Module 4
Module 4
Module 4
Strength of Concrete-
Strength of concrete is very important property of hardened concrete because quality of
concrete used in structure is depends upon its strength.
It is defined as the ability to resist stress without failure.
The compressive strength is one of the most important property of concrete.
In some situation, other strength of concrete is play a role are flexural strength of concrete
and tensile strength of concrete.
The strength of concrete is influenced by various factor that are type of cement, shape and
size of aggregate, concrete mix proportion, moisture content, type and rate of loading etc.
1
Abram’s law is based on assumptions:
(i) Concrete is of ordinary grade (and not dry mixes)
(ii) Water-cement is more than 0.45.
(iii) Mix is workable and fully compacted.
By proper compaction of concrete, these pores can be reduced and strength can be
improved. Fig. 4.1 shows the relation between strength and water-cement ratio of
concrete.
The graph of compressive strength verses water-cement ratio is hyperbolic in shape
and it is difficult to interpolate results.
22.5
𝑆= − 13 …..MPa
(water − cement rati𝑜)
𝐶
= (22.5) × − 13
water
2
2. Gel space ratio:
Gel-space ratio is a better approach than that of Abram’s Law, as it takes into account
the following five factors mentioned which are also responsible for strength of
concrete:
(i) Degree of hydration of cement,
(ii) Chemical and physical properties of cement,
(iii) Temperature at which hydration takes place,
(iv) Air content in case of air entrained concrete, etc.
(v) Effective water-cement ratio, formation of fissures due to bleeding.
Gel-space ratio is the ratio of the volume of hydrated cement paste to the sum of
volumes of the hydrated cement and of the capillary pores.
Volume of gel 𝑉
𝑥= =
space available 𝑉 + 𝑉
Where,
x = gel-space ratio
Vhc = volume of hydrated cement gel and
Vcp = volume of the capillary pores.
Power experiment shows that relation between strength and gel-space ratio is given
as:
𝑓 = 𝑎 𝑥 = 240 𝑥
Strength obtained by Abram’s law is based in water/cement ratio and is dependent on
age, whereas strength obtained by get space ratio is independent of age.
Theoretical strength of concrete at 100% hydration can be as high as 120 MPa, as
against partially hydrated concrete.
Fig. 4.3: Relation between compressive strength of mortar and gel-space ratio
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3. Effect of Size of Aggregate on Strength:
Large size of aggregate has lesser surface area, and requires less water to achieve
workability. Hence lower water-cement ratio can be used and higher strength can be
obtained. However, Large size of aggregate do not give very higher strength due to:
i. With large size of aggregate, internal bleeding takes place, resulting weaker
transition zone and micro cracks are developed.
ii. Large size aggregate result in non uniform distribution of load.
In lean mixes, larger aggregates give highest strength, however, in case of rich mixes,
use of smaller size aggregate give higher strength than use of bigger size aggregate.
From graph shown in Fig. 4.4, it is seen that
i. Reduction in strength of concrete is pronounced with small size aggregate due to
reduction in water-cement ratio.
ii. In respect of lean mixes for large size aggregate, strength increases as cement content
increases.
(b)
(a)
Fig. 4.4: Influence of size of aggregate on compressive strength of concrete
4. Maturity of Concrete:
Increase in strength of concrete is not only depends upon curing period of concrete,
but also on the temperature at which concrete is cured.
Maturity of concrete is expressed as the function of summation of product of time and
temperature.
Maturit = (time × temperture)
Hydration of concrete is continuing upto -11°C, therefore, -11°C is considered as a
datum for calculating maturity of concrete.
Concrete cured at 18°C for 28 days, is considered to be fully matured, and its maturity
is calculated as,
= (28 days × 24 hrs) 18 − (−11) °
= 19,488°C
= 19,800℃ hours (say)
4
Fig. 4.5: Relation between logarithm of maturity and strength
Fig. 4.6: Relationship of flexural strength with compressive strength and tensile
strength of concrete
5
As per IS 456,2000, The amount of increase in strength of concrete beyond age of 28
days depends upon type of cement, grade of cement, curing. environmental condition
and temperature.
