4: Carbon and Its Compounds
4: Carbon and Its Compounds
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attain electron configuration of noble gas helium. The shared pair of electron constitute
a single covalent bond between the 2 hydrogen atoms
ii.Oxygen molecule
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v.Sulphur molecule
Allotropes – They are different forms of the same element having different physical
properties , but almost similar chemical properties.
Allotropes Of carbon - The two common allotropic forms of carbon are graphite
and diamond .
Others are fullerenes (ball like structures). Eg: C32, C60, C70, C240 etc..
C60 Fullerenes (Buckminster fullerene) is more stable
6.Differentiate between graphite and diamond
Graphite Diamond
a.Each carbon atom is joined to 3 other a.Each carbon atom is joined to 4 other carbon
carbon atom. atoms
b.The carbon atoms form flat hexagonal b.The carbon atoms together form three
layers. dimensional structure
c.Greyish black and opaque substance. c.Lustrous and transparent.
d.It is soft and lighter than diamond. d.It is the hardest substance.
e.It conduct electricity because of free e.It cannot conduct electricity
electrons f.It is used for making jewellery because of its
f.It is used as a lubricant because its lustrous nature.
slippery nature
Versatile Nature Of Carbon
7.Carbon can form large number of compounds .Give reasons.
a.Catenation – Carbon has the unique ability to form bonds with other atoms of carbon
,giving rise to large molecules .This property is called catenation.These compounds may
have long chains of carbon ,branched chains or even carbon atoms arranged in rings.
b.Tetravalency – Carbon has a valency of 4 .It is capable of bonding with 4 other atoms
of carbon or atoms of some other mono-valent element .Compounds of carbon are
formed with oxygen,hydrogen,nitrogen,sulphur and many other elements giving rise to
compounds with specific properties which depend on the elements other than carbon
present in the molecule.
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c.Multiple bonds – Due to small size ,carbon can easily form double or triple bonds by
sharing more than one electrons . As a result it can form variety of compounds.
8.HYDROCARBONS
Hydrocarbons: Compounds of carbon and hydrogen are known as hydrocarbons.
For example; Methane (CH4), Ethane (C2H6), Ethene (C2H4), Ethyne (C2H2) etc.
Classification Of Hydrocarbons
Hydrocarbons
Alkynes
Hydrocarbons with at least one carbon-carbon triple bond are called alkynes. General
formula = CnH2n−2 where n = 2,3,4…..where
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n = number of carbon atoms.
Refer note book for electron dot structures of the above hydrocarbon
10.CYCLIC HYDROCARBONS
cyclopropane
Cyclobutane
Cyclopentane
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Cyclohexane
Unsaturated cyclic hydrocarbon
Benzene is the simplest organic, aromatic hydrocarbon.
or
Cyclic in nature with chemical formula, C6H6, i.e., each carbon atom in benzene is
arranged in a six-membered ring and is bonded to only one hydrogen atom.It includes 3-
double bonds which are separated by a single bond(alternating double and single bond).
Physical properties: colourless liquid, pungent odour, flammable & volatile.
12.ISOMERISM
Isomerism is the phenomenon in which more than one compounds have the same chemical
formula but different chemical structures. Chemical compounds that have identical chemical
formulae but differ in properties and the arrangement of atoms in the molecule are called
isomers.
Structural Isomers
Compounds with identical molecular formula but different structures are called
structural isomers and the phenomenon is known as structural isomerism.
Isomers of butane
Isomers of pentane
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Isomers of hexane
HOMOLOGOUS SERIES
13.What are homologous series? Give examples.
Homologous series is a group of organic compounds having similar structure,same
functional group,similar chemical properties and the successive members differ by a CH 2
group .
Eg: The homologous of methane are ethane, propane and butane.
The homologous of Alkene
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The homologous of Alcohol
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18. Functional Group And Heteroatom
Functional group can be defined as an atom or a group of atoms that
determines the properties of organic compounds.
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Naming a carbon compound can be done by the following method
1. Identify the number of carbon atoms in the compound.
2. Functional group is indicated either by prefix or suffix.
3. If the name of the functional group is to be given as a suffix, and the suffix of the
functional group begins with a vowel a, e, i, o, u, then the name of the carbon chain is
modified by deleting the final ‘e’ and adding the appropriate suffix. For example, a
three-carbon chain with a ketone group would be named in the following manner –
Propane – ‘e’ = propan + ‘one’ = propanone.
4. If the carbon chain is unsaturated,then the final ‘ane’ in the name of the carbon chain
is substituted by ‘ene’ or ‘yne
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Refer Note Book For Electron Dot Structures 0f Hydrocarbon With Functional
Group
Oxidation Reaction
25. a)What is meant by oxidation reaction? What would be
observed on adding a 5% solution of KMnO4 in NaOH solution or
alk.KMnO4 solution drop by drop to some warm Ethanol taken in a
test tube? Write the name of the compound and equation.
