Key Unit 12 Transition Elements
Key Unit 12 Transition Elements
PMC – NMDCAT Lecture by Sheikh Shahbaz Ali A.INORGANIC CHEMISTRY 12. TRANSITION ELEMENTS
Co2+
27 [Ar] 3d74s 3
Zn2+
30 [Ar] 3d104s0 0
alkaline sodium
nitroprusside solution to O=C–O O–C=O 2–
give a complex of colour: 2+
A). brick red +
B). wine red or orange red 2K Pt
C). white D). violet
13). What is the correct O=C–O O–C=O
name of the given complex
ion? COLOUR OF COORDINATION COMPOUND(COMPLEXES)
[MnCl4 ]2 – Complex ion absorbs wavelength of visible light and transmits a set of
A). Manganese tetrachloride(I) radiation and imparts colour. The d – d splitting is due to crystal field
B). Tetrachloromanganese (II) effect of ligands
C). dx2– y2 dz2
Tetrachloromanganate(II)
D). Tetrachoridemanganate(II) d – d after
14). Which complex after absorbing ∆E
compound is used during
the study X – ray spectrum.
∆E
A). [Cr(H2O)6]Cl3 B).
K3[Fe(CN)6]
B). [Ag(NH3)2]Cl D).
K4[Fe(CN)6] dxy dxz dxy
14). Which compound has a
colour not due to d – d Red Orange
transition? [Ti(H2O)6 ]3+ = Y – BR – V
A). FeSO4 C). Coloured ions = Ni2+, Cu2+, Mn2+ , Co2+, Fe2+ violet
CuSO4.5H2O Yellow
B). KMnO4 D). NiCl2 Fe3+, Cr3+
15). The aqueous solution of 10 0
d or d = Colourless
ScCl3 is :
A). green C). black
Blue Green
B). orange red D).
colourless
16). The absorption energy
of d – d transition lies in:
A). visible region C).
ultraviolet region
B). infra red region D). x –rays
region
Practice # 2
1). PtCl4 reacts with NH3 to form complex in which coordination number of Pt is 6. One
formula unit of this complex contains a cation and only two Cl – ions. What is its formula?
A). [Pt(NH3)6]Cl4 C). [Pt(NH 3)5Cl]Cl3
B). [Pt(NH3)4Cl2]Cl2 D). [Pt(NH 3)3Cl3]Cl3
2). Which species does not act as a ligand in the formation of complexes?
A). CH3NH2 C). NH4+
+
B). H3N – NH2 D). OH –
3). Which of the following does not involve the lone pair of electrons on the nitrogen atom of
the ammonia molecule?
A). formation of NH4+ in NH3(aq) C). formation of NH2 – during the
reaction of Na and NH3
B). dissolution of AgCl in NH3(aq) D). formation of hydrogen bond between
the molecules of NH3
4). What is oxidation number of platinum in the reactant and product in the given Lewis acid
base reaction?
[Pt(NH3)2Cl2] + H2O [Pt (NH3)2(H2O)(Cl)]+ + Cl –
A). +2, +1 C). +4, +3
B). +2, +2 D). +4, +4
5). Which process does not occur during the given reaction? Cu(NO3)2 + 4NH3
[Cu (NH3)4](NO3)2]
A). dative bond formation C). precipitation of Cu(OH) 2
B). formation of a complex ion D). reduction of Cu2+ ions
2+
6). Zn has a full set of valence ‘d’ electrons. What is not a direct consequence of this
property?
A). it aqueous does not absorb visible light C). its complexes are octahedral
B). its complexes are colourless D). metal exhibit only one oxidation
state
7). The element with the outer electronic structure 3d5 4s2 will be expected not to
A). form coloured ions C). have low melting point
B). form complex compounds D). have paramagnetic behaviour
8). 50mg of CN – is fatal to humans. Which of the following produces free CN – ions in water?
A). Fe(CN)2 C). [Fe(CN) 6]6 –
B). CH3CN D). K 2[Cu(CN)4]
9). Which one of the following is correct?
Complex Compound Geometry Hybridization Oxidation state of
transition metal
A). [MnCl4]2 – Tetrahedral sp 3 +4
B). [Fe(CO)5] Trigonal bipyramidal dsp3 0
C). [Cu(NH3)4]2+ Tetrahedral dsp 2 +2
6
General Description
Characteristi
c
Definition Transition elements = Partially filled d or f sub-shells in atomic
state or in any of their commonly occurring oxidation states.
Properties
(1) Metals in true sense
(2) Hard and strong metals with high melting and boiling points.
(3) Good conductors of heat and electricity.
(4) Show variable valency or oxidation state(with few excepions)
(5) Their ions and compounds are coloured in solid state as well as in
solution form at least in one oxidation state
Types •Typical Transition element = IVB_____VIIIB, IB
•Nontypical Transition element = IIIB, IIB
•Outer Transition Elements = d – Block Elements
•Inner Transition Elements = f – Block Elements
•Lanthanides = 4f series Actinides = 5f series
Binding Good mechanical properties[Tough, malleable and ductile]. Strong metallic binding
[Use of s – electrons and d – electrons]
Energy •Binding Energy, Melting Point & Boiling Point α No. of
Melting point unpaired electrons
Boiling Point They upto group VIB and weakens progressively upto group IIB. But “Cr” and “Mn” are
exception cases. [ V = Maximum B.E in first series ] [Melting point α B.E]
Covalent •Covalent radii = Decrease rapidly at the start of the series,
Radii then become almost constant, and finally begin to increase at
the end of the series.
And
[Increase is due to contraction of filled 3d orbitals into the
Ionic Radii electron core and shielding of the 4s electrons more
effectively from the nucleus]
•Ionic radii = Variation is much less regular and difficult to
rationalize.
Paramagnetis •Paramagnetism α No. of unpaired electrons
m&
Diamagnetis 1
m •Diamagnetism α No. of unpaired electrons