Scribd
Upload
19 views20 pages

JEE Advanced 2023 paper 1

The document contains solutions and answers to various questions from the JEE Advanced 2023 paper, covering topics such as molecular orbital diagrams, colloids, isomerism, and reactions involving organic compounds. It includes multiple-choice questions with correct answers and explanations for each question. Additionally, it features integer-type questions related to chemical reactions and properties.

Uploaded by

sivasankare G
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
19 views20 pages

JEE Advanced 2023 paper 1

The document contains solutions and answers to various questions from the JEE Advanced 2023 paper, covering topics such as molecular orbital diagrams, colloids, isomerism, and reactions involving organic compounds. It includes multiple-choice questions with correct answers and explanations for each question. Additionally, it features integer-type questions related to chemical reactions and properties.

Uploaded by

sivasankare G
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 20

JEE Advanced 2023 paper -1

1. The correct molecular orbital diagram for F2 molecules in the


ground state

(A) 1 : 1.128 : 1
Answer : B
Solution:
The given graph is symmetrical, so the average speed and
most probable speed will coincide. Because the most
probable speed is the speed possessed by the maximum
number of molecules of the gas, and the average speed is
the sum of the speeds of all the molecules divide it by total
number of molecules, so it will be in the middle. But the
3𝑅𝑇
root mean square velocity will remain √
𝑀

2𝑅𝑇
So, 𝑢𝑚𝑝 = √ = 𝑢𝑎𝑣
𝑀

3
𝑢𝑚𝑝 ∶ 𝑢𝑎𝑣 : 𝑢𝑟𝑚𝑠 = √2 : √2 ∶ √3 = 1:1: √ = 1 : 1 : 1.224
2

Ans: C
2. Which of the following liberates O2 upon hydrolysis? Consider
the following statements related to colloids.
I. Lyophobic colloids are not formed by simple mixing of
dispersed phase and dispersion medium.
II. For emulsions, both the dispersed phase and the
dispersion medium are liquid.
III. Micelles are produced by dissolving a surfactant in any
solvent at any temperature.
IV. Tyndall effect can be observed from a colloidal solution
with dispersed phase having the same refractive index as
that of the dispersion medium.
The option with the correct set of statements is
(A) (I) and (II) (B) (II) and (III)
(C) (III) and (IV) (D) (II) and (IV)
Ans : A
Solution:
In Tyndall effect, refractive indices of dispersed phase and
dispersion medium differ greatly in magnitude. Micelles are
formed by surfactant at CMC (critical micelle Concentration)
or above CMC and at Kraft temperature or above Kraft
temperature
3. In the following reactions, P, Q, R, and S are the major products.

The correct statement about P, Q, R, and S is

A) P is a primary alcohol with four carbons.


B) Q undergoes Kolbe’s electrolysis to give an eight-carbon
product.
C) R has six carbons and it undergoes Cannizzaro reaction.
D) S is a primary amine with six carbons.
Ans : B
4. A disaccharide X cannot be oxidised by bromine water. The
acid hydrolysis of X leads to a laevorotatory solution. The
disaccharide X is
Ans : A
Solution :

Hydrolysis of sucrose brings about a change in the sign of rotation


from dextro(+) to laevo(–) and the product named as invert sugar

Section -2 More than one correct


5. The complex(es), which can exhibit the type of isomerism
shown by [Pt(NH3)2Br2], is(are) [en = H2NCH2CH2NH2]

A) [Pt(en)(SCN)2]
B) [Zn(NH3)2Cl2]
C) [Pt(NH3)2Cl4]
D) [Cr(en)2(H2O)(SO4)]+
Ans : C, D
Solution:
[Pt(NH3)2Br2], is a square planar complex.The given
compound can show geometrical isomerism (cis-trans
form)
Option (A) : [Pt(en)(SCN)2] cannot show geometrical
isomerism.
Option (B) : [Zn(NH3)2Cl2] is a tetrahedral complex, cannot
show geometrical isomerism.
Option (C) : [Pt(NH3)2Cl4] is a octahedral complex, can
show geometrical isomerism.

Option (D) : [Cr(en)2(H2O)(SO4)]+


is octahedral complex and is of type [M(AA)2bc]
can show geometrical isomerism

6. Atoms of metals x, y, and z form face-centred cubic (fcc) unit


cell of edge length Lx, body-centred cubic (bcc) unit cell of
edge length Ly, and simple cubic unit cell of edge length Lz,
respectively.

then the correct statement(s) is(are)


[Given: Mx, My, and Mz are molar masses of metals x, y, and
z, respectively. rx, ry, and rz are atomic radii of metals x, y,
and z, respectively.]

