1

LAKSHYA JEE (2024)

Solutions DPP-01

1. Homogeneous mixture of two or more than two 6. Given, 5 × 10–3 kg of urea of dissolved in 2 × 10–3
components is called kg of water. Calculate the percent by mass of urea.
(1) Solute (2) Solvent (1) 90% (2) 71.42%
(3) Both (1) & (2) (4) Solution (3) 70% (4) 80%

2. Which of the following is an example of gaseous 7. Calculate the volume of volume percentage of a
solution? solution of 15 ml of alcohol in 60 ml of water
(1) Camphor in nitrogen gas (1) 20 (2) 25
(2) Solution of hydrogen in palladium (3) 30 (4) 50
(3) Chloroform mixed with nitrogen gas
(4) Both (1) & (3) 8. Which of the following is not a binary solution?
(1) Pure water + Sugar
3. In amalgam of mercury with sodium, solvent is (2) Air
(1) Mercury (2) Sodium
(3) Mixture of benzene and toluene
(3) Amalgam (4) None of these
(4) Mixture of ethanol and methanol

4. What is the mass percentage of carbon tetrachloride

9. If 2 moles of CaCO3 is dissolved in 900g of water
if 22 g of benzene is dissolved in 122g of carbon
then percentage by mass of solution formed is
tetrachloride?
(1) 36.36% (2) 9.9%
(1) 84.72% (2) 15.28%
(3) 18.18% (4) 11.75%
(3) 50% (4) 44%

10. 60 ml of liquid A is mixed with another liquid B and

5. Rashida dissolved 40 g of sugar in 600 mL of sugar
the solution was made upto 300 ml. Find volume %
solution. Calculate the mass by volume percentage.
of liquid B in the solution formed
(1) 66.6 (2) 70
(1) 40% (2) 60%
(3) 6.66 (4) 50
(3) 20% (4) 80%
 1

LAKSHYA JEE (2024)

Solutions DPP-02

1. Determine the volume/volume percent solution 8. What is the molarity of NaOH solution if 250 mL of
made by containing 25 mL of ethanol with enough it contains 1 mg of NaOH?
water to produce 200 mL of the solution: (1) 10-1 M (2) 10-2 M
(1) 12.5 (2) 20 (3) 10-4 M (4) 10-3 M
(3) 40 (4) 25
9. How much solute should be dissolved in 20 ml of
2. A solution is obtained by mixing 200g of 30% and solution so that mass by volume % of solute is 30?
(1) 6g (2) 4g
300g of 20% solution by weight. What is the
(3) 8g (4) 10g
percentage of solute in the final solution?
(1) 50% (2) 28% 10. A tank contains 5 moles of oxygen, 2 moles of
(3) 64% (4) 24% nitrogen and 20g of hydrogen at room temperature.
Find the mole fraction of hydrogen.
3. What is the mole fraction of glucose in 10% w/W 5 2
(1) (2)
glucose solution? 17 15
(1) 0.01 (2) 0.02 8 10
(3) 0.03 (4) 0.04 (3) (4)
15 17

4. Molarity is expressed as 11. An aqueous solution of ethanol contains 23g of

(1) L/mol (2) Mol/L ethanol dissolved in 90g of water. Find mole fraction
(3) Mol/1000 g (4) g/L of ethanol in the solution.
3 3
(1) (2)
5. What is the total number of moles of H2SO4 needed 4 5
to prepare 5.0 L of a 2.0 M solution of H2SO4 ? 2 1
(3) (4)
(1) 2.5 (2) 5.0 7 11
(3) 10 (4) 20
12. A solution contains 50g of CaCO3 dissolved in 3
6. The molarity of H2SO4 solution, which has a density
liters of water. Find the molarity of the solution
1.84 g/cc at 35oC and contains 98% by weight is formed.
(1) 1.84 M (2) 18.4 M 1 1
(1) (2)
(3) 20.6 M (4) 24.5 M 2 3
1 1
(3) (4)
6 4
7. A solution is prepared by dissolving 24.5 g of
13. The concentration of CaCl2 solution is 0.5 mole L–1.
sodium hydroxide in distilled water to give 1L
Find the moles of CaCl2 in 500 ml in the solution.
solution. The molarity of NaOH in the solution is (1) 0.25 (2) 0.45
(Given, that molar mass of NaOH = 40.0 gmol-1) (3) 0.3 (4) 0.5
(1) 1.6326 M (2) 0.9800 M
(3) 0.6125 M (4) 0.2450 M
 1