Increase in strength, beyond 28 days age and upto one year is of the order of 10 to
20%. Indian practice does not consider this increase in strength while designing,
whereas British code permits to take this into account.
Fineness of cement plays an important role, in early strength of concrete as under:
6
Fig. 4.8: Relation between flexural strength with compressive strength & tensile
strength of concrete
The strength of concrete in tension and compression are closely related, but there is no
direct proportionality.
As the compressive strength of concrete increase, the tensile strength is also increases, but
at the decreasing rate.
The relationship between compressive and tensile strength is affected by various factors:
i. crushed coarse aggregate
ii. fine aggregate
iii. grading of aggregate
iv. age of concrete
The Fig. 4.8 shows a relationship of flexural strength with compressive strength and
tensile strength of concrete.
Theoretically, the compressive strength of concrete is ten times of its tensile strength.
A number of empirical formulae have been suggested to relate tensile strength and
compressive strength of concrete. Most of them are in the following form,
𝑓 =𝑘𝑓
Where,
ft = tensile strength of concrete
fc = compressive strength of concrete
k and n are coefficients which depends on the factors mentioned above and shape of the
specimen (cube or cylinder).
ACI suggests a formula
𝑓 =𝑘 𝑓
In the absence of test results, As per IS:456-2000, the flexural tensile strength is calculate
from the compressive strength by the following Equation.
𝑓 = 0.7 𝑓
7
Where,
fcr = flexural tensile strength in N/mm²
fck = characteristic compressive strength of cubes in N/mm².
8
5. The moulds are stored under damp sunny bags for 24 hours. The further the cubes are
removed from the mould and submerged in fresh water.
6. At the end of 7 days (counted from time of mixing of water with cement and aggregates)
three cubes are taken out.
7. The excess water is allowed to drain off and then the cube is placed in a compression
testing machine.
8. Load is applied gradually till the failure occurs. Maximum load reading is noted down.
We know that the strength of concrete increases with age. Assuming the strength of concrete
to be 100% at the end of 28 days, the percentage strength at various ages are as follows:
Age Strength %
1 day 16
3 days 40
7 days 67
28 days 100
3 months 122
6 months 146
1 year 155
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Wheel loads cause high tensile stress due to bending in Concrete highway, concrete road
must resist tensile (flexural) strength. Also volume changes in concrete induced tensile
stresses in concrete due to temperature warping.
when a > 200 mm for 150 mm specimen or a > 133 mm for 100 mm specimen.
or
3𝑝 × 𝑎
𝑓 =
𝑏×𝑑
10
when 170 mm < a < 200 mm for 150 mm specimen or 110 mm < a < 133 mm for 100 mm
specimen.
Where,
fb = Flexural strength or modulus of rupture, MPa
b = Measured width of specimen (mm)
d = Measured depth of specimen at the point of failure (mm)
l = Span on which specimen was supported (mm)
p = Maximum load applied to the specimen (N)
Fig. 4.11
Procedure:
1. Cast the beam in the mould and keep it in water at a temperature 24° to 30°C for 48 hours
before testing.
2. After 48 hours, the beam is placed in the machine such that two point loads are applied at
distance L/3 from the supports. Test two more specimen beams and find the flexural
strength of each specimen.
As per IS 456:2000, relation between flexural strength and compressive strength is
𝑓 = 0.7 𝑓
Bond Strength-
The resistance to separation of mortar and concrete from reinforcing steel (or other
materials) with which it is in contact.
Forces that resist separation, such as adhesion, friction.
It consider two angles:
1. The bond strength between paste and steel reinforcement
2. The bond strength between paste and aggregate.
1. The bond strength between paste and steel reinforcement:
- A perfect bond, existing between concrete and steel reinforcement is one of the
fundamental assumptions of reinforced concrete.
- Bond strength arises primarily from the friction and adhesion between concrete and
steel.
2. The bond strength between paste and aggregate:
- Concrete can be regarded as a chain in which aggregates are the links bonded together
by cement paste.
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- The strength of concrete as a whole is depending upon the strength (bond strength) of
the hydrated hardened cement paste (hcp).
- Strength of hep is depending upon w/c ratio and the products of hydration in
particular the C-S-H gel.
Modulus of Elasticity-
Concrete shows remarkable elastic properties and follows the Hooke’s law upto a high
value of compressive loading. The modulus of elasticity of concrete is defined as,
Compressive strength
𝐸 =
Strain
The modulus of elasticity varies from 2 x 105 kg/cm² to 5 x 105 kg/cm² for different
grades of concrete.
Concrete is not perfectly elastic material and the value of modulus of elastics is not
constant for all stress.
Modulus of elasticity of concrete is obtained by following ways:
Fig. 4.12
As the stress-strain curve for concrete is not straight. Hence, modulus of Elasticity is
found out by drawing tangent to initial part of curve and is called as Initial Tangent
Modulus.
Modulus of Elasticity determined using secant is called on secant modulus, However,
there is no standard method of determining secant modulus.
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If modulus of elasticity is found out using chord drawn between two specified points on
stress-strain curve is called as chord modulus.
Static modulus of elasticity does not represent elastic behavior of concrete, especially at
higher stresses due to effect of creep.
Where,
L = length of specimen
ρ = density of concrete
k = constant
Dynamic modulus of elasticity is not affected by creep, hence is more than the modulus
of elasticity obtained by static method.
Poisson’s Ratio:
Poisson’s ratio for a concrete is defined as the ratio of lateral strain to axial strain under
uniaxial loading within elastic range.
Depending upon the properties of aggregate, Poisson’s ratio for normal concrete ranges
between 0.15 to 0.20.
Ultra pulse velocity method can also used for finding Poisson’s ratio.
The value of Poisson’s ratio is slightly increases to 0.2 to 0.25, if it is determined by
dynamic test.
Poisson’s ratio for concrete increase with richer mix.
Creep-
Creep of concrete can be defined as the permanent strain induced in concrete due to
sustained load over a long period of time.
The stress strain curve of concrete is not a straight line but a curve and the strain will go
on increasing after a certain value without appreciable increase in stress.
As long as, the stress in concrete does not exceed one-third of its characteristic
compressive strength, creep may be assumed to be proportional to the stress.
Creep is desirable under some situations such as RCC columns and continuous beams as
it adjusts the stresses in highly stressed and less stressed parts of the members.
Creep in concrete is undesirable particularly in prestressed concrete structures
When concrete member is loaded the member defines to a certain amount as soon as the
load is applied. The deformation increases with time evaluation load of member is kept
constant.
Creep is a function time and is very difficult to avoid, creep occurs both in compressive
and tensile loading and its magnitude is same in both cases.
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Factors Affecting Creep:
Following are the factors which affect creep in concrete:
1. Quality of aggregate:
Good quality aggregate retards the creep.
2. Mix proportion:
A poor mix proportion shows more creep and water cement ratio used in the mix
proportion is the main factor affecting creep. Creep increases with increase in water
cement ratio. Thus creep can be said to be inversely proportional to strength.
3. Age of Concrete:
With age of concrete, creep goes on increasing. In the beginning, rate of creep decreases
with age as concrete achieves complete strength. But after 3 to 5 years the ageing process
increases the creep due to sustained load.
Shrinkage-
Shrinkage is the decrease in volume of concrete in the absence of load with time.
In the plastic stage, concrete shrinks in volume due to absorption of water or loss of
water.
Due to bleeding, the surface water evaporates rapidly causing shrinkage and this uneven
shrinkage causes shrinkage cracks.
Shrinkage depends upon the efficiency of curing method as well as water cement ratio,
cements lean mixes and amount of water added.
