Past Papers Multiple Choice Questions First Year Chemistry Topicwise 1

Past Multiple Choice Questions Chapter #01 Basic Concepts Book – 1

(1). Haemoglobin is a macromolecule and consists of approximately atom: (BWP,2017)
(a).5000 (b).10,000 (c).68000 (d).15000
(2). Number of isotopes of arsenic are: (LHR,2018)
(a). 1 (b). 2 (c). 9 (d). 11
(3). 1A0 = _____ m (MLN,2018)
(a). 10 – 10 (b). 10 – 11 (c). 10 – 12 (d). 10 – 13
(4). The atomicity of C6H12O6 is: (RWP,2018)
(a). 6 (b). 12 (c). 3 (d). 24
(5). The number of moles of CO2 that contains 0.5 mole of oxygen is: (DGK,2019)
(a). 0.25 (b). 0.50 (c).1.0 (d). 1.5
(6). The mass of one mole of electrons in milligrams is: (DGK,2019)
(a). 1.008 (b). 0.5500 (c). 0.1840 (d). 1.673
(7). The Branch of Chemistry which deals with the calculations based on balanced chemical equation is
called: (BWP,2021g1)
(a). Thermochemistry (b). Thermochemistry (c). Stoichiometry (d). Physical Chemistry
(8). Average Atomic Mass of Neon is: (BWP,2021g1)
(a). 20.00 (b). 20.18 (c). 20.20 (d). 22.0
(9). The branch of chemistry which tells us the quantitative relationship between reactants and products is
called: (DGK,2021g1)
(a). Stoichiometry (b). Thermometry (c). Organic chemistry (d). physical chemistry
(10). A beaker contains 9g of water. The number of H – atoms in it is: (FSD,2021g1)
(a). NA of atoms (b). 2 x NA of atoms (c). ½ NA of atoms (d). 3 x NA of atoms
(11). The ratio of actual yield to theoretical yield multiplied by 100 is called: (FSD,2021g2)
(a). Complex yield (b). Experimental yield (c). %age yield (d). None of these
(12). The calculation based on balanced chemical equation is called: (FSD,2012g2)
(a). Complex calculation (b). Stoichiometric calculation (c). Non – stoichiometric calculation (d). None of these
(13). Number of isotopes of oxygen is: (GRW,2021g1)
(a). two (b).three (c). four (d). five
(14). Oxygen molecule is heavier than hydrogen by: (GRW,2021g1)
(a). 1 time (b). 8 times (c). 16 times (d). 32 times
(15). 1 g formula of NaCℓ is equal to: (LHR,2021g1)
(a). 58.5 g (b). 23 g (c). 35.5 g (d). 12 g
Or 1 gram formula of NaCℓ is equal to: (LHR,2021g2)
(a). 58.5 g (b). 23 g (c). 35.5 g (d). 12 g
(16). Many elements have fractional atomic masses, this is because: (LHR,2021g1)
(a). The mass of an atom is itself fractional (b). Atomic masses are average masses of isobars
(c). Atomic masses are average masses of isotopes
(d). Atomic masses are average masses of isotopes proportional to their relative abundance
(17). A pair of elements having single isotope are: (MTN,2021g1)
(a).9F19 , 79 Au197 (b). 53I127 , 35 Br81 (c). 8O16 , 7 N14 (d). 33As75 , 7 N14
(18). 1 mole of CH3OH and C2H5OH have: (MTN,2021g1)
(a). Equal number of molecules (b). Equal number of atoms (c). Equal number of ions (d). Equal number of protons
(19). The total number of Fundamental particle in an atom of Carbon – 14 is: (MTN,2021g1)
(a). 6 (b). 8 (c).14 (d). 20
(20). In 98 g of sulphuric acid H2SO4 number of O atoms: (MTN,2021g2)
(a). 6.02x1023 (b). 2.408x1024 (c). 1.2x1024 (d). 6.02x1024
(21). Sn(Tin) has number of isotopes: (MTN,2021g2)
(a). 10 (b). 11 (c).5 (d).6
Or Number of isotopes of Tin is/are: (RWP,21)
(a).one (b).eleven (c).fifteen (d).eighteen
(22). The number of atoms in 1.79 g of gold and _____ g of sodium are equal: (SGD,2021g2)
(a). 0.023 (b). 23 (c).230 (d).2300 [Correction=0.197 g gold]
(23). How many subatomic particles are thought to exist in an atom. (GRW,2022g2)
(a). 3 (b). 20 (c). 50 (d). 100
(24). The volume occupied by 16g of O2 at STP is: (RWP,2022g2)
(a). 22.4dm3 (b). 2.24dm3 (c). 11.2dm3 (d). 1.12dm3
(25). 22 g of CO2 sample has : (RWP,2022g2)
(a). ½ mole of O atoms (b). 1 mole of O atoms (c). 1.5 mole of O atoms (d). 6.02x1023 molecules of CO2
(26). Number of isotopes of calcium are (DGK,2022g2)
(a). 02 (b). 03 (c). 05 (d). 06

PAST MULTIPLE CHOICE QUESTIONS F.Sc PART – 1 CHEMISTRY | Shahbaz Ali

 Past Papers Multiple Choice Questions First Year Chemistry Topicwise 2

KEY
(1). (b).10,000 (2). (a). 1 (3). (a). 10 – 10 (4). (d). 24 (5). (b). 0.50
(6). (b). 0.5500 (7). (c). Stoichiometry (8). (b). 20.18 (9). (a). Stoichiometry
(10). (a). NA of atoms (11). (c). %age yield (12). (b). Stoichiometric calculation (13). (b).three
(14). (c). 16 times (15). (a). 58.5 g Or (a). 58.5 g
(16).(d). Atomic masses are average masses of isotopes proportional to their relative abundance
(17). (a).9F19 , 79 Au197 (18). (a). Equal number of molecules (19). (d). 20 (20). (b). 2.408x1024
(21). (b). 11 Or (b).eleven (22). (a). 0.023 (23). (d). 100 (24). (c). 11.2dm3
(25). (b). 1 mole of O atoms (26). (d). 06

Past Multiple Choice Questions Chapter #02Experimental Techniques in Chemistry Book – 1