LAKSHYA JEE (2024)

Solutions DPP-03

1. Mole fraction of solute in benzene is 0.2 then find 6. A room has oxygen and nitrogen in mass ratio of 8 :
molality of solute 7. Find mole fraction of oxygen gas.
(1) 3.2 (2) 2 (1) 0.2 (2) 0.3
(3) 4 (4) 3.6 (3) 0.5 (4) 0.8

2. The unit of molality is 7. Find molarity of a sample of pure water. Consider

(1) mol L-1 (2) mol kg-1 density = 1 g/ml.
(3) mol-1 L-1 (4) mol L (1) 27.7 (2) 33.3
(3) 55.5 (4) 11.1
3. Which of the following concentration factors is
affected by change in temperature? 8. What is the molality of a solution containing 2 moles
(1) Molarity of a solute dissolved in 500g of a solvent?
(2) Molality (1) 3 (2) 2
(3) Mole fraction (3) 1 (4) 4
(4) Weight fraction
9. An aqueous solution of glucose is prepared by
4. Which of the following concentration units is dissolving 45 g of glucose in 1 liter of water. Find
independent of temperature? molality of solution formed.
(1) Normality (2) Molarity 1 3
(1) (2)
(3) Molality (4) ppm 4 5
1 2
(3) (4)
5. What will be the molality of a solution having 18 g 3 3
glucose (mol. wt. = 180) is dissolved in 500 g of
water? 10. If a gas mixture of two gases. A and B contains gas
(1) 1 m (2) 0.5 m A of mole fraction 0.3. Find molality of A.
(3) 0.2 m (4) 2 m (Molar mass of A = 10g ; B = 20g)
(1) 21.42 (2) 6.7
(3) 12.14 (4) 8.21
 1

LAKSHYA JEE (2024)

Solutions DPP-04

1. What will be the mole fraction of ethanol in a 6. Molarity of a given orthophosphoric acid solution is
sample of spirit containing 85% ethanol by mass? 3 M. It’s normality is
(1) 0.69 (2) 0.82 (1) 9 N (2) 0.3 N
(3) 0.85 (4) 0.60 (3) 3 N (4) 1 N

2. Mole fraction of solute in benzene is 0.2 then find 7. A 5.2 molal aqueous solution of methyl alcohol,
molality of solute CH3OH, is supplied. What is the mole fraction of
(1) 3.2 (2) 2 methyl alcohol in the solution?
(3) 4 (4) 3.6 (1) 1.100 (2) 0.190
(3) 0.086 (4) 0.050
3. What is molarity of K+ in aqueous solution that
contains 17.4 ppm of K2SO4 (174 g mol-1)? 8. What is the concentration of mercury in ppm if 3g
(1) 2 10−2 M (2) 2  10−3 M mercury is found in 15kg sample of ocean water?
(1) 300 (2) 400
(3) 4 10−4 M (4) 2 10−4 M
(3) 500 (4) 200

4. How many grams of dibasic acid (mol. wt. 200) 9. If 3.0 mg of Cr+6 is dissolved in 3 L of water, find
should be present in 100 mL of the aqueous solution the concentration of Cr+6 in ppm.
to give 0.1 N? (1) 2 ppm (2) 1 ppm
(1) 10 g (2) 20 g (3) 3 ppm (4) 9 ppm
(3) 2 g (4) 1 g
10. A liquid solution consists of three liquids A, B and C
5. A 5-molar solution of H2SO4 is diluted from 1 L to with mole fractions of A = 0.3 and mole fraction of
10 L. What is the normality of the solution? B = 0.2. Find mole fraction of C.
(1) 0.25 N (2) 1 N (1) 0.5 (2) 0.2
(3) 2 N (4) 7 N (3) 0.3 (4) 0.7
 1

LAKSHYA JEE (2024)

Solutions DPP-05

1. Which of the following is insoluble in water? 7. The partial pressure of the gas in vapour phase is
(1) salt (2) acid proportional to the mole fraction of the gas in the
(3) base (4) oil solution is given by
(1) Raoult’s law

