THE VELAMMAL INTERNATIONAL

SCHOOL
SUB JECT: CHEMISTRY
CLASS: XII NEET (10.10.2024) DRT- 06
MARK: 40

SECTION: A
1. In case of isoelectronic species the size of F -1, Ne and Na+ is affected by
(a) Principal quantum number (n)
(b) electron-electron interaction in the outer orbital’s
(c) Nuclear charges (z)
(d) None of the factors because their size is the same.
2. Arrange the following elements in increasing order of electro negativity: N, O, E, C,
Si Choose the correct answer from the options given below:
(a) Si < C < N < O < F (b) Si < C < O < N < F
(c) 0 < F < N < C < Si (d) F < O < N < C < Si
3. The number of s-electrons present in an ion with 55protons in its unpositive state is
(a) 8 (b) 12 (c) 9 (d) 10
4. The element expected to form largest ion to achieve the nearest noble gas
configuration is
(a) N (b) Na (c) O (d) F
5. The IUPAC name of an element with atomic number 119 is
(a) ununennium (b) unnilennium (c) unununnium (d) ununoctium
6. The characteristics of elements X, Y and Z with atomic numbers respectively, 33,
53 and 83 are
(a) X is a metalloid, Y is a non-metal and Z is a metal
(b) X, Y and Z are metals
(c) X and Y are metalloids and Z is a metal
(d) X and Z are non-metals and Y is a metalloid
7. The total number of acidic oxides from the following list is
NO, N2O, B2O3, N2O5, CO, SO3,P4O10
(a) 3 (b) (c) O (d) F
8. In which of the following pairs, electron gain enthalpies of constituent elements are
nearly the same or identical?
(a) Rb and Cs (b) Na and K (c) Ar and Kr (d) I and At
9. Choose the correct answer from the options given below:
(a) (A) and (B) only (b) (B) and (C) only
(c) (A) and (C) only (d) (C) and (D) only
10. Element "E" belongs to the period 4 and group 16 of the periodic table. The
valence shell electron configuration of the element which is just above "E" in the
group is
 (a) 3S2, 3p4 (b) 3d10, 4s2, 4p4 (c) 4d10, 5s2, 5p4 (d) 2s2, 2p4
11. The set in which compounds have different nature is
(a) Be (OH)2 and Al (OH)3 (b) B (OH)3 and Al (OH)3
(c) B (OH)3 and H3PO3 (d) NaOH and Ca (OH)2
12. The metal that has very low melting point and its periodic position is closer to a
metalloid is
(a) Al (b) Ga (c) Se
(d) In
13. 12. Identify the incorrect match. Name IUPAC Official Name
(A) Unnilunium (i) Mendelevium
(B) Unniltrium (ii) Lawrencium
(C) Unnilhexium (iii) Seaborgium
(D) Unununnium (iv) Darmstadtium
(a) (A), (i) (b) (B), (ii) (c) (C), (iii) (d) (D), (iv)
14. Outermost electronic configuration of a group 13 element, E, is 4s2, 4p 1. The
electronic configuration of an element of -block period-five placed diagonally to
element, E is
(a) [Xe] 5d10 6s2 6p2 (b) [Ar] 3d10 4s2 4p2
(c) [Kr] 3d10 4s2 4p2 (d) [Kr] 4d10 5s2 5p2
15. The element Z = 114 has been discovered recently. It will belong to which of the
following family/ group and electronic configuration?
(a) Carbon family, [Rn] 5f146d107s2 7p 2
(b) Oxygen family, [Rn] 5f146d107s2 7p4
(c) Nitrogen family, [Rn] 5f146d107s27p6
(d) Halogen family, [Rn] 5f146d107s27p5
16. The element with Z = 120 (not yet discovered) will be an/a
(a) inner-transition metal (b) alkaline earth metal (c) alkali metal (d)
transition metal
For the second period elements the correct increasing order of first ionization
enthalpy is
(a) Li < Be < B < C < O < N < F < Ne (b) Li < Be < B < C < N < O < F <
Ne
(c) Li < B < Be < C < O < N < F < Ne (d) Li < B < Be < C < N < O < F <
Ne
17. Match the oxide given in column I with its property given in column II.
S.N Column I S.No Column II
o
i. Na2O A. Neutral
ii. Al2O3 B. Basic
iii. N2O C. Acidic
iv. Cl2O7 D. Amphoteric
Which of the following options has all correct pairs?
(a) (i)-B, (ii)-A, (iii)-D, (iv)-C (b) (i)-C, (ii)-B, (iii)-A, (iv)-D
(c) (i)-A, (ii)-D, (iii)-B, (iv)-C (d) (i)-B, (ii)-D, (iii)-A, (iv)-C
18. The size of ionic species is correctly given in order
 (a) C l7 > Si4+> Mg2+> Na+ (b) Na+>Mg2+>Si4+>Cl7+
(c) Na+ >Mg2+>Cl7+>Si4+ (d) Cl7+>Na+>Mg2+> Si4+
19. Assertion: Helium has the highest value of ionization energy among all the
elements known.
Reason: Helium has the highest value of electron affinity among all the elements
known.
(a) If both assertion and reason are true and reason is the correct explanation of
assertion.
(b) If both assertion and reason are true but reason is not the correct explanation
of assertion.
(c) If assertion is true but reason is false.
(d) If both assertion and reason are false
20. Correct I.U.P.A.C name for:

