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Introduction to Atomic
Structure
• Definition of an atom: The smallest unit of an
element that retains the properties of that element. • Historical development of atomic theory: From ancient Greek philosophers like Democritus, who proposed the idea of indivisible atoms, to modern scientists. • Importance of understanding atomic structure: Fundamental to chemistry, explaining the behavior of elements and compounds, and essential for advancements in technology and medicine. Dalton’s Atomic Theory
• Proposed by John Dalton in 1803.
• Key Postulates: • All matter is composed of indivisible atoms. • Atoms of a given element are identical in mass and properties. • Compounds are formed by a combination of two or more different kinds of atoms. • A chemical reaction is a rearrangement of atoms. • Limitations: Did not explain the internal structure of the atom or the existence of subatomic particles. Thomson’s Plum Pudding Model
• Proposed by J.J. Thomson in 1904.
• Key Features: • Atoms are composed of electrons (negatively charged particles) embedded within a positively charged “soup.” • The atom is electrically neutral overall. • Discovery: Thomson discovered the electron through his experiments with cathode rays. • Limitations: Could not explain the results of later experiments, such as Rutherford’s gold foil experiment. Rutherford’s Nuclear Model
• Proposed by Ernest Rutherford in 1911.
• Key Features: • Atoms consist of a small, dense, positively charged nucleus surrounded by electrons. • Most of the atom’s mass is concentrated in the nucleus. • Electrons orbit the nucleus, similar to planets orbiting the sun. • Discovery: Rutherford’s gold foil experiment demonstrated that a small fraction of alpha particles were deflected at large angles, indicating the presence of a dense nucleus. • Limitations: Did not explain the stability of electron orbits or the discrete energy levels observed in atomic spectra. Bohr-Rutherford Model
• Combination of Bohr’s and Rutherford’s ideas: Electrons orbit
the nucleus in defined paths or energy levels. • Structure of the atom: Central nucleus containing protons and neutrons, surrounded by electrons in orbits. • Energy levels and electron configurations: Electrons occupy specific energy levels; transitions between levels involve absorption or emission of energy. • Bohr’s Postulates: • Electrons move in fixed orbits around the nucleus. • Each orbit corresponds to a specific energy level. • Electrons can jump between energy levels by absorbing or emitting photons. Subatomic Particles
• Protons: Positively charged particles found in the nucleus.
• Neutrons: Neutral particles found in the nucleus. • Electrons: Negatively charged particles orbiting the nucleus. • Relative masses: Protons and neutrons have similar masses (approximately 1 atomic mass unit), much heavier than electrons (approximately 1/1836 of a proton’s mass). • Charge and Location: • Protons: +1 charge, in the nucleus. • Neutrons: 0 charge, in the nucleus. • Electrons: -1 charge, in electron orbits around the nucleus. Atomic Number and Mass Number
• Atomic number: Number of protons
in the nucleus, defines the element. • Mass number: Total number of protons and neutrons in the nucleus. • Examples: • Hydrogen: Atomic number 1, mass number 1 (1 proton, 0 neutrons). • Carbon: Atomic number 6, mass number 12 (6 protons, 6 neutrons). • Oxygen: Atomic number 8, mass number 16 (8 protons, 8 neutrons). Isotopes
• Definition of isotopes: Atoms of the same
element with different numbers of neutrons. • Examples: • Carbon-12: 6 protons, 6 neutrons. • Carbon-14: 6 protons, 8 neutrons. • Importance: • Used in radiocarbon dating to determine the age of archaeological finds. • Medical applications, such as in diagnostic imaging (e.g., PET scans). • Nuclear energy and research. Bohr-Rutherford Diagrams
• How to draw Bohr-Rutherford diagrams:
Representing the nucleus and electron orbits. • Steps to Draw: • Write the element symbol. • Draw the nucleus with the number of protons and neutrons. • Add electron orbits around the nucleus. • Place electrons in the orbits according to the element’s electron configuration. Summary
• Recap of atomic structure: Overview of the
atom’s components and models. • Key concepts: Importance of atomic models in explaining chemical behavior and reactions. • Significance: Understanding atomic structure is crucial for studying chemistry, physics, and various applications in technology and medicine.