(1). During chromatography strip of paper should be dipped into solvent mixture to a depth of: (DG,2014)
(a). 3 – 4 mm (b). 4 – 5 mm (c). 5 – 6 mm (d). 6 – 7 mm
(2). During paper chromatography, the stationary phase is: (RWP,2014)
(a). Solid (b). Liquid (c). Gas (d). Plasma
(3). Insoluble particles can be separated from liquid by: (DGK,2018)
(a). Sublimation (b). Solvent extraction (c). Crystallization (d). Filtration
(4). In _____ technique a solute distribute between two immiscible liquids. (MLN,2019)
(a). Crystallization (b). Solvent extraction (c). Filtration (d). Distillation
(5). Which one of the following compound is purified by sublimation ; (LHR,2019)
(a). Benzoic acid (b). SiO2 (c). CS2 (d). NaI
(6). Direct conversion of solid into its vapours is called: (DGK,209)
(a). Crystallization (b). Sublimation (c). Vapourization (d). Distribution
(7). Which one of the following is not purified by sublimation: (AJK,2019)
(a). Naphthalene (b). Silicon dioxide (c). I2 (d). Benzoic acid
(8). Which of the following compounds do not show process of sublimation: (LHR,2021g1)
(a). Ammonium chloride (b). Iodine (c).Naphthalene (d). Carbon tetra chloride
(9). Drying agent used in desiccator is: (BWP,2022g2)
(a). NH4Cl (b). AgCl (c). NaCl (d). CaCl2
(10). Solvent commonly used in solvent extraction is: (DGK,2022g1)
(a). Methyl alcohol (b). Diethyl ether (c). Liquid ammonia (d). Hydrochloric acid
(12). The technique of chromatography is useful in organic synthesis for : (FSD,2022g1)
(a). Separation (b). Isolation (c). Purification (d). All these
(13). Separating funnel is used in the technique of analysis: (FSD,2022g1)
(a). Crystallization (b). Filtration (c). Solvent extraction (d). Sublimation
(14). Coloured impurities appear during crystallization are removed by boiling the substance in the solvent
with: (FSD,2022g2)
(a). Silica gel (b). Benzoic acid (c). Powdered animal charcoal (d). CaCℓ2
(15). A technique in which a solute distribute itself in stationary phase and mobile phase is called :
(FSD,2022g2)
(a). Sublimation (b). Solvent extraction (c). Chromatography (d). None of these
(16). _______ is not used as drying agent in a desiccator. (GRW,2022g1)
(a). water (b). CaCl2 (c). silica gel (d). phosphorus pentaoxide
(17). ______ substance is used as decolorizing agent in crystallization process. (GRW,2022g2)
(a). silica gel (b). animal charcoal (c). CaCl2 (d). H2SO4
(18). The drying agent used in vacuum desiccator is: (SWL,2022g2)
(a). Silica gel (b). NaCl (c). AgCl (d). l2

KEY
(1). (c). 5 – 6 mm (2). (b). Liquid (3). (d). Filtration (4). (b). Solvent extraction
(5). (a). Benzoic acid (6). (b). Sublimation (7). (b). Silicon dioxide (8). (d). Carbon tetra chloride
(9). (d). CaCl2 (10). (b). Diethyl ether (12). (d). All these (13). (c). Solvent extraction
(14). (c). Powdered animal charcoal (15). (c). Chromatography (16). (a). water
(17). (b). animal charcoal (18). (a). Silica gel

Past Multiple Choice Questions Chapter #03 Gases Book – 1

(1). Formula used for the conversion of F into C is:
0 0
(RWP,2014)
(a). 0F = 9/5 (0C) + 32 (b). 0F = 5/9 [0F – 32] (c). 0F = 5/9 (0C) + 32 (d). 0F = 9/5 [0F – 32]
(2). The temperature of natural plasma is about: (DGK,2017)
(a). 200000C (b). 100000C (c). 50000C (d). 10000C

PAST MULTIPLE CHOICE QUESTIONS F.Sc PART – 1 CHEMISTRY | Shahbaz Ali

 Past Papers Multiple Choice Questions First Year Chemistry Topicwise 3

Or The temperature of natural plasma is about: (LHR,2017g2)

(a). 200000C (b). 10000C (c). 50000C (d). 100000C

(3). The commonly unit of pressure by meteorologists is: (AJK,2017)

(a). Atmosphere (b). Pascal (c). Millibar (d). Pound inch – 2
(4). Partial pressure of oxygen in the air is: (LHR,2018)
(a). 156 torr (b). 157 torr (c). 158 torr (d). 159 torr
(5). The gases show more deviation at : (FSD,2018)
(a). Low temperature and low pressure (b). High temperature and low pressure
(c). High temperature and high pressure (d). Low temperature and high pressure
(6). The spreading of fragrance of scent is due to : (SWL,2018)
(a). effusion (b). diffusion (c).osmosis (d). evaporation
(7). Volume occupied by one mole of gas at standard temperature and pressure is : (DGK,2019)
(a). 54 dm3 (b). 22.414 dm3 (c). 2.24 dm3 (d). 2.4 dm3
(8). The unit millibar is commonly used by : (LHR,2019)
(a).meteorologists (b).astronauts (c).engineers (d).Dalton
(9). The sum of mole fraction of gases in the mixture of gases is : (RWP,2019)
(a). always more than one (b). always lesser than one (c). always one (d). may be less or more than one
(10). The highest temperature at which a substance can exist as a liquid at its critical pressure is:(DGk,2019)
(a). Transition temperature (b). Critical temperature (c). Boiling point (d). Consulate temperature
(11). Temperature and number of moles are kept constant is: (DGK,2021g1)
(a). Boyle’s Law (b). Charles’ Law (c). Avogadro’s Law (d). Dalton’s Law of Partial Pressures
(12). Dalton’s Law of Partial Pressure can be derived from: (MTN,2021g1)
(a).Avogadro’s law (b). General gas equation (c). Charles’ Law (d). All of these
(13). At absolute zero total kinetic energy of gas molecules is: (MTN,2021g1)
(a). Maximum (b). Zero (c).Never becomes lower than 20J (d). Minimum

(14). Kinetic equation PV = 1/3 mNc2 is derived by: (MTN,2021g2)

(a).Maxwell (b). Boltzmann (c). Clausius (d). Bernulli
(15). The sun is a _____ ball of plasma heated by nuclear fusion process. (MTN,2021g2)
(a). 1.5 million kilometer (b). 1.5 billion kilometer (c). 3 million kilometer (d). None of these
(16). Kinetic energy of gas molecules is zero at: (SGD,2021g1)
(a).0 C0 (b). 0 F0 (c).0k (d). – 100 C0
(17). At what temperature does the gaseous state of any type of matter can’t exist? (SWL,2021)
(a).– 330C (b). 273.150C (c).– 273.150C (d). – 237.150C
(18). Density of an ideal gas can be calculated by using equation: (SWL,2021)
(a).PV=nRT (b). PM = dPV (c).d = RT/MP (d). PM = dRT
(19). How should the conditions be changed to prevent the volume of a gas from expanding when its mass
is increased? (DGK,2022g1)
(a). Temperature is lowered and pressure is increased (b). Temperature is increased and pressure is lowered
(c). Temperature and pressure both are lowered (d). Temperature and pressure both are increased
(20). Value of R at STP : (FSD,2022g2)
(a). 8.21dm3.atm.K – 1.mol– 1 (b). 0.821dm3.atm.K – 1.mol– 1
(c). 0.00821dm3.atm.K – 1.mol– 1 (d). 0.000821dm3.atm.K – 1.mol– 1
(21). Gases deviate from ideal behaviour at high pressure because: (FSD,2022g2)(RWP,2022g2)
(a). At high pressure, the gas molecule move in one direction only
(b). At high pressure, the gas molecule move in all direction
(c). At high pressure, there are significant attractive forces
(d). All these