2. According to the law ‘like dissolves like’ (2) Ostwald’s law

(1) salt is soluble in oil (3) Distribution law

(2) I2 is soluble in water (4) Henry’s law

(3) NaOH is soluble in crude oil

(4) acid is soluble in water 8. Four gases like H2, He, CH4 and CO2 has Henry’s
constant values (KH) are 69.16, 144.979, 0.413 and
3. Which of the following dissolves in water due to H- 1.67. The gas which is more soluble in liquid is
bond formation? (1) He (2) CH4
(1) NaCl (2) BaSO4 (3) H2 (4) CO2
(3) R – O – H (4) AgCl
9. The solubility of gas in a liquid increase with
4. Benzene is soluble in (1) Increase of temperature
(1) Water (2) Naphthalene (2) Amount of liquid taken
(3) Acid (4) Alcohol (3) Decreases in temperature
(4) Reduction of gas pressure
5. When a solid solute is added to the solvent some
solute dissolves and its concentration increases in
10. Solubility of a substance is its maximum amount
solution. This process is called
that can be dissolved in a specified amount of
(1) Osmosis solvent. It depends upon
(2) Dissolution (i) nature of solute
(3) Preferential osmosis (ii) nature of solvent
(4) Discharging (iii) temperature
(iv) pressure
6. Fishes feel uncomfortable in warm water due to (1) Only (i), (ii) and (iii)
(1) fishes do not like warmness (2) Only (i), (iii) and (iv)
(2) higher amount of impurities (3) Only (i) and (iv)
(3) low solubility of oxygen at higher temperature (4) (i), (ii), (iii) and (iv)
(4) greater population of fishes
 2

11. During dissolution when solute is a added to the Which of the following statements regarding the
solvent, some solute particles separate out from the experiment is true?
solution as a result of crystallization. At the stage of (1) The solubility of a gas in liquid in beaker (i) is
equilibrium, the concentration of solute in the greater than that in beaker (ii).
solution at given temperature and pressure. (2) The solubility of gas in beaker (i) is less than
(1) increases (2) decreases that in beaker (ii)
(3) remains constant (4) keeps changing (3) The solubility of gas is equal in both beakers.
(4) The solubility of gas remains unaffected by
12. Consider the two figures given below. change in weights.
 1

LAKSHYA JEE (2024)

Solutions DPP-06

1. The gas for which Henry’s law is not applicable in 7. Henry’s law constant for molality of methane in
aqueous solution is benzene at 298 K is 4.27 × 105 mm Hg. The mole
(1) HCl (2) N2 fraction of methane in benzene at 298 K under 760
(3) Xe (4) He
mm Hg is
2. The gas dissolved in carbonated drinks escapes an (1) 1.78 × 10–3 (2) 17.43
opening the bottle due to (3) 0.114 (4) 2.814
(1) increase in temperature
(2) increase in pressure 8. When a gas is bubbled through water at 298 K, a
(3) decrease in pressure over gas very dilute solution of gas is obtained. Henry’s law
(4) Increase in molecular interaction
constant for the gas is 100 k bar. If gas exerts a
3. A person feels more fatigue at high altitudes due to pressure of 1 bar, the number of moles of gas
(1) low pressure of oxygen dissolved in 1 litre of water is
(2) low temperature (1) 0.555 (2) 55.55 × 10-5
(3) nausea (3) 55.55 × 10-3 (4) 5.55 × 10-5
(4) contraction of body

4. Henry’s law is not applicable for aqueous solution of 9. How much oxygen is dissolved in 100 mL water at
(1) O2 (2) N2 298 K if partial pressure of oxygen is 0.5 atm and
(3) SO3 (4) He KH = 1.4 × 10-3 mol/L/atm?
(1) 22.4 mg (2) 22.4 g
5. Henry’s law is not applicable at (3) 2.24 g (4) 2.24 mg
(1) low pressure
(2) high pressure
(3) gas does not react with liquid 10. O2 is bubbled through water at 293K. Assume that
(4) high temperature O2 exerts a partial pressure of 0.98 bar, find the
solubility of O2 in g L-1. The value of Henry’s Law
6. H2S is a toxic gas used in qualitative analysis. If
constant KH for O2 is 34.84 k bar
solubility of H2S in water at STP is 0.195m, what is
(1) 0.05 (2) 0.08
the value of KH?
(1) 0.0263 bar (2) 69.16 bar (3) 0.07 (4) 0.01
(3) 192 bar (4) 282 bar
 1

LAKSHYA JEE (2024)