(A) Packing efficiency of unit cell of x > Packing efficiency of


unit cell of y > Packing efficiency of unit
(B) Ly > Lz
(C) Lx > Ly
(D) density of x > Density of y
Ans : A, B, D
Solution:
For metal ‘x’
Fcc: Edge length , a1 = Lx
For metal ‘y’
Bcc: Edge length , a2 = Ly
For metal ‘z’
Bcc: Edge length , a3 = Lz
For Option (B)

For Option C,
For option d,

7. In the following reactions, P, Q, R, and S are the major products.


The correct statement(s) about P, Q, R, and S is(are)
(A) P and Q are monomers of polymers dacron and glyptal,
respectively.
(B) P, Q, and R are dicarboxylic acids.
(C) Compounds Q and R are the same.
(D) R does not undergo aldol condensation and S does not
undergo Cannizzaro reaction.
Answer : C,D
Solution:
Section-3 (Integer Type)

8. H2S (5 moles) reacts completely with acidified aqueous


potassium permanganate solution. In this reaction, the number
of moles of water produced is x, and the number of moles of
electrons involved is y. The value of (x + y) is _
Answer : 18

9. Among [I3]+, [SiO4]4−, SO2Cl2, XeF2, SF4, ClF3, Ni(CO)4, XeO2F2,


[PtCl4]2−, XeF4, and SOCl2, the total number of species having sp3
hybridised central atom is
Ans: 5
10. Consider the following molecules: Br3O8, F2O, H2S4O6,
H2S5O6, and C3O2. Count the number of atoms existing in their
zero oxidation state in each molecule.Their sum is-------
Ans : 6

11. For He+, a transition takes place from the orbit of radius 105.8
pm to the orbit of radius 26.45 pm.The wavelength (in nm) of the
emitted photon during the transition is ___.
[Use: Bohr radius, a = 52.9 pm, Rydberg constant, RH = 2.2 x
10-18 J, Planck’s constant, h = 6.6 × 10 – 34 J s
Speed of light, c = 3 × 108 m s – 1]
Ans: 30
12. 50 mL of 0.2 molal urea solution (density = 1.012 g mL −1 at 300K)
is mixed with 250 mL of a solution containing 0.06 g of urea.
Both the solutions were prepared in the same solvent. The
osmotic pressure (in Torr) of the resulting solution at 300 K is
___.
[Use: Molar mass of urea = 60 g mol −1 ; gas constant,
R = 62 L Torr K −1 mol -1 ; Assume, ∆ mix H = 0, ∆ mix V = 0]
Ans: 682
0.2 molal means 0.2 moles in 1000 g of solvent
13. The reaction of 4-methyloct-1-ene (P, 2.52 g) with HBr in the
presence of (C6H5CO)2O2 gives two isomeric bromides in a 9 : 1
ratio, with a combined yield of 50%. Of these, the entire amount
of the primary alkyl bromide was reacted with an appropriate
amount of diethylamine followed by treatment with aq. K2CO3 to
give a non-ionic product S in 100% yield. The mass (in mg) of S
obtained is ___. [Use molar mass (in g mol –1 ): H = 1, C = 12, N =
14, Br = 80]
Ans : 1791
Section -4
Paragraph – 1
The entropy versus temperature plot for phases α and β at 1 bar
pressure is given.ST and S0 are entropies of the phases at
temperatures T and 0 K, respectively.

The transition temperature for α to β phase change is 600 K and


Cp,β − Cp,α = 1 J mol-1 K−1 . Assume (Cp,β − Cp,α ) is independent of
temperature in the range of 200 to 700 K. Cp,α and Cp,β are heat
capacities of α and β phases respectively.
14. The value of entropy change, Sβ − Sα (in J mol −1 K -1 ), at 300 K is
___. [Use: ln2 = 0.69 Given: Sβ − Sα = 0 at 0 K
Ans : 0.31

15. The value of enthalpy change, Hβ − Hα (in J mol −1 ), at 300 K is -


----------
Ans : 300
Paragraph – 2
A trinitro compound, 1,3,5-tris-(4-nitrophenyl)benzene, on complete
reaction with an excess of Sn/HCl gives a major product, which on
treatment with an excess of NaNO2/HCl at 0 oC provides P as the
product. P, upon treatment with excess of H2O at room temperature,
gives the product Q. Bromination of Q in aqueous medium furnishes
the product R. The compound P upon treatment with an excess of
phenol under basic conditions gives the product S. The molar mass
difference between compounds Q and R is 474 g mol-1 and between
compounds P and S is 172.5 g mol –1 .

16. The number of heteroatoms present in one molecule of R is


______ . [Use: Molar mass (in g mol–1): H = 1, C = 12, N = 14, O =
16, Br = 80, Cl = 35.5 Atoms other than C and H are considered as
heteroatoms]
Ans : 9
17. The total number of carbon atoms and heteroatoms present in
one molecule of S is ______ . [Use: Molar mass (in g mol – 1 ): H =
1, C = 12, N = 14, O = 16, Br = 80, Cl = 35.5 Atoms other than C
and H are considered as heteroatoms
Ans : 51

You might also like

pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy