A.

ATOMIC STRUCTURE
The atom is the smallest particle of an element that take part in a chemical reaction. The
atom is made up of three subatomic particles:
(i)Protons
(ii)Electrons
(iii)Neutrons
(i)Protons
1. The proton is positively charged
2. Is found in the centre of an atom called nucleus
3. It has a relative mass 1
4. The number of protons in a atom of an element is its Atomic number
(ii)Electrons
1. The Electrons is negatively charged
2. Is found in fixed regions surrounding the centre of an atom called energy levels/orbitals.
3. It has a relative mass 1/1840
4. The number of protons and electrons in a atom of an element is always equal
(iii)Neutrons
1. The Neutron is neither positively nor negatively charged thus neutral.
2. Like protons it is found in the centre of an atom called nucleus
3. It has a relative mass 1
4. The number of protons and neutrons in a atom of an element is its Mass number
Diagram showing the relative positions of protons, electrons and neutrons in an atom of an
element

1
Diagram showing the relative positions of protons, electrons and neutrons in an atom of
Carbon

The table below show atomic structure of the 1st twenty elements.
Symbol Protons Electrons Neutrons Atomic Mass number
Element number

Hydrogen H 1 1 0 1 1
Helium He 2 2 2 2 4
Lithium Li 3 3 4 3 7

2
Beryllium Be 4 4 5 4 9
Boron B 5 5 6 5 11
Carbon C 6 6 6 6 12
Nitrogen N 7 7 7 7 14
Oxygen O 8 8 8 8 16
Fluorine F 9 9 10 9 19
Neon Ne 10 10 10 10 20
Sodium Na 11 11 12 11 23
Magnesium Mg 12 12 12 12 24
Aluminium Al 13 13 14 13 27
Silicon Si 14 14 14 14 28
PhosphorusP 15 15 16 15 31
Sulphur S 16 16 16 16 32
Chlorine Cl 17 17 18 17 35
Argon Ar 18 18 22 18 40
Potassium K 19 19 20 19 39
Calcium Ca 20 20 20 20 40
Most atoms of elements exist as isotopes.
Isotopes are atoms of the same element, having the same number of protons/atomic number
but different number of neutrons/mass number.
By convention, isotopes are written with the mass number as superscript and the atomic
number as subscript to the left of the chemical symbol of the element. i.e.
mass number
m
atomic number n X symbol of element

3
Below is the conventional method of writing the 1st twenty elements showing the mass
numbers and atomic numbers:
1 4 7 9 11 12
1H 2He 3Li 4Be 5B 6C

14 16 19 20 23 24
7N 8O 9F 10Ne 11Na 12Mg

27 28 31 32 35 40
13Al 14Si 15P 16S 17Cl 18Ar

39 40
19K 20C

The table below shows some common natural isotopes of some elements
Element Isotopes Protons Electrons Neutrons Atomic Mass
number number
1
Hydrogen 1H 1 1 0 1 1
2
1H(deuterium) 1 1 2 1 2
3
1H(Tritium) 1 1 3 1 3

35
Chlorine 17Cl 17 17 18 17 35
37
17Cl 17 17 20 17 37
39
Potassium 19K 19 19 20 19 39
40
19K 19 19 21 19 40
41
19K 19 19 22 19 41
16
Oxygen 8O 8 8 8 8 16
18
8O 8 8 10 8 18
235
Uranium 92U 92 92 143 92 235

4
 238
92U 92 92 146 92 238

22
Neon 10Ne 10 10 12 10 22
20
10Ne 10 10 10 10 20
21
10Ne 10 10 11 10 21
The mass of an average atom is very small (10-22 g).Masses of atoms are therefore expressed in
relation to a chosen element.
The atom recommended is 12C isotope whose mass is arbitrarily assigned as 12.000 atomic
mass units(a.m.u) .
All other atoms are compared to the mass of 12C isotope to give the relative at The relative
atomic mass(RAM) is therefore defined as “the mass of average atom of an element
compared to 1/12 an atom of 12C isotope whose mass is arbitrarily fixed as 12.000 atomic
mass units(a.m.u) ” i.e;
RAM = mass of atom of an element
1
/12 of one atom of 12C isotope
Accurate relative atomic masses (RAM) are got from the mass spectrometer. Mass
spectrometer determines the isotopes of the element and their relative
abundance/availability.
Using the relative abundances/availability of the isotopes, the relative atomic mass (RAM) can
be determined /calculated as in the below examples.
a) Chlorine occurs as 75% 3517Cl and 25% 3717Cl isotopes. Calculate the relative atomic mass
of Chlorine.
Working
100 atoms of chlorine contains 75 atoms of 3517Cl isotopes
100 atoms of chlorine contains 75 atoms of 3717Cl isotopes

5
 Therefore;
RAM of chlorine = ( 75/100 x 35) + 25/100 x 37 = 35.5
Note that:
Relative atomic mass has no units
More atoms of chlorine exist as 3517Cl(75%) than as 3717Cl(25%) therefore RAM is
nearer to the more abundant isotope.
b) Calculate the relative atomic mass of potassium given that it exist as;
39 40 41
93.1% 19K , 0.01% 19K , 6.89% 19K ,
Working
100 atoms of potassium contains 93.1 atoms of 3919K isotopes
100 atoms of potassium contains 0.01 atoms of 4019K isotopes
100 atoms of potassium contains 6.89 atoms of 4119K isotopes
Therefore;
RAM of potassium = (93.1/100 x39) + (0.01/100 x 40) +(6.89 /100 x 39) Note that:
Relative atomic mass has no units
More atoms of potassium exist as 3919K (93.1%) therefore RAM is nearer to the more
abundant 3919K isotope.
c) Calculate the relative atomic mass of Neon given that it exist as;
20 21 22
90.92% 10Ne , 0.26% 10Ne , 8.82% 10Ne,

Working
100 atoms of Neon contains 90.92 atoms of 2010Ne isotopes
100 atoms of Neon contains 0.26 atoms of 2110Ne isotopes
100 atoms of Neon contains 8.82 atoms of 2210 Ne isotopes Therefore;
RAM of Neon = (90.92/100 x20) + (0.26/100 x 21) +(8.82 /100 x 22)

6
 Note that:
Relative atomic mass has no units
More atoms of Neon exist as 2010Ne (90.92%) therefore RAM is nearer to the more
abundant 2010Ne isotope.
d) Calculate the relative atomic mass of Argon given that it exist as;
20 21 22
90.92% 10Ne , 0.26% 10Ne , 8.82% 10Ne,

NB
The relative atomic mass is a measure of the masses of atoms. The higher the relative atomic
mass, the heavier the atom.
Electrons are found in energy levels/orbital.
An energy level is a fixed region around/surrounding the nucleus of an atom occupied by
electrons of the same (potential) energy.
By convention energy levels are named 1,2,3… outwards from the region nearest to nucleus.
Each energy level is occupied by a fixed number of electrons:
The 1st energy level is occupied by a maximum of two electrons
The 2nd energy level is occupied by a maximum of eight electrons
The 3rd energy level is occupied by a maximum of eight electrons( or eighteen
electrons if available)
The 4th energy level is occupied by a maximum of eight electrons( or eighteen or thirty
two electrons if available)
This arrangement of electrons in an atom is called electron configuration / structure.
By convention the electron configuration / structure of an atom of an element can be shown in
form of a diagram using either cross(x) or dot(●) to
Practice examples drawing electronic configurations
a)11H has - in nucleus1proton and 0 neutrons

7
 - 1 electron in the 1st energy levels thus:
Nucleus
Energy levels
Electrons (represented by cross(x)
Electronic structure of Hydrogen is thus: 1:

b) 42He has - in nucleus 2 proton and 2 neutrons Commented [s1]:

- 2 electron in the 1st energy levels thus:

Nucleus
Energy levels
Electrons (represented by cross(x)
Electronic structure of Helium is thus: 2:
c) 73Li has - in nucleus 3 proton and 4 neutrons
- 2 electron in the 1st energy levels
-1 electron in the 2nd energy levels thus
Nucleus
Energy levels
Electrons (represented by cross(x)
Electronic structure of Lithium is thus: 2:1
d) 94Be has - in nucleus 4 proton and 5 neutrons
- 2 electron in the 1st energy levels
-2 electron in the 2nd energy levels thus
Nucleus
Energy levels
Electrons (represented by cross(x)

8
Electronic structure of Beryllium is thus: 2:2
e) 115B has - in nucleus 5 proton and 6 neutrons
- 2 electron in the 1st energy levels
-3 electron in the 2nd energy levels thus
Nucleus
Energy levels
Electrons (represented by cross(x)
Electronic structure of Boron is thus: 2:3
12
f) 6C has - in nucleus 6 proton and 6 neutrons
- 2 electron in the 1st energy levels
-4 electron in the 2nd energy levels thus
Nucleus
Energy levels
Electrons (represented by cross(x)
Electronic structure of Carbon is thus: 2:4
g) 147N has - in nucleus 7 proton and 7 neutrons
- 2 electron in the 1st energy levels
-5 electron in the 2nd energy levels thus

Nucleus
Energy levels
Electrons (represented by cross(x)
Electronic structure of Nitrogen is thus: 2:5
h) 168O has - in nucleus 8 proton and 8 neutrons
- 2 electron in the 1st energy levels

