Final XI-IIT-IC & IR - CTA-02 - 30-09-2024 - QP
Final XI-IIT-IC & IR - CTA-02 - 30-09-2024 - QP
Total 18 62
CHEMISTRY :
+Ve –Ve No.of Total
Section Question Type
Marks Marks Qs. marks
Sec – I
Questions with Single Correct Choice 3 –1 4 12
(Q.N : 19 – 22)
Sec – II AS PER
Questions with Multiple Correct Choice 8 32
(Q.N : 23 – 30) INSTRUCTIONS
Total 18 62
MATHEMATICS:
+Ve –Ve No.of Total
Section Question Type
Marks Marks Qs. marks
Sec – I
Questions with Single Correct Choice 3 –1 4 12
(Q.N : 37 – 40)
Sec – II AS PER
Questions with Multiple Correct Choice 8 32
(Q.N : 41 – 48) INSTRUCTIONS
Total 18 62
XI-IIT-IC & IR_CTA-02_30-09-2024
Exam Syllabus
80% : River- swimmer problems, Rain man problems, Relative projectile motion Kinematics of Circular Motion in a
plane, Newton's Laws of Motion Equilibrium of Particles Pulley mass system, Pseudo force, Constraint relations
Introduction to Friction, Friction force in simple cases, angle of repose, angle of friction Multiple block system with
friction Dynamics of circular motion Work done by constant and variable force Work energy theorem, Conservation
of mechanical energy Motion in a vertical circle Location of centre of mass Motion of centre of mass Linear
momentum, Impulse, Conservation of linear momentum
20% : MATHEMATICAL PHYSICS : Application of differentiation in physics, Maxima & Minima Integration and its
application in physics
PHYSICS
Unit and Dimension : Introduction of physics, physical quantities and physical laws Fundamental and derived
quantities and ways to write dimension, Unit and Dimension Uses of dimensional analysis (Principle of homogeneity)
Unit and Dimension : Significant figures, Errors in measurements Problems discussion from material KINEMATICS :
Frame of Reference , Mathematical Expression and definition of position, distance and displacement Avg velocity&
instantaneous velocity, Avg speed & instantaneous speed, acceleration KINEMATICS : Uniformly accelerated motion
(1D) Motion under gravity Graphs, Motion under variable acceleration, Motion in a plane, Oblique projectile motion
Horizontal Projectile Motion Projectile motion from tower Practice on oblique and horizontal projectile motion
Projectile motion in inclined plane Relative Velocity, Closest distance of approach
80% : Quantum numbers, Introduction of wave mechanical model of atom (ψ,ψ2), Shape of orbitals Radial probability
graphs for various orbitals Aufbau principle, Pauli's exclusion principle, Hund's rule of maximum mulitplicity Electronic
configuration, Electronic configuration of Half-filled and full-filled orbitals Modern periodic law and prediction of
periodic table, IUPAC naming of element (Z > 100), Location of element by using atomic number and vice versa
Periodic properties: atomic and ionic size including screening effect ionization enthalpy, electron affinity and electron
gain enthalpy. Anomalous behaviour of 2nd period elements Types of bond ionic, covalent and coordinate covalent,
properties of ionic compounds, VBT (including types of overlaping sigma and pie bonds), Fajans Rule Hybridisation
VSEPR Theory, Dipole moment Molecular orbital theory, shape of molecular orbitals, bond order of diatomic
molecules, calculation of bond order from resonance, hydrogen bonding.