Shrinkage can be reduced by using low water cement ratio, presaturated aggregate, water
tight and non-absorbent,.
Types of Shrinkage:
Shrinkage can be classified in the following ways:
1. Plastic shrinkage.
2. Drying shrinkage.
3. Autogeneous shrinkage.
4. Carbonation shrinkage.
1. Plastic shrinkage:
Plastic shrinkage occurs soon after the concrete is placed or when the concrete is in
plastic state. The reason of plastic shrinkage is loss of water from the surface of
concrete due to evaporation or by absorption by aggregates or subgrade. The loss of
water results in reduction of volume.
In case of floor and pavements where the large surface area is exposed to drying as
compared to depth, the drying of concrete is very fast. In such cases, due to exposed
surface area to hot sun and drying wind result is plastic shrinkage.
Sometimes if concrete surface is not subjected to drying but made with high water-
cement ratio, large quantity of water bleeds and rise to the surface. When this water
dries, the surface of concrete gets cracked. This type of effect may occur due to the
excess vibration or yielding of formwork.
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The shrinkage can be reduced by controlling the loss of water from the surface of
concrete. This can be done by proper curing or by covering the surface of concrete by
polyethylene sheeting immediately after placing the concrete or by working at night.
2. Drying shrinkage:
The hydration is the continuous process, the drying shrinkage is also a continuous
process when concrete is subjected to drying condition. Drying shrinkage of concrete
is similar to drying of timber. The loss of free water from concrete does not cause any
volume change. But the loss of water held in gel pores causes the volume change. The
shrinkage may be defined as, “volume change that takes place after the concrete has
set and hardened”. Windrawal of water from concrete stored in unsaturated air voids
causes shrinkage, a part of this shrinkage can be recovered on immersion of concrete
in water.
3. Autogeneous shrinkage:
In a sealed concrete where no moisture movement to or from the paste is permitted
when temperature is constant some shrinkage may occur, known as autogeneous
shrinkage. This occurs in the interior of large concrete mass. This type of shrinkage is
of least importance and hence not applicable in the practice.
4. Carbonation shrinkage:
The CO2 present in atmosphere reacts with Ca(OH)2 present in cement in the presence
of moisture forming CaCO3. Carbonation penetrates beyond the exposed surface of
concrete only very slowly. Carbonation is accompanied by increase in weight and
shrinkage. Carbonation also results in increased strength and reduced permeability.
The magnitude of carbonation shrinkage is very small and hence it is not of much
significance.
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Durability of Concrete-
Durability of concrete is defined as the ability to resist weathering action, chemical
attack, abrasion, or any process of deterioration.
In other words, It is defined as the ability to perform satisfactorily in the exposure
condition to which it is subjected over an intended period of time with minimum of
maintenance.
Different concretes require different degrees of durability depending on the exposure
environment and the properties desired.
Deterioration of concrete either due to Mechanical, physical or chemical action on
concrete which affects durability
The mechanical deterioration of concrete is due to
1. Impact
2. Abration
3. Erosion
4. Cavitation
The physical deterioration of concrete is due to
1. Freezing and thawing action.
2. Permeability of water
3. High heat of hydration
The chemical reactions which degrade the concrete are
1. Alkali Aggregate Reaction.
2. Sulphate Attack.
3. Chloride Ingress.
4. Delay Ettringite Formation.
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Moderate: Concrete surfaces sheltered from severe rain or freezing whilst wet Concrete
exposed to condensation and rain Concrete continuously under water Concrete in contact or
buried under non-aggressive soil/ground water Concrete surfaces sheltered from saturated salt
air in coastal area.
Severe: Concrete surfaces exposed to severe rain, alternate wetting and drying or occasional
freezing whilst wet or severe condensation.
Very Severe: Concrete surfaces exposed to sea water spray, corrosive fumes or severe
freezing conditions whilst wetConcrete in contact with or buried under aggressive sub-
soil/ground water.
Extreme: Surface of members in tidal zone Members in direct contact with liquid/ solid
aggressive chemicals.
