Carnot engine
Carnot engine
Carnot Cycle
The Carnot engine is a theoretical
thermodynamic cycle proposed by Leonard Carnot. It
estimates the maximum possible efficiency that a heat
engine during the conversion process of heat into work and,
conversely, working between two reservoirs can possess.
Process in Carnot cycle:
1. Isothermal Expansion (Process 1-2)
Type of Process: Isothermal (constant temperature)
Description:
The working substance absorbs heat QHQ_HQH from a
high-temperature reservoir at temperature THT_HTH.
During this process, the gas expands and does work
on the piston. Since the temperature remains
constant, the internal energy of the gas does not
change, and the heat absorbed by the gas is entirely
converted into work.
2. Adiabatic Expansion (Process 2-3)
Type of Process: Adiabatic (no heat exchange)
Description:
In this phase, the gas continues to expand, but without
any heat exchange with the surroundings. As the gas
expands, it does work on the piston, and its
temperature and pressure decrease. The internal
energy of the gas decreases because no heat is
added, and the energy is used to do work.
3. Isothermal Compression (Process 3-4)
Type of Process: Isothermal (constant temperature)
Description:
The gas is now in contact with a cold reservoir at
temperature TCT_CTC. During this process, the gas is
compressed, and heat QCQ_CQC is expelled to the
cold reservoir. The temperature remains constant at
TCT_CTC, and the work done on the gas equals the
heat rejected to the cold reservoir.
4. Adiabatic Compression (Process 4-1)
Type of Process: Adiabatic (no heat exchange)
Description:
The gas is compressed further without any heat
exchange. As a result, its temperature and pressure
rise. The work done on the gas increases its internal
energy, and the temperature increases from TCT_CTC
to THT_HTH.
nV3V4
12. Step 4→1 : Work done on the environment,
13. W4→1=μR(T1−T2)γ−1W4→1=μR(T1−T2)γ
−1
14. The total work done by the gas,
15. W=W1→2+W2→3−W3→4−W4→1W=W1→
2+W2→3−W3→4−W4→1
16. =μRT1ln(V2V1)−μRT2(V3V4)=μRT1ln
(V2V
1)−μRT2(V3V4)
17. The efficiency of a Carnot engine is given
by,
18. η=WQ1=1−Q2Q1η=WQ1=1−Q2Q1
19. =(1−T2T1)ln(V3V4)ln(V2V1)=(1−T2T1)ln
(
V3V4)ln(V2V1)
20. Step 2→3 is an adiabatic process,
21. T1V γ−12=T2V γ−13T1V2 γ−1=T2V3 γ−1
22. V2V3=T2T1(1γ−1)V2V3=T2T1(1γ−1) –
equation (1)
23. Similarly, step 4→1 is an adiabatic
process,
24. T2V γ−14=T1V γ−11T2V4 γ−1=T1V1 γ−1
25. V1V4=(T2T1)1γ−1V1V4=(T2T1)1γ−1-
equation (2)
26. Hence from equation (1) and (2) we get,
27. V2V3=V1V4V2V3=V1V4.