20% : Nature of Matter, Properties of matter & their measurement SI unit, Mass weight, Volume temperature, Need
for standard reference, Scientific notation, Precision & accuracy, Significant figure and calculation involving significant
figure. Law of chemical combination : (i) Law of conservation of mass, (ii) Law of constant combination, (iii) Law of
CHEMIST multiple proportion, (v) Gay Lussac's law, (vi) Avagdro law, (vii) Dalton's atomic theory Atomic mass Mole concept:
RY Calculation based on mole concept, concept of gram atom, gram molecule Percentage by mass (w/w), percentage by
volume (v/v) ,Concentration terms: Molarity, molality, mole fraction and their interconversions, relation between
density & molarity , Concentration terms & their interconversions, relation between density & molarity Question
practice on concentration Concept of limiting reagent : Use of stoichiometry in balanced equation & limiting reagent
concept Percentage calculation of elements, Formula representation of molecule : (i) Empirical formula, (ii) Molecular
formula, (iii) Formula unit n-factor of acid, base and salts equivalent weight & related numericals (excluding redox),
Normality and equivalent concept, calculation based on weight-weight relation, weight-volume relation, volume-
volume relation (Excluding redox and double titration), Relation between normality and molarity, percentage of free
SO3 in oleum, Volume strength of H2O2, hardness of water (ppm), Practice questions and Package Discussion (i)Basic
discovery of subatomic particles (Cathode rays, anode rays, Chadwick experiment), (ii) Rutherford experiment i)
Introduction to electromagnetic wave, (ii) Principle of quantization (Planck theory), (iii) Black body radiation, (iv)
Photoelectric effect Bohr's Atomic Model with mathematical derivations Emission and Absorption Spectrum,
Hydrogen spectrum (i)Dual Behaviour of matter, (ii) de-broglie equation, Heisenberg's principle of Uncertainity
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80% : Binomial theorem Introduction: Notation of factorial and definition of C(n, r) and P(n, r) Pascal triangle,
Binomial theorem for a positive integer index, Some special forms of binomial theorem. Problem based on direct
expansion, General term in the expansion of (a + x)n, middle term in the expansion of (a + x)n Greatest binomial
coefficient, numerically greatest term in the binomial expansion. properties of Binomial coefficients, Binomial series.
Straight Line Introduction, distance formula, section formula, area of triangle. Definitions of centroid, circumcentre
and orthocentre of triangle Collinearly of three points, slope of line, various forms of line, locus of a point. Position of
two points relative to a line, Angle between two lines, condition for two lines to be parallel and perpendicular
Perpendicular distance of a point from a line, distance between two parallel lines, foot of perpendicular, Image of point
w.r.t a line. Condition of concurrency for three lines, Family of lines. Equation of bisectors Transformation of axes,
General equation second degree, homogenaous equation of second degree Angle between lines , nature of pair of lines,
homogenious concept,
20% : SEQUENCE AND SERIES Introduction of Sequence and Series, nth term of AP. Properties of A.P. ,Sum of n
term of an AP, Arithmetic Mean, nth term of G.P., sum of n term of GP. Properties of G.P., Geometric mean, A.G.P.
MATHE
Introduction to HP, HM, Relation between AM, GM and HM, Difference method, Vn method, special series
MATICS TRIGONOMETRIC FUNCTIONS Angle, system of measurement of angles, trigonometric function, Values of
trigonometric function for some specific angles , Trigonometric ratios of allied angles, Transforming product into sum
or difference, Transforming the sum or difference into product. Domain and ranges of trigonometric function, Graph
of trigonometric functions. Trigonometric ratio of multiple angles, submultiple angles. maximum and minimum value
of trignometric expressions, anaylsis of the form y=asinx+bcosx., conditional identities, sum of Trigonometric series.
TRIGONOMETRIC EQUATIONS: Types of trigonometric equation, Principal value, General solution of basic
trigonometric equation. Solution by reducing trigonometric equations to algebraic one's, solution of the form acos x +
bsin x = c Problems involving more than one equation, equation containing more than one variable. Equation containing
different functions and variables , Trigonometric Inequalities. Quadratic Equations Introduction, nature of roots of
quadratic equations ax2 + bx+ c= 0, Relation between roots of an equation., Transformation of equation, Condition for
common roots of quadratic equations. Quadratic expression y = ax2 + bx + c, sign of quadratic expression., maximum
and minimum value of quadratic equations Location of roots, Descartes rule of signs, Quadratic expression in two
variables Theory of Equations
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1. Figure shows a block kept on a rough inclined plane. The maximum external force down the incline
for which the block remains at rest is 1 N while the maximum external force up the incline for
which the block is at rest is 7 N. The coefficient of static friction is
√
A) B) C) √3 D)
√ √
2. The masses of 10 kg and 20 kg respectively are connected by a massless spring as shown in figure.
A force of 200 N acts on the 20 kg mass. At the instant shown, the 10 kg mass has acceleration 12
m/sec2. What is the acceleration of 20 kg mass? (All surfaces are smooth)
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3. An object is projected with a velocity of 20 m/s making an angle of 45o with horizontal under
gravity. The equation for the trajectory is ℎ = − where h is height, x is horizontal distance,
A and B are constants. The ratio A:B is ( = 10 )
A) 1:5 B) 5:1 C) 1:40 D) 40:1
4. Two blocks of masses 2 kg and 1 kg respectively are tied to the ends of a strings which passes over
a light frictionless pulley. The masses are held at rest at the same horizontal level and then released.