9
 -6 electron in the 2nd energy levels thus
Nucleus
Energy levels
Electrons (represented by cross(x)
Electronic structure of Oxygen is thus: 2:6
i) 199F has - in nucleus 9 proton and 10 neutrons
- 2 electron in the 1st energy levels
-7 electron in the 2nd energy levels thus
Nucleus
Energy levels
Electrons (represented by cross(x)
Electronic structure of Fluorine is thus: 2:7
i) 2010Ne has - in nucleus 10 proton and 10 neutrons
- 2 electron in the 1st energy levels
-8 electron in the 2nd energy levels thus
Nucleus
Energy levels
Electrons (represented by cross(x)
Electronic structure of Neon is thus: 2:8
j) 2311Na has - in nucleus 11 proton and 12 neutrons
- 2 electron in the 1st energy levels
-8 electron in the 2nd energy levels
-1 electron in the 3rd energy levels thus
Nucleus
Energy levels

10
Electrons (represented by dot (.)
Electronic structure of Sodium is thus: 2:8:1
k) 2412Mg has - in nucleus 12 proton and 12 neutrons
- 2 electron in the 1st energy levels
-8 electron in the 2nd energy levels
-2 electron in the 3rd energy levels thus

Nucleus
Energy levels
Electrons (represented by dot (.)
Electronic structure of Magnesium is thus: 2:8:2
l) 2713Al has - in nucleus 13 proton and 14 neutrons
- 2 electron in the 1st energy levels
-8 electron in the 2nd energy levels
-3 electron in the 3rd energy levels thus
Nucleus
Energy levels
Electrons (represented by dot (.)
Electronic structure of Aluminium is thus: 2:8:3
m) 2814Si has - in nucleus 14 proton and 14 neutrons
- 2 electron in the 1st energy levels
-8 electron in the 2nd energy levels
-4 electron in the 3rd energy levels thus
Nucleus
Energy levels

11
Electrons (represented by dot (.)
Electronic structure of Silicon is thus: 2:8:4
n) 3115P has - in nucleus 14 proton and 15 neutrons
- 2 electron in the 1st energy levels
-8 electron in the 2nd energy levels
-5 electron in the 3rd energy levels thus
Nucleus
Energy levels
Electrons (represented by dot (.)
Electronic structure of Phosphorus is thus: 2:8:5
o) 3216S has - in nucleus 16 proton and 16 neutrons
- 2 electron in the 1st energy levels
-8 electron in the 2nd energy levels
-6 electron in the 3rd energy levels thus
Nucleus
Energy levels
Electrons (represented by dot (.)
Electronic structure of Sulphur is thus: 2:8:6

p) 3517Cl has - in nucleus 18 proton and 17 neutrons

- 2 electron in the 1st energy levels
-8 electron in the 2nd energy levels
-7 electron in the 3rd energy levels thus
Nucleus
Energy levels

12
Electrons (represented by dot (.)
Electronic structure of Chlorine is thus: 2:8:7
p) 4018Ar has - in nucleus 22 proton and 18 neutrons
- 2 electron in the 1st energy levels
-8 electron in the 2nd energy levels
-8 electron in the 3rd energy levels thus
Nucleus
Energy levels
Electrons (represented by dot (.)
Electronic structure of Argon is thus: 2:8:8
q) 3919K has - in nucleus 20 proton and 19 neutrons
- 2 electron in the 1st energy levels
-8 electron in the 2nd energy levels
-8 electron in the 3rd energy levels
-1 electron in the 4th energy levels thus
Nucleus
Energy levels
Electrons (represented by dot (.)
Electronic structure of Potassium is thus: 2:8:8:1
r) 4020Ca has - in nucleus 20 proton and 20 neutrons
- 2 electron in the 1st energy levels
-8 electron in the 2nd energy levels
-8 electron in the 3rd energy levels
-2 electron in the 4th energy levels thus
Nucleus

13
Energy levels
Electrons (represented by dot (.)
Electronic structure of Calcium is thus: 2:8:8:2

B.PERIODIC TABLE
There are over 100 elements so far discovered. Scientists have tried to group them together in
a periodic table.
A periodic table is a horizontal and vertical arrangement of elements according to their atomic
numbers.
This table was successfully arranged in 1913 by the British scientist Henry Moseley from the
previous work of the Russian Scientist Dmitri Mendeleev.
The horizontal arrangement forms period. Atoms in the same period have the same the same
number of energy levels in their electronic structure. i.e.
The number of energy levels in the electronic configuration of an element determine the
period to which the element is in the periodic table.
e.g.
Which period of the periodic table are the following isotopes/elements/atoms?
12
a) 6C

Electron structure 2:4 => 2 energy levels used thus Period 2

23
b) 11Na

Electron structure 2:8:1 => 3 energy levels used thus Period 3

14
 39
c) 19K

Electron structure 2:8:8:1 => 4 energy levels used thus Period 4

1
d) 1H

Electron structure 1: => 1 energy level used thus Period 1

The vertical arrangement of elements forms a group. Atoms in the same have the same the
same group have the same number of outer energy level electrons as per their electronic
structure. i.e.
The number of electrons in the outer energy level an element determine the group to which
the element is, in the periodic table.
12
a) 6C

Electron structure 2:4 => 4 electrons in outer energy level thus Group IV
23
b) 11C

Electron structure 2:8:1 => 1 electron in outer energy level thus Group I
39
c) 19K

Electron structure 2:8:8:1=>1 electron in outer energy level thus Group I

1
d) 1H

Electron structure 1: => 1 electron in outer energy level thus Group I

By convention;
(i)Periods are named using English numerals 1, 2, 3, 4…
(ii)Groups are named using Roman numerals I, II, III, IV…

There are eighteen groups in a standard periodic table.

There are seven periods in a standard periodic table.

THE STANDARD PERIODIC TABLE OF ELEMENTS

15
When an atom has maximum number of electrons in its outer energy level, it is said to be
stable.
When an atom has no maximum number of electrons in its outer energy level, it is said to be
unstable.
All stable atoms are in group 8/18 of the periodic table. All other elements are unstable.
All unstable atoms/isotopes try to be stable through chemical reactions. A chemical reaction
involves gaining or losing outer electrons (electron transfer) .When electron transfer take
place, an ion is formed.
An ion is formed when an unstable atom gain or donate electrons in its outer energy level in
order to be stable. Whether an atom gain or donate electrons depend on the relative energy
required to donate or gain extra electrons i.e.
Examples
19
1. 9F has electronic structure/configuration 2:7.

16
It can donate the seven outer electrons to have stable electronic structure/configuration 2:.
It can gain one extra electron to have stable electronic structure/configuration 2:8. Gaining
requires less energy, and thus Fluorine reacts by gaining one extra electrons.
23
2. 13 Al has electronic structure/configuration 2:8:3
It can donate the three outer electrons to have stable electronic structure/configuration 2:8.
It can gain five extra electrons to have stable electronic structure/configuration 2:8:8. Donating
requires less energy, and thus Aluminium reacts by donating its three outer electrons.
Elements with less than four electrons in the outer energy level donates /lose the outer
electrons to be stable and form a positively charged ion called cation.
A cation therefore has more protons (positive charge) than electrons (negative charge)
Generally metals usually form cation
Elements with more than four electrons in the outer energy level gain /acquire extra electrons
in the outer energy level to be stable and form a negatively charged ion called anion.
An anion therefore has fewer protons (positive charge) than electrons (negative charge)
Generally non metals usually form anion. Except Hydrogen
The charge carried by an ion is equal to the number of electrons gained/acquired or
donated/lost.
Examples of ion formation
1.11H
H -> H+ + e
(atom) (monovalent cation) (electrons donated/lost)
Electronic configuration 1: (No electrons remains)
2. 2713 Al
Al -> Al3+ + 3e
(atom) (trivalent cation) (3 electrons donated/lost)

17
Electron 2:8:3 2:8
structure (unstable) (stable)
3. 2311 Na
Na -> Na+ + e
(atom) (cation) ( 1 electrons donated/lost)
Electron 2:8:1 2:8
structure (unstable) (stable)
4. 2412Mg
Mg -> Mg2+ + 2e
(atom) (cation) ( 2 electrons donated/lost)
Electron 2:8:1 2:8
structure (unstable) (stable)

5. 168O
O + 2e -> O2-
(atom) ( 2 electrons gained/acquired) (anion)
Electron 2:6 2:8
structure (unstable) (stable)
6. 147N
N + 3e -> N3-
(atom) ( 3 electrons gained/acquired) (anion)
Electron 2:5 2:8
structure (unstable) (stable)
7. 3115P
P + 3e -> P3-

18
 (atom) ( 3 electrons gained/acquired) (anion)
Electron 2:5 2:8
structure (unstable) (stable)
8. 199F
F + e -> F-
(atom) ( 1 electrons gained/acquired) (anion)
Electron 2:7 2:8
structure (unstable) (stable)
9. 3517Cl
Cl + e -> Cl-
(atom) ( 1 electrons gained/acquired) (anion)
Electron 2:8:7 2:8:8
structure (unstable) (stable)
3. 3919 K
K -> K+ + e
(atom) (cation) ( 1 electrons donated/lost)
Electron 2:8:8:1 2:8:8
structure (unstable) (stable)
When an element donates/loses its outer electrons, the process is called oxidation. When an
element acquires/gains extra electrons in its outer energy level, the process is called reduction.
The charge carried by an atom, cation or anion is its oxidation state.
Table showing the oxidation states of some isotopes
Element Symbol of element / Charge of ion Oxidation state
isotopes
1
Hydrogen 1H H+ +1

19
 2
1H(deuterium) H+ +1
3 +
1H(Tritium) H +1
35
Chlorine 17Cl Cl- -1
37
17Cl Cl- -1

39
Potassium 19K K+ +1
40
19K K+ +1
41
19K K+ +1

16
Oxygen 8O O2- -2
18
8O O2- -2

24
Magnesium 12Mg Mg2+ +2

23
sodium 11Na Na+ +1

Copper Cu Cu+ +1
Cu2+ +2
Iron Fe2+ +2
3+
Fe +3
Lead Pb2+ +2
Pb4+ +4
Manganese Mn2+ +2
Mn7+ +7

20
Chromium Cr3+ +3
6+
Cr +6
Sulphur S4+ +4
S6+ +6
Carbon C2+ +2
C4+ +4

Note:
Some elements can exist in more than one oxidation state. They are said to have variable
oxidation state.
Roman capital numeral is used to indicate the oxidation state of an element with a variable
oxidation state in a compound.