KEY
(1). (b). 0F = 5/9 [0F – 32] (2). (a). 200000C Or (a). 200000C (3). (c). Millibar
(4). (d). 159 torr (5). (d). Low temperature and high pressure (6). (b). diffusion
(7). (b). 22.414 dm3 (8). (a).meteorologists (9). (c). always one
(10). (b). Critical temperature (11). (a). Boyle’s Law (12). (b). General gas equation
(13). (b). Zero (14). (c). Clausius (15). (a). 1.5 million kilometer
(16). (c).0k (17). (c).– 273.150C (18). (d). PM = dRT
(19). (a). Temperature is lowered and pressure is increased (20). (b). 0.0821dm3.atm.K – 1.mol– 1
(21). (c). At high pressure, there are significant attractive forces

PAST MULTIPLE CHOICE QUESTIONS F.Sc PART – 1 CHEMISTRY | Shahbaz Ali

 Past Papers Multiple Choice Questions First Year Chemistry Topicwise 4

Past Multiple Choice Questions Chapter #04 Liquids and Solids Book – 1
(1). The distillation of liquid under reduced pressure is called : (SGD,2014)
(a). Destructive distillation (b). Vacuum distillation (c). Fractional distillation (d). Simple distillation
(2). Allotropy is the property of : (SGD,2014)
(a). Compound (b). Element (c). Atom (d). Mixture
(3). The axis(unit cell length) for cubic is: RWP,2014)
(a). a ≠ b = c (b). a ≠ b ≠ c (c). a = b ≠ c (d). a = b = c
(4). Which of the given has hydrogen bonding : (BWP,2017)
(a). CH4 (b). CCℓ4 (c). NH3 (d). NaCℓ
(5). The dipole – dipole forces are present among: (SGD,2017)
(a). Molecules of iodine (b). Atoms of neon in gaseous state
(c). Chloroform molecules (d). CCℓ4 molecules
(6). Crystal of diamond is : (SGD,2017)
(a). Ionic (b). Covalent (c). Molecular (d). Metallic
(7). The liquid having the highest boiling point is : (FSD,2018)
(a). Hydrofluoric acid (b). Water (c). Hydrogen sulphide (d). Ammonia
(8). The strongest acid among halogen acids is : (MLN,2018)
(a). HCl (b). HBr (c). HI (d). HF
(9). Dipole – induced dipole forces are also called: (MLN,DGK,2018)
(a).Dipole – dipole forces (b). Ion – dipole forces (c). Debye forces (d). London dispersion forces
(10). Which one of the following is in liquid state at room temperature ? (SWL,2018)
(a). Methane (b). Ethane (c). Hexane (d). Propane
(11). Which of the following will have H – bonding in its molecules ? (AJK,2018)
(a). C2H5OH (b). CCℓ4 (c). I2 (d). NaCℓ
(12). Geometry of diamond is : (LHR,2018)
(a). Tetragonal (b). Cubic (c). Rhombohedral (d). None of these
(13). Which impurity makes the shape of sodium chloride crystal needle like: (FBD,2018)
(a). MgSO4 (b). Urea (c). Glucose (d). MgCO3
(14). ____ is molecular solid. (MLN,2018)
(a). NaCℓ (b). CO2 dry ice form (c). Diamond (d). Aluminium nitride
(15). Heat change for one mole of a solid during converting it into liquid is called : (DKG,2018)
(a).molar heat of fusion (b). molar heat of vapourization
(c). molar heat of sublimation (d). enthalpy change
(16). Density of ice is maximum at 40C due to : (LHR,2019)
(a). Empty spaces in structure of ice (b). Tetrahedral shape of crystal of ice
(c). Large bond lengths (d). Large bond angles
(17). The solid which has no definite crystalline shape: (LHR,2019)
(a). Sugar (b). Salt (c). Glass (d). Dry ice
(18). Hydrogen bonding is maximum in: (LHR,2019)
(a). HI (b). HBr (c). HCℓ (d). H2O
(19). Transition temperature of S8(Monoclinic) S8(Rhombic) is: (DGk,2019)
(a). 13.2 0C (b). 95.5 0C (c). 128 0C (d). 110 0C
(20). At 323 torr boiling point of H2O is: (AJK,2019)
(a). 1200C (b). 1000C (c). 690C (d). 1100C
(21). The solid which has no definite crystalline shape : (LHR,2019)
(a). sugar (b). salt (c).glass (d). dry ice
(22). Amorphous solids: (MLN,2019)
(a). have sharp melting points (b). undergo clean cleavage when cut with knife
(c). have perfect arrangement of atoms (d). can possess small regions of orderly arrangement
(23). The Crystal System of Sugar is: (BWP,2021g2)
(a). Monoclinic (b). Cubic (c). Hexagonal (d). Triclinic
(24). Which one pair is isomorphic in nature: (FSD,2021g1)
(a). NaCℓ,KBr (b). CaC2ℓ, CaCO3 (c). NaF, MgCℓ2 (d). Na2CO3, MgCO3
(25). Which is not isomorphic pair? (FSD,2021g2)
(a). NaNO3, KNO3 (b). MgO and NaF (c). K2SO4 and K2Cr2O7 (d). NaF and CaCℓ2
(26). The crystal system of sulphur is: (GRW,2012g1)
(a). cubic (b). hexagonal (c). triclinic (d). monoclinic
(27). In monoclinic crystal system, bond axes are: (LHR,2021g1)
(a). a = b = c (b). a = b ≠ c (c). a ≠ b = c (d). a ≠ b ≠ c
(28). Bond angles α = γ = 900 ; β ≠900 and a ≠ b ≠ c is for crystal system: (LHR,2021g2)
(a). Tetragonal (b). Hexagonal (c). Monoclinic (d). Triclinic
(29). Debye forces are also called : (MTN,2021g1)
(a).Dipole – dipole forces (b). Dipole – induced dipole forces (c). London forces (d). Ion – dipole forces
PAST MULTIPLE CHOICE QUESTIONS F.Sc PART – 1 CHEMISTRY | Shahbaz Ali
 Past Papers Multiple Choice Questions First Year Chemistry Topicwise 5

(30). The order of acidic strength : (MTN,2021g2)

