wy ORGANIC | CHEMISTRY Aly Walidea aa ongante wompoundo terttodii ys taflagens ages ~ ox Hagen wneud. -G Hanet Cr Homay?® aa be ~t Aust group - Aled Haids . Nohejen. ToPAC . Halo Mone . s — 1 Teak : Ut, — : = CHa Medias * 1 7 3) ° CHs aI CH, - CH * Etna. 2 2 ca 5 : * ag-d-chy ; Neo Cy — Ha Tsopreryl. bug penta. Hs Hy CH, Uy — + PERG! O4,- CH CH, = h- Cute} 4 Ona, — ee cH, un, + Seondony butyl — Ut 2 Dev butyl. Ga, — Ma why CHa JBordlength: %2y4 oda. wu Storangth » % +a ae ST "9 Vv . ah . spt ve ~ ee aoe sp* + aa le ws) oe 5e* os? et oN bord . 6) oy § (i E \ pi) > TF a a . oo XK xX x > x: i 7 < > CQ = {yr , ~ Resonance i hybiua 4 Halogen clineck bo ndad fo _ em zune Pool Hobide mae J th cc y C=O CH Or cee. eran. poodias. BBE 1 CO KX CHO KM CRO CCRC oscy ° ot fondandod Aiea | G@xbon o ho SRConbon MEA Yo benrang 5. db * | » $p* Corban: ae iba nang «Not fey! Halide PER Malia ‘N | ¥ On - yy 1 oe ‘ i Lage Com Aly « tAy= can A ee! sgt at Te: Trduck . y T Conty “E vB rit= TT e CHECK gropongy- : halicle ro KS Co aa + propane x fi \ _t- ¢ bese i ideal Wegioe € brembnah dthads Se catjont? a dhalide - — {praxant on Samesida/) ‘: Cn Kanea, "i Ca¥ont 2 alkane | Perhalle Mkane &* CAy . Cy Metro - Pen dulnsee methane, Xk aly aoe a-* on Mania ¢ a stato Aluanz - Nudes pailic Aubstitubion en's) Su ; we EE ee + Nv ——> R-Nu + x° J | ; lee 5 | Ally), hoki Nook 2 La: tteg sisi base. Foe Electron sien Spent - Alkene (Elimination 5) R—X + Barve nen By’ be , £koH ——a> U3- on > MEEK (sn y Ruy ok A> w= cH oy Re Ethene CElimination AK yy 2G = igh Heme Coa 6+ cn ack as base alse act oa Nuweashiy — OX g bow Jome foyeur> Substitution Nuceoprile- No + — == & 2& vida spec - , : fous Lereng spent - Readily seous uot He set Tye of nuwleogirilen © iy -ved dang Spee | x2 CF OP a”, uo 2? 9, # OW NM ‘ . ‘ oy 7 0 vobudes nie tengo ofr owe oteant eR : NO q 2 po, Bae a te ES 2 d Mic ics SCS QQ &us I gh called bose. off king n* then at acts “neucleop hile\ roodtty an Re Saar cyst, + Oo Unt. & re * Bes K fends Ekrorddle to ‘Dee pe noise neo a Gyn : $8 eg Neudon Prilied ty tses ” boner oko Som =BES 4 ; 20, NH, ; “ oy 5 Shee polar Sowert ~ (FO) = = polar rest Solvents { (rps) yer Gor Shenk eho car. lose cabled PPS e By yr ioln mas aS Ms fi ns ~ NHS, wre OH, or ae ca, E- OH, Mig We oe ePEC a) 7 $=cCc=s5 jJLeo N Polo tic. Solvent - Solver ushidn cannot swloose wr called PRS “UW not bonded with nuee EN afore ' gtke FON, § a t Acetone uk a cH JipD i| oes a bv 4 Fis vr z Cc ur a ; PN 647 My b SS c N ae On / Wy NO, (D9) saycet! Yon. A ape bez nate!Sa Hrudeophitictty A gett a Serko (Manley. Reackivity