Examples:
(i) Copper (I) means Cu+ as in Copper(I)oxide
(ii) Copper (II) means Cu2+ as in Copper(II)oxide
(iii) Iron (II) means Fe2+ as in Iron(II)sulphide
(iv) Iron (III) means Fe3+ as in Iron(III)chloride
(iv) Sulphur(VI)mean S6+ as in Iron(III)sulphate(VI)
(v) Sulphur(VI)mean S6+ as in sulphur(VI)oxide
(vi) Sulphur(IV)mean S4+ as in sulphur(IV)oxide
(vii) Sulphur(IV)mean S4+ as in sodium sulphate(IV)
(ix) Carbon(IV)mean C4+ as in carbon(IV)oxide
(x) Carbon(IV)mean C4+ as in Lead(II)carbonate(IV)
(xi) Carbon(II)mean C2+ as in carbon(II)oxide

21
 (xii) Manganese(IV)mean Mn4+ as in Manganese(IV)oxide
A compound is a combination of two or more elements in fixed proportions. The ratio of the
atoms making a compound is called the chemical formulae. Elements combine together to
form a compound depending on their combining power.
The combining power of atoms in an element is called Valency. Valency of an element is equal
to the number of:
(i) Hydrogen atoms that an atom of element can combine with or displace.
(ii) Electrons gained /acquired in outer energy level by non metals to be stable/attain
duplet/octet.
(iii) Electrons donated/lost by outer energy level of metals to be stable/attain
octet/duplet.
(iv) Charges carried by ions/cations/ions
Group of atoms that react as a unit during chemical reactions are called radicals. Elements with
variable oxidation state also have more than one valency.
Table showing the valency of common radicals
Radical name Chemical formulae Combining power /
Valency
Ammonium NH4 + 1
Hydroxide OH- 1
Nitrate(V) NO3 - 1
Hydrogen carbonate HCO3- 1
Hydrogen HSO4- 1
sulphate(VI)
Hydrogen HSO3- 1
sulphate(IV)

22
Manganate(VII) MnO4- 1
Chromate(VI) CrO42- 2
2-
Dichromate(VI) Cr2O7 2
Sulphate(VI) SO42- 2
Sulphate(IV) SO32- 2
Carbonate(IV) CO32- 2
Phosphate(V) PO42- 3
Table showing the valency of some common metal and non metals
Element/metal Valency Element/non metal Valency

Hydrogen 1 Florine 1
Lithium 1 Chlorine 1
Beryllium 2 Bromine 1
Boron 3 Iodine 1
Sodium 1 Carbon 4
Magnesium 2 Nitrogen 3
Aluminium 3 Oxygen 2
Potassium 1 Phosphorus 3
Calcium 2
Zinc 2
Barium 2
Mercury 2
Iron 2 and 3
Copper 1 and 2
Manganese 2 and 4

23
Lead 2 and 4

From the valency of elements, the chemical formular of a compound can be derived using the
following procedure:
(i)Identify the elements and radicals making the compound
(ii)Write the symbol/formular of the elements making the compound starting with the
metallic element
(iii)Assign the valency of each element /radical as superscript.
(iv)Interchange/exchange the valencies of each element as subscript.
(v)Divide by the smallest/lowest valency to derive the smallest whole number ratios
Ignore a valency of 1.
This is the chemical formula.

Practice examples
Write the chemical formula of
(a)Aluminium oxide
Elements making compound Aluminium Oxygen
Symbol of elements/radicals in compound Al O
Assign valencies as superscript Al3 O2
Exchange/Interchange the valencies as Al2 O3
subscript
Divide by smallest valency to get whole - -
number
Chemical formula of Aluminium oxide is thus: Al2 O3
This means: 2atoms of Aluminium combine with 3 atoms of Oxygen

24
(b)Sodium oxide
Elements making compound Sodium Oxygen
Symbol of elements/radicals in compound Na O
Assign valencies as superscript Na1 O2
Exchange/Interchange the valencies as Na2 O1
subscript
Divide by smallest valency to get whole - -
number
Chemical formula of Sodium oxide is thus: Na2 O
This means: 2atoms of Sodium combine with 1 atom of Oxygen
(c)Calcium oxide
Elements making compound Calcium Oxygen
Symbol of elements/radicals in compound Ca O
Assign valencies as superscript Ca2 O2
Exchange/Interchange the valencies as Ca2 O2
subscript
Divide by two to get smallest whole number Ca1 O1
ratio
Chemical formula of Calcium oxide is thus: CaO
This means: 1 atom of calcium combine with 1 atom of Oxygen.
(d)Lead (IV) oxide
Elements making compound Lead Oxygen
Symbol of elements/radicals in compound Pb O
Assign valencies as superscript Pb4 O2

25
 Exchange/Interchange the valencies as Pb2 O4
subscript
Divide by two to get smallest whole number Pb1 O2
ratio
Chemical formula of Lead (IV) oxide is thus: PbO2
This means: 1 atom of lead combine with 2 atoms of Oxygen.
(e)Lead (II) oxide
Elements making compound Lead Oxygen
Symbol of elements/radicals in compound Pb O
Assign valencies as superscript Pb2 O2
Exchange/Interchange the valencies as Pb2 O2
subscript
Divide by two to get smallest whole number Pb1 O1
ratio
Chemical formula of Lead (II) oxide is thus: PbO
This means: 1 atom of lead combine with 1 atom of Oxygen.
(e)Iron (III) oxide
Elements making compound Iron Oxygen
Symbol of elements/radicals in compound Fe O
Assign valencies as superscript Fe3 O2
Exchange/Interchange the valencies as Fe2 O3
subscript
Divide by two to get smallest whole number - -
ratio
Chemical formula of Iron(III) oxide is thus: Fe2O3

26
This means: 2 atom of lead combine with 3 atom of Oxygen.
(f)Iron (II) sulphate (VI)
Elements making compound Iron sulphate(VI)
Symbol of elements/radicals in compound Fe SO4
Assign valencies as superscript Fe2 SO4 2
Exchange/Interchange the valencies as Fe2 SO4 2
subscript
Divide by two to get smallest whole number Fe1 SO4 1

ratio
Chemical formula of Iron (II) sulphate (VI) is thus: FeSO4
This means: 1 atom of Iron combine with 1 sulphate (VI) radical.
(g)Copper (II) sulphate (VI)
Elements making compound Copper sulphate(VI)
Symbol of elements/radicals in compound Cu SO4
Assign valencies as superscript Cu2 SO4 2
Exchange/Interchange the valencies as Cu2 SO4 2
subscript
Divide by two to get smallest whole number Cu1 SO4 1

ratio
Chemical formula of Cu(II)sulphate(VI) is thus: CuSO4
This means: 1 atom of Copper combine with 1 sulphate (VI) radical.
(h)Aluminium sulphate (VI)
Elements making compound Aluminium sulphate(VI)
Symbol of elements/radicals in compound Al SO4
Assign valencies as superscript Al3 SO4 2

27
Exchange/Interchange the valencies as Al2 SO4 3
subscript
Divide by two to get smallest whole number - -
ratio
Chemical formula of Aluminium sulphate (VI) is thus: Al2(SO4)3
This means: 2 atom of Aluminium combine with 3 sulphate (VI) radical.
(i)Aluminium nitrate (V)
Elements making compound Aluminium nitrate(V)
Symbol of elements/radicals in compound Al NO3
Assign valencies as superscript Al3 NO3 1
Exchange/Interchange the valencies as Al1 NO3 3
subscript
Divide by two to get smallest whole number - -
ratio
Chemical formula of Aluminium sulphate (VI) is thus: Al (NO3)3
This means: 1 atom of Aluminium combine with 3 nitrate (V) radical.
(j)Potassium manganate (VII)
Elements making compound Potassium manganate(VII)
Symbol of elements/radicals in compound K MnO4
Assign valencies as superscript K1 MnO4 1
Exchange/Interchange the valencies as K1 MnO4 1
subscript
Divide by two to get smallest whole number - -
ratio
Chemical formula of Potassium manganate (VII) is thus: KMnO4

28
This means: 1 atom of Potassium combine with 4 manganate (VII) radical.
(k)Sodium dichromate (VI)

Elements making compound Sodium dichromate(VI)

Symbol of elements/radicals in compound Na Cr2O7
Assign valencies as superscript Na 1 Cr2O7 2
Exchange/Interchange the valencies as Na2 Cr2O7 1
subscript
Divide by two to get smallest whole number - -
ratio
Chemical formula of Sodium dichromate (VI) is thus: Na2 Cr2O7
This means: 2 atom of Sodium combine with 1 dichromate (VI) radical.
(l)Calcium hydrogen carbonate
Elements making compound Calcium Hydrogen
carbonate
Symbol of elements/radicals in compound Ca CO3
Assign valencies as superscript Ca 2 HCO3 1
Exchange/Interchange the valencies as Ca1 HCO3 2
subscript
Divide by two to get smallest whole number - -
ratio
Chemical formula of Calcium hydrogen carbonate is thus: Ca (HCO3)2
This means: 1 atom of Calcium combine with 2 hydrogen carbonate radical.
(l)Magnesium hydrogen sulphate (VI)