Solutions DPP-07

1. At vapour pressure 6. If P° → vapour pressure of solvent and

(1) (rate)evaporation = (rate)condensation P → vapour pressure of solution then
(2) (rate)evaporation > (rate)condensation (assume the solute used is non-volatile)
(3) (rate)evaporation < (rate)condensation (1) P° > P (2) P° < P
(4) None of the above (3) P° = P (4) none of these

2. The factor which affect vapour pressure is 7. If vapour pressure of 10 gram of a liquid solution is
(1) forces between liquid molecules ‘P’, then what is the vapour pressure of 5 gram of
(2) temperature same liquid solution?
(3) volatile solute (1) P (2) 2P
(4) all of these (3) P/2 (4) none of these
3. The correct relationship of vapour pressure and
temperature is given by
8. An unopened soda has an aqueous concentration of
CO2 at 25°C equal to 0.05 mole kg–1. The pressure
of CO2 gas in the can is (KH = 0.34 mole/kg bar)
(1) (2) (1) 0.671 bar (2) 1.49 bar
(3) 0.147 bar (4) 1.71 bar

9. The vapour pressure of pure benzene and toluene

are 160 and 60 torr respectively. The mole fraction
(3) (4)
of toluene in vapour phase in contact with equimolar
solution of benzene and toluene is
(1) 0.50 (2) 0.6
4. The vapour pressure of ethanol is 115 torr at 34.9°C. (3) 0.27 (4) 0.73
if Hvap of ethanol is 38.6 kJ/mol. Calculate the
temp. (°C) when then vapour pressure is 760 torr. 10. The vapour pressure of pure CHCl3 and CH2Cl2 are
(1) 69°C (2) 89°C
200 and 41.5 atm respectively. The weight of CHCl3
(3) 99°C (4) 79°C
and CH2Cl2 are 11.9 g and 17 g respectively in a
5. A container having liquid in equilibrium with its solution. The vapour pressure of solution (in atm)
vapour has volume of 10 L. If the volume of will
container is reduced to 5 L, the vapour pressure (1) 80.5 (2) 79.5
(consider constant temperature) (3) 94.3 (4) 105.5
(1) is reduced by 50%
(2) is increased by 50%
(3) remain constant
(4) none of these
 1

LAKSHYA JEE (2024)

Solutions DPP-08

1. If liquids A and B form an ideal solution, the 7. Positive deviation from Raoult’s law is shown by
(1) Enthalpy of mixing is zero which of the following mixtures?
(2) Entropy of mixing is zero (1) Benzene and toluene
(3) Free energy of mixing is zero (2) CHCl3 and Acetone
(4) Free energy as well as the entropy of mixing are (3) Ethanol and Water
each zero
(4) HCl and Water

2. The mixture that forms maximum boiling azeotrope

8. When two liquids A and B are mixed then their
is:
(1) Water + Nitric Acid boiling points becomes greater than both of them.
(2) Ethanol + Water What is the nature of this solution?
(3) Acetone + Carbon disulphide (1) Ideal solution
(4) Heptane + Octane (2) Normal solution
(3) Negative deviation from ideal solution
3. An azeotropic mixture of two liquids has (4) Positive deviation from ideal solution
boiling point lower than either of them, when it
(1) Shows a negative deviation from Raoult’s law 9. The diagram given below is a vapour pressure
(2) Shows no deviation from Raoult’s law
composition diagram for a binary solution of A and B.
(3) Shows positive deviation from Raoult’s law
(4) Is saturated

4. A non-ideal solution was prepared by mixing 30 mL

chloroform and 50 mL acetone. The volume of
mixture will be
(1) > 80 mL (2) < 80 mL
(3) = 80 mL (4)  80 mL In the solution, A – B interactions are
(1) similar to A – A and B – B interactions
5. Which pair from the following will not form an ideal (2) greater than A – A and B – B interactions
solution?
(3) smaller than A – A and B – B interactions
(1) CCl4 + SiCl4 (2) H2O + C4H9OH
(4) unpredictable
(3) C2H5Br + C2H5I (4) C6H14 + C7H16
10. Which of the following is not a characteristic of non-
6. The azeotropic mixture of water (b. pt.100oC) and ideal solution with positive deviation?
HCl (b.pt. 85oC) boils at 108.5oC. When this mixture
(1) Vmix > 0
is distilled it is possible to obtain
(1) Pure HCl (2) Hmix > 0
(2) Pure water (3) Smix < 0
(3) Pure water as well as HCl (4) Gmix < 0
(4) Neither HCl nor H2O in their pure states
 2