(a).HF > HCℓ > HBr > HI (b). HCℓ > HF > HI > HBr (c). HI > HBr > HCℓ > HF (d). HBr > HF > HI > HCℓ
(31). Which one of the following an example of cubic system: (RWP,2021)
(a).Diamond (b). Borax (c).Iodine (d).Graphite
(32). The unit cell parameters are: (SGD,2021g1)
(a). 2 (b). 4 (c). 6 (d). 8
(33). The angle between sides ‘b’ and ‘c’ is: (SGD,2021g2)
(a). Beta (b). Alpha (c). Theta (d). Gamma
(34). Intermolecular forces present in ammonia are _____. (SGD,2021g2)
(a).Hydrogen bonding (b). Ion–dipole forces (c).Dipole–induced dipole forces (d). London–dispersion forces
(35). Among the given H – bonding maximum in: (SWL,2021)
(a). Alcohol (b). Benzene (c). Water (d). Diethyl ether
(36). In chloroform and acetone, how many chlorine atoms are responsible for hydrogen bonding:(SWL,2021)
(a). 1 (b). 2 (c). 3 (d). 4
(37). _____ is a pseudo solid. (GRW,2022g2)
(a). glass (b). CaF2 (c). NaCl (d). HCl
(38). Dipole – dipole forces are present among the : (RWP,2022g2)
(a). Atoms of helium gas (b). Molecules of CCl4 (c). Molecules of solid I2 (d). Molecules of HCl
(25). Which of the given pair do not isomorphism ? (FSD,2022g1)
(a). NaNO3, KNO3 (b). ZnSO4 and NiSO4 (c). Cu, Ag (d). NaCl and CuCℓ2

KEY
(1). (b). Vacuum distillation (2). (b). Element (3). (d). a = b = c
(4). (c). NH3 (5). (c). Chloroform molecules (6). (b). Covalent
(7). (b). Water (8). (c). HI (9). (c). Debye forces
(10). (c). Hexane (11). (a). C2H5OH (12). (b). Cubic
(13). (b). Urea (14). (b). CO2 dry ice form (15). (a).molar heat of fusion
(16). (a). Empty spaces in structure of ice (17). (c). Glass
(18). (d). H2O (19). (b). 95.5 0C (20). (c). 690C
(21). (c).glass (22). (d). can possess small regions of orderly arrangement
(23). (a). Monoclinic (24). (a). NaCℓ ,KBr (25). (d). NaF and CaCℓ2
(26). (d). monoclinic (27). (d). a ≠ b ≠ c (28). (c). Monoclinic
(29). (b). Dipole – induced dipole forces (30). (c). HI > HBr > HCℓ > HF (31). (a).Diamond
(32). (c). 6 (33). (b). Alpha (34). (a).Hydrogen bonding
(35). (c). Water (36). (c). 3 (37). (a). glass
(38). (d). Molecules of HCl (25). (d). NaCl and CuCℓ2

Past Multiple Choice Questions Chapter #05 Atomic Structure Book – 1

(1). When fast neutron carries nuclear reaction with nitrogen it ejects particles : (RWP,2014)
(a). α (b). β (c). γ (d). δ
(2). Cathode rays strike alumina and produce a ____ colour. (GRW,2014)
(a). red (b). blue (c). yellow (d). green
(3). Maximum number of electrons in f – subshell is : (DGk,2015)
(a). 2 (b). 6 (c). 10 (d). 14
(4). de Broglie equation is represented by : (DGK,2017)
(a). h = λ /mv (b). m = h/λv (c). m = λ /hv (d). λ = h/mv
(5). When 5d orbital is completed then entering electron goes formula : (DGK,2017)
(a). 6s (b). 6p (c). 6d (d). 6f
(6). When one beta (β) particle is emitted from the nucleus of an atom its : (FSD,2018)
(a). Atomic number increases by 1 (b). Atomic number decreases by 1
(c). Atomic mass increases by 1 (d). Atomic mass decreases by 1
(7). Splitting of spectral lines when atoms are subjected to strong electrical field is called: (LHR,2019)
(a).Zeeman effect (b). Stark effect (c). Photoelectric effect (d). Compton effect
(8). Splitting of spectral lines of hydrogen atoms under magnetic field is called: (FSD,2019)
(a). Stark effect (b). Zeeman’s effect (c). Compton effect (d). Splitting effect
(10). The value of Quantum Number, ℓ = 0,1,2,3 --------(n – 1) is for: (BWP,2021g2)
(a). Principal Quantum Number (b). Azimuthal Quantum Number
(c). Magnetic Quantum Number (d). Spin Quantum Number
(11). Mass of electron is: (DGK,2021g1)
(a).9.1095x10 – 31 kg (b). 6.02x1023 (c). 6.022x10 22 (d). 10.10x1030

PAST MULTIPLE CHOICE QUESTIONS F.Sc PART – 1 CHEMISTRY | Shahbaz Ali

 Past Papers Multiple Choice Questions First Year Chemistry Topicwise 6

(12). Which is correct? (FSD,2021g1)

(a). Idea of presence of neutron in an atom was provided by Chadwick
(b). Neutron was discovered by using radioactive Beryllium
(c). Fast neutron having energy 1.2 eV (d). Slow neutron have energy above 1 eV
(13). The value of quantum number is n = 1,2,3,4,5 -------- for (GRW,2021g1)
(a). Principal Quantum Number (b). Azimuthal Quantum Number
(c). Magnetic Quantum Number (d). Spin Quantum Number
(14). Total number of electrons in f orbital is: (MTN,2012g2)
(a). 14 (b). 10 (c). 6 (d). 2
(15). Brackett series lie in the region: (RWP,2021)
(a). U.V (b). I.R (c).Visible (d). X – Ray
(16). Quantum number values of ‘3d’ orbitals will be: (SGD,2021g2)
(a). n=3, ℓ=0 (b). n=3, ℓ=1 (c). n=3, ℓ=2 (d). n=3, ℓ=3
(17). Most stable electronic configuration is of a/an: (SWL,2021)
(a). Noble gas (b). Electronegative element (c). Alkali metals (d). Halogen
(18). Among the given e/m value is maximum for: (SWL,2021)
(a). Oxygen (b). Nitrogen (c). Helium (d). Hydrogen
(19). The value of charge on electron is: (RWP,2022g1)
(a). 2.602x10 – 19Coulombs (b). 1.602x1019Coulombs (c). 1.6023x10 – 19Coulombs (d). 1.602x10 – 19 Kg
(20). Which of the given sub – atomic particle does not show ionization? (SWL,2022g1)
(a). Electron (b). Proton (c). Neutron (d). Alpha ray

KEY
(1). (a). α (2). (a). red (3). (d). 14 (4). (d). λ = h/mv
(5). (b). 6p (6). (a). Atomic number increases by 1 (7). (b). Stark effect
(8). (b). Zeeman’s effect (10). (b). Azimuthal Quantum Number (11). (a).9.1095x10 – 31 kg
(12). Idea of presence of neutron in an atom was provided by Chadwick (13). (a). Principal Quantum Number
(14). (a). 14 or (d). 2 (15). (b). I.R (16). (c). n=3, ℓ=2 (17). (a). Noble gas
(18). (d). Hydrogen (19). (c). 1.6023x10 – 19Coulombs (20). (c). Neutron

Past Multiple Choice Questions Chapter #06 Chemical Bonding Book – 1

(1). In methanol, bond between carbon and oxygen : (RWP,2014)
(a). ionic (b).nonpolar (c). polar (d). co-ordinate
(2). The molecular shape of SO3 is : (DGK,2014)
(a). triangular planar (b). tetrahedral (c). pyramidal (d). linear
(3). The tendency of an atom to attract shared pair of electron towards itself is called its : (SGD,2014)
(a). ionization energy (b). electron affinity (c). electronegativity (d). dipole moment
(4). The paramagnetic behaviour of oxygen is well explained on the basis of : (SGD,2014)
(a). M.O theory (b). VSEPR theory (c). V.B theory (d). CF theory
(5). The number of bonds in oxygen molecule : (LHR,2015)
(a). one σ and one π (b). one σ and two π (c). three sigma only (d). two σ and two π
(6). Which of the following has linear structure : (LHR,2017)
(a). CO2 (b). NH3 (c). CH4 (d). H2O
(7). Which element has highest ionization potential : (SGD,2017)
(a). Li (b). Be (c). B (d). C
(8). Which of the following has bond angle of 1200 : (LHR,2017)
(a). BeCℓ2 (b). BF3 (c). CH4 (d). NH3
(9). Percentage ionic character of HF is : (DGK,2017)
(a). 100% (b). 80% (c). 43% (d). 57%
(10). Which of the following molecule do not obey the Octet rule? (SWL,2018)
(a).CH4 (b). CO2 (c). PF5 (d). CS2
(11). Which one of the following molecules has zero dipole moment : (LHR,2018)
(a). H2S (b). SO2 (c). H2O (d). CH4
(12). Which one of the following molecules has zero dipole moment : (GRW,2018)
(a). NH3 (b). CHCℓ3 (c). H2O (d). CS2
(13). In nitrogen(N2) each nitrogen atom contributes in sharing for formation of bond: (FSD,2018)
(a). one electron (b). two electrons (c).three electrons (d). four electrons
(14). Which one has the highest value of ionization energy: (FSD,2018)
(a). Be (b). C (c). O (d). F
(15). In ethyne molecule the number and nature of bonds are : (MLN,2018)
(a). one sigma two pi (b). two sigma one pi (c). three sigma two pi (d). two sigma two pi
PAST MULTIPLE CHOICE QUESTIONS F.Sc PART – 1 CHEMISTRY | Shahbaz Ali
 Past Papers Multiple Choice Questions First Year Chemistry Topicwise 7

(16). ______ element has highest value of electron affinity. (MLN,2018)

(a).fluorine (b). chlorine (c). bromine (d). iodine
(17). ______ is not paramagnetic. (MLN,2018)
(a). O22 – (b). N2 (c). N22 – (d). None of these
(18). Geometry of SO2 molecule is : (DGK,2018)
(a). linear (b). angular (c). tetrahedral (d). trigonal planar
(19). The amount of energy released by absorbing an electron in the valence shell of an atom is: (DGK,2018)
(a). ionization energy (b). electron affinity (c). electronegativity (d). bond energy
(20). Which of the following species has unpaired electron in the antibonding molecular orbitals: (BWP,2018)
(a). O22 – (b). N22 – (c). B2 (d). F2
(21). For HF molecule µobs is 1.90D ; µionic is 4.4D. The percentage ionic character of HF molecule is: (LHR,2019)
(a). 100 (b). 80 (c). 57 (d). 43
(22). The type of hybridization in BeCl2 is: (LHR,2019)
(a). sp3 (b). sp2 (c). sp (d).dsp2
(23). One of the following molecule is polar in nature: (DGK,2019)
(a). CH4 (b). CO2 (c). SO2 (d). CCℓ4
(24). The Bond which is formed by mutual sharing of Electrons is called: (BWP,2021)
(a). Ionic bond (b). Covalent bond (c). Metallic bond (d). Coordinate covalent bond
(25). Type of Hybridization in H2O is: (BWP,2021g2)
(a). sp (b). sp2 (c). sp3 (d).dsp2
(26). Minimum amount of energy required to remove an electron from its gaseous atom is called:
(DGK,2021g1)
(a). Ionization energy (b). Electron – Affinity (c). Oxidation (d). Reduction
(27). Methane molecule contains type of hybridization: (DGK,2021g1)
(a). sp (b). sp2 (c). sp3 (d). dsp2
(28). The amount of energy released by absorbing an electron in the valence shell is: (DGK,2021g2)
(a). ionization energy (b). electron affinity (c). electronegativity (d). atomization energy
(29). The bond angle in ammonia molecule is: (DGK,2012g2)
(a). 109.50 (b).107.50 (c).104.50 (d). 1800
(30). The geometry of SO2 molecule is: (FSD,2021g1)
(a). Angular (b). Linear (c). Tetrahedral (d). Trigonal pyramid
(31). The planar structure of BF3 can be explained by the fact that BF3 is: (FSD,2021g1)
(a). sp - hybridized (b). sp2 - hybridized (c). sp3 - hybridized (d). dsp2 - hybridized
(32). The type of hybridization of in NH3 is: (GRW,2021g1)
(a). SP (b). SP2 (c). SP3 (d). dSP2
(33). According to VSEPR theory, the shape of PH3 molecule is: (LHR,2021g1)
(a). Trigonal pyramidal (b). Tetragonal (c). Linear (d). Trigonal planer
(34). Ionization energy for Mg Mg+ + 1e – has ∆H= ------
(a).738kJmoℓ –
(b). 238kJmoℓ – (c). 448kJmoℓ – (d). 138kJmoℓ –
(35). Among the following quantum a pair of molecule having similar geometry: (MTN,2021g1)
(a). BF3 , NH3 (b). BF3 , AℓF3 (c). BeF2 , H2O (d). BCℓ3 , PCℓ3 [Correction: replace “quantum” with “given”]
(36). Which one of the following has the highest bond order? (MTN,2021g1)
(a). O21+ (b). O22+ (c). O2 – 1 (d). O2 – 2
(37). The bond order of He2 is : (MTN,2021g2)(BWP,2022g2)
(a). Two (b). Three (c). Zero (d). One
Or The bond order of helium molecule is : (SGD,2021g1)
(a). Zero (b). One (c). Two (d). Three
Or Bond order of helium molecule is _____: (SGD,2021g2)
(a). Two (b). One (c). Zero (d). Three
(38). How many types of bonds in NH4Cℓ are: (MTN,2021g2)
(a). One type (b). Two types (c). Three types (d). Four types
(39). The covalent radius of Cl – atom is: (RWP,2021)
(a).99.4pm (b). 80pm (c).70pm (d). 66.4pm
(40). Beryllium dichloride follows_____ hybridization. (SGD,2021g2)
(a). sp (b).sp3 (c).sp2 (d).dsp2
(41). Which one of given is a linear molecule? (SWL,2021)
(a). H2O (b). HCN (c). Cl2O (d). C2H4
(42). Which one has perfectly triangular shape? (DGK,2022g1)
(a). SnCl2 (b). CO2 (c).SO3 (d). NH3
(43). In sp hybrid orbital percentage of S – character is (DGK,2022g2)
(a). 100% (b). 25% (c). 75% (d). 50%