29
Elements making compound Magnesium Hydrogen
sulphate(VI)
Symbol of elements/radicals in compound Mg HSO4
Assign valencies as superscript Mg 2 HSO4 1
Exchange/Interchange the valencies as Mg1 HSO4 2
subscript
Divide by two to get smallest whole number - -
ratio
Chemical formula of Magnesium hydrogen sulphate (VI) is thus: Mg (HSO4)2
This means: 1 atom of Magnesium combine with 2 hydrogen sulphate (VI) radical.
Compounds are formed from chemical reactions. A chemical reaction is formed when atoms of
the reactants break free to bond again and form products. A chemical reaction is a statement
showing the movement of reactants to form products. The following procedure is used in
writing chemical equations:
1. Write the word equation
2. Write the correct chemical formula for each of the reactants and products
3. Check if the number of atoms of each element on the reactant side is equal to the number of
atoms of each element on the product side.
4. Multiply the chemical formula containing the unbalanced atoms with the lowest common
multiple if the number of atoms on one side is not equal. This is called balancing.
Do not change the chemical formula of the products/reactants.
5. Assign in brackets, the physical state/state symbols of the reactants and products after each
chemical formula as:
(i) (s) for solids
(ii) (l) for liquids

30
 (iii) (g) for gas
(iv) (aq) for aqueous/dissolved in water to make a solution.
Practice examples
Write a balanced chemical equation for the following
(a) Hydrogen gas is prepared from reacting Zinc granules with dilute hydrochloric acid.
Procedure
1. Write the word equation
Zinc + Hydrochloric acid -> Zinc chloride + hydrogen gas
2. Write the correct chemical formula for each of the reactants and products
Zn + HCl -> ZnCl2 + H2
3. Check if the number of atoms of each element on the reactant side is equal to the
number of atoms of each element on the product side.
Number of atoms of Zn on the reactant side is equal to product side
One atom of H in HCl on the reactant side is not equal to two atoms in H2 on product side.
One atom of Cl in HCl on the reactant side is not equal to two atoms in ZnCl2 on product
side.
4. Multiply the chemical formula containing the unbalanced atoms with the lowest
common multiple if the number of atoms on one side is not equal.
Multiply HCl by “2” to get “2” Hydrogen and “2” Chlorine on product and reactant side.
Zn + 2 HCl -> ZnCl2 + H2
5. Assign in brackets, the physical state/state symbols .
Zn(s) + 2 HCl(aq) -> ZnCl2 (aq) + H2(g)
(b) Oxygen gas is prepared from decomposition of Hydrogen peroxide solution to water
Procedure
1. Write the word equation

31
 Hydrogen peroxide -> Water + oxygen gas
2. Write the correct chemical formula for each of the reactants and products
H2O2 -> H2O + O2
3. Check if the number of atoms of each element on the reactant side is equal to the
number of atoms of each element on the product side.
Number of atoms of H on the reactant side is equal to product side
Two atom of O in H2O2 on the reactant side is not equal to three atoms (one in H2O and
two in O2) on product side.
4. Multiply the chemical formula containing the unbalanced atoms with the lowest
common multiple if the number of atoms on one side is not equal.
Multiply H2O2 by “2” to get “4” Hydrogen and “4” Oxygen on reactants
Multiply H2O by “2” to get “4” Hydrogen and “2” Oxygen on product side
When the “2” Oxygen in O2 and the“2” in H2O are added on product side they are equal to
the“4” Oxygen on reactants side.
2H2O2 -> 2H2O + O2
5. Assign in brackets, the physical state/state symbols.
2H2O2(aq) -> 2H2O(l) + O2(g)
(c) Chlorine gas is prepared from Potassium manganate (VII) reacting with hydrochloric acid
to form potassium chloride solution, manganese (II) chloride solution, water and chlorine
gas.
Procedure
1. Write the word equation
Potassium manganate (VII) + Hydrochloric acid ->
Potassium chloride + manganese (II) chloride + chlorine +water
2. Write the correct chemical formula for each of the reactants and products

32
 KMnO4 + HCl -> KCl + MnCl2 +H2O + Cl2
3. Check if the number of atoms of each element on the reactant side is equal to the
number of atoms of each element on the product side.
Number of atoms of K and Mn on the reactant side is equal to product side
Two atom of H in H2O on the product side is not equal to one atom on reactant side.
Four atom of O in KMnO4 is not equal to one in H2O
One atom of Cl in HCl on reactant side is not equal to three (one in H2O and two in Cl2)
4. Multiply the chemical formula containing the unbalanced atoms with the lowest
common multiple if the number of atoms on one side is not equal.
Multiply HCl by “16” to get “16” Hydrogen and “16” Chlorine on reactants
Multiply KMnO4 by “2” to get “2” Potassium and “2” manganese, “2 x4 =8” Oxygen on
reactant side.
Balance the product side to get:
2 KMnO4 +16 HCl -> 2 KCl + 2 MnCl2 +8 H2O + 5 Cl2
5. Assign in brackets, the physical state/state symbols.
2KMnO4(s) +16 HCl(aq)-> 2 KCl (aq) + 2MnCl2(aq)+8 H2O(l)+5 Cl2(g)
(d)Carbon (IV) oxide gas is prepared from Calcium carbonate reacting with hydrochloric acid
to form calcium chloride solution, water and carbon (IV) oxide gas.
Procedure
1. Write the word equation
Calcium carbonate + Hydrochloric acid ->
Calcium chloride solution+ water +carbon (IV)oxide
2. Write the correct chemical formula for each of the reactants and products
CaCO3 + HCl -> CaCl2 +H2O + CO2

33
 3. Check if the number of atoms of each element on the reactant side is equal to the
number of atoms of each element on the product side.
4. Multiply the chemical formula containing the unbalanced atoms with the lowest
common multiple if the number of atoms on one side is not equal.
5. Assign in brackets, the physical state/state symbols.
CaCO3(s) + 2 HCl(aq) -> CaCl2(aq) + H2O(l) + CO2(g)
(d)Sodium hydroxide solution neutralizes hydrochloric acid to form salt and water.
NaOH(aq) + HCl(aq) -> NaCl (aq) + H2O(l)
(e)Sodium reacts with water to form sodium hydroxide and hydrogen gas.
2Na(s) + 2H2O(l) -> 2NaOH(aq) + H2(g)
(f)Calcium reacts with water to form calcium hydroxide and hydrogen gas
Ca(s) + 2H2O(l) -> Ca(OH)2(aq) + H2(g)
(g)Copper (II) Oxide solid reacts with dilute hydrochloric acid to form copper (II) chloride
and water.
CuO(s) + 2HCl(aq) -> CuCl2(aq) + H2O(l)
(h)Hydrogen sulphide reacts with Oxygen to form sulphur (IV) Oxide and water.
2H2S(g) + 3O2(g) -> 2SO2(g) + 2H2O(l)
(i)Magnesium reacts with steam to form Magnesium Oxide and Hydrogen gas.
Mg(s) + 2H2O(g) -> MgO(s) + H2(g)
(j)Ethane (C2H6) gas burns in air to form Carbon (IV) Oxide and water.
2C2H6(g) + 7O2(g) -> 4CO2(g) + 6H2O(l)
(k)Ethene (C2H4) gas burns in air to form Carbon (IV) Oxide and water.
C2H4(g) + 3O2(g) -> 2CO2(g) + 2H2O(l)

(l)Ethyne (C2H2) gas burns in air to form Carbon (IV) Oxide and water.

34
 2C2H2(g) + 5O2(g) -> 4CO2(g) + 2H2O(l)

C. PERIODICITY OF CHEMICAL FAMILES/DOWN THE GROUP

The number of valence electrons and the number of occupied energy levels in an atom of an
element determine the position of an element in the periodic table .i.e
The number of occupied energy levels determines the Period and the valence electrons
determine the Group.
Elements in the same group have similar physical and chemical properties. The trends in
physical and chemical properties of elements in the same group vary down the group. Elements
in the same group thus constitute a chemical family.
(a) Group I elements: Alkali metals
Group I elements are called Alkali metals except Hydrogen which is a non metal. The alkali
metals include:
Element Symbol Atomic Electron Oxidation Valency
number structure state
Lithium Li 3 2:1 Li+ 1
Sodium Na 11 2:8:1 Na+ 1
Potassium K 19 2:8:8:1 K+ 1
Rubidium Rb 37 2:8:18:8:1 Rb+ 1
Caesium Cs 55 2:8:18:18:8:1 Cs+ 1
Francium Fr 87 2:8:18:32:18:8:1 Fr+ 1
All alkali metals atom has one electron in the outer energy level. They therefore are
monovalent. They donate /lose the outer electron to have oxidation state M+
The number of energy levels increases down the group from Lithium to Francium. The more
the number of energy levels the bigger/larger the atomic size. e.g.

