Time Allowed: 2 Hours Maximum Marks: 80

General Instructions: As given in Practice Paper-1

SECTION- A
(Attempt all questions from this Section)

1. Choose the correct answers to the questions from the given options. [15]
() In refining of Aluminium by Hoope's process, which of the following is/are correct?
P. Pure molten aluminium acts as cathode
Q. Pure molten aluminium acts as anode
R. Impure molten Al acts as anode
S. Molten fluorides of Na, Ba and Al act as electrolytes.
(a) P Q, R (b) P,R, S
(c) Q, R, S (d) P and R only
(i) A compound X, when heated with Ca(0H), forms a gas Y' which turns red litmus blue and
phenolphthalein pink, X and Y respectively are
(a) NaCI, HCI (6) NH,CI, NH,
(c) (NH),SO,S0, () KNO, H,SO,
(iti) The atomic mass of oxygen is 16u. Which of the following statements is correct?
P 1g0, and 1 g ofO, contain equal number of molecules.
Q. 1mole of O, and1 mole of O, both have volume 22.4 L at STP.
(a) Only P (6) Only Q
(c) Both P and Q (d) Neither P nor Q

(iv) HCI (g) is passed through following two solutions, which of the following observation is correct
Blue litmus solution lead nitrate solution
X Blue Blue ppt.
Y Red White ppt.
Blue No reaction

M Red Green ppt.

 (b) Y
(d) M
correct diagram for electrorefining of copper?
followingis
ofthe
f (b)
Whlch
Cathode +Anode
eAnode -Acidified
( a )Cathode-y LAcidified |bCu CuSO,
bCu CuSO, Cu' Soution
Soution
Cute Impurities
Impurities
(d) eAnode
Cathode
Anode -Acidified
Cathode Acidified CuSo,
CuSO, CUZ Solution
Cul& Solution
-Impuritie s
-Impurities
maximumn ionization potential is:
having
v) Element (6) Ne (c) Ca (d) He
(a)Na
acid which has two replaceable hydrogen ions:
(i)An (6) Hydrochloric acid
(a) Acetic acid
(c) Phosphoric acid (d) Carbonic acid
and volume of nitric oxide formed when 100 ml of ammonia is catalytically
Thevolumeof oxygen required I equation
oxidized according to the balanced chemical
4NH, + 50,’ 4NO + 6H,0 is
(a) 125 ml of 0, and NO (b) 100 ml of 0, and NO
(c) 125 ml of 0, and 100 ml of NO (d) 100 ml of 0, and 125 ml of NO
(ün) The sulphuric acid anhydride is:
(a) Ammonia (b) Nitrogen dioxide gas
(c) Sulphur trioxide gas (d) Sulphur dioxide gas
() The IUPAC name of formic acid:
(a) Propanoic acid (b) Methanoic acid c) Ethanoic acid (d) Butanoic acid
3) The gas liberated at anode during the electrolysis of molten NaCl is:
(a) H, (b) O, (c) CI, (d) Na vapours
(ii) An alkaline earth metal found in
period 3 and group 2:
(a) Magnesium (b) Lithium (d) Calcium
(c) Sodium
(ai) Sulphurreacts with conc. HNO, to give
(a) HSO, (b) NO, (c) H,0 (d) all of these
(i) Which of the following will give white precipitate with BaCi, (aq)?
(a) HSO,
w) AgC] is (b) HNO, (c) HCI (a) CH,CO0H
(a) Watersolmble excess 01
in
(6) NH,g) (c) HCI (d) NH,OH
(b) 32 gof (ii) (b) 2NH,CI + Ca(OH), ’ CaCl, + H,0 + NH,
O, Contains 2 X 6.022 x 10 atoms
lgof O, contains= 2x6.022x1023 60.22
x 10 = 3.76 x 10 atoms
32
48 g of 16
O, contains 3 X 6.022 x 1023 atoms
 3x6.022 x 1023
1g of O, contains = = 3.76 X 10 atoms
48
Both contain equal number of atoms but not equal number of molecules
1mole of every gas at STP occupies volume equal to 22.4 L.
(v) (6) HCI (g) turns blue litmus solution red. Pb(NO,),(aq) + 2HCI(e) ’ PbCI,(9) + 2HNO,
() (c) (vi) (d) (vii) (d) (vii) (c)
(ir) (c) () (b) (xi) (c) (xi) (a)
(riii) (d) S+ 6HNO, (conc.) ’ H,SO, + 6NO, + 2H,0
(xiv) (a) BaCl,(aq) + H,SO, ’ BaSO,(s) + 2HCI(aq)
(v) (a) AgCl + 2NH,OH ’ [Ag(NH,),j*cr + 2H,0
2. () The set up shown below is that of fountain experiment by NH, gas in the flask. The fountain starts
when few drops from dropper are introduced into the flask (5]