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The high strength concrete may share some concepts of mix design with the durable
concrete such as the use of low/lower W/CM ratio or the use of some types of additives
that help achieving a higher strength such as silica fume. But, these concepts are just few
concepts that can be used for designing a durable concrete among many other concepts.
A concrete of 35MPa or 40 MPa can be a more durable concrete than a concrete of 60
MPa or 70MPa from the point of the view of durability performance indicators such as
Water absorption, Water permeability, RCP and other durability testing parameters.
Specifying a higher strength for achieving a more durable concrete is a wrong
engineering practice. Strength should not be used as a durability performance indicator. It
is not a good or recommended engineering practice to specify 50 MPa for a concrete that
requires a design strength of only 35MPa in order to use the extra 15 MPa for achieving a
concrete with a better durability performance. The extra cost required for achieving the
unnecessary extra 15 MPa can be utilized effectively in the concepts rated to durability
based-thinking such as:
- The use of cementitious additives such as silica fume, GGBFS, fly ash, or natural
pozzolans either in binary or ternary blends with cement.
- The use of one of hydrophobic or crystalline admixtures.
- Setting a limit on W/CM ratio.
- Specifying appropriate level of concrete workability that facilities easier construction
processes of concrete casting, compaction and finishing, and eliminates the wrong
practices by the workmanship such as adding extra water on-site.
- Facilitating of better construction processes related to concrete casting, compacting,
finishing and curing of the concrete.
- Specifying “performance-based durability specifications” that focus on the
performance indicators of concrete durability without the need of setting limits on
every single material that would be used as an ingredient in the mix.
While a minimum cement content has been specified in some US, BS and EU based
standards, it is not necessary that the use of a higher cement content will provide a better
durability performance. The type of the binder has a more significant effect on the
durability performance indicators than its content. From durability point of view, a 400 kg
of binder containing 7% silica fume and 50% GGBFS can be significantly better than a
binder containing a 500 kg or more of plain Ordinary Portland Cement (Type I as per
ASTM C150). While a more cement content usually grantees a higher strength at the
same water content, a more cement content does not grantee a better durability
performance.
The durability of the concrete is the responsibility of all parties in the project. It is the
responsibility of the consultant to use the durability-based concepts and not the strength-
based concepts in specifying the durability performance indicators to grantee a durable
concrete as a (Designed Product). The responsibility of the concrete supplier to utilize
proper mix design and production processes to grantee a durable concrete as a (Delivered
“On-site” Product). The responsibility of the contractor to apply the proper construction
processes related to casting, compaction, finishing and curing procedures to grantee a
durable concrete as a (Finished Product). The responsibility of the owner to provide a
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proper maintenance, preventive and corrective procedures to grantee a durable concrete as
(In-Service Product).
In conclusion, concrete durability should be specified based on “Durability-Based
Thinking” and not based on “Strength-Based Thinking”. Strength and durability are
different concepts and should be dealt as different concepts. Sometimes, they may share
some few design parameters but they are still different concepts.
Permeability of concrete-
Permeability is the ease with which liquids or gases can travel through concrete
Permeability is the rate of flow of fluid (i.e. distance penetrated/time) through concrete
The coefficient of permeability, K, of concrete for steady-state flow of water through a
sample of concrete is determined from Darcy’s expression:
𝑑𝑞 ∆ℎ
=𝐾 𝐴.
𝑑𝑡 𝐿
Where,
dq/dt = rate of flow of water through the sample
A = cross-sectional area of the sample
∆h = drop in hydraulic head through the sample
L = thickness of the sample
Significance of Permeability:
Permeability of concrete plays an important role in durability because it controls the rate
of entry of moisture that may contain aggressive chemicals and the movement of water
during heating or freezing. Higher the permeability lesser will be the durability.
Permeability of concrete is of interest also in relation to the water-tightness of liquid-
retaining structures. Higher the permeability lesser will be the water-tightness.