35
The atomic size of Potassium is bigger/larger than that of sodium because Potassium has
more/4 energy levels than sodium (3 energy levels).
Atomic and ionic radius
The distance between the centre of the nucleus of an atom and the outermost energy level
occupied by electron/s is called atomic radius. Atomic radius is measured in
nanometers(n).The higher /bigger the atomic radius the bigger /larger the atomic size.
The distance between the centre of the nucleus of an ion and the outermost energy level
occupied by electron/s is called ionic radius. Ionic radius is also measured in nanometers
(n).The higher /bigger the ionic radius the bigger /larger the size of the ion.
Atomic radius and ionic radius depend on the number of energy levels occupied by electrons.
The more the number of energy levels the bigger/larger the atomic /ionic radius. e.g.
The atomic radius of Francium is bigger/larger than that of sodium because Francium has
more/7 energy levels than sodium (3 energy levels).
Atomic radius and ionic radius of alkali metals increase down the group as the number of
energy levels increases.
The atomic radius of alkali metals is bigger than the ionic radius. This is because alkali metals
react by losing/donating the outer electron and hence lose the outer energy level.
Table showing the atomic and ionic radius of some alkali metals
Element Symbol Atomic Atomic Ionic radius(nM)
number radius(nM)
Lithium Li 3 0.133 0.060
Sodium Na 11 0.157 0.095
Potassium K 19 0.203 0.133

36
The atomic radius of sodium is 0.157nM .The ionic radius of Na+ is 0.095nM. This is because
sodium reacts by donating/losing the outer electrons and hence the outer energy level. The
remaining electrons/energy levels experience more effective / greater nuclear attraction/pull
towards the nucleus reducing the atomic radius.
Electropositivity
The ease of donating/losing electrons is called electropositivity. All alkali metals are
electropositive. Electropositivity increase as atomic radius increase. This is because the
effective nuclear attraction on outer electrons decreases with increase in atomic radius. The
outer electrons experience less nuclear attraction and can be lost/ donated easily/with ease.
Francium is the most electropositive element in the periodic table because it has the
highest/biggest atomic radius.
Ionization energy
The minimum amount of energy required to remove an electron from an atom of element in its
gaseous state is called 1st ionization energy. The SI unit of ionization energy is kilojoules per
mole/kJmole-1 .Ionization energy depend on atomic radius. The higher the atomic radius, the
less effective the nuclear attraction on outer electrons/energy level and thus the lower the
ionization energy. For alkali metals the 1st ionization energy decrease down the group as the
atomic radius increase and the effective nuclear attraction on outer energy level electrons
decrease.
e.g. The 1st ionization energy of sodium is 496 kJmole-1 while that of potassium is 419 kJmole-1
.This is because atomic radius increase and thus effective nuclear attraction on outer energy
level electrons decrease down the group from sodium to Potassium. It requires therefore less
energy to donate/lose outer electrons in Potassium than in sodium.
Physical properties

37
Soft/Easy to cut: Alkali metals are soft and easy to cut with a knife. The softness and ease of
cutting increase down the group from Lithium to Francium. This is because an increase in
atomic radius, decreases the strength of metallic bond and the packing of the metallic structure
Appearance: Alkali metals have a shiny grey metallic luster when freshly cut. The surface
rapidly/quickly tarnishes on exposure to air. This is because the metal surface rapidly/quickly
reacts with elements of air/oxygen.
Melting and boiling points: Alkali metals have a relatively low melting/boiling point than
common metals like Iron. This is because alkali metals use only one delocalized electron to
form a weak metallic bond/structure.
Electrical/thermal conductivity: Alkali metals are good thermal and electrical conductors.
Metals conduct using the outer mobile delocalized electrons. The delocalized electrons move
randomly within the metallic structure.
Summary of some physical properties of the 1st three alkali metals
Alkali Appearanc Ease Melting Boiling Conductivit 1st
metal e of point point y ionizatio
cutting (oC) (oC) n energy
Lithium Silvery Not 180 1330 Good 520
white easy
Sodium Shiny grey Easy 98 890 Good 496

Potassiu Shiny grey Very 64 774 Good 419

m easy
Chemical properties
(i)Reaction with air/oxygen
On exposure to air, alkali metals react with the elements in the air.

38
Example
On exposure to air, Sodium first reacts with Oxygen to form sodium oxide.
4Na(s) + O2(g) -> 2Na2O(s)
The sodium oxide formed further reacts with water/moisture in the air to form sodium
hydroxide solution.
Na2O(s) + H2O(l) -> 2NaOH(aq)
Sodium hydroxide solution reacts with carbon (IV) oxide in the air to form sodium carbonate.
2NaOH (aq) + CO2 (g) -> Na2CO3 (g) + H2O (l)
(ii)Burning in air/oxygen
Lithium burns in air with a crimson/deep red flame to form Lithium oxide
4Li (s)+ O2 (g) -> 2Li2O(s)
Sodium burns in air with a yellow flame to form sodium oxide
4Na (s) + O2 (g) -> 2Na2O(s)
Sodium burns in oxygen with a yellow flame to form sodium peroxide
2Na (s) + O2 (g) -> Na2O2 (s)
Potassium burns in air with a lilac/purple flame to form potassium oxide
4K (s) + O2 (g) -> 2K2O (s)
(iii) Reaction with water:
Experiment
Measure 500 cm3 of water into a beaker.
Put three drops of phenolphthalein indicator.
Put about 0.5g of Lithium metal into the beaker.
Determine the pH of final product
Repeat the experiment using about 0.1 g of Sodium and Potassium.
Caution: Keep a distance

39
Observations
Alkali metal Observations Comparative
speed/rate of the
reaction
Lithium -Metal floats in water Moderately vigorous
-rapid
effervescence/fizzing/bubbling
-colourless gas produced (that
extinguishes burning splint with
explosion /“pop” sound)
-resulting solution turn
phenolphthalein indicator pink
-pH of solution = 12/13/14

Sodium -Metal floats in water Very vigorous

-very rapid effervescence /fizzing
/bubbling
-colourless gas produced (that
extinguishes burning splint with
explosion /“pop” sound)
-resulting solution turn
phenolphthalein indicator pink
-pH of solution = 12/13/14
Potassium -Metal floats in water Explosive/burst into
flames

40
 -explosive effervescence /fizzing
/bubbling
-colourless gas produced (that
extinguishes burning splint with
explosion /“pop” sound)
-resulting solution turn
phenolphthalein indicator pink
-pH of solution = 12/13/14

Explanation
Alkali metals are less dense than water. They therefore float in water. They react with water to
form a strongly alkaline solution of their hydroxides and producing hydrogen gas. The rate of
this reaction increase down the group. i.e. Potassium is more reactive than sodium .Sodium is
more reactive than Lithium.
The reactivity increases as electropositivity increases of the alkali increases. This is because as
the atomic radius increases, the ease of donating/losing outer electron increases during
chemical reactions.
Chemical equations
2Li(s) + 2H2O(l) -> 2LiOH(aq) + H2(g)
2Na(s) + 2H2O(l) -> 2NaOH(aq) + H2(g)
2K(s) + 2H2O(l) -> 2KOH(aq) + H2(g)
2Rb(s) + 2H2O(l) -> 2RbOH(aq) + H2(g)
2Cs(s) + 2H2O(l) -> 2CsOH(aq) + H2(g)
2Fr(s) + 2H2O(l) -> 2FrOH(aq) + H2(g)
Reactivity increase down the group

41
(iv) Reaction with chlorine:
Experiment
Cut about 0.5g of sodium into a deflagrating spoon with a lid cover. Introduce it on a Bunsen
flame until it catches fire. Quickly and carefully lower it into a gas jar containing dry chlorine to
cover the gas jar.
Repeat with about 0.5g of Lithium.
Caution: This experiment should be done in fume chamber because chlorine is poisonous
/toxic.
Observation
Sodium metal continues to burn with a yellow flame forming white solid/fumes.
Lithium metal continues to burn with a crimson flame forming white solid / fumes.
Alkali metals react with chlorine gas to form the corresponding metal chlorides. The reactivity
increase as electropositivity increase down the group from Lithium to Francium. The ease of
donating/losing the outer electrons increase as the atomic radius increase and the outer
electron is less attracted to the nucleus.
Chemical equations
2Li(s) + Cl2(g) -> 2LiCl(s)
2Na(s) + Cl2(g) -> 2NaCl(s)
2K(s) + Cl2(g) -> 2KCl(s)
2Rb(s) + Cl2(g) -> 2RbCl(s)
2Cs(s) + Cl2(g) -> 2CsCl(s)
2Fr(s) + Cl2(g) -> 2FrCl(s)
Reactivity increase down the group
The table below shows some compounds of the 1st three alkali metals

42
 Lithium sodium Potassium
Hydroxide LiOH NaOH KOH Some uses of

Oxide Li2O Na2O K2O alkali metals

Sulphide Li2S Na2S K2S include:

Chloride LiCl NaCl KCl (i)Sodium is used

Carbonate Li2CO3 Na2CO3 K2CO3 in making sodium

Nitrate(V) LiNO3 NaNO3 KNO3 cyanide for

Nitrate(III) - NaNO2 KNO2 extracting gold

Sulphate(VI) Li2SO4 Na2SO4 K2SO4 from gold ore.