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b)Why is the conversion of ethanol to ethanoic acid is an oxidation
reaction?
a)When we are adding a 5% solution of KMnO4 in a NaOH solution to warm Ethanol
drop wise the purple colour of KMnO4 disappears .When excess of alk.KMnO4 of added
the purple colour of KMnO4 persists because of complete oxidation of Ethanol. (In
acidified K2Cr2O7 orange colour changes to green)
Addition Reaction
26. What is meant by addition reaction?
The reaction in which an unsaturated Hydrocarbon combines with other substance like
Hydrogen in the presence of catalyst such as platinum, palladium, nickel, or rhodium to
give the saturated hydrocarbon is called addition reaction. It is a characteristic
property of unsaturated hydrocarbons.
Catalyst: They are substances that change the rate of reaction without themselves
undergoing any change. OR Substances that cause a reaction to occur or proceeds to
different rate without consuming in it are called a catalyst. For example; Ni, Pt, Pd, etc.
27.Explain the process of Hydrogenation? What is meant by
Hydrogenation? What is its industrial applications?
The addition of Hydrogen to an unsaturated compound to obtain a saturated compound
is called Hydrogenation. The process of Hydrogenation takes place in the presence of
Nickel catalyst.
Its important industrial application is to prepare vegetable ghee (Vanaspati) from
vegetable oil. Vegetable oils are unsaturated fats having double bonds between some of
their Carbon atoms. When vegetable oil is heated with hydrogen in the presence of
catalyst like Ni , it is changed into saturated fat called vegetable ghee.
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(Veg.Oil liquid Unsaturated) (Veg.Ghee Solid Saturated)
28.Which of the following Hydrocarbons undergo addition
reactions? C2H6, C2H8, C3H6, C2H2, CH4 Why?
C3H6, C2H2 undergo addition reaction because they are unsaturated.
substitution reaction
29.What is meant by substitution reaction? Write the chemical
equation for reaction of Methane with chlorine.
The reaction in which one or more Hydrogen atom are replaced by some other atoms
like Chlorine. OR Replacement of one or more hydrogen atom of an organic molecule by
another atom or group of the atom is known as Substitution Reaction. . It is a
characteristic property of saturated Hydrocarbons.
Methane reacts with Chlorine in the presence of sunlight forming Chloromethane and
Hydrogen Chloride.
Ethanol
(CH3CH2—OH): Commonly known as Ethyl Alcohol.
Physical properties of Ethanol
1.Colourless inflammable liquid with a pleasant smell.
2.Boiling point is 351K & Melting point is 156K.
3.It is miscible with water in all proportions.
4.It has no effect on litmus solution.
Chemical Properties
a)Combustion
30. Why is Ethanol used is a fuel?
Ethanol burns with a clear blue flame giving a lot of heat. It gives only harmless
products like CO2 & H2O
CH3CH2OH + 3O2 ------>2CO2 + 3H2O +Heat and light (exothermic)
b)Oxidation reaction
+ H2O
Refer Question No 25
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c)Reaction with sodium
31.Name the products obtained when Ethanol reacts with Sodium
metal. Write the Chemical reaction.
Hydrogen gas and Sodium Ethoxide are formed.
Ethanoic acid
Ethanoic Acid (CH3COOH): Commonly known as acetic acid and belongs to a group of
organic acids called carboxylic acid. The functional group present in it is – COOH.
Phyisical properties of Ethanoic acid.
a) Colourless, corrosive liquid and it has a sour taste.
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b) Pungent smell like vinegar.
c) Mixes with water in all proportions.
d) Melting Point 290K, Boiling point 391 K.
e) Turns blue litmus to red.
37.What is Vinegar?
5-8% dilute solution of acetic acid in water is called Vinegar.
38.Why is pure Ethanoic acid is known as glacial acetic acid?
Ethanoic acid is commonly known as acetic acid. The melting point of pure Ethanoic acid
is 290K. So it often freezes during winter in cold climates and appears like glaciers. So
pure Ethanoic acid is also known as glacial acetic acid.
39. Mineral acids are strong whereas Carboxylic acid Or Ethanoic
acids are weak . Why?
Mineral acids are completely ionized whereas carboxylic acids are only partially ionized.
So the hydrogen ion concentration of mineral acids are comparatively more than
carboxylic acids.
Chemical Properties
a)Esterification reaction
40. What is meant by Esterification reaction? Explain with a
reaction?
Ethanoic acid reacts with Ethanol in the presence of concentrated Sulphuric acid (acid
catalyst) to form a pleasant smelling substance called Ester. This reaction is known as
Esterification reaction.
Ester
41. What is an ester?How to prepare an ester ? Explain it with the
help of an activity and diagram.
⚫ An ester is an organic compound where the hydrogen in the compounds carboxylic
acid group is replaced with a hydrocarbon group.
⚫ It is a sweet-smelling substance.