1. Cement contant:
To make an impermeable concrete, it is necessary to provide adequate cement
content.
Permeability of concrete also reduces with the fineness of cement. Finer cement
particles will hydrate much faster, thus creating the impermeable concrete faster.
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2. Quality of aggregatess:
Good quality normal aggregates have very low permeability. Normal weight concrete
generally has permeability similar to that of the cement paste.
Permeability of concrete increases when more porous aggregates are used in the
concrete. If the pores of aggregates are getting connected with the micro- cracks of
the cement paste, then the ingress of moisture, alkalies, etc will be very fast and
accordingly deterioration of the concrete structure will be fast, affecting the durability
of concrete.
Larger size aggregates if used, increases the permeability considerably due to the
development of micro-cracks in the weak transition zone at early age. The aggregates
from different sources have different permeability as given in Table 4.1.
3. Pore structure:
It is clear that decreasing porosity of paste up to a typical value of 30% is highly
beneficial in decreasing the permeability. Causing any decrease in porosity below this
typical value is not accompanied by a substantial decrease in the permeability.
As shown in Fig. 4.13, the paste permeability is very low at and below a paste
porosity of 30%. A small increase in porosity above around 30% causes a steep
increase in the permeability.
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space after the water is consumed by either cement hydration reactions or evaporation
to the environment.
The loss of mixing water is one of the reasons for higher permeability. Hence, simply
adding water to concrete will create more air space after evaporation. Therefore, for
any concrete to be watertight, the water-cement ratio shall be as low as possible.
Concrete produced with low water-cement ratio shows low coefficient of permeability
as compared to concrete produced with high water-cement ratio as shown in Fig. 4.14.
The coefficient of permeability increases about 1000 times with the increase in w/c
ratio from 0.35 to 0.65.
ACI 301-89 suggests water-cement ratio not more than 0.48 for concrete exposed to
fresh water and not more than 0.44 for concrete exposed to sea water.
5. Age of concrete:
Concrete continues to hydrate over a long period of time as long as there is a presence
of un-hydrated lime. Hence, as the age of the concrete increases, the permeability will
reduce.
The water present in the capillary pore will be utilized by the cement for hydration,
continuously producing the hydration products which will fill the empty spaces in the
matrix. The reduction in permeability with age is shown in Fig. 4.15.
7. Adequacy of curing:
Curing will continue the hydration process which occupies the pore space making the
concrete more impermeable.
Concrete with steam curing is more permeable than that provided moist curing.
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slag, silica fumes, metakaoline, natural pozzolanic materials, etc. should be used to
reduce the heat of hydration. The use of these materials not only improves the properties
of fresh concrete but also enhances the long term durability characteristics.
Compressive strength
50 75 100 125 150
(MPa)
High Performance
I II III IV V
Class
Table 4.2: Classification of High Performance Concrete related to strength
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Sulphate Attack-
The sulphates of sodium, magnesium and calcium are present in alkali soils and waters.
These sulphates react chemically with the hydrated lime and hydrated calcium aluminate
in the cement paste to form calcium sulphate and calcium sulphoaluminate.
These reactions result in the expansion and disruption of the concrete. The deposition of
sulphate crystals in the pores of the concrete tends to disintegrate the concrete.
Alkali waters entering concrete may evaporate and deposit their salts. The growing
crystals resulting from alternate wetting and drying may eventually fill the pores and
develop pressures sufficient to disrupt the concrete.
Resistance to disintegration is more in dense, impervious concrete having low water-
cement ratio and containing entrained air.
The vulnerability of concrete to sulphate attack can be reduced by the use of low C3A
content cement.
Use of pozzolans increases the resistance to sulphate attack. High pressure steam curing
improves the resistance of concrete to sulphate attack.
Addition of calcium chloride reduces the resistance to sulphate attack, whatever may be
the type of cement used.
The resistance of concrete to sulphate attack can be tested by storing the specimens in a
solution of sodium or magnesium sulphate or in a mixture of the two.