(ii)Sodium
Sulphate(IV) - Na2SO3 K2SO3
chloride is used in
Hydrogen carbonate - NaHCO3 KHCO3
seasoning food.
Hydrogen - NaHSO4 KHSO4
(iii)Molten
sulphate(VI)
mixture of
Hydrogen - NaHSO3 KHSO3
sodium and
sulphate(IV)
potassium is used
Phosphate - Na3PO4 K3PO4
as coolant in
Manganate(VI) - NaMnO4 KMnO4
nuclear reactors.
Dichromate(VI) - Na2Cr2O7 K2Cr2O7
(iv)Sodium is used
Chromate(VI) - Na2CrO4 K2CrO4
in making sodium
hydroxide used in making soapy and soapless detergents.
(v)Sodium is used as a reducing agent for the extraction of titanium from Titanium (IV) chloride.
(vi)Lithium is used in making special high strength glasses
(vii)Lithium compounds are used to make dry cells in mobile phones and computer laptops.
Group II elements: Alkaline earth metals

43
Group II elements are called Alkaline earth metals . The alkaline earth metals include:
Element Symbol Atomic Electron Oxidation Valency
number structure state
Beryllium Be 4 2:2 Be2+ 2
Magnesium Mg 12 2:8:2 Mg2+ 2
Calcium Ca 20 2:8:8:2 Ca2+ 2
Strontium Sr 38 2:8:18:8:2 Sr2+ 2
Barium Ba 56 2:8:18:18:8:2 Ba2+ 2
Radium Ra 88 2:8:18:32:18:8:2 Ra2+ 2
All alkaline earth metal atoms have two electrons in the outer energy level. They therefore are
divalent. They donate /lose the two outer electrons to have oxidation state M2+
The number of energy levels increases down the group from Beryllium to Radium. The more
the number of energy levels the bigger/larger the atomic size. e.g.
The atomic size/radius of Calcium is bigger/larger than that of Magnesium because Calcium
has more/4 energy levels than Magnesium (3 energy levels).
Atomic radius and ionic radius of alkaline earth metals increase down the group as the number
of energy levels increases.
The atomic radius of alkaline earth metals is bigger than the ionic radius. This is because they
react by losing/donating the two outer electrons and hence lose the outer energy level.
Table showing the atomic and ionic radius of the 1st three alkaline earth metals
Element Symbol Atomic Atomic Ionic radius(nM)
number radius(nM)
Beryllium Be 4 0.089 0.031
Magnesium Mg 12 0.136 0.065
Calcium Ca 20 0.174 0.099

44
The atomic radius of Magnesium is 0.136nM .The ionic radius of Mg2+ is 0.065nM. This is
because Magnesium reacts by donating/losing the two outer electrons and hence the outer
energy level. The remaining electrons/energy levels experience more effective / greater
nuclear attraction/pull towards the nucleus reducing the atomic radius.
Electropositivity
All alkaline earth metals are also electropositive like alkali metals. The electropositivity increase
with increase in atomic radius/size. Calcium is more electropositive than Magnesium. This is
because the effective nuclear attraction on outer electrons decreases with increase in atomic
radius. The two outer electrons in calcium experience less nuclear attraction and can be lost/
donated easily/with ease because of the higher/bigger atomic radius.
Ionization energy
For alkaline earth metals the 1st ionization energy decrease down the group as the atomic
radius increase and the effective nuclear attraction on outer energy level electrons decrease.
e.g. The 1st ionization energy of Magnesium is 900 kJmole-1 while that of Calcium is 590
kJmole-1 .This is because atomic radius increase and thus effective nuclear attraction on outer
energy level electrons decrease down the group from magnesium to calcium.
It requires therefore less energy to donate/lose outer electron in calcium than in magnesium.
The minimum amount of energy required to remove a second electron from an ion of an
element in its gaseous state is called the 2nd ionization energy.
The 2nd ionization energy is always higher /bigger than the 1st ionization energy.
This is because once an electron is donated /lost form an atom, the overall effective nuclear
attraction on the remaining electrons/energy level increase. Removing a second electron from
the ion require therefore more energy than the first electron.

45
The atomic radius of alkali metals is higher/bigger than that of alkaline earth metals. This is
because across/along the period from left to right there is an increase in nuclear charge from
additional number of protons and still additional number of electrons entering the same energy
level. Increase in nuclear charge increases the effective nuclear attraction on the outer energy
level which pulls it closer to the nucleus. e.g.
Atomic radius of Sodium (0.157nM) is higher than that of Magnesium (0.137nM). This is
because Magnesium has more effective nuclear attraction on the outer energy level than
Sodium hence pulls outer energy level more nearer to its nucleus.

Physical properties
Soft/Easy to cut: Alkaline earth metals are not soft and easy to cut with a knife like alkali
metals. This is because of the decrease in atomic radius of corresponding alkaline earth metal,
increases the strength of metallic bond and the packing of the metallic structure. Alkaline earth
metals are:
(i) ductile(able to form wire/thin long rods)
(ii) malleable(able to be hammered into sheet/long thin plates)
(iii) have high tensile strength(able to be coiled without breaking/ not brittle/withstand
stress)
Appearance: Alkali earth metals have a shiny grey metallic luster when their surface is freshly
polished /scrubbed. The surface slowly tarnishes on exposure to air. This is because the metal
surface slowly undergoes oxidation to form an oxide. This oxide layer should be removed
before using the alkaline earth metals.

46
Melting and boiling points: Alkaline earth metals have a relatively high melting/ boiling point
than alkali metals. This is because alkali metals use only one delocalized electron to form a
weaker metallic bond/structure. Alkaline earth metals use two delocalized electrons to form a
stronger metallic bond /structure.
The melting and boiling points decrease down the group as the atomic radius/size increase
reducing the strength of metallic bond and packing of the metallic structure. e.g.
Beryllium has a melting point of 1280oC. Magnesium has a melting point of 650oC.Beryllium has
a smaller atomic radius/size than magnesium .The strength of metallic bond and packing of the
metallic structure is thus stronger in beryllium.
Electrical/thermal conductivity: Alkaline earth metals are good thermal and electrical
conductors. The two delocalized valence electrons move randomly within the metallic
structure.
Electrical conductivity increase down the group as the atomic radius/size increase making the
delocalized outer electrons less attracted to nucleus. Alkaline earth metals are better thermal
and electrical conductors than alkali metals because they have more/two outer delocalized
electrons. e.g.
Magnesium is a better conductor than sodium because it has more/two delocalized electrons
than sodium. The more delocalized electrons the better the electrical conductor.
Calcium is a better conductor than magnesium.
Calcium has bigger/larger atomic radius than magnesium because the delocalized electrons are
less attracted to the nucleus of calcium and thus more free /mobile and thus better the
electrical conductor
Summary of some physical properties of the 1st three alkaline earth metals

47
 Alkaline Appearan Ease Melti Boilin Condu 1st 2nd
earth ce of ng g ct- ionizatio ionizatio
metal cutti point point ivity n n
ng (oC) (oC) energy energy
Berylliu Shiny Not 1280 3450 Good 900 1800
m grey easy
Magnesi Shiny Not 650 1110 Good 736 1450
um grey Easy
calcium Shiny Not 850 1140 Good 590 970
grey easy
Chemical properties
(i) Reaction with air/oxygen
On exposure to air, the surface of alkaline earth metals is slowly oxidized to its oxide on
prolonged exposure to air.
Example
On exposure to air, the surface of magnesium ribbon is oxidized to form a thin film of
Magnesium oxide
. 2Mg(s) + O2(g) -> 2MgO(s)
(ii) Burning in air/oxygen
Experiment
Hold a about 2cm length of Magnesium ribbon on a Bunsen flame. Stop heating when it
catches fire/start burning.
Caution: Do not look directly at the flame

48
Put the products of burning into 100cm3 beaker. Add about 5cm3 of distilled water. Swirl. Test
the mixture using litmus papers.
Repeat with Calcium
Observations
-Magnesium burns with a bright blindening flame
-White solid /ash produced
-Solid dissolves in water to form a colourless solution
-Blue litmus paper remain blue
-Red litmus paper turns blue
-colourless gas with pungent smell of urine
Explanation
Magnesium burns in air with a bright blindening flame to form a mixture of Magnesium oxide
and Magnesium nitride.
2Mg (s) + O2 (g) -> 2MgO(s)
3Mg (s) + N2 (g) -> Mg3N2 (s)
Magnesium oxide dissolves in water to form magnesium hydroxide.
MgO(s) + H2O (l) -> Mg (OH)2(aq)
Magnesium nitride dissolves in water to form magnesium hydroxide and produce ammonia
gas.
Mg3N2 (s) + 6H2O (l) -> 3Mg (OH)2(aq) + 2NH3 (g)
Magnesium hydroxide and ammonia are weakly alkaline with pH 8/9/10/11 and turns red
litmus paper blue.
Calcium burns in air with faint orange/red flame to form a mixture of both Calcium oxide and
calcium nitride.
2Ca (s) + O2 (g) -> 2CaO(s)

49
 3Ca (s) + N2 (g) -> Ca3N2 (s)
Calcium oxide dissolves in water to form calcium hydroxide.
CaO(s) + H2O (l) -> Ca (OH)2(aq)
Calcium nitride dissolves in water to form calcium hydroxide and produce ammonia gas.
Ca3N2 (s) + 6H2O (l) -> 3Ca (OH)2(aq) + 2NH3 (g)
Calcium hydroxide is also weakly alkaline solution with pH 8/9/10/11 and turns red litmus
paper blue.
(ii) Reaction with water
Experiment
Measure 50 cm3 of distilled water into a beaker.
Scrub/polish with sand paper 1cm length of Magnesium ribbon
Place it in the water. Test the product-mixture with blue and red litmus papers.
Repeat with Calcium metal.
Observations
-Surface of magnesium covered by bubbles of colourless gas.
-Colourless solution formed.
-Effervescence/bubbles/fizzing takes place in Calcium.
-Red litmus paper turns blue.
-Blue litmus paper remains blue.
Explanations
Magnesium slowly reacts with cold water to form Magnesium hydroxide and bubbles of
Hydrogen gas that stick on the surface of the ribbon.
Mg(s) + 2H2O (l) -> Mg(OH)2(aq) + H2 (g)
Calcium moderately reacts with cold water to form Calcium hydroxide and produce a steady
stream of Hydrogen gas.

