SAFETY DATA SHEETS (SDS)

1. PRODUCT IDENTIFICATION

PRODUCT NAME: BLACK SILICON CARBIDE

SYNONYMS: Black SiC, “C” Abrasive, “NC” Abrasive, Sika IV A, Black Crystal, Crystolon (37),
EC6, EC6R, S/C, Electrocarb Carbolon, Silcarbide RA, C-6, HBD, SICSK-B, SICPL-B,
SIC-ST

FORMULA: SiC (>96%)

RECOMMENDED USES: For Bonded Abrasives and General Industries: It is typically used on hard or brittle
materials. It is also used for pressure blasting, kiln furniture, lapping and polishing, non-
woven, tumbling, anti-skid, electrical heating elements, aerospace and composites.
For Coated Abrasives Industries: It can be used for the polishing, finishing or stock
removal from wood, metal, ceramic, plastic rubber, stone and other materials.

COMPANY: Graystar LLC

ADDRESS: 9 Simmonsville Road
Bluffton, SC 29910
PHONE: 843-815-5600

2. HAZARD IDENTIFICATION
HAZARD CLASSIFICATION:
o Non-flammable black or gray solid grain or powder that is non-combustible and is stable.
o Abrasive particulate may cause minor Eye Irritation and/or Skin Irritation.
o Specific Target Organ Toxicity - May cause damage to lungs through prolonged or repeated exposure to dust.
o Quartz (SiO2) component may cause cancer via inhalation.

Danger
HAZARD STATEMENTS:
o Harmful if swallowed.
o May cause minor skin or eye irritation. Particulate may scratch cornea or cause other mechanical eye injury.
o In Inhaled; May cause respiratory irritation through single use, or cause damage to lungs through prolonged or
repeated exposure to concentrations in excess of the PEL or TVL without respiratory protection. This may also
decrease the ability of the lungs to clear particulate matter which may cause shortness of breath and increase
susceptibility to respiratory disease. Quartz (SiO2) component may cause cancer via inhalation.

PREVENTION:
o Wash hands thoroughly after use.
o Wear protective gloves and eye/face protection.
o Do not breathe dust. Do not use compressed air or dry sweeping to remove dust from work areas.
o Wear respiratory protection for concentrations in excess of the PEL or TVL.
o Store in dry area in closed containers.
o Dispose of according to applicable federal, state and local regulation.
FIRST AID:
o If Swallowed: Call doctor if you feel unwell.
o If on Skin: Wash with soap and water. Seek medical advice if symptoms persist.
o If in Eyes: Flush with warm water for 15 minutes (remove contacts if possible). Seek medical attention if
symptoms persist.
o If Inhaled: If breathing is difficult - Remove person to fresh air and keep comfortable for breathing.
If experiencing respiratory symptoms or feels unwell - Seek immediate medical attention.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Typical
Ingredient** CAS# Weight(%) PEL-OSHA TLV-ACGIH Carcinogen
(mg/m3) (mg/m3) (Y/N)

Silicon Carbide (SiC) 409-21-2 96 - 100 10 (dust)* 10 (dust)* No

Carbon (C) 1333-86-4 0-3 3.5 3.5 No
Quartz (SiO2) 14808-60-7 0-1 0.1 0.1 Yes***

*Respirable Fraction is: 5 5

** Others Ingredients (small amounts < 0.65% each): Si, Fe, CaO, and MgO.
*** Quartz (SiO2) component may cause cancer via inhalation (Carc. 1A H350).

Materials are regulated under OSHA 29 CFR 1900.1200, Hazard Communication Standard.
Source of exposure limit data; ACGIH Threshold Limit Values; (OSHA Tables Z-1-A, Z-2, Z-3)
All ingredients are listed under TSCA.

4. FIRST-AID MEASURES

EYES: Flush eyes with lukewarm water for 15 minutes, opening and closing eyelids to ensure adequate rinsing. If
redness, irritation, pain, or tearing occurs, seek medical attention.

SKIN: Wash contaminated area with soap and water. Wash contaminated clothing. Seek medical attention if symptoms
persist.

INHALATION: If inhalation of high concentrations occurs, move to fresh air. If breathing has stopped, a certified
professional should give CPR. Seek immediate medical attention.

INGESTION: Do not induce vomiting unless suggested by a doctor. Seek medical attention.

5. FIRE FIGHTING MEASURES

FLASH POINT: Not Applicable

FLAMMABLE LIMITS: LEL: Not Applicable UEL: Not Applicable
AUTO IGNITION TEMPERATURES: Not Applicable.
EXTINGUISHING MEDIA: Use media appropriate for surrounding fire.
FIRE AND EXPLOSION HAZARDS: Non-flammable, non-combustible. Product will not burn.
HAZARDOUS DECOMPOSITION PRODUCTS: None
FIRE FIGHTING INSTRUCTIONS: Firefighters should wear a NIOSH/MSHA approved full-faced self-contained
breathing apparatus (SCBA) operated in positive pressure mode, and full turnout or bunker gear.

NFPA CLASSIFICATION: HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0

 6. ACCIDENTAL RELEASE MEASURES

Isolate hazard area and deny entry to unauthorized and/or unprotected personnel. Avoid dust generation. Water mist may
be added as necessary to control the level of airborne dusts. Respiratory protection for clean-up personnel depends on the
level of exposure anticipated. (See Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION). Gently shovel or
scoop into clean dry container for later recycle or disposal. Comply with Federal, State and Local regulations regarding
reporting of spills and disposal.

