³ − 0.0526278861005 x² + 3.55181524429 x
Temperature, oC

− 4.700827074291
R² = 0.999764471540114
150

ASTM D86
100 TBP(Daubert's method)
Polynomial
(TBP(Daubert's
method))
50

0
0 10 20 30 40 50 60 70 80 90 100

-50

Volume % distilled

450

400
f(x) = − 0.000003095074143 x⁴ + 0.0010133118103 x³ − 0.094786443638 x² + 6.3943090316304 x
+ 23.535802739961
350 R² = 0.99976389473403

300

250
Column I
Power (Column I)
200 Polynomial (Column I)

150

100

50

0
0 10 20 30 40 50 60 70 80 90 100
 4.85902825E-09 x⁴ − 0.00000616813319 x³ + 0.0024298683905 x² − 0.056862920094 x
38511964627
.999762340788044

Column V
Polynomial (Column V)

73.5 123.5 173.5 223.5 273.5 323.5 373.5 423.5

100
f(x) = 0
R² = 0

80

60

Column W
80

60

Column W
Polynomial (Column W)
40

20

0
23.5 73.5 123.5 173.5 223.5 273.5 323.5 373.5 423.5
 This table is generated from polynomial fit of vol % .vs. TBP

Vol % TBP, oF Sp.Gr. o

API TBP, oF Vol %
0 23.536 0.645038 87.86694 23.536 1.298674
5181524429 x 2 35.95335 0.650458 86.03905 48.536 3.618903
4 47.65963 0.655485 84.37071 73.536 7.939319
6 58.70111 0.660156 82.84336 98.536 13.81186
8 69.12291 0.664504 81.44087 123.536 20.83535
10 78.969 0.668559 80.14921 148.536 28.65548
M D86
Daubert's method)
12 88.28219 0.67235 78.95601 173.536 36.96482
nomial 14 97.10415 0.6759 77.85035 198.536 45.50281
(Daubert's 16 105.4754 0.679235 76.8225 223.536 54.05576
hod))
18 113.4353 0.682376 75.86375 248.536 62.45687
20 121.022 0.685342 74.96629 273.536 70.58621
22 128.2726 0.688153 74.12302 298.536 78.37072
24 135.2231 0.690825 73.32755 323.536 85.78421
26 141.9081 0.693376 72.57403 348.536 92.84739
28 148.3612 0.69582 71.85712 373.536 99.62781
30 154.615 0.698173 71.17195 398.536 106.2399
32 160.7007 0.700446 70.51404 423.536 112.845
34 166.6484 0.702654 69.87929 441.5 117.7015
36 172.4872 0.704808 69.2639 464 124.0717
38 178.2448 0.706919 68.66442
40 183.948 0.708997 68.07766
43090316304 x
42 189.6223 0.711053 67.50069
44 195.2921 0.713095 66.93084
46 200.9806 0.715132 66.36565
48 206.71 0.717171 65.80292
50 212.501 0.719221 65.24062
Column I 52 218.3736 0.721288 64.67694
Power (Column I) 54 224.3462 0.723377 64.11027
Polynomial (Column I) 56 230.4365 0.725495 63.53918
58 236.6607 0.727647 62.96241
60 243.034 0.729837 62.37888
62 249.5704 0.732069 61.78769
64 256.2828 0.734348 61.18806
66 263.1828 0.736674 60.57942
68 270.2811 0.739053 59.96129
70 277.587 0.741485 59.33337
72 285.1088 0.743971 58.69548
74 292.8537 0.746514 58.04756
76 300.8275 0.749114 57.38969
78 309.035 0.751772 56.72204
80 317.48 0.754486 56.0449
 82 326.1649 0.757257 55.35865
84 335.091 0.760083 54.66376
86 344.2586 0.762964 53.9608
88 353.6666 0.765898 53.25039
90 363.313 0.768883 52.53323
92 373.1945 0.771916 51.8101
94 383.3067 0.774995 51.08179
96 393.644 0.778117 50.34918
98 404.1998 0.781279 49.61317
100 414.966 0.784478 48.87469

Cut distribution of Straight Run Products

Cut, End Point Cum. Vol %

oF vol %. of cut
1 Off gas 50 3.82135 3.82135
2 Lt St. Run 158 31.758634 31.758634
3 Naphtha 356 94.897072 63.138438
4 Kerosene 464 100 5.1029275
5 Light Diesel 554 100 0
6 Heavy Diesel 644 100 0
7 Atmos Gas oil 698 100 0
Residue