oe me by chaseged... Nuchio piles of Nucteophile drain ate. Newkxoh- 8 a 8 Bre OH PHO « Ho > HS ‘ S * NH SNH, OO OO > OSH a oO ares s wb ys C -oH aw @ght do dna _potod Nucleophtlic. ty Cay, x Nk, «28 < AF (hadic Nekasie), Teen , Bnstitity Tseay 6 > > nif, > On > F 2 ave «> ow > ee (Nudeophicity Thadwre, ) Hos) © (Carte nabs) okoms “hot Sama . LEN i (Nucleopht baky) ! Cr bossicity Same) je 1 fenep dement Bk Safes ih 4 fox nucleophiles with some Sines fore Jn _Sbeorgin diet we “Seong # WE < NRG Acidic Nasu, Cony bape Cig -OH OP * penal 20k ay Boon x art “¢ reticattd * Si me/ 48E Bortc i anaes ee orders | yg Uta > & > tated i Sony Sans vin be Hao Ly Gohe oa of givers ucleophike 1 Gono dy Need. fe) lashodk Heteroatem: esttr €° paix Ca-_ York) ; Yoru pain * NH < Nw Na, # HOP << H-b-— 0% * e-8-R . ee H—F < HO—W x wns \ J Je ok ae >a2 »T oo we OF Nudeophi ay! F° goo Coe oD HON a St ~ “ . 5 > 4 or oO A ‘ oe BOS OE Halide sole. UF : , me RA ile NG, st oy St S67" 2§-€ To polar gt Soluues, MO SSpriirg asda © < woe g wise < H— Se (wae ge Nudrephilicity, cud ce Fe uP ate > mm prcence A folox protic Solver - ans ¢ eee a8 CLT? | D) Me prreree H polar apsetic solvers ~ > which ers? ce youl BS > TO tanast as et D vedke Bantully & Nucleophilicity oder fo the Aathousing + Penre ® +e °F LQ iD Rasdeity: See a boo DR. Basidty : A2 b-esol i nc # ROK +N — > Ru + 2° La Alkyl Halide. R-F ane > Nu + Fe A-u + Nu —— vo +9 re tt {ge R-@rn + nue — oy + Be R-T + ne —— a Lan? eauing comp o> ac> ue> Fe capouity Yeaddivity foeords ge KC R-UK RERC RT ON a pre a-P+ NE __, A-NUt Ft ‘ R-NEN + Nw —> RaNu+ Na ; . vous goad HR good, deaving . rt xo the L.A ona tnod “becomes Atable oafet its depaskusce ., * Pope When cOmMPLLENG 4090 Aavineg Toups : Ta general ae bebor Leouing ry & a Weakur ase . oo” G+ F a Bu 72 Bark chy AlWeest Saautoag grusiap apouity Taco, s Rus ShSo basi diy, \ses - — coqasity Tsed- Tme ey HR at tn 5 i ge ° ; C%—S RI + NE - S 0 ° 2 e-Nu xe 5 Tasflke (ove) a‘ 3 ion. = oe ~ F ak | -2€ : © : Eqpivabert fC ge ° Ravonoting ae , Sburetuoad S@ Ja Mlp ne Stoletr a Nr > Gdtlote fon KGuED) eee Nuobrol nue stable CStabi lity s eon — derssiing FOR: Capacity oy _ R-N=SN—> RF '* Ren (Nz —T tran gen , ¥ Mose ; ercelen’ Le oe Rap Gore Stab. wo fi Ae Une Ro6- 3 — c-F ROOF Coes, \ Lo FJ Lb i ek -oTs Muyt Todtlake Alley \Tosy | s a a : ag | R-6 I Ce Bae tog. | yee Co UI qe ae i mpigre ee ° F 3 e | 7 fo Ping —<* Base eae > ! { ee el ote oO : ; 8 M » e ae ~ ¢ Kops }a | ®. ; = RUENEN > R-OTE > R-OTS 5 R~9 bs y R-omMSs Sabot tule on Types of Nudeophicy . | sean’ on By W Met, \ \ 1 | —t_ { 2 \ © Ee dt (ap) Lg Nu ¥ One ‘nucle opi te wubsti based Soy notte, nachsophite. 