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 Ca(s) + 2H2O (l) -> Ca (OH)2(aq) + H2 (g)
(iii) Reaction with water vapour/steam
Experiment
Put some cotton wool soaked in water/wet sand in a long boiling tube.
Coil a well polished magnesium ribbon into the boiling tube.
Ensure the coil touches the side of the boiling tube. Heat the cotton wool/sand slightly then
strongly heat the Magnesium ribbon.
Set up of apparatus

Observations
-Magnesium glows red hot then burns with a blindening flame.
-Magnesium continues to glow/burning even without more heating.
-White solid/residue.
-colourless gas collected over water.

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Explanation
On heating wet sand, steam is generated which drives out the air that would otherwise react
with /oxidize the ribbon.
Magnesium burns in steam/water vapour generating enough heat that ensures the reaction
goes to completion even without further heating. White Magnesium oxide is formed and
hydrogen gas is evolved.
To prevent suck back, the delivery tube should be removed from the water before heating is
stopped at the end of the experiment.
Mg(s) + H2O (l) -> MgO(s) + H2 (g)
(iv) Reaction with chlorine gas.
Experiment
Lower slowly burning magnesium ribbon/shavings into a gas jar containing Chlorine gas. Repeat
with a hot piece of calcium metal.
Observation
-Magnesium continues to burn in chlorine with a bright blindening flame.
-Calcium continues to burn for a short time.
-White solid formed.
-Pale green colour of chlorine fades.
Explanation
Magnesium continues to burn in chlorine gas forming white magnesium oxide solid.
Mg(s) + Cl2 (g) -> MgCl2 (s)
Calcium burns slightly in chlorine gas to form white calcium oxide solid. Calcium oxide formed
coat unreacted Calcium stopping further reaction
Ca(s) + Cl2 (g) -> CaCl2 (s)
(v) Reaction with dilute acids.

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Experiment
Place about 4.0cm3 of 0.1M dilute sulphuric (VI) acid into a test tube. Add about 1.0cm length
of magnesium ribbon into the test tube. Cover the mouth of the test tube using a thumb.
Release the gas and test the gas using a burning splint.
Repeat with about 4.0cm3 of 0.1M dilute hydrochloric/nitric (V) acid.
Repeat with 0.1g of Calcium in a beaker with all the above acid
Caution: Keep distance when using calcium
Observation
-Effervescence/fizzing/bubbles with dilute sulphuric (VI) and nitric (V) acids
-Little Effervescence/fizzing/bubbles with calcium and dilute sulphuric (VI) acid.
-Colourless gas produced that extinguishes a burning splint with an explosion/ “pop” sound.
-No gas is produced with Nitric (V) acid.
-Colourless solution is formed.
Explanation
Dilute acids react with alkaline earth metals to form a salt and produce hydrogen gas.
Nitric (V) acid is a strong oxidizing agent. It quickly oxidizes the hydrogen produced to water.
Calcium is very reactive with dilute acids and thus a very small piece of very dilute acid should
be used.
Chemical equations
Mg(s) + H2SO4 (aq) -> MgSO4 (aq) + H2 (g)
Mg(s) + 2HNO3 (aq) -> Mg(NO3)2(aq) + H2 (g)
Mg(s) + 2HCl (aq) -> MgCl2(aq) + H2 (g)

Ca(s) + H2SO4 (aq) -> CaSO4(s) + H2 (g)

(insoluble CaSO4(s) coat/cover Ca(s))

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 Ca(s) + 2HNO3 (aq) -> Ca(NO3)2(aq) + H2 (g)
Ca(s) + 2HCl (aq) -> CaCl2(aq) + H2 (g)

Ba(s) + H2SO4 (aq) -> BaSO4(s) + H2 (g)

(insoluble BaSO4(s) coat/cover Ba(s))
Ba(s) + 2HNO3 (aq) -> Ba(NO3)2(aq) + H2 (g)
Ba(s) + 2HCl (aq) -> BaCl2(aq) + H2 (g)
The table below shows some compounds of some alkaline earth metals

Beryllium Magnesium Calcium Barium

Hydroxide Be(OH)2 Mg(OH)2 Ca(OH)2 Ba(OH)2 Some uses of

Oxide BeO MgO CaO BaO alkaline earth

Sulphide - MgS CaS BaS metals include:

Chloride BeCl2 MgCl2 CaCl2 BaCl2 (i)Magnesium

Carbonate BeCO3 MgCO3 CaCO3 BaCO3 hydroxide is a

Nitrate(V) Be(NO3)2 Mg(NO3)2 Ca(NO3)2 Ba(NO3)2 non-

Sulphate(VI) BeSO4 MgSO4 CaSO4 BaSO toxic/poisonous
4

Sulphate(IV) - - CaSO3 BaSO3 mild base used as

an anti acid
Hydrogen carbonate - Mg(HCO3)2 Ca(HCO3)2 -
medicine to
Hydrogen sulphate(VI) - Mg(HSO4)2 Ca(HSO4)2 -
relieve stomach
acidity.
(ii) Making duralumin. Duralumin is an alloy of Magnesium and aluminium used for making
aeroplane bodies because it is light.
(iii) Making plaster of Paris-Calcium sulphate (VI) is used in hospitals to set a fractures bone.

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(iii)Making cement-Calcium carbonate is mixed with clay and sand then heated to form cement
for construction/building.
(iv)Raise soil pH-Quicklime/calcium oxide is added to acidic soils to neutralize and raise the soil
pH in agricultural farms.
(v) As nitrogenous fertilizer-Calcium nitrate (V) is used as an agricultural fertilizer because
plants require calcium for proper growth.
(vi)In the blast furnace-Limestone is added to the blast furnace to produce more reducing
agent and remove slag in the blast furnace for extraction of Iron.
(c)Group VII elements: Halogens
Group VII elements are called Halogens. They are all non metals. They include:
Element Symbol Atomic Electronicc Charge Valency State at Room
number configuration of ion Temperature
Fluorine F 9 2:7 F- 1 Pale yellow gas
Chlorine Cl 17 2:8:7 Cl- 1 Pale green gas
Bromine Br 35 2:8:18:7 Br- 1 Red liquid
Iodine I 53 2:8:18:18:7 I- 1 Grey Solid
-
Astatine At 85 2:8:18:32:18:7 At 1 Radioactive
All halogen atoms have seven electrons in the outer energy level. They acquire/gain one
electron in the outer energy level to be stable. They therefore are therefore monovalent .They
exist in oxidation state X-
The number of energy levels increases down the group from Fluorine to Astatine. The more
the number of energy levels the bigger/larger the atomic size. e.g.
The atomic size/radius of Chlorine is bigger/larger than that of Fluorine because Chlorine has
more/3 energy levels than Fluorine (2 energy levels).

55
Atomic radius and ionic radius of Halogens increase down the group as the number of energy
levels increases.
The atomic radius of Halogens is smaller than the ionic radius. This is because they react by
gaining/acquiring extra one electron in the outer energy level. The effective nuclear attraction
on the more/extra electrons decreases. The incoming extra electron is also repelled causing the
outer energy level to expand to reduce the repulsion and accommodate more electrons.
Table showing the atomic and ionic radius of four Halogens
Element Symbol Atomic Atomic Ionic radius(nM)
number radius(nM)
Fluorine F 9 0.064 0.136
Chlorine Cl 17 0.099 0.181
Bromine Br 35 0.114 0.195
Iodine I 53 0.133 0.216
The atomic radius of Chlorine is 0.099nM .The ionic radius of Cl- is 0.181nM. This is because
Chlorine atom/molecule reacts by gaining/acquiring extra one electron. The more/extra
electrons/energy level experience less effective nuclear attraction /pull towards the nucleus.
The outer energy level expand/increase to reduce the repulsion of the existing and incoming
gained /acquired electrons.

Electronegativity
The ease of gaining/acquiring extra electrons is called electronegativity. All halogens are
electronegative. Electronegativity decreases as atomic radius increase. This is because the
effective nuclear attraction on outer electrons decreases with increase in atomic radius.
The outer electrons experience less nuclear attraction and thus ease of gaining/acquiring extra
electrons decrease.

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It is measured using Pauling’s scale.
Where Fluorine with Pauling scale 4.0 is the most electronegative element and thus the highest
tendency to acquire/gain extra electron.
Table showing the electronegativity of the halogens
Halogen F Cl Br I At
Electronegativity (Pauling scale) 4.0 3.0 2.8 2.5 2.2
The electronegativity of the halogens decrease down the group from fluorine to Astatine. This
is because atomic radius increases down the group and thus decrease electron – attracting
power down the group from fluorine to astatine.
Fluorine is the most electronegative element in the periodic table because it has the small
atomic radius.
Electron affinity
The minimum amount of energy required to gain/acquire an extra electron by an atom of
element in its gaseous state is called 1st electron affinity. The SI unit of electron affinity is
kilojoules per mole/kJmole-1. Electron affinity depends on atomic radius. The higher the
atomic radius, the less effective the nuclear attraction on outer energy level electrons and thus
the lower the electron affinity. For halogens the 1st electron affinity decrease down the group
as the atomic radius increase and the effective nuclear attraction on outer energy level
electrons decrease. Due to its small size/atomic radius Fluorine shows exceptionally low
electron affinity. This is because a lot of energy is required to overcome the high repulsion of
the existing and incoming electrons.
Table showing the election affinity of halogens for the process
X + e -> X-

Halogen F Cl Br I
Electron affinity kJmole-1 -333 -364 -342 -295

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The higher the electron affinity the more stable theion.i.e
Cl- is a more stable ion than Br- because it has a more negative / exothermic electron affinity
than Br-
Electron affinity is different from:
(i) Ionization energy.
Ionization energy is the energy required to lose/donate an electron in an atom of an element in
its gaseous state while electron affinity is the energy required to gain/acquire extra electron by
an atom of an element in its gaseous state.
(ii) Electronegativity.
-Electron affinity is the energy required to gain an electron in an atom of an element in gaseous
state. It involves the process:
X(g) + e -> X-(g)
Electronegativity is the ease/tendency of gaining/ acquiring electrons by an element during
chemical reactions.
It does not involve use of energy but theoretical arbitrary Pauling’ scale of measurements.
Physical properties
State at room temperature
Fluorine and Chlorine are gases, Bromine is a liquid and Iodine is a solid. Astatine is
radioactive.
All halogens exist as diatomic molecules bonded by strong covalent bond. Each molecule is
joined to the other by weak intermolecular forces/ Van-der-waals forces.
Melting/Boiling point
The strength of intermolecular/Van-der-waals forces of attraction increase with increase in
molecular size/atomic radius.