The distance traversed by centre of mass in 2 second is ( = 10 / )
A) 1.42 m B) 2.22 m C) 3.12 m D) 3.33 m
SECTION-II
(ONE OR MORE THAN ONE CORRECT ANSWER)
This section contains 8 questions. The answer to each question is multiple choice. The question will be evaluated
according to the following marking scheme:
Full Marks: +4 (If the answer is correct)
Partial Marks: +3 (If all the four options are correct but only 3 are chosen)
Partial Marks: +2 (If THREE or More options are correct but only 2 correct answers are chosen)
Partial Marks: +1 (If TWO or More options are correct but only 1 correct answer is chosen)
Zero Marks: 0 (If the question is unanswered)
Negative Marks: -1 (In all other cases)
5. A single conservative force ( ) acts on a particle that moves along the x-axis. The graph of the
potential energy with x is given. At x = 5 m, the particle has a kinetic energy of 50 J and its potential
energy is related to position ‘x’ as = 15 + ( − 3) Joule, where x is in meter. Then
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6. Figure shows two blocks A and B connected to an ideal pulley string system. In this system when
bodies are released then (neglect friction and take g = 10 m/s2)
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8. In the arrangement shown in figure, coefficient of friction between the two block is = and the
ground is smooth. A constant horizontal force = 20 is applied on the 4 kg block. The 2 kg block
is being pulled by a stationary man using a horizontal string with a force of .
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A) ℎ =ℎ B) − = C) − = D) − =
11. A wave is propagating along x-axis in medium, so that displacement y of particle at any position x, at
any time t is given by
=
Where a, b and c are constants. Choose the correct option(s).
A) Dimension of b is [T] B) Dimension of a is [LT2]
A) =2 B) tan =
C) exp − = D) =
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SECTION-III
(Numerical Value Answer Type)
This section contains 6 questions. The answer to each question is a Numerical value. If the Answer is in the decimals,
Mark the nearest Integer only. The question will be evaluated according to the following marking scheme:
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
13. A block of mass 0.18 kg is attached to a spring of force constant 2 N/m. The coefficient of friction
between the block and the floor is 0.1. Initially the block is at rest and the spring is unstretched. An
impulse is given to the block as shown in the figure. The block slides a distance of 0.06 m and comes
to rest for the first time. The initial velocity of the block in m/s is = . Then N is
14. A chain has 48 links of equal masses. It has been placed on an incline with a part of it hanging
vertically. The inclination angle of the incline is = sin and coefficient of friction between the
chain and the incline is = 1.0. When the chain is released its initial acceleration is found to be .
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15. A block is lying on a long horizontal conveyer belt moving at a constant velocity. It is given a velocity
v = 5 ms-1 relative to ground in a direction opposite to the direction of motion of conveyer. After
t = 4s as the velocity of block becomes equal to the velocity of the belt. If = 0.2, find velocity of
the belt (in m/s)
16. A man with some passengers in his boat starts to row perpendicular to a river 200m wide which is
flowing at 2 ms-1. Speed of boat in still water is 4 ms-1. When he reaches half the width of river (at
C), the passengers told him that they want to reach the just opposite end (at B) from where they had
started (at A). If is the angle from line CB of the direction due to which he must row to reach the
required end, then find the value of (1/ tan ).
17. Two balls fall freely from different heights and reach the ground simultaneously. The time of descent
for the first body is = 2 and for the second it is = 1 . At what height was the first ball situated
when the other began to fall? (in m) (Take = 10 / ).
18. Two blocks A and B of masses m and 2m placed on smooth horizontal surface are connected with a
light spring. The two blocks are given velocities as shown when spring is at natural length.
If =2 , =2 / = 300 / then find the maximum extension in the spring (in m).
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A) → B) → C) → D) →
20. In which of the following pairs, both the species have the same hybridisation?
(I) , (II) , (III) , (IV) ,
A) I, II B) II, III C) II, IV D) I, II, III
21. 1 M HCl and 2 M HCl are mixed in volume ratio of 4:1. What is the final molarity of HCl solution?