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1. Material Properties:
a) Aggregates:
Aggregates used for concrete may come from rock that is used under conditions that
are different from those obtaining in its natural state. The rock will have evolved
slowly from the time it was first formed, slowly undergoing chemical alteration and
weathering until it has reached equilibrium. When it is suddenly put into an
environment with an average pH of 12.6 (rising locally to 13.6) which occurs in the
pore water within concrete, the constituent minerals will once again start to evolve in
an attempt to find a new equilibrium. This new stage of alteration leads to the
appearance of a partial solution which tends to form what might become an expansive
gel. When it does so, it is known as reactivity. Reactivity is dependent partly on the
minerals and partly on the rocks formed by the combination of minerals. Thus we
must distinguish between.
Factors connected with the constituent minerals:
a) Type
b) Tectonic and weathering history
Factors Connected with the Rock:
Structure, grain size, porosity, permeability, specific surface
Composition
b) Cement:
Very high alkali content in the pore water phase is usually due to presence of the
alkalis in the cement and other cementitious materials. Alkalis can also come from
certain aggregates (feldspars) or admixtures. However the presence of free Ca (OH)2
is prerequisite for expansion to occur. Limiting permissible alkali content in portland
cement is considered a sufficient control measure. However, today there is beginning
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to emerge general agreement that the swelling risk with reactive aggregates is
proportional to the total alkali content of the concrete. Control measures should
recognize this fact as in British practice. With reactive aggregates, the use of alkali-
rich Portland cements can cause problems after only a few years. Mixing Water and
Admixtures Alkalies can also come into concrete from mixing water and chemical
admixtures in concrete. In many of the projects, ground water or boring water and
runoff river water is used in concrete. The ground water may contain dissolve alkalies
from the surrounding soil/ rocks and river water may also contain industrial and
agricultural effluent which may be the source of alkalies.
2. External Influences:
a) Environmental Humidity:
The alkali-aggregate reaction is greatly promoted by a relative humidity of 80% or
more.
b) Temperature:
Like all chemical reactions, AAR is affected by temperature. In general the rate of
reaction and formation of gel will increase as the temperature rises. At the same time,
gel at high temperatures will be less viscous and more able to escape into cracks and
voids within the concrete. Temperature of concrete is governed by ambient conditions
once the heat of hydration has subsided.
c) Compressive Stresses:
The expansion and damage due to AAR are greatly influenced by the presence of
restraints and stresses applied to the concrete. In fact well distributed compressive
stresses can reduce the concrete expansion in the direction of compression and
prevent cracks to open, limiting in this way the water circulation. From this point of
view there is a difference between primary cracking directly due to irregular local
concrete expansion (typical map cracking pattern) and secondary, or structural,
cracking which is produced by any structural restraint opposing the expansion. From
some observations it appears that the expansion at the bottom section of dams, where
stresses are high, is likely to be less important than a higher elevations. As such
stresses, also called backpressures, are produced by the expansion itself, they may
likely be one of the causes which in some cases slow down the expansion and
eventually stop it.
3. Time:
Time cracks appear after variable lengths of time. Concrete swelling may be gradual or
may occur suddenly at a later time. Swelling may eventually stop when all the reactive
fractions of polyphase aggregate have been exhausted. The structures where this was
studied were never in any danger of immediate failure.
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Chloride Attack-
Chloride exists in concrete as both bound and free ions, but free chlorides directly affect
the concrete. Chlorides may present in the concrete from several different sources.
For e.g., soluble chlorides may be introduced in fresh concrete by the use of aggregates
containing chlorides. Some cement may also contain small amount of chlorides.
Chlorides may also enter the concrete from the environment. But the chloride ions in the
concrete should be limited to its critical value to control the corrosion of reinforcement.
Following table 4.3 gives the quantitative risk of concrete based on chloride content.
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Mechanism of Electro-Chemical Corrosion:
The metals have a tendency to oxidize to a metal ion in an aqueous solution of normal
ionic activity at standard temperature.