8 Called MoteeiN Salih, possible medranism » * sw . Bimolecan Nudleophilic oa | * Sy Yrirmroteclan Nudkee pac Substavtan, e SN Trbxomolicwan Nudleoplic substitub.(Ny it MH ae He Cy Lay mh Mts GH matt, Hig oe f ON @ 4 a OL = ashen, ea ie Uy sy ey ele Jon ‘ 4 ONG Uy Ot Chl, pedo yr od Weg dor dicipotion awe ‘ Netgr ourighing Arviup pordicipa (or i J toi wh srios for, i AG : nadiKon Follouwsed t AYU, : ) ERS Elimination folloused by Nas, $ Sn . Lin eset directly tondad wutth ~C".) benune Ring, - ‘} 1 fry. dubsirase. SN’ Bimolewrlor | Nucleoplilic Substitution = 3 & > hitb 6 oP + one A “a, N HK no N ile cena NP (nae T a a Le (® cs) 4 4 Clock wise Articlock wiee.- . Oo sare aergon? D a yi th ow | ‘ TR , ye ELE Thatta bse f ¥ | Mea ge Why cea if eaill wot Slabilsed by i Side, ' Sue = ar te. di eS attacks . ssomate neat ily rps. 2 Wwerdeh dertailtsed by “Poxadgy FOG gps. e Hesse, Lnvecion w bondy _ g el not opbicall Suwension . SN se St Le stagle odep sux # Ran Intex mediate is nod foruned. Grboestion net fosunsd i x Transition thote oY tu onion 8 pene, \ 4 Rote of SN™ of Sobility 4, Tos * 7.5 State srabliaod by Brot Aenbabt ies \ ; by £0. e Rohe oo [Rx] LN] of Sut ; x Mode oHsn> oc Ie gag ER TE TENE \ued..do 2&5 Rn R.D.S too Sree tno lecudore © Hil Made A Ned Bimo : Abr SUT Follows Strend 6 vdor x =Fy Tevoked . “prcodek,. vor Fooume-. es oy ey 3 : on? \ .: H ae yo 44 z ao | R © 3 D 3 ' ber YW hos 40 present on vertical line + 4 £ a Kinektc tsotoptc efgeck CH/0/T) — obsewed Tr ROS CoH = bond & not Booalivg. ford. Stxangth! CH T>E—O > OR. Read vity, | FFF Element ape (wort L&D obsewed. ee 35 37 Raclividy ,o-a > CTW SUKM. ' 7 wre’ teothennte, generat Nudeo*philic ty oh Nu® =| y, In a . ae duning toue In Sy —= a+ foertiol energy) Plognam [aX Sry” re > Poros sass ot Ren, Rate of SF oO { “3 : Which 35 atlahed 40. Cee defidenay of conbon which ’a BHadned to Lar. SN. Unimale wiles Nuceophitic Substitubton i o R te ~~ OW we 4aI a Non guger imposable miro ae aw coiled enantferrars 1.2, 50%, 60/- vs called Racemic Mixtusce [ace mack prevent Mechonis oe , — at oe BR Ne ese set. J Lt - =-ADsSs a pd ~ lee ee DS Ry Lin empty R 5 Bs. pronbital 2 3 Aissoctased Carbo colion Note? Se ROMO w& not aatebby gies pee for NUS de to akenntic Greoding # Nudeop hile com aktode Conbotation ny © Shep from ett aldle thotd oly apecoducls Cast Ri {See 1 fi Sui - - rs D A. vw A orn oN AR i 2 Sn Dw k - Rs dm step caters, Bruerrted ‘5 product Pprodice ve Bete teteralys’s eo C~x “ond 60 