11. A solution of strong acid and water is an 12.

o
A container contains component A with PA = 200
(1) ideal solution o
(2) non-ideal solution with positive deviation mm and component B of PB = 500 mm. If moles of
(3) non-ideal solution with negative deviation A = 2 and moles of B = 3, find vapour pressure of
(4) none of the above solution if solute is volatile.
(1) 120 mm (2) 520 mm
(3) 380 mm (4) 420 mm
 1

LAKSHYA JEE (2024)

Solutions DPP-09

1. Colligative properties of the solution depend upon 6. Which of the following can be measured by the
(1) Nature of the solution ostwald – walker method?
(2) Nature of the solvent (1) V.P. of the solvent.
(3) Number of solute particles (2) Relative lowering of V.P.
(4) Number of moles of solvent (3) Lowering of V.P.
(4) All of these
2. 30 g of a non-volatile solute is dissolved in 360 g of
water at 100°C. If vapour pressure of solution is 7. A solution is obtained by dissolving 12 g of urea
570 mm of Hg, find molar mass of solute (M = 60) in one litre of solution. Another solution is
(1) 5.5 g (2) 4.5 g made by dissolving 68.4 g of cane sugar (M = 342) in
(3) 6.5 g (4) 7.5 g a litre of solution at the same temperature. The
lowering of vapour pressure in the first solution is
3. The vapour pressure of water at 20°C is 18 mm. When (1) Nearly 5 times that of second solution
20 g of a non-ionic substance is dissolved in 100 g of (2) Same as that of second solution
water the vapour pressure is lowered by 6 mm. What (3) Double that of second solution
is the molar mass of the non-ionic substance? (4) Nearly one fifth of the second solution
(1) 10.8 g (2) 7.2 g
(3) 4.4 g (4) 6.4 g 8. The vapour pressure lowering caused by the addition
of 100g of sucrose (molecular mass = 342) to 1000g
4. Calculate the relative lowering in vapour pressure of water if the vapour pressure of pure water at 25oC
(RLVP) if 100 g of a non-volatile solute of molar is 23.8 mm Hg
mass 100 g/mol is dissolved in 432 g of water. (1) 1.25 mm Hg (2) 0.125 mm Hg
(1) 0.04 (2) 0.07 (3) 1.15 mm Hg (4) 0.012 mm Hg
(3) 0.06 (4) 0.09

5. The vapour pressure of water at room temperature is 9. Which one is a colligative property?
23.8 mm of Hg. The vapour pressure of an aqueous (1) Boiling point
solution of sucrose with mole fraction 0.1 is equal to: (2) Vapour pressure
(1) 23.9 mm Hg (2) 24.2 mm Hg (3) Osmotic pressure
(3) 21.42 mm Hg (4) 31.44 mm Hg (4) Freezing point
 1

Lakshya JEE (2024)

Solution DPP-10

1. Elevation in boiling point was 0.52o C when 6 g of a 6. Find elevation in boiling point of a solution obtained
compound X was dissolved in 100 g of water. by dissolving 90 g of glucose in 200 g of water.
Molecular weight of X is (Kb = 0.52 k kg mol–1) (Kb of H2O = 0.52 K kg/mole)
(1) 120 (2) 60 (1) 2.6 K
(3) 600 (4) 180 (2) 5.3 K
(3) 1.3 K
2. If 0.15g of a solute dissolved in 15g of solvent is (4) 4.2 K
boiled at a temperature higher by 0.216 oC than that
of the pure solvent. The molecular weight of the 7. Find molar mass of a non-volatile solute whose 20 g
substance (molal elevation constant for the solvent on dissolving in 500 g of water produces a solution
is 2.16 oC kg mol–1) is having boiling point = 105.2°C.
(1) 1.01 g/mol (2) 10 g/mol [Kb = 0.52 K kg mole–1]
(3) 10.1 g/mol (4) 100 g/mol (1) 8 g mol–1
(2) 6 g mol–1
3. If the elevation in boiling point of a solution of 10 g (3) 4 g mol–1
of solute (mol. wt. = 100 g) of 100g water is ∆Tb, (4) 12 g mol–1
the ebullioscopic constant of water is
(1) 10 (2) 100 ΔTb 8. Find boiling point of deci molal aqueous solution of
Tb glucose. (Kb = 0.52 K kg/mole)
(3) ΔTb (4) (1) 373.052
10
(2) 473.052
(3) 573.052
4. When 10 g of a non-volatile solute is dissolved in
(4) 273.052
100 g of benzene, it raises boiling point by 1oC then
molecular mass of the solute is
9. Find the molality of an aqueous solution of urea
(kb for C6H6 = 2.53 K kg mol–1)
which has a boiling point of 102.08°C.
(1) 223g/mol (2) 233g/mol
(Take Kb = 0.52 K kg mol–1)
(3) 243g/mol (4) 253g/mol
(1) 1 (2) 2
(3) 3 (4) 4
5. The temperature at which the vapour pressure of a
liquid becomes equal to the atmospheric pressure is
10. A centimolal non aqueous solution of a non-
known as
electrolyte has elevation in boiling point of 0.6°C.
(1) Boiling point
Find elevation in boiling point of the same solution
(2) Freezing point
if molality is 0.4 mole/kg.
(3) Absolute temperature
(1) 12°C (2) 24°C
(4) none of these
(3) 6°C (4) 36°C
 1