(a) 2-ethyl-3-methylpentane (b) 3,4-dimethylhexanme

(c) 2-sec-butylbutane (d) 2,3-dimenthylbutane
21. The IUPAC name for:

(a) 1-Hydroxypentane-1, 4-dione (b) 1, 4-Dioxopentanol

(c) 1- Carboxybutan-3-one (d) 4-Oxopentanoic acid
22. The IUPAC name for:

(a) 1-Chloro-2-nitro-4-methybenzene (b) 1-Chloro-4-methy-2-nitrobenzene

(c) 2-Chloro-1-nitro-5-methylbenzene (d) m-Nitro-p-chlorotoluene
23. The correct structure of 2,6-Dimethyl-dec-4-ene is

24. The number of σ bonds, π bonds and lone pair of electrons in pyridine,
respectively are
(a) 12, 2, 1 (b) 11, 2, 0 (c) 12, 3, 0 (d) 11, 3, 1
25. Which of the compounds will show G.I.?
(a)

(b) C6H5-CH=NOH (c) CH 3-CH=CH-CH3 (d) All of these

26. Which among these can exhibit tautomerism?

(a) II only (b) I only (c) III only (d) II & III

27. Which of the following is correct order of physical properties of Geometrical

Isomers:

28. What is the configuration of the following molecules?

(a) 2S, 3R (b) 3R, 3S (c) 2S, 3S (d) 2R, 3R

29.

Among these, positional isomers are:

(a) I, II (b) II, III (c) I, III (d) All of these
30. In the following electron-dot structure, dot = dot N calculate the formal
charge on each nitrogen atom from left to right.
(a) -1, -1, +1 (b) -1, +1,-1 (c) +1,-1,-1 (d) +1,-
1,+1
31. Which of the following is the correct order of dipole moment?
(a) NH3 < BF3 < NF3 < H2O (b) BF3 < NF3 < NH3 < H2O
(c) BF3 < NH3 < NF3 < H2O (d) H2O < NF3 < NH3 < BF3
32. Which of the following order is correct?
(a) AICI3 < MgCI : NaCI : Polarizing power
- 2−¿3 ¿
(b CO ¿ CO ¿HCO2 ¿ CO ¿ : Bond length
(c) BeCl2 < NH3 < NH3 : Dipole moment
(d) H2S ¿ NH3 ¿ SiH4 ¿ BF3 : Bond angle
33. The bond length of HCl bond is 2.29 x 10 -10 m. The percentage ionic character of
HCl, if measured dipole moment is 6.226 x 10-30 C m, is
(a) 8% (b) 20% (c) 17% (d) 50%
34. Which of the following statements about CO2−¿3 ¿ ion is correct?
¿
(a) The C−¿O bond order is 1.5.
(b) The formal charge on each oxygen atom is−¿0.67.
(c) It has two C−¿O single bonds and one C = O double bond.
(d) The hybridization of central atom is sp 3
35. Which of the following pairs have different hybridization and same shape?
- 2−¿3 ¿
(i) NO3 and CO ¿ (ii) SO2 and NH-2

(iii) XeF2 and CO2 (iv) H2O and NH3

(a) (i) and (iv) (b) (ii) and (iv) (c) (ii) and (iii) (d) None of these
36. The dipole moments of CCl4, CHCI3, and CH44 are in the order

37. Which of the following pairs does not have same bond order?
(a) N2 and CN- (b) O+¿ 2 ¿ and NO
¿
(c) F−¿ 2 ¿ and O2−¿2 ¿ (d) B 2−¿2 ¿ and C N+
¿ ¿ ¿
38. Which one of the following pairs of species have the same bond order?
(a) O2 NO+ (b) CN-, CO (c) N2 O2 - (d) CO, NO
39. Which of the following diatomic molecular species has only bonds according to
molecular orbital theory?
(a) Be2 (b) O2 (c) N2 (d) C2
40. Which of the following is paramagnetic?
(a) N2 (b) H2 (c) Li2 (d) O2
41. Number of molecules/ions from the following in which the central atom is involved
in hybridization is ____________NO−¿ 3 ¿, BCI3, CIO−¿ 2 ¿, CIO3
¿ ¿
(a) 2 (b) 4 (c) 1 (d) 3
42. Intramolecular hydrogen bonding is present in

43. Given below are two statements:

Statement I: SO2 and H2O both possess V-shaped structure.
Statement II: The bond angle of SO2 less than that of H2O. In the light above
statements, choose the most appropriate answer from the options given below:
(a) Statement 1 is incorrect but Statement II is correct.
(b) Both Statement I and Statement Il are incorrect.
(c) Both Statement I and Statement II are correct.
(d) Statement I is correct but Statement II is Incorrect.
44. Amongst the following, the total number of species not having eight electrons
around central atom in its outermost shell, is
NH3, AICI3, BeCI2, CCI4, PCI5
(a) 4 (b) 1 (c) 3 (d) 2
45. The correct order of energies of molecular orbitals of N 2 molecules, is

46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
61.