Ammonia

Blue fountain

-Dropper containing water

Jet tube

-Blue litmus
solution

(a) Which two properties of ammonia can be proved by the fountain experiment?
(6) What will be colour of the fountain?
(c) What will be the colour of fountain if phenolphthalein is used instead of red litmus solution.
Given reason.
(i) Match the following Column A with Column B. [5]
Column A Column B
(a) Fe(0H), (i) Yellow ppt
(b) Fe(0H), (üü) Green ppt
(c) Al(OH), (üi) Reddish brown ppt
(d) Cu(0H), (iv) Gelatenious white ppt
(e) Pbl, () Blue precipitate
(5]
(üüi) Complete the following by choosing correct answers from the brackets:
(a) NaOH is (strong/weak) base
(6) NH,Cl is (Acidic/Basic) salt
(c) Tin is purified by (Liquation/Electrorefining)
(d) Process of coating zinc over iron (Anodising/Galvanisation)
(e) Tomato contains (Oxalic acid/Tartaric acid)
 thefollowing: which
ldentify by the compounds have same molecular
) Theproperty formula hut different structural
(a)formula.
proCess the enrichment of sulphide ore.
usedfor
The required to remove an electron
from the valence shell of a
The energy neutral isolated gaseous
i) atom.
name of the process by
which the Bauxite ore is concentrated.
The
Thebond formed by a shared pair of electrons with both electrons coming from the same atom.
d)
(e) diagram for the following compounds:
Drawthe strructural
r) (a) 2. 1, 2-dichloro propane
1. 2-Propanol 3. But-2-yne.
Namethe following organic compounds in
IUPAC system:
(6) H H
H H H

2. H-C=CC-H

H H H H H
in water.
) (a) 1. NH, is highly soluble
2. NH, is alkaline in nature.
(b) Blue colour fountain will be produced.
(c) The colour of fountain will be pink if phenolphthalein is used.
It is because NH,OH is basic in nature.
() (a) () (b) (üi) (c) (iv) (d) (v) (e) ()
() (a) Strong (b) Acidic (c) Liquation (d) Galvanisation(e) Oxalic acid
(iv) (a) Isomerism
(b) Froath floatation process
(c) Ionization potential
(d) Baeyer's process
(e) Co-ordinate bond
(0) (a) 1. CH, ÇHCH, 2. CH, ÇH-CHCI 3. CH, C=C CH,
OH CI
(b) 1. 1-Butanol 2. Propyne

SECTION -B
(Attempt any four questions)
3 () Give the equation for the preparation of each of the following salts from the starting material given.
[2)