Lakshya JEE (2024)

Solution DPP-11

1. 1.00 g of a non-electrolyte solute dissolved in 50 g 6. Elevation in boiling point of an aqueous solution of

of benzene lowered the freezing point of benzene by glucose is 2K. Find the depression in freezing point
0.40 K. Kf for benzene is 5.12 K kg mol-1. of the same solution. (Kf = 1.86 K kg/mole and Kb =
Molecular mass of the solute will be: 0.52 K kg/mole)
(1) 256 g mol-1 (1) 2.16 K (2) 7.14 K
(2) 2.56 g mol-1 (3) 3.38 K (4) 6.28 K
(3) 512 × 103 g mol-1
7. Find depression in freezing point of a glucose
(4) 2.56 × 104 g mol-1
solution in which mole fraction of glucose is 0.25.
(1) 34.4 K (2) 18.2 K
2. Osmotic pressure of a solution at a given
(3) 24.6 K (4) 6.2 K
temperature
(1) Increases with concentration
8. What is the molecular mass of a non-ionizing solid
(2) Decreases with concentration
if 10 g of this solid, when dissolved in 100 g of
(3) Remains same
water forms a solution which freezes at – 1.24°C?
(4) Initially increases and then decreases
Kf(H2O) = 1.86°C kg mol–1.
(1) 250 (2) 150
3. Calculate the apparent degree of ionization of an
(3) 120 (4) 75
electrolyte MX2 in water, if the observed molar
mass of the solute by measuring elevation in boiling
9. A solution containing 62 g ethylene glycol in 250g
point is 65.6 g/mol (Normal molar mass of the
water is cooled to –10°C. If Kf for water is 1.86K kg
solute = 164 g/mol).
mol–1, the amount of water (in g) separated as ice is:
(1) 75% (2) 85%
(3) 65% (4) 25% (1) 148 (2) 32
(3) 64 (4) 16
4. The freezing point of the solution obtained by
dissolving 0.5 moles of glucose in 500 g of water 10. A membrane which allows the movement of only
will be solvent particles through it is called
(1) –1.86°C (2) –3.2°C (1) Animal membrane
(3) –0.92°C (4) –2.24°C (2) Plant membrane
(3) Semipermeable membrane
5. In a cold climate, water gets frozen causing damage (4) Permeable membrane
to radiator of a car. Ethylene glycol is used as anti-
freezing agent. Calculate the amount of ethylene
glycol to be added to 4 kg of water to prevent it
from freezing at –6°C (Kf for water = 1.85 K kg
mol–1)
(1) 8.04 g (2) 80.4 g
(3) 0.80 g (4) 804.32 g
 1

LAKSHYA JEE (2024)

Solutions DPP-12

1. Osmotic pressure is 0.0821 atm at temperature of 300 8. The vant’s Hoff factor for 0.1 M Ba(NO3)2
K. Find concentration in mole/litre. solution is 2.74. The degree of dissociation is
(1) 0.033 (2) 0.066 (1) 91.3%
-2
(3) 0.33 × 10 (4) 3 (2) 87%
(3) 100%
2. Which one is a colligative property? (4) 74%
(1) Boiling point
(2) Vapour pressure 9. The osmotic pressure of 5% (w/v) solution of urea at
(3) Osmotic pressure 27°C is
(4) Freezing point (1) 20.5 atm (2) 10.5 atm
(3) 12.5 atm (4) 15.5 atm
3. The osmotic pressure of a solution containing 1.71g
of sucrose (mol. wt. 348) dissolved to make a litre of 10. The osmotic pressure of a M/5 solution of glucose at
solution at 27 oC (R = 0.082 L atm K-1 mol-1) is 47°C is
(1) 0.246 (2) 0.0273 (1) 1.25 atm (2) 2.25 atm
(3) 0.164 (4) 0.123 (3) 5.25 atm (4) 7.25 atm