103.82135
 Index Volume % Temp D86 Temp D86 ΔT ΔT' TBP TBP
number, i distilled Ai Bi o
C o
F o
F o
F o
C
1 0 7.4012 0.6024 138 280.4 20.88 46.16 228.76 109.31
2 10 4.9004 0.7164 149.6 301.28 16.56 36.61 274.92 134.96
3 30 3.0305 0.8008 158.8 317.84 12.6 23.05 311.53 155.29
4 50 0.8718 1.0258 165.8 330.44 0 334.58 168.1
5 70 2.5282 0.82 169.9 337.82 7.38 13.02 347.6 175.33
6 90 3.0419 0.775 178.1 352.58 14.76 24.5 372.1 188.94
7 95 0.118 1.6606 180.4 356.72 4.14 1.25 373.35 189.64
100 199.72 391.5 205.19

Volume average boiling point (VABP)

Volume %
AVBP= 327.992 oF 164.44 o
C distilled
0
SL = (T90-T10)/(90-10) 0.64125 10
30
ln Δ = -0.94402-0.00865(VABP-32)^0.6667+2.99791SL^0.333 50
70
Δ = EXP(-0.94402-0.00865(VABP-32)^0.6667+2.99791SL^0.333) 90
95
Δ 3.515312

Mean average boiling point (MeABP)

MeABP 324.4767 oF 162.49 o

C

o
API 45.2

Specific gravity 0.801

Watson characterization factor K 11.49

190
f(x) = 2.8378915042E-07 x⁴ + 0.0001884958432 x³ − 0.0377848486879 x² + 2.5274321081551 x +
R² = 0.993047625546588
180

170
190
f(x) = 2.8378915042E-07 x⁴ + 0.0001884958432 x³ − 0.0377848486879 x² + 2.5274321081551 x +
R² = 0.993047625546588
180

170

160

150

140

130

120

110

100
0 10 20 30 40 50 60 70 80 90 100
 This table is generated from polynomial fit of vol % .vs. TBP

Vol % TBP.oC TBP,oF Sp.Gr. o

API
0 109.65 229.37 0.752262 56.5993
2 115.5433 239.978 0.756063 55.65379
4 120.8934 249.6081 0.75948 54.81179
6 125.741 258.3338 0.762549 54.06189
8 130.1256 266.2261 0.765303 53.39397
10 134.085 273.353 0.767774 52.79907
12 137.6555 279.7798 0.769988 52.26917
14 140.8717 285.5691 0.771971 51.79704
16 143.7671 290.7807 0.773748 51.37618
18 146.3731 295.4716 0.77534 51.00068
TBP Temp D86 20 148.72 299.696 0.776768 50.66516
o
C o
C 22 150.8364 303.5055 0.778051 50.36472
109.31 138 24 152.7493 306.9487 0.779207 50.09487
134.96 149.6 26 154.4843 310.0717 0.780253 49.85151
155.29 158.8 28 156.0654 312.9177 0.781203 49.63088
168.1 165.8 30 157.515 315.527 0.782072 49.42954
175.33 169.9 32 158.8541 317.9374 0.782874 49.24435
188.94 178.1 34 160.1021 320.1837 0.783619 49.07245
189.64 180.4 36 161.2767 322.2981 0.784319 48.91125
38 162.3945 324.31 0.784984 48.7584
40 163.47 326.246 0.785623 48.61181
42 164.5166 328.1299 0.786244 48.46962
44 165.546 329.9828 0.786853 48.33021
46 166.5684 331.8231 0.787458 48.19218
48 167.5923 333.6662 0.788062 48.05436
50 168.625 335.525 0.788671 47.91581
52 169.6719 337.4095 0.789287 47.77577
54 170.7372 339.3269 0.789913 47.63374
56 171.8232 341.2818 0.79055 47.48941
58 172.931 343.2758 0.791198 47.34266
60 174.06 345.308 0.791858 47.1936
62 175.2081 347.3745 0.792528 47.04254
64 176.3715 349.4688 0.793206 46.88997
66 177.5453 351.5815 0.793889 46.73659
68 178.7225 353.7005 0.794572 46.58328
70 179.895 355.811 0.795252 46.43112
72 181.053 357.8954 0.795921 46.28136
74 182.1851 359.9332 0.796575 46.13542
79 x² + 2.5274321081551 x + 110.55141187919 76 183.2785 361.9013 0.797206 45.99494
78 184.3188 363.7738 0.797805 45.8617
79 x² + 2.5274321081551 x + 110.55141187919

80 185.29 365.522 0.798363 45.73766

82 186.1747 367.1145 0.798871 45.62498
84 186.9539 368.5169 0.799318 45.52598
86 187.6069 369.6925 0.799692 45.44317
Column E 88 188.1119 370.6013 0.799981 45.37926
Column J 90 188.445 371.201 0.800171 45.33713
Polynomial 92 188.5812 371.4462 0.800249 45.31992
(Column J)
94 188.4938 371.2889 0.800199 45.33097
96 188.1546 370.6782 0.800005 45.37385
98 187.5337 369.5607 0.79965 45.45245
100 186.6 367.88 0.799115 45.57091

80 90 100