PAST MULTIPLE CHOICE QUESTIONS F.Sc PART – 1 CHEMISTRY | Shahbaz Ali

 Past Papers Multiple Choice Questions First Year Chemistry Topicwise 8

(44). VSEPR theory was developed by_____ (GRW,2022g1)

(a). Sidgwick and Powell (b). Sidgwick and Nylholm
(c). Powell and Gillespie (d). Nylholm and Gillespie
(45). BF3 shows ______ hybridization. (GRW,2022g1)
(a).sp2 (b). sp3 (c). sp (d). sp3d
(46). In sp hybrid orbital “S” character is _____.
3
(GRW,2022g2)
(a). 25% (b). 50% (c). 75% (d). 100%
(47). Which one has a regular tetrahedral shape: (LHR,2022g1)
(a). SnCℓ2 (b). CH4 (c). SO3 (d). BF3
(48). Geometry of H2O on the basis of VSEPR theory: (RWP,2022g1)
(a). Linear (b). Trigonal planer (c). Tetrahedral (d). Bent
(49). Which of the following hydrocarbons has shortest C – C bond length ? (RWP,2022g2)
(a). Ethyne (b). Ethene (c). Ethane (d). Benzene
(50). The type of hybridization in molecule of CH2 =CH2 is: (SWL,2022g1)
(a). sp (b). sp3 (c). sp2 (d). dsp
(51). Which one of the given compounds possess ionic bonding? (SWL,2022g1)
(a). CaO (b). CH4 (c). CH3Cl (d). C2H6

KEY
(1). (c). polar (2). (a). triangular planar (3). (c). electronegativity (4). (a). M.O theory
(5). (a). one σ and one π (6). (a). CO2 (7). (d). C
(8). (b). BF3 (9). (c). 43% (10). (c). PF5 (11). (d). CH4
(12). (d). CS2 (13). (c).three electrons (14). (d). F (15). (c). three sigma two pi
(16). (b). chlorine (17). (a). O22 – (18). (b). angular (19). (b). electron affinity
(20). (b). N22 – (21). (d). 43 (22). (c). sp (23). (c). SO2
(24). (b). Covalent bond (25). (c). sp3 (26). (a). Ionization energy
(27). (c). sp3 (28). (b). electron affinity (29). (b).107.50 (30). (a). Angular
(31). (b). sp2 - hybridized (32). (c). SP3 (33). (a). Trigonal pyramidal
(34). (a).738kJmoℓ – (35). (b). BF3 , AℓF3 (36). (a). O21+
(37). (c). Zero Or (a). Zero Or (c). Zero (38). (c). Three types (39). (a).99.4pm
(40). (a). sp (41). (b). HCN (42). (c).SO3 (43). (d). 50%
(44). (d). Nylholm and Gillespie (45). (a). sp2 (46). (a). 25%
(47). (b). CH4 (48). (d). Bent (49). (a). Ethyne (50). (c). sp2
(51). (a). CaO

Past Multiple Choice Questions Chapter #07 Thermochemistry Book – 1

(1). Which of the following statement is contrary to the first law of thermodynamic? (RWP,2014)
(a). an equivalent amount of heat energy can either be created or destroyed
(b). one form of energy can be transferred into an equivalent amount of other kinds of energy
(c). in an adiabatic process, the work done is independent of its path
(d). continuous production of mechanical work without supplying an equivalent amount of heat is possible
(2). Enthalpies of all elements in their standard states are : (SGD,2018)
(a). unity (b). zero (c). always positive (d). always negative
(3). The amount of heat absorbed when one mole of gaseous atoms are formed from the element is called :
(LHR,2019)
(a). formation (b). reaction (c). combustion (d). atomization
(4). The property of a system which has some definite values for initial and final states is called:
(DGK,2021g1)
(a). State (b). State function (c). System (d). Surroundings
(5). Energy of universe remains constant it is called: (MTN,2021g1)
(a). First law of thermodynamics (b). First law of thermochemistry
(c). Second law of thermochemistry (d). Second law of thermodynamics
(6). ∑∆H(cycles) = 0 The above law is known as : (MTN,2021g2)
(a). Henry’s law (b). Hess’s law (c). Kohlarus law (d). Darwins law
(7). Which of these is not a state function: (SGD,2021g1)
(a). Temperature (b). Pressure (c). Volume (d). Heat
(8). The Born – Haber cycle is application of ______ law. (SGD,2021g2)
(a). Hess’s (b). Le-Chatelier (c). Coulomb (d). Pascal
(9). The pH of 0.001moldm – 3 of an aqueous solution of H2SO4 is: (SGD,2021g2)
(a).3 (b).2.7 (c).2.0 (d). 1.5

PAST MULTIPLE CHOICE QUESTIONS F.Sc PART – 1 CHEMISTRY | Shahbaz Ali

 Past Papers Multiple Choice Questions First Year Chemistry Topicwise 9

(10). 1 kilo carlorie is equivalent to : (SWL,2021)

(a). 0.4184 J (b). 4184 J (c).4184KJ (d). 4.18 J
(11). Which does not undergo sublimation : (LHR,2022g1)
(a). Ammonium chloride (b). Naphthalene (c). Iodine (d). Mercury

KEY
(1). (d). continuous production of mechanical work without supplying an equivalent amount of heat is possible
(2). (b). zero (3). (d). atomization (4). (b). State function
(5). (a). First law of thermodynamics (6). (b). Hess’s law
(7). (d). Heat (8). (a). Hess’s (9). (b).2.7
(10). (b). 4184 J (11). (d). Mercury