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Iodine has therefore the largest atomic radius and thus strongest intermolecular forces to
make it a solid.
Iodine sublimes when heated to form (caution: highly toxic/poisonous) purple vapour.
This is because Iodine molecules are held together by weak van-der-waals/intermolecular
forces which require little heat energy to break.
Electrical conductivity
All Halogens are poor conductors of electricity because they have no free delocalized electrons.
Solubility in polar and non-polar solvents
All halogens are soluble in water (polar solvent).
When a boiling tube containing either chlorine gas or bromine vapour is separately inverted in
a beaker containing distilled water and tetrachloromethane (non-polar solvent), the level of
solution in boiling tube rises in both water and tetrachloromethane.
This is because halogen are soluble in both polar and non-polar solvents. Solubility of halogens
in water/polar solvents decrease down the group. Solubility of halogens in non-polar solvent
increases down the group.
The level of water in chlorine is higher than in bromine and the level of tetrachloromethane in
chlorine is lower than in bromine.
Caution: Tetrachloromethane , Bromine vapour and Chlorine gas are all highly toxic/poisonous.
Table showing the physical properties of Halogens
Halogen Formula Electrical Solubility Melting Boiling
of conductivity in water point(oC) point(oC)
molecule
Fluorine F2 Poor Insoluble/soluble in -238 -188
tetrachloromethane

59
 Chlorine Cl2 Poor Insoluble/soluble in -101 -35
tetrachloromethane
Bromine Br2 Poor Insoluble/soluble in 7 59
tetrachloromethane
Iodine I2 Poor Insoluble/soluble in 114 sublimes
tetrachloromethane
Chemical properties
(i)Displacement
Experiment
Place separately in test tubes about 5cm3 of sodium chloride, Sodium bromide and Sodium
iodide solutions.
Add 5 drops of chlorine water to each test tube:
Repeat with 5 drops of bromine water instead of chlorine water
Observation
Using Chlorine water
-Yellow colour of chlorine water fades in all test tubes except with sodium chloride.
-Coloured Solution formed.
Using Bromine water
-Yellow colour of bromine water fades in test tubes containing sodium iodide.
-Coloured Solution formed.
Explanation
The halogens displace each other from their solution. The more electronegative displace the
less electronegative from their solution.
Chlorine is more electronegative than bromine and iodine.
On adding chlorine water, bromine and Iodine are displaced from their solutions by chlorine.

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Bromine is more electronegative than iodide but less 6than chlorine.
On adding Bromine water, iodine is displaced from its solution but not chlorine.
Table showing the displacement of the halogens
(V) means there is displacement (x ) means there is no displacement
F- Cl- Br- I-
Halogen ion in

solution
Halogen
F2 X
Cl2 X X
Br2 X X X
I2 X X X X

Chemical /ionic equations

With Fluorine
F2(g) + 2NaCl-(aq) -> 2NaF(aq) + Cl2(aq)
F2(g) + 2Cl-(aq) -> 2F-(aq) + Cl2(aq)
F2(g) + 2NaBr-(aq) -> 2NaF(aq) + Br2(aq)
F2(g) + 2Br-(aq) -> 2F-(aq) + Br2(aq)
F2(g) + 2NaI-(aq) -> 2NaF(aq) + I2(aq)
F2(g) + 2I-(aq) -> 2F-(aq) + I2(aq)
With chlorine
Cl2(g) + 2NaCl-(aq) -> 2NaCl(aq) + Br2(aq)
Cl2(g) + 2Br-(aq) -> 2Cl-(aq) + Br2(aq)

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Cl2(g) + 2NaI-(aq) -> 2NaCl(aq) + I2(aq)
Cl2(g) + 2I-(aq) -> 2Cl-(aq) + I2(aq)
With Bromine
Br2(g) + 2NaI-(aq) -> 2NaBr(aq) + I2(aq)
Br2(g) + 2I-(aq) -> 2Br-(aq) + I2(aq)
Uses of halogens
(i) Florine – manufacture of P.T.F.E (Poly tetra fluoroethene) synthetic fiber.
- Reduce tooth decay when added in small amounts/quantities in tooth paste.
NB –large small quantities of fluorine /fluoride ions in water cause browning of
teeth/flourosis.
- Hydrogen fluoride is used to engrave words /pictures in glass.
(ii) Bromine - Silver bromide is used to make light sensitive photographic paper/films.

(iii) Iodide – Iodine dissolved in alcohol is used as medicine to kill bacteria in skin cuts. It is
called tincture of iodine.
The table below to show some compounds of halogens

H Na Mg Al Si C P
Element
Halogen (i) Below is the table
F HF NaF MgH2 AlF3 SiF4 CF4 PF3 showing the bond energy
Cl HCl NaCl MgCl AlCl3 SiCl3 CCl4 PCl3 of four halogens.
Br HBr NaBr MgBr2 AlBr3 SiBr4 CBr4 PBr3 Bond Bond
-1
I Hl Nal Mgl2 All3 SiI4 Cl2 PBr3 energy k J mole

62
 Cl-Cl 242
Br-Br 193
I-I 151
I. What do you understand by the term “bond energy”
Bond energy is the energy required to break/ form one mole of chemical bond
II. Explain the trend in bond Energy of the halogens above:
-Decrease down the group from chlorine to Iodine
-Atomic radius increase down the group decreasing the energy required to break the
covalent bonds between the larger atom with reduced effective nuclear @ charge an
outer energy level that take part in bonding.
(c)Group VIII elements: Noble gases
Group VIII elements are called Noble gases. They are all non metals. Noble gases occupy about
1.0% of the atmosphere as colourless gaseous mixture. Argon is the most abundant with 0.9%.
They exist as monatomic molecules with very weak van-der-waals /intermolecular forces
holding the molecules.
They include:
Element Symbol Atomic Electron structure State at room
number temperature
Helium He 2 2: Colourless gas
Neon Ne 10 2:8 Colourless gas
Argon Ar 18 2:8:8 Colourless gas
Krypton Kr 36 2:8:18:8 Colourless gas
Xenon Xe 54 2:8:18:18:8 Colourless gas
Radon Rn 86 2:8:18:32:18:8 Radioctive

63
All noble gas atoms have a stable duplet(two electrons in the 1st energy level) or octet(eight
electrons in other outer energy level)in the outer energy level. They therefore do not
acquire/gain extra electron in the outer energy level or donate/lose. They therefore are
therefore zerovalent .
The number of energy levels increases down the group from Helium to Randon. The more the
number of energy levels the bigger/larger the atomic size/radius. e.g.
The atomic size/radius of Argon is bigger/larger than that of Neon because Argon has more/3
energy levels than Neon (2 energy levels).
Atomic radius noble gases increase down the group as the number of energy levels increases.
The effective nuclear attraction on the outer electrons thus decrease down the group.
The noble gases are generally unreactive because the outer energy level has the stable
octet/duplet. The stable octet/duplet in noble gas atoms lead to comparatively very high 1st
ionization energy. This is because losing /donating an electron from the stable atom require a
lot of energy to lose/donate and make it unstable.
As atomic radius increase down the group and the 1st ionization energy decrease, very
electronegative elements like Oxygen and Fluorine are able to react and bond with lower
members of the noble gases.e.g
Xenon reacts with Fluorine to form a covalent compound XeF6.This is because the outer
electrons/energy level if Xenon is far from the nucleus and thus experience less effective
nuclear attraction.
Noble gases have low melting and boiling points. This is because they exist as monatomic
molecules joined by very weak intermolecular/van-der-waals forces that require very little
energy to weaken and form liquid and break to form a gas.

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The intermolecular/van-der-waals forces increase down the group as the atomic radius/size
increase from Helium to Radon. The melting and boiling points thus increase also down the
group.
Noble gases are insoluble in water and are poor conductors of electricity.
Element Formula Electrical Solubility Atomic 1st Melting Boiling
of conductivity in water radius(nM) ionization point(0C) point(0C)
molecule energy
Helium He Poor Insoluble 0.128 2372 -270 -269
Neon Ne Poor Insoluble 0.160 2080 -249 -246
Argon Ar Poor Insoluble 0.192 1520 -189 -186
Krypton Kr Poor Insoluble 0.197 1350 -157 -152
Xenon Xe Poor Insoluble 0.217 1170 -112 -108
Radon Rn Poor Insoluble 0.221 1134 -104 -93
Uses of noble gases
Argon is used in light bulbs to provide an inert environment to prevent oxidation of the bulb
filament
Argon is used in arch welding as an insulator.
Neon is used in street and advertisement light
Helium is mixed with Oxygen during deep sea diving and mountaineering.
Helium is used in weather balloon for meteorological research instead of Hydrogen because it
is unreactive/inert.Hydrogen when impure can ignite with an explosion.
Helium is used in making thermometers for measuring very low temperatures.

CaO (s) + H2O(l) -> Ca(OH)2(aq)

65