Fouma Hon e Grbecahion ae 3 adSince — Gxboakien i footed. - Nancy, of Gxbocaltor xo ssible - . Steg? * Nudleo phile astaets coscho obit, fom Lor aide - Producds ustth ronterdion Of Onftornasy, a Tramsohon oy ongigaraliton . fermalion % Sve ton @stbocokion . > Rabe con Dussecadion Wy CHx | bord inky eo CR. Faeem &- D-S “ Be awe he RET Br ROG ater ye rele th s me 3! a _ Aig ee Savolued - Herte tke Uindens fans eS Rout onder kinek£ce , w Sn follo Note + ; f Losdee Qa Some books ~ ais eS ora neg ete eS Ebene} Eton elg® a gute Ka =:4 Gn presence of deusts ac ackela °° cehcotan ag? , Rote of Ext Enicaases RK A | Gf vag Vue fy \C [ ss ae wg Po wal | & © R, @ i 3 orca ve Mn 2 Core disse clokton a7 Nas easy BCR ralonagen ott Goreng tors totals 80 c-& woaks fonder shan CO%* bond J 0 Qe! powbenct a Dousts atde , (oscbocation diy 4 | Mesdcbokion vt -* eens ocidy celeste - , of oN mens. e * ye seactank LS chiral | thane Reemate sill fosun Ow EnodBeomens wilt dosun a Non Super tmposabse foo: trier tmoyor will _a %j I, Veen Page of Sabi ty ee pea aie ‘aj, sendte_cootort HS ~ 4 /» ia a shserwe Nake‘ sp gaest Ging oar These ‘mechanism ebserwed ae tn a ee puladna dea, also gnduden Benulie W Ce 2 a= m—w,- ae Nw. ——— y Fackores arrecting Sn A Sn — Saeting ~ Ae Nowe OF Reactant | bubstafe B- Nature oly LG mate of Nucleo prt ‘Cs oe e le Mu d- Noche Of. dolwent az Nobu of Sabatade / Reactor Poo SN> * = = 7 \ we a ee ey rane | as, of Coane 4 5 ~ Ww / \ xd TS -G) K ; w | pO cH - Ve § a ames Noo | eS % 4 4 > wl Ts i) H © Abus vate Os i s- ng 52 Ww) a, oh lenge \ : _ ne” c Ke N ne Za ¥% ae H pac Methaneee i cH oo ine s- (ww) 3 Nue---c¢ 77 cA i x JN oS as, CMe “ Jf _ T.s Ww) u a (oenenally not posst ble Soar comeansion) t s- \ _ ae H eae we aK © c-*X oo Saas, 15 7 H v EW. stabilises T.S Reakiut Sousands 2 . sivity — a as 3 ‘alkyl halide . pximony OX cen hy. \ A ° wba me > oye >>> 5 EW. LU 3 Sat tot &: “NOD i ‘bak Con give - ' =e j i Odor VCsVoce bn: nate of Sn" ol stabi Giy of. Crcbocato fosune 0 OL Dissociation tendency C~P bony dominati, . 1 e Eq: qa) CH soe co x —» we : tam ca “"S On . * | > o Alley! halide. \ 3 cardoocaffon | ah a "N27 ok o4@ ow et ; ue% mt, me liicad Z Alkyd Malice. z wi) ‘ a aoa Xx —— Een FB habe ower colt 3°yU> t> on sebilthy se OREN a — eee i Carbotastin, (WW) Gh, Obpee = Ray T\ @ H§-O,E* HOOD a 72. } -Te. pose Stools 4 Nae er | a @ ul 36 —O +6 oO 6 r Oa Wee te ge \ be Jf ve Be 5 4 _ { . bee etexo atom with — atleast Ont ‘ Caupe® stulattises erbotobion wiry olen than, ‘C' ROH" : a ee called ap ‘where abom . iaity ondan towards $n' a-d-u,—x > 8 