22. The ratio of velocity of the electron in the third and fifth orbit of Li2+ would be :
SECTION-II
(ONE OR MORE THAN ONE CORRECT ANSWER)
This section contains 8 questions. The answer to each question is a Numerical value. If the Answer is in the decimals,
Mark the nearest Integer only. The question will be evaluated according to the following marking scheme:
Full Marks: +4 (If the answer is correct)
Partial Marks: +3 (If all the four options are correct but only 3 are chosen)
Partial Marks: +2 (If THREE or More options are correct but only 2 correct answers are chosen)
Partial Marks: +1 (If TWO or More options are correct but only 1 correct answer is chosen)
Zero Marks: 0 (If the question is unanswered)
Negative Marks: -1 (In all other cases)
23. Which of the following match is/are correct regarding B, Al, C and S elements?
A) The highest first ionisation enthalpy : C B) The largest atomic size : Al
C) The most negative electron gain enthalpy : C D) The most metallic character : Al
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28. For radial probability curves, which of the following is/are correct?
A) The number of maxima in 2s orbital are two B) The number of spherical or radial nodes
is equal to n – l – 1
C) The number of angular nodes are ‘l’ D) 3 has 3 angular nodes
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A) B)
C) D)
A) 0.5 B) C) D) 2.5
.
SECTION-III
(Numerical Value Answer Type)
This section contains 6 questions. The answer to each question is a Numerical value. If the Answer is in the decimals, Mark
the nearest Integer only. The question will be evaluated according to the following marking scheme:
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
31. How many pairs are, in which first species has lower ionisation energy than second species:
(i) N and O (ii) Br and K (iii) Be and B (iv) I and I- (v) Li and Li+ (vi) O and S
(vii) Ba and Sr
32. Calculate value of , here is O – N – O bond angle in Y is O – N – O bond angle in
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34. One commercial system removes SO2 emission from smoke at 95°C by the following set of
reaction:
( )+ ( )→ ( )
( )+ ( )→ +
+ ( ) → +
Grams of that may be produced from 3.78 g are.
35. In a sample of excited hydrogen atoms electrons make transition from n = 2 to n = 1. Emitted quanta
strike on a metal of work function ( ) 4.2eV.
Calculate the wavelength (in Å) associated with ejected electrons having maximum kinetic energy
36. Find out the difference in number of angular nodes and number of radial nodes in the orbital to which
last electron of chromium present.
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37. Let (1,0), (−1,0) and (0,2) be the vertices of ∆ . Then all the values of parameter for
which the point ( , ) lies outside the triangle ABC but lies inside the circumcircle of triangle
ABC, lie in the interval
A) √
,
√ B) √
,0 ∪ ,
√
C) √
, 0 ∪ 0, D) 0,
40. The real numbers , , satisfying the equation − + + = 0, are in A.P., then the
intervals in which and lie, are
A) −∞, , − ,∞ B) − , ∞ , −∞,
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SECTION-II
(ONE OR MORE THAN ONE CORRECT ANSWER)
This section contains 8 questions. The answer to each question is a Numerical value. If the Answer is in the decimals,
Mark the nearest Integer only. The question will be evaluated according to the following marking scheme:
5 4
42. Find the coefficient of x5 in the expansion of 1 x 2 . 1 x is .
A) 60 B) 80
C) 40 D) 100
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A) 5 + 6 = 0 B) 6 − 5 = 56
C) 6 − 5 + 14 = 0 D) 6 − 5 − 14 = 0
+3 + + must be
A) odd B) even
C) D)
47. Orthocentre of triangle with vertices (0, 0), (3, 4) and (4, 0) is
5 3
A) 3, B) (3, 12) C) 3, D) (3, 9)
4 4
48. If the point P a 2 , a lies in the region corresponding to the acute angle between the lines 2y = x and
C) a 4,8 D) a 2, 0
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SECTION-III
(Numerical Value Answer Type)
This section contains 6 questions. The answer to each question is a Numerical value. If the Answer is in the decimals,
Mark the nearest Integer only. The question will be evaluated according to the following marking scheme:
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
50. If all chords of the curve 3 − − 2 − 4 = 0, which subtend a right angle at the origin, pass
through a fixed point. Then the ordinate of the fixed point must
51. (2, −7) is vertex of a triangle. Equation of altitudes and median drawn from different vertices are
3 + + 11 = 0 and + 2 + 7 = 0. If the equation of side AC is 7 + 9 + = 0 then the
numerical quantity should be
52. Find the remainder when 599 is divided by 8 is
53. A pair of straight lines is drawn through the origin to form with the line 2 + 3 = 6 an isosceles
triangle right angled at the origin. If the area of the triangle is . Then the numerical quantity
must be equal to
54. Two vertices of a triangle are (4, −3) and (−2,5), if the orthocentre of the triangle is (1,2). Then
the co-ordinates of the third vertex are ( , 26). The numerical quantity must be equal to
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