(a) Copper
C sulphate from copper(I) oxide.
0) Iron(I)
(i) Write chloride from Iron. [21
the balance the equations:
(a) S +
conc.
(6) ZnS + HINO3
HCI
 (m) (a) How many elements are present in 3rd period?
(b) Arrange the elements of 2nd period in the increasing order of their atomic size
(c) How does ionization potential differ in group and period?
(iv) (a) state whether the followingstatement are TRUE or FALSE. Justify your answer. [3)
1. Sodium chloride is an ionic compound.
2. Carbon tetrachloride is a covalent compound.
(6) Why is ammonia soluble in water?
Ans. () (a) CuO + H,SO, ’ CuSO, + H,0
(b) 2Fe + 3Cl, ’ 2FeCl,
(ü) (a) S + 6HNO, ’ H,SO, + 6NO, + 2H,0
(b) ZnS + 2HCI ZnCl, + H,S
(üi) (a) Eight elements are present in 3rd period.
(b) Fluorine, Oxygen, Nitrogen, Carbon, Boron, Beryllium, lithium
(c) Group: As we move down the group, ionization potential decreases.
Period: As we move across the period, ionization potential increases.
(iv) (a) 1. True; Sodium chloride because it is formed by transfer of electrons.
2. True; Carbon tetrachloride because it is formed by sharing of electrons.
(b) Ammonia has polar covalent bonding and forms ions in aqueous solution.
4. () Fillin the blanks: (2]
NaOH H,0 B
Al,0,
(ü) The equation 4NH, + 50, ’ 4NO t 6H,0, represents the catalytic oxidation of ammonia. II 100
cm of ammonia is used, calculate the volumeof oxygen required to oxidise the ammonia completely.
[2]
(it) The following questions are pertaining to the laboratory preparation of Hydrogen chloride gas 31
(a) Write abalanced chemical equation for its preparation mentioning the condition required.
(6) Why is concentrated Nitric Acid not used in the preparation of Hydrogen Chloride gas?
(c) How is Hydrogen Chloride gas collected?
(iv) Write balanced chemical equations for the following: [3)
(a) Potassium nitrate reacts with conc. H,SO,
(b) Nitric acid is heated.
(c) Copper reacts with conc. HNO,
Ans. () A:NaAlO,
B:Al(OH),
(i) 4NH, + 50, 4NO + 6H,0
4 volume of NH, requires 5 volume of O,
100 x 5
:. 100 cm' of NH, requires = = 125 cm of O,
4
below
(ii) (a) NaCl + H,SO,(conc.) 200°C NaHS0, + HCI
(b) As it is a very strong oxidizing agent, it will oxidise HCI into chlorine.
(c) Upward displacement air because it is heavier than air.
 below

H,SO, (conc.) 200°C KHSO, + HNO,.

(a)
KNO, +
A 4NO, + 2H,0+ 0,
a)
(b) 4HNO0,

4HNO, (conc.) ’ Cu(NO,), + 2H,0 + 2NO,:

Cu +
Ammonia demonstrated in the Fountain Experiment.
propertyof [21
State one
(D (a) equation when Ammonium Hydroxide is dissolved in water.
(6) Givetheionic
colour of the following: [2]
Statethe
(a) Zn(0H), (6) Fe(OH),
structural formula of: [3]
Drawthe
(i)
(a) Ethanal (b) 2-Propanol (c) 2-Methyl propane
one relevant observation for each of the following reactions: [3]
li) State
When excess Ammonia is passed through an aqueous solution of Lead Nitrate.

(h) Copper Sulphate solution is electrolysed using Copper electrodes.

(c) Ammonium hydroxide is
added to Ferrous Sulphate solution.
() (a) Extreme solubility of ammonia gas in water.
(b) NH,OH NH, + OH
(ü) (a) white (b) dirty green
H O H H H