2 I> UL-X ac rene ee ty Be ou ga on” x Gur tr ce Mos. C—% 2 [ Alesse clackion dendonsy G 7ee eo x Tw aN Se Ha AS Bt dhe i Vin! holide [Substrate poroddol daual, , “tend $3: ex: ’ x [> pode) ey Ta oon rahide Choy! gulostrote ) > Due te parifial debe Lond hone. =< CHK yo VK Waragt b Pay fraSidas denct wadergs Sx 4 Sn" ” S dS » , Hy ah>rr® LG dendency * ae 8x me + HO N= : > 2 -Gu, NEN > ats Cc a SSN RO END cot Nokwee of Muclrophtle = oa Neue -B rod Involved Jn Rds, Siygihadee Rate of Ss doe ret — on 2) Blan % Nut Deane nue si) Mandy of NUP (Wusleopiit ch) > 1 nue Lavelued in RD. S tsa fn Agyd* SN So Age Ther witr y 1 \ oo Asp aky AMY oe Cone . A Nu®6 eo % e parte ssfth $e An thas. G, Wor Hoe Headc Winds cyrus. ) aj ° 2 pie Oe Han Ow . ro Hon” Tse with THe 4h sLaIS nr CV ie aia = ’ no? & ae ° ) gi e-* Ae to idunkify cae Sy [ Sn* 1 Small Siar 4 mee —neackive Me peeypet of EY : O. yo (Hees) naw ——> RT x le pissocicclion- dasour 4 7 olen protic sole PPS) aa Polar protic eel auoH o bluerts Sayows ye bc o% i Sn a ee PPS - onolan apseoic Solvents faveurnd ¥ ry BN, ue Ree | nee nee — Nu---- R-* He fon 2 th NU Se anes Ry cee ace ee OE ~ sn & Ce a ae reockiuity Ordon Shusoods yt: mete A = es (Oe advert Paronance ) find = 2 oN 2. D> i i Zo a b. oY “ Oo So Ane’. a7 b rY< Bue 1 ae en parcial a bond aes iat aioe Not OR) snake LOLA very DOO Jouoand BW 4 x ea ; 9 Tene Oe Oe a* [NZS * gr G7 are 1 hem t ae a: x ° ai aa ie ar oa af I . (o.¥ Ewe) ya ae C72 . a = oe io C 0 bra LEG capaity). ee dee > de x to or ros Mh 2-OS) Oo: OLX by) ow, —* ach (Kinelic tsotople effect Ans not obsowed ) . o %& : ° é) *) b: 2D SXewimaaig) YY S Ars > B® (Astle onder” Se te &.00.4) Do Cc. b: Ce “Or Rr’. Garonne. ~— CSieante udromer > g. Rrxonge follousir~g, An 4, sino) Orden ot Hel 2 d a: ut, —* oe x Gus won Ans! bp er bra ») +) am bi AYX* fms: >ab> as w ; Cy o x No Ret 2 a >rb we oe OY ey mi Oo vb (det peretted douse lpera in b) : a 4 Wie“ en ce Ao q OQ “O “Wo ' a: ee es arbrcerd awe -0-' m1 wutth ae + Daxzens Sx (Pete oy. ot and er Sng Made . 800, — 7 PhS +H Tt 50,7 R-O-K Vy ee Gaseour by produ, —— 7 Ho BA ped chemcseeroseee. Mitaderer ap Non Sererimposeeiea 4 faseo' A ao Sn Us Phase . We tu) “eh er dissodase ay HT dam i. i — Na HUQ ~ wu ee . He ° $ dre. 7 JS Me a 0 \ + 4 wiv 7° f 2. Me ° H i bd 0b Fe is Tt, es . A =o ' a one OF ee \ bond uw _ rfo Form, | hh membowd, Ring wgn + 50,0 O™ “ Ot Hvia fontornorte tod rs, ; ¢ - Fuokd *¥ es Me oO tHe Sut Me Mia e t & 7 ‘ i age os % Pa 7 a8 8 ed cH, os wee fF i $- aL 8 eae Grramb oad adic (rw. sD She oe + So, <{<—— of ba cl SEN UN Cont")dyrt