Past Multiple Choice Questions Chapter #08 Chemical Equilibrium Book – 1

(1). In the presence of common ion, the ionization of an electrolyte will: (RWP,2014)
(a). increase (b).decrease (c). no effect (d). moderate change
(2). Acid having Ka > 1 will be : (RWP,2014)
(a). weak (b). very weak (c). moderate (d). strong
(3). pH of bananas is: (SGD,2014)
(a). 2.1 (b). 4.6 (c). 9.4 (d). 9.6
(4). pOH of water is: (DGK,2015)
(a).2.0 (b).4.0 (c).6.0 (d). 7.0
(5). Catalyst used in preparation of NH3 from N2 and H2 is: (SGD,2017)
(a). Fe (b). Ni (c). Pt (d). V2O5
(6).pH of soft drinks at 250C is about : (DGK,2017)
(a). 3.0 (b). 11.0 (c). 1.0 (d). 7.0
(7). The ionization constant of pure water ( Kw ) at 250C is: (MLN,2017)
(a). 1.8x10 – 16 mol.dm – 3 (b). 1.6x10 – 14 mol.dm – 3 (c). 1.0x10 – 14 mol2.dm – 6 (d). 1.8x10 – 14 mol2.dm – 6
(8). Approximate pH of apple is : (LHR,2018)
(a). 2.7 (b). 3.1 (c). 4.2 (d). 4.5
(9). Rain water is : (LHR,2018)
(a).slightly acidic (b).slightly basic (c). neutral (d). strong
(10). Which one affects the value of Kc ? (FSD,2018)
(a). concentration (b). temperature (c). pressure (d). catalyst
(11). The sum of pH and pOH at 250C always equal to : (MLN,2018)
(a). 7 (b). zero (c).14 (d). 10 – 14
(12). The units of Kw of H2O are : (MLN,2018)
(a).mol/dm3 (b). mol2.dm – 6 (c). mol – 2 .dm 6 (d). mol– 2.dm – 6
(13). The value of Kw of water at 250C is: (DGK,2018)
(a). 0.11 x 10 – 14 (b). 0.30 x 10 – 14 mol.dm – 3 (c). 1.0 x 10 – 14 (d). 7.5 x 10 – 14
(14). When Kc value of a reaction is very small, the equilibrium position lies to : (DGK,2018)
(a).left (b). right (c). may be left or right (d). cannot be predicted
(15). Catalyst used in preparation of SO3 gas from SO2 is : (AJK,2018)
(a).Al2O3 (b).CaO (c). V2O5 (d). SiO2
(16). The salt dissolved in water forms a solution of pH greater than 7: (LHR,2019)(DGK,2019)
(a). NaCℓ (b). Na2CO3 (c). CuSO4 (d). NH4Cℓ
(17). The pH of a solution is 9 the solution is : (DGK,2019)
(a). weakly acidic (b).weakly basic (c). strongly acidic (d).strongly basic
(18). Following halide has the highest ionic character: (DGK,2019)
(a).HBr (b). HCℓ (c). HF (d). HI
(19). The solution which resists change in its pH either an Acid or Base is added in it is called:(BWP,2021)
(a).Buffer solution (b). Acid (c). Base (d). Alkali
(20). The reaction which proceeds in both forward and backward directions is called: (DGK,2021g1)
(a). Irreversible reaction (b). Reversible reaction (c). Spontaneous reaction (d). Non spontaneous reaction
(21). In Haber process, for formation of NH3, the process(pressure) used is: (DGK,2021g2)
(a). 100 atm (b). 200 – 300 atm (c). 600 atm (d). 1000 atm
(22). A solution with pH =2 is more acidic than a solution with pH = 6 by a factor of: (FSD,2021g1)
(a). 4 (b). 8 (c).1000 (d). 10000
(23). The value of ∆n for the given equilibrium N2 + 3H2 2NH3 is: (FSD,2021g1)
(a). – 2 (b). +2 (c). +1 (d). + 4
(24). The pH of buffers cam be calculated by: (FSD,2021g2)
(a).Henderson equation (b). Nernst equation (c).Kinetic equation (d). Arrhenius equation

PAST MULTIPLE CHOICE QUESTIONS F.Sc PART – 1 CHEMISTRY | Shahbaz Ali

 Past Papers Multiple Choice Questions First Year Chemistry Topicwise 10

(25). Less soluble KCℓO3 is precipitated from its solution by common ion effect on adding: (FSD,2021g2)
(a). HCℓ (b). KCℓ (c). H2S (d). NaCℓ
(26). Law of mass action states that the rate at which the reaction proceeds is directly proportional to the
product of the active masses of : (GRW,2021g1)
(a). reactants (b). products (c).concentration (d). equilibrium
(27). The pH of mixture of CH3COONa and CH3COOH is : (LHR,2021g1)
(a).7 (b). > 7 (c). < 7 (d). 1
(28). 2O3 3O2 Kc at 250C is : (MTN,2021g2)
(a). 1055
(b). 10 – 13 (c). 2.5 (d). 104
(29). Among the following which equation has no unit of Kc : (MTN,2021g2)
(a). N2(g) + 3H2(g) 2NH3(g) (b). PCℓ5(g) PCℓ3(g) + Cℓ2(g)

O O
‖ H+ ‖
(c).CH3 – C – OC2H5 + H2O CH3 – C – OH + C2H5OH (d). N2O4 2NO2
(30). pH of vinegar is: (RWP,2021)
(a). 1.1 (b).2.0 (c). 2.8 (d).3.5
(31). How many nitrogen fixation is carried out by Haber’s Process: (SGD,2021g1)
(a). 13% (b). 35% (c). 50% (d). 73%
(32). The value of pKw at 250C for water is: (SGD,2021g1)
(a). 10 – 7 (b). 7 (c).10 – 14 (d). 14
(33). pH of 10 – 4 mol.dm– 3 of HCℓ is: (FSD,2022g2)
(a).1 (b).2 (c).3 (d).4
(34). For which system, does the equilibrium constant Ice has no units: [correction replace word ice with Kc]
[RWP,2022p1)
(a). N2 + 3H2 2NH3 (b). H2 + I2 2HI (c). 2NO2 N2H4 (d). None of these
(35). The aqueous solution of BiCl3 is cloudy. The cloudness of BiCl3 solution can be vanished by :
(RWP,2022g2)
(a). Addition of BiCl3 (b). Addition of H2O (c). Addition of HCl (d). Addition of both BiCl3 and H2O

KEY
(1). (b). decrease (2). (d). strong (3). (b). 4.6 (4). (d). 7.0
(5). (a). Fe (6). (a). 3.0 (7). (c). 1.0x10 – 14 mol2.dm – 6 (8). (b). 3.1
(9). (a). slightly acidic (10). (b). temperature (11). (c).14 (12). (b). mol2.dm – 6
(13). (c). 1.0 x 10 – 14 (14). (a). left (15). (c). V2O5 (16). (b). Na2CO3
(17). (b). weakly basic (18). (c). HF (19). (a). Buffer solution (20). (b). Reversible reaction
(21). (b). 200 – 300 atm (22). (d). 10000 (23). (a). – 2 (24). (a).Henderson equation
(25). (b). KCℓ (26). (a). reactants (27). (c). < 7 (28). (a). 1055
(29). (c). (30). (c). 2.8 (31). (a). 13% (32). (d). 14
(33). (d).4 (34). (b). H2 + I2 2HI (35). (c). Addition of HCl

Past Multiple Choice Questions Chapter #09 Solutions Book – 1

(1). Two solutions of NaCl and KCl are prepared separately by dissolving same amount of the solute in
water. Which of the following statement is true for these solutions? (SGD,2003)
(a). KCl solution will have higher boiling point than NaCl solution.
(b). Both the solutions have different boiling points.
(c). KCl and NaCl solutions possess same vapour pressure.
(d). KCl solution possesses lower freezing point than NaCl solution.
(2). Melting point of ice can be lowered by the use of : (RWP,2014)
(a). LiCℓ (b). BeCℓ2 (c).NaCℓ (d). AgCℓ
(3). Colligative properties are the properties of : (SGD,2014)(RWP,2022g1)
(a).Dilute solutions which behave as nearly ideal solutions
(b). concentrated solutions which behave as nearly nonideal solutions
(c). Both (a) and (b) (d). Neither (a) nor (b)
(4). The relative lowering of vapour pressure is equal to: (LHR,2017)
(a).mole fraction of solute (b). mole fraction of solvent (c). molarity (d). molality
(5). In azeotropic mixture showing positive deviation from Raoult’s law, the volume of the mixture is:
(a). Slightly more than the total volume of the components. (LHR,2017)
(b). Slightly less than the total volume of the components.
(c). Equal to the total volume of the components.
(d). None of these.