The ionization of metal i.e. oxidation of metal at the anode is often referred to as the
primary stage of the corrosion reaction called anodic reaction and can be represented by
𝐹 →𝐹 + 2𝑒
This reaction results in the anodic region of the metal to have an excess of electrons.
Therefore, to maintain equilibrium of electric charges an equivalent quantity of hydrogen
is plated out at adjacent surfaces of the metal.
This thin film of hydrogen around the cathode exhibits further progress of corrosion
reaction, unless the hydrogen film is removed in some manner.
The destruction of hydrogen film may take by oxygen depolarisation at the cathode or by
evolution of hydrogen as a gas. These processes called cathodic reactions are usually
represented by:
1
𝑂 + 𝐻 𝑂 + 2𝑒 → 2𝑂𝐻
2
𝑜𝑟
2𝐻 + 2𝑒 → 𝐻
These cathodic reactions which are often called the secondary reactions control the rate of
corrosion of the structural steel.
Therefore, any environmental condition which influences these reaction will influence the
rate of corrosion.
Since cathodic depolarisation is dependent on the concentration of dissolved oxygen next
to the metal, it is influenced by the degree of aeration, temperature, salt concentration etc.
The secondary reactions permit the primary reaction to proceed with the accumulation of
ferrous ion in the solution which in the presence of water and oxygen are oxidised and
precipitated as rust.
The Following Methods are Adopted to Prevent the Reinforcement from Corrosion:
Using adequate concrete cover. It is necessary to ensure that minimum required cover has
been provided to all elements everywhere.
Corrosion inhabitators are used as additives in concrete.
Surface sealants are used on the surface of concrete
(Silane, epoxy or methyl mithacrylate). Reinforcements are coated with corrosion
resistant material.
Cathodic protection (Powerful method to stop corrosion in salt contaminated bridge
decks).
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If, however, the cause of damage is of a continuing or recurring nature, remediation must
be addressed, or the repair method and materials must in some manner be made resistant
to predictable future damage.
A quick review of the common causes of damage reveals that the majority of them are of
a continuing or recurring nature.
It is important to differentiate between causes of damage and symptoms of damage.
In the above case of the river barge hitting the bridge pier, the cause of damage is the
impact to the concrete.
The resultant cracking is a symptom of that impact. In the event of freezing and thawing
deterioration to modern concrete, the cause of the damage may well lie with the use of
low quality or dirty fine or coarse aggregate in the concrete mix.
The resultant scaling and cracking are a symptom of low durability concrete. The
application of high-cost repairs to low quality concrete is usually economically
questionable.
It is somewhat common to find that multiple causes of damage exist. Improper design,
low quality materials, or poor construction practices reduce the durability of concrete and
increase its susceptibility to deterioration from other causes.
Similarly, sulphate and alkali-silica deterioration cause cracks in the exterior surfaces of
concrete that allow accelerated deterioration from cycles of freezing and thawing.
The deterioration resulting from the lowered resistance to cyclic freezing and thawing
might mask the original cause of the damage.
Finally, it is important to fully understand the original design intent and concepts of a
damaged structure before attempting repair.
Low quality local aggregate may have intentionally been used in the concrete mix
because the costs associated with hauling higher quality aggregate, more distances may
have made it more economical to repair the structure when required at some future date.
A classic example of misunderstanding the intent of design recently occurred on a project
in Nebraska.
A concrete sluiceway that would experience great quantities of waterborne sand was
designed with an abrasion-resistant protective overlay of silica fume concrete. This
overlay was intentionally designed so that it would not bond to the base concrete, making
replacement easier when required by the anticipated abrasion-erosion damage.
This design concept, however, was not communicated to construction personnel who
became deeply concerned when the silica fume overlay was found to be “disbanded”
shortly after placement and curing was completed.
Some difficulty was experienced in preventing field personnel from requiring the
construction contractor to repair a perfectly serviceable overlay that was performing
exactly as intended.
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