(ü) (a) H- -Þ-H (b) H- ((-H

H H

H ÇH, H
(c) H-c
H
H H

") (a) White precipitate appears which is insoluble in excess of ammonium hydroxide.
(b) Size of cathode
increases.
Size of anode
decreases.
Colour of the electrolyte remains same i.e., blue.
6.
(c) Dirty green ppt appears which is insoluble in excess of NH,OH.
(i) Find the total percentage of oxygen in Magnesium nitrate Mg(NO),.6H,0 crystals. [2]
H= 1, N= 14. O = 16, Mg =
24]
Oxygen oxidises ethyne to carbon dioxide and water as shown by the equation: [2]
2C,H, + 50,’ 4C0, + 2H,0
What volume of ethyne gas at S.T.P. is required to produce 8.4 dm of carbon dioxide at S.T.P.?
(i) H=1,C=
State the
12,0= 16] [3]
following:
(a) ACompounds is obtained when ammonia mixes with hydrogen chloride gas.
(b) Acolourless
(c) AlWloy liquid formed when H,S gas is passed through lead acetate solution.
used for making bodies of aircraft.
 (iv) Choose the role played by concentrated Sulphuric acid which is responsible for the reactions 1to 3
of
A. Oxidizing agent (3|
B. Non-Volatile Acid
C. Dehydrating agent
<200°C
1. NaNO, + H,S0, ’ NaHSO, + HNO, It acts as

2. CuSO,.5H,0 H,SO, CuSO, + 5H,0, It acts as agent.

3. S + 2H,SO, ’3S0, + 2H,0, It acts as agent.

Ans. ) Mg(NO,),.6H,OMolecular weight = 24 + 28 + 96 + 108 = 256 g/mol

Mol. weight = 256 g/mol
192
Percentage of oxygen = x 100 = 75% of Oxygen
256

(ü) 4 volume of CO, is produced by 2 volume of C,H,.

.:. 1volume of CO, will be produced by 24 volume of C,H,.
. 8.4 dm' is produced by 2 x 8.4 = 4.2 dm
4

(iü) (a) Ammonium chloride

(b) Acetic acid
(c) Duralumin
(iv) 1. Non-volatile and
2. Dehydrating agent
3. Oxidising agent
7. () (a) If the molecular formula of the compound is C,H, and its empirical formula is CH,, then what is
the value n? (3]
(b) If the molecular formula of the compound is CH and the empirical formula is CH, what is the
value of n?

(c) Write the structural formula of CH,

(iü) Identify the functional group in the following organic compounds: [3]
(a) HCHO
(6) C,H,COOH
(c) CH,CO0CH,
(iüi) (a) Name the ion which must be present in the electrolyte in electroplating of copper spoon with
silver. [4]
(6) Choose from the list and answer the questions that follow:
NaOH, KOH, CuCO,, Ca
() An element which combines directly with Nitrogen on heating.
(iü) A green coloured compound which on heating changes to black.
(iiü) Solution which readily absorbs CO,.
 H

H
(b) cartmti ad
(c) Estet
(7) Cuc0,
bonding present in: () KOH
Mealli hkride
A Nu-sllà chkride
Barium hloridee
solutioa help in
distinguishing between Zinc nitrate and Zinc salphate
A Nate hat do y oene when Ammonium
Nrtk and then in exes hydruride is added to Copper salphate 21
g te prduts
Rrmed at
cathode and at anode during the sotatioa. first
Melten lead bromide
electrolysis ofthe following with inert
(b)
eknt N has atomic
Acidulated water (c) Dilute HCI
number 17. Answer the following
Stste the period and group to which it belongs. questioas 31
) Isita Mletal or Non-Metal?
Write the formula between X and
Hydrogen.
.à loni (electrovalent) bond
() Covalent bond
a ) Barium choride
soluton on rICtion with Zinc nitrate, give o
be rton
BaCl, + Zn(NO), ’ Ba(NO, t ZnCl,
Oa the ontrary. Barium
chloride solution, on
wih is insoluble in all the mineral acids reaction with Zinc sulphate. gives awhite
preipitate
BaC1, + ZnSO, BaSO, + ZnCl,
(b) On adding Ammonium (White ppt.)
hydroide to Copper sulphate solution irst a little. a bluish white
isfomed which dissolves in exces of Ammonium
hydroide to givea deep blue stution. prcipitate
Cathode Anode
(e) Lead
(b) Hydrogen Bromine vapours
Oxygen
(c) Hydrogen
Oxygen
) (a)
Period-3.
(b) Non-metal. Group-17.
(c) HX.