PAST MULTIPLE CHOICE QUESTIONS F.Sc PART – 1 CHEMISTRY | Shahbaz Ali

 Past Papers Multiple Choice Questions First Year Chemistry Topicwise 11

(6). The molal boiling point constant is the ratio of the elevation in boiling point to: (SGD,2017)
(a). molarity (b). molality (c). mole fraction of solvent (d). mole fraction of solute
(7). The number of water molecules in CuSO4.5H2O attached with Cu2+ ion : (MLN,2018)
(a). One (b). Two (c). Three (d). Four
(8). Upper consulate temperature of water phenol system is: (AJK,2018)
(a). 1500C (b). 65.90C (c). 1200C (d). 1300C
(9). Ideal solutions obey: (LHR,2018)
(a). Henry’s Law (b). Avogadro’s Law (c). Raoult’s Law (d). Smith’s Law
(10). One molar solution of glucose (C6H12O6) contains the amount of solute in 500cm3 solution:(FSD,2018)
(a). 180 g (b). 90 g (c). 45 g (d). 270 g
(11). Liquids which are practically immiscible: (LHR,2019)
(a).H2O+C6H6 (b). H2O+C2H5OH (c). H2O+HCl (d). H2O+CH3 – O – CH3
(12). An aqueous solution of ethanol(C2H6O) in water has vapour pressure: (DGK,2019)
(a). Equal to that of ethanol (b). Equal to that of water
(c). More than that of water (d). Less than that of water
(13). Which one of the following is not a colligative property: (AJK,2019)
(a).lowering of vapour pressure (b). elevation of B.P
(c). depression of freezing point (d). boiling point of solution
(14). Osmotic pressure is an example is: (DGK,2021g1)
(a). Colligative properties (b). Additive properties (c). Constitutive properties (d). Internal energy
(15). The properties of substances which depend solely on number of particles present is known as:
(FSD,2021g1)
(a). Additive properties (b). Constitutive properties
(c). Additive and constitutive properties (d). Colligative properties
(16). A thermometer used Landsberger’s method can read upto: (LHR,2021g1)
(a). 0.1K (b). 0.01 F (c).0.01 K (d). 0.01 0C
(17). The correct equation of Raoult’s law: (MTN,2021g2)
(a). ∆p/p0 = X2 (b). ∆p/p0 = X1 (c). p0 /∆p = X2 (d). p0 /∆p = x2 – x1
(18). Mathematical expression of Raoult’s Law is : (SWL,2021)
(a). P α X1 (b). ΔP α X2 (c). ΔP/Po = X2 (d). All of these

KEY
(1). (b). Both the solutions have different boiling points. (2). (c).NaCℓ
(3). (a).Dilute solutions which behave as nearly ideal solutions (4). (a).mole fraction of solute
(5). (a). Slightly more than the total volume of the components. (6). (b). molality (7). (d). Four
(8). (b). 65.90C (9). (c). Raoult’s Law (10). (b). 90 g
(11). (a).H2O+C6H6 (12). (c). More than that of water
(13). (d). boiling point of solution (14). (a). Colligative properties
(15). (d). Colligative properties (16). (c).0.01 K (17). (a). ∆p/p0 = X2
(18). (d). All of these

Past Multiple Choice Questions Chapter #10 Electrochemistry Book – 1

(1). In silver oxide battery, the cathode is made up of : (RWP,2014)
(a). AgO (b).Ag2O (c). Ag2O3 (d). Ag
(2). If the salt bridge is not used between two half cells then the voltage: (GRW,2018)
(a). decreases rapidly (b). decreases slowly (c). does not change (d). drops top zero
(3). Cathode in NICAD cell is of: (SGD,2018)
(a). Ag2O (b). Zn (c). Cd (d). NiO2
(4). Standard hydrogen electrode(SHE) is made of : (SGD,2018)
(a). Ag foil (b). Au foil (c). Cu foil (d). Pt foil
(5). The standard electrode potential(in volt) of SHE is taken as: (DGK,2019)
(a). 0.00 (b). 1.00 (c). 10.0 (d). 100
(6). Stronger the reducing agent, greater is the: (FSD,2021g1)
(a). Oxidation potential (b). Reduction potential (c). Redox potential (d). Electromotive force of cell
(7). The standard redox potential of following reaction is: Zn2+ + 2e – Zn (MTN,2021g2)
(a). – 0.76 V (b). 2.87 V (c). – 0.026 V (d). – 3.045 Volt

KEY
(1). (b).Ag2O (2). (d). drops top zero (3). (d). NiO2 (4). (d). Pt foil
(5). (a). 0.00 (6). (b). Reduction potential (7). (a). – 0.76 V

PAST MULTIPLE CHOICE QUESTIONS F.Sc PART – 1 CHEMISTRY | Shahbaz Ali

 Past Papers Multiple Choice Questions First Year Chemistry Topicwise 12

Past Multiple Choice Questions Chapter #11 Reactions Kinetics Book – 1

(1). The rate of reaction determined at any given time is called: (SGD,2014)
(a). average rate (b). instantaneous rate (c). spontaneous rate (d). overall rate
(2). Half – life period for U92 235 is: (AJK,2015)
(a). 710 million years (b). 720 million years (c). 810 million years (d). 820 million years
(3). With increase in 100C temperature, the rate of reaction doubles. This increase in the rate of reaction
due to: (FSD,2017)
(a). Decrease in the activation energy of reaction
(b). Decrease in the number of collisions between the reactant molecules
(c). Increase in the activation energy of reactants
(d). Increase in the number of effective collisions
(4). The rate of reaction _____ as the reaction proceeds. (GRW,2017)
(a). increases (b). decreases (c). remains the same (d). may decrease or increase
(5). Photochemical reactions are usually: (GRW,2018)
(a). zero order (b). first order (c). second order (d). third order
(6). The order of following reaction CHCℓ3(g) + Cℓ2(g) CCℓ4(l) + HCℓ(g) (MTN,2021g2)
(a). 1st (b). 1.5 (c). 2.5 (d). Zero
(7). In Zero order reaction the rate is independent of: (SGD,2021g1)
(a).Temperature (b). Pressure (c).Concentration (d). Volume
(8). Catalyst for a catalyst is also called : (SWL,2022g1)
(a). Promotor (b). inhibitor (c). Poisoning (d). Retarder

KEY
(1). (b). instantaneous rate (2). (a). 710 million years (3). (d). Increase in the number of effective collisions
(4). (b). decreases (5). (a). zero order (6). (b). 1.5 (7). (c).Concentration
(8). (a). Promotor

PAST MULTIPLE CHOICE QUESTIONS F.Sc PART – 1 CHEMISTRY | Shahbaz Ali