⚫ Functional group of Ester is R-COO-R’ where R and R’ represents alkyl groups.
⚫ Esters are used in making perfumes and as flavouring agents.
Take 1 ml ethanol (absolute alcohol) and 1 ml glacial acetic acid along with a few drops
of concentrated sulphuric acid in a test tube. Warm in a water-bath for at least five
minutes as shown in Fig. Pour into a beaker containing 20-50 ml of water and smell the
resulting mixture. A colourless liquid with fruity smell is obtained.
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42.What is saponification reaction? Explain with an equation.
Esters react in the presence of a base to give back the alcohol and carboxylic acid
or sodium salt of carboxylic acid . This reaction is known as Saponification reaction
because it is used in the preparation of Soaps.
USES
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a) It is used as a solvent in in the production of camphor.
b) It is used in the manufacture of Plastics and Silk industries.
c) It is used in the manufacture of Dyes, Perfumes and Rayons.
d) It is used as a preservative in pickles.
e) It commonly serves as a chemical reagent in laboratories.
Chemical properties
1.Does not react with NaHCO3 1.CO2 is evolved on reacting with
NaHCO3
2.It does not react with a base or 2.It reacts with base or alkali forming salt
alkali. and water.
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47.Draw a neat labelled diagram.
A) Soap molecule.
B) Formation of Micelles.
(1) (2)
C)Cleansing action of Soap.
For cleansing action of soap -refer Pg. no 75 orange colour para fig:4.13 and fig (1) and
(2).
48.Explain the mechanism of cleansing action of Soap.
A soap molecule is made of two parts- a long Hydrocarbon part and a short ionic part.
The hydrocarbon part of soap molecule is insoluble in water (Hydrophobic) but soluble
in oil and grease. The ionic part of the soap molecule is soluble in water (Hydrophilic)
but is insoluble, in oil and grease. When soap is dissolved in water, the soap molecules
cluster together to form micelles. In a soap micelle, the molecules are arranged radially
with Hydrocarbon ends directed at the center and ionic ends directed outwards.
When dirty cloth is put in the soap solution, then the Hydrocarbon ends of the soap
micelle entraps the oily or grease particle by which the dirt is formed. The ionic end of
the soap molecule remains attached to water. Thus the cloth gets cleaned.
49. Why is soap solution Colloidal?
When soap is dissolved in water, soap molecule cluster together to form micelles. These
micelles are large enough to scatter light. So the solution is colloidal.
50. Why is soap not suitable for washing clothes in hard water?
How can we overcome this problem? OR Explain the formation of
scum when hard water is treated with soaps.
Hard water contains both Calcium and Magnesium salts dissolved in it. When soap is
used for washing clothes with hard water a large amount of soap is wasted in reacting
with the calcium and Magnesium ions to form an insoluble precipitates called scum. This
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problem is overcome by using detergents. Detergents are generally Ammonium or
sulphonate salts of long chain Carboxylic acids which does not form insoluble
precipitates with Calcium and Magnesium ions.
R R R R
\ / l l
C = C + Br2 --------------------> Br— C--- C--- Br
/ \ l l
R R R R
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55.Distinguish between unsaturated and saturated Hydrocarbons.
Unsaturated Hydrocarbons Saturated Hydrocarbons
1 Decolourise Bromine water Do not decolourise Bromine
(Brown) water
2 Decolourise alk-KMnO4 Do not decolourise alk.KMnO4
(Purple)
3 Burn with yellow (sooty) Burn with Blue (non sooty)
flame flame
56.Would you be able to check if water is hard by using a
detergent?
No, we cannot because detergents form lather easily with hard water also, as they do
not form insoluble precipitate with Calcium and Magnesium ions in hard water.
57.People use a variety of methods to wash clothes. Usually after
adding the soap, they ‘beat’ the clothes on a stone, or beat it with
a paddle, scrub with a brush or the mixture is agitated in a
washing machine. Why is agitation necessary to get clean clothes?
Agitation will help to disperse the dirt trapped by the micelle to the solution. Agitation is
necessary to get clean clothes as agitation help soap micelles to trap the oil, grease or
any other impurities that have to be removed. When they are being beaten or agitated,
the particles are removed from the clothes’ surfaces and go into the water, thus cleaning
the clothes.
58.Explain the nature of the covalent bond using the bond
formation in CH3Cl
Carbon can neither lose 4 electrons nor do gain four electrons as these process make the
system unstable due to requirement of extra energy. Therefore CH 3Cl completes its octet
configuration by sharing its 4 electrons with carbon atoms or with atoms of other
elements. Hence the bonding that exists in CH3Cl is a covalent bonding.Here, carbon
requires 4 electrons to complete its octet, while each hydrogen atom requires one
electron to complete its duplet. Also, chlorine requires an electron to complete the
octet. Therefore, all of these share the electrons and as a result, carbon forms 3 bonds
with hydrogen and one with chlorine.
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