oes ee — Aleoho ( aaytie aliolhol + 50U, i) R-oh + sou, a 1 Rekentee St (+4 Config 1 ont ) gon + Sou, + byuidina : 5n7 nH ae \ as 50U, ww 9 aoe, Wh (entig nt charge) 500, ——, ) ce / ay = g0UL of —,,..’” C=¢-c-oy : pe S002. Ni\ Meshot. oman > ot aaa, | ots wou °*) * a styNAP. Ned housing yp Por fet ON Cs ' | : NoOH wy Sy* yw Nv HO dN Oo e-o-H CO Naok ye co q@) Ht Merhanism ° adtdic E-0-W> a “A off acid 7 c y =a, n'y - base ni N a daxn 5 . oO o a ow” — 9 gmenboud’o | > Arce VW Bars Se 2/ REE unstable dut to angle strode ww/ HO. : yr ao Relention | cantly. ( due +o 2 thmes look sicle oda. Trverctien 6! in Tuer ston —» Aekentien )e i fespivament, for sn” + ae) ® pap eielieectand 7 sroubd contokn — asern Gr) group atom With oseant on. Kye? wscesplnille athe unt be Socased at fudlobla distor OME hans Node ophiltc gbstitution — dabing plats, = —c—cer ae f a TT a 3 mamdoassh rig Nu? i 4 uvtable - =) —C—G— Sar {| Cinyersion) Nu z \ 2 eles \ a y 1 otun gentility de Mls, “6 _% \ ! Nu (hy a Oo Nash Cy 4.54 Ud, — Ar =, W 1 2 OHS \ Not 44S NES, NEE . a 4 Su “ CH, ~~ $4 3h, — Ay J Ou a NEt,¥ NaOH. 9 Si dn NOP Y - 4. : Cylras ee Me 8) —| s-—m q S. e mag Ky UO posible Me CC bond srotahion 4s possible a 19-Me SN ho SMe ¢ SN swadons win Ambidantated Nadecp Ege C= ¢ Nucleophiles vetth More tran ond . e - Nucheoptale site a No (no,© ) K woo Nitrdfe . ~ 70 [Hot Oimb\ dentate oz a oe Ve ~\ Non Sod & Potassium ee F ON + ON Sas. ane tonic 9 (Fojon cite é e Rex + NacN kon — 5 Roo e RENCE lox! ~ ° a kX Poni ork Boeqyonice (Maj UMineD ‘ gp Mase Nut beoehilic. Noa ieue fig EN ——> Rent 4 RNC + Ag mide Rosey ae (Mayor ) Hirer Co} owe an + tenhe Stte ge NaNO, | KAO, —? RENO, + A-O-N=O Mo Alley! ug Nitaite <= ee + niax] 4 x 4 i Pon’ ag7NN6 3 polonising - - viene polortsing ; ] ~o-N=o+ lee ppfO,, —> A-NO +h eee nite ca ae ie (MajedaS we Finkelstein earkion’ s ON, = si 7 Not a-T . pmalcerar) -T an Rae in Acetone . oN Ch Ah chloride. — Aha Pohile | ae Mgt arte ay t st) Halogen cmhange , (Poup oe, Toko aLnons’) feetone i : heebone’s pla 4 pO! Split ee He cs Ae a tvR 2 = = Moone Same ~pusducs . ee = Nat a TS IO rae =Me Me Ne te w _— D 4 B Naf axons. 1 x a ie iy . @ G o-Hs CH, - Ct, © * inverted produ an fe oO Se OO : —— Aeebens. a K H H Asien cts OA a > Hs, Hq Br Nat A H a K Acton Ww a Os : Ody co Sword Rea 2i(Sx)} Flounide Salts are a red od a-F preperation, Nuchop li les a PE > Halogen crubange a ae ag F, Hg. ce fx 3 alkone. eer | CH+ X WU cao + HX Rat fF —> F- aa ae ae oF eas = vn otal t Bq: Dne Sram ane di er, lack side | Fee frood Polax Aprotic | Ruchoplale is Solvert-