7. HANDLING AND STORAGE

HANDLING: Prevent formation of dust, and avoid dust inhalation. Use only in well ventilated areas. Any deposit of dust
that cannot be avoided must be regularly removed. DO NOT use compressed air or dry sweeping to remove dust from
work area. Wash thoroughly with plenty of water.

STORAGE: Store in dry area in closed containers. Protect from high humidity and water.
Store receptacle in a well ventilated area.
Store away from oxidizing agents. Store away from foodstuffs.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

RESPIRATORY PROTECTION: Under normal working conditions, below acceptable exposure guidelines, none is
required. For concentrations above the PEL but less than 10X the PEL, a NIOSH/MSHA approved dust mist respirator
should be worn. Appropriate respirator selection will be dependent upon the magnitude of exposure and should be
selected in accordance with 29 CFR 1910.134. (See Section 3. COMPOSITION for PEL’s and TWA’s).

SKIN PROTCTION: Protective gloves, as needed, to prevent skin contact.

EYE PROTECTION: Safety-glasses with side shields or goggles to prevent dust and particles from entering the
eye. See OSHA 29 CFR 1910.133.
OTHER: Under dusty conditions, employees should wear coveralls or other suitable work clothing. Contaminated
clothing must be vacuumed before removal. DO NOT REMOVE dust from clothing by blowing or
shaking. Keep away from foodstuff, beverages and feed.

ENGINEERING CONTROLS: Use general ventilation. Local exhaust may be necessary for processes which generate
large quantities of airborne dust. Keep exposures below applicable OSHA PEL’s and ACGIH-TLV’s.

9. PHYSICAL AND CHEMICAL PROPERTIES

Formula SiC
Molecular Weight 40.07
Boiling Point Not Applicable
Melting Point Does not melt but dissociates at about 2300oC
Specific Gravity (H20 = 1) 3.21
Percent Volatile 0
Evaporation Rate None
Solubility in Water Insoluble
Solubility in Alcohol Insoluble
pH (10% slurry) Not applicable
Appearance/Odor Black or Gray solid or powder/odorless
 10. STABILITY AND REACTIVITY

STABILITY: Stable under normal ambient conditions of temperature and pressure.

THERMAL DOCOMPOSTION: No decomposition if used and stored to specifications.

POSIBLE HAZARDOUS REACTIONS: Reacts with strong acids, oxidizing agents, and with strong alkali.

CONDITIONS TO AVOID & INCOMPATIBLE MATERIALS: No further relevant information available.

HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide.

11. TOXICOLOGICAL INFORMATION

EYE: Particulate matter may cause physical injury to the eye.

SKIN: May cause minor irritation.
INHALATION: May cause respiratory irritation through single use.
May cause damage to lungs or pulmonary disease through prolonged/repeated exposure to dust.
Quartz (SiO2) component may cause cancer via inhalation.
INGESTION: Ingestion of large quantities may result in gastrointestinal irritation and eventually interference
with phosphate absorption which results in rickets.

12. ECOLOGICAL INFORMATION

Aquatic Toxicity: Generally not hazardous for water.

Persistence & Degradability: No further relevant information available.
Bioaccumulative Potential: Does not accumulate in organisms.
Mobility In Soil: No further relevant information available

13. DISPOSAL CONSIDERATIONS

Dispose of according to applicable federal, state, and local regulations. Dispose per 40 CFR 261 and 262.

14. TRANSPORT INFORMATION

U.S. Department of Transportation (D.O.T.): Not Regulated as a Hazardous Material

D.O.T. HAZARD CLASS (49 CFR 172.101): N/A
D.O.T. PROPER SHIPPING NAME (49 CFR 172.101): N/A
D.O.T. LABELS REQUIRED (49 CFR 172.101): N/A
D.O.T. PLACARDS REQUIRED: N/A
IMDG: Not Regulated Under IMDG (is not hazardous cargo for sea transportation).

15. REGULATORY INFORMATION

TSCA (Toxic Substance Control Act): All components on TSCA inventory.

Canadian WHMIS: D2B

EPCRA Section 302 (EHSs): This product does not contain ingredients subject to reporting requirements of 40 CFR Part
355, Appendices A and B (Extremely Hazardous Substances).

CERCLA, Section 304: This product does not contain ingredients subject to state and local reporting under Section 304
of SARA Title III as listed in 40 CFR Part 302 Table 302.4.

SARA 313 REPORTING REQUIREMENTS: This product does not contain ingredients subject to the reporting
requirements of Section 313 SARA, and Section 5607 of the Pollution Prevention Act.

SARA HAZARD CATEGORY: This product has been reviewed according to the EPA Hazard Categories promulgated
under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and by
definition meets the requirements of the following category: Acute Health Hazard

16. OTHER INFORMATION & LAST REVISION DATE

KEY:
ACGIH American Conference of Governmental Industrial Hygienists
CAS Chemical Abstracts Service
DOT Department of Transportation
IARC International Agency for Research on Cancer
IMDG International Maritime Dangerous Goods
MSHA Mine Safety and Health Administration
NFPA National Fire Protection Association
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
SARA Superfund Amendment and Reauthorization Act
TLV Threshold Limit Valve
TSCA Toxic Substance Control Act

DISCLAIMER:

Although reasonable care has been taken in the preparation of the information contained herein, the originator and
Graystar*LLC extends no warranties, makes no representation and assumes no responsibility as to the accuracy of
suitability of such information for application to the purchaser’s intended purposes or for consequences of its use.

LAST REVISION DATE: 05-31-2016