4. For determination of molar mass of colloids, 11. Correct expression for Van’t Hoff factor in case of
polymers and protein, which property is used? dissociation of Al2(SO4)3 is
(1) Diffusion pressure (1) i = 1 + 3 (2) i = 1 + 2
(2) Atmospheric pressure 
(3) i = 1 + 4 (4) i = 1 +
(3) Osmotic pressure 2
(4) Turgor pressure
12. K2[PtCl4] is 30% ionized in aqueous solution. The
5. Desalination of sea water can be done by value of its Vant Hoff factor is
(1) Osmosis (1) 1.2 (2) 1.4
(2) Reverse osmosis (3) 1.6 (4) 1.8
(3) Filtration
(4) Diffusion 13. The process of separating solvent from its solution by
applying pressure greater than osmotic pressure is
6. The Van’t Hoff’s factor (i) for a dilute aqueous called
solution of Na2SO4 is (1) fractional distillation
(1) 1 + α (2) 1 - α (2) condensation
(3) 1 + 2α (4) 1 - 2α (3) distillation
(4) reverse osmosis
7. Phenol dimerises in benzene having van’t Hoff
factor 0.54. What is the degree of association?
(1) 1.92 (2) 0.98
(3) 1.08 (4) 0.92
 1

LAKSHYA JEE (2024)

Solutions DPP-13

1. 0.04 M Na2SO4 solution is isotonic with 0.1 M 6. The relationship between osmotic pressure of
glucose at the same temperature. What is the equimolar solutions of KCl, Ca(NO3)2 and Na2SO4
apparent degree of dissociation of Na2SO4? is ( = 1)
(1) 0.25 (2) 0.50 (1) Na2SO4  Ca2 (NO3 )2 = KCl
(3) 0.75 (4) 0.85 (2) KCl  Ca(NO3 )2 = Na2SO4

2. What is the freezing point of a solution containing (3) Ca(NO3 )2 = KCl = Na2SO4
8.1 g HBr in 100 g water assuming the acid to be (4) Ca(NO3 )2  KCl  Na2SO4
90% ionized (kf for water = 1.86°C kg mol-1)?
(1) –0.35°C 7. A solution of a non-electrolyte substance is isotonic
(2) –1.35°C with decimolar solution of NaCl. The molarity of
(3) –2.35°C solution of substance is
(4) –3.53°C (1) 0.2 (2) 0.4
(3) 0.5 (4) 0.9
3. Calculate the apparent degree of ionization of an
electrolyte MX2 in water, if the observed molar 8. Which of the following pairs of solutions are
mass of the solute by measuring elevation in boiling expected to be isotonic at same temperature?
point is 65.6 g/mol (Normal molar mass of the (1) 0.1 M urea and 0.1 M NaCl
solute = 164 g/mol). (2) 0.1 M urea and 0.2 M MgCl2
(1) 75% (2) 85% (3) 0.1 M NaCl and 0.1 M Na2SO4
(3) 65% (4) 25% (4) 0.1 M Ca(NO3)2 and 0.1 M Na2SO4

4. Elevation in boiling point for equimolal solutions of 9. A 0.2 molal aqueous solution of a weak acid HX is
NaCl, Al2(SO4)3, BaCl2 and MgSO4 is highest for 20% ionized. The freezing point of this solution is
(assume  = 1) (Kf = 1.86 K kg/mole)
(1) NaCl (1) –0.45°C
(2) Na2SO4 (2) –0.34°C
(3) Al2(SO4)3 (3) –0.54°C
(4) MgSO4 (4) –0.24°C

5. Elevation in boiling point of 1 molal aqueous 10. Osmotic pressure of 3.725% (w/v) solution of KCl
solution of Na3PO4 is (assume  = 0.2) at 27°C is 21.6 atm. Find degree of dissociation of
(1) 0.52°C KCl.
(2) 0.83°C (1) 20%
(3) 0.46°C (2) 30%
(4) 0.64°C (3) 60%
(4) 80%