CHEMISTRY

BOOKS - DISHA PUBLICATION CHEMISTRY

(HINGLISH)

SOLUTIONS

Exercise

1. The mass of non-volatile, non-electrolyte solute

(molar mass = 50gmol

−1
) needed to be dissolved in 114g

octane to reduce its vapour pressure to 75%, is :

A. 37.5g

B. 75g
 C. 150 g

D. 50 g

Answer: C

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2. Two 5 molal solution are prepared by dissoliving a non

elecrtroyte non volatile solute separately in the solvents X nad

Y The molecular weights of the solvents are Mx and My

respecitvely where
3
Mx = My The relative lowering of vapour pressure of the
4

solution in is 'm' times that of the solution in y given that the

number of moles of solute is very small in comparison to that

of solvent the value of ''m'' is :

 3
A.
4

1
B.
2

1
C.
4

4
D.
3

Answer: A

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3. For 1 molal aqueous solution of the following compounds,

which one will show the highest freezing point ?

A. [Co(H 2
O) ]Cl3
6

B. [Co(H 2
O) Cl]Cl2 . H2 O
5

C. [Co(H 2
O) Cl2 ]Cl.2H2 O
4
 D. [Co(H 2
O) ].3H2 O
3

Answer: D

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4. 5 g of N a 2
SO4 was dissolved in x g of H 2
O . The change in

freezing point was found to be 3.82

∘
C . If N a2 SO4 is 81.5 %

ionised , the value of x

(k for water =1.86

f
∘
C kg mol −1
) is apporximately :

(molar mass of S=32 g mol −1

and that of Na=23 g mol −1
)

A. 15g

B. 25g

C. 45 g

D. 65 g
Answer: C

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5. A solution is prepared by mixing 8.5g of CH 2

Cl2 and 11.95g

of CH Cl . If vapour pressure of CH
3 2
Cl2 and CH Cl3 at 298 K

are 415 and 200 mm Hg respectively, the mole fraction of

CH Cl3 in vapour form is :

−1
(Molar mass of Cl = 35.5 g mol )

A. 0.162

B. 0.675

C. 0.325

D. 0.486

Answer: C
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6. The freezing point of benzene decreases by 0.45

∘
C when

0.2g of acetic acid is added to 20g of benzene. IF acetic acid

associates to form a dimer in benzene, percentage association

of acetic acid in benzene will be

−1
(Kf for benzene = 5.12Kkgmol )

A. 0.646

B. 0.804

C. 0.746

D. 0.946

Answer: D

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7. The solubility of N2 in water at 300K at 300K and 500 torr

partial pressure 0.01gL −1

. The solubility (in gL
−1
) at 750 torr

partial pressure is :

A. 0.0075

B. 0.005

C. 0.02

D. 0.015

Answer: D

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8. An aqueous solution of a salt M X2 at certain temperature

has a van'f Hoff factor of 2. The degree of dissociation for this

solution of the salt is:

A. 0.5

B. 0.33

C. 0.67

D. 0.8

Answer: A

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9. 18g glucose (C6 H12 O6 ) is added to 178.2g water. The

vapour pressure of water (in torr) for this aqueous solution is:

A. 752.4

B. 759
 C. 7.6

D. 76

Answer: A

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10. A solution at 20
∘
C is composed of 1.5 mol of benzene and

3.5 mol of toluene. If the vapour pressure of pure benzene and

pure toluene at this temperature are 74.7 torr and 22.3 torr,

respectively, then the total vapour pressure of the solution and

the benzene mole fraction in equilibrium with it will be,

respectively:

A. 35.8 torr and 0.280

B. 38.0 torr and 0.589

 C. 30.5 torr and 0.389

D. 30.5 torr and 0.480

Answer: B

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11. Determination of the molar mass of acetic acid in benzene

using freezing point depression is affected by:

A. partial ionization

B. dissociation

C. complex formation

D. association

Answer: D
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12. The vapor pressure of acetone at 20

∘
C is 185 torr. When

1.2g of a non-volatile solute was dissolved in 100g of acetone

at 20
∘
C , it vapour pressure was 183 torr. The molar mass

(gmol
−1
) of solute is:

A. 128

B. 488

C. 32

D. 64

Answer: D

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13. Choose the correct statement with respect to the vapour

pressure of a liquid among the following:

A. Increases linearly with increasing temperature

B. Increases non-linearly with increasing temperature

C. Decreases linearly with increasing temperature

D. Decreases non-linearly with increasing temperature

Answer: B

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14. For an ideal solution of two components A and B, which of

the following is true?

A. ΔH mixing
< 0 (zero)
 B. ΔH mixing
> 0 (zero)

C. A-B interaction is stronger than A-A and B - B interations

D. A-A, B -B and A- B interactions are identical.

Answer: D

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15. The observed osmotic pressure for a 0.10M solution of

F e(N H4 ) (SO4 )
2 2
at 25
∘
C is 10.8atm . The expected and

experimental (observed) values of Van't Hoff factor (i) will be

respectively: (R = 0.082Latmk
−
mol
−1
)

A. 5 and 4.42

B. 4 and 4.00

C. 5 and 3.42
 D. 3 and 5.42

Answer: A

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16. Consider separate solution of

0.500M C2 H5 OH (aq), 0.100M M g3 (P O4 ) (aq), 0.250M KBr(aq)

2

and 0.125M N a3 P O4 (aq) at 25

∘
C . Which statement is true

about these solutions, assuming all salts to be strong

electrolytes?

A. They all have the same osmotic pressure.

B. 0.100M M g 3
(P O4 )(aq) has the highest osmotic

pressure.

C. 0.125M N a 2
P O4 (aq) has the highest osmotic pressure.
 D. 0.500M C 2
H5 OH (aq) has the highest osotic pressure.

Answer: A

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17. When the solute is present in trace quantities the following

expression is used

A. gram per million

B. milligram percent

C. microgram precent

D. parts per million

Answer: D

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18. Which one of the following gases has the lowest value of

Henry law constant ?

A. N2

B. H e

C. H 2

D. CO 2

Answer: D

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19. Equal moles of water and user are taken in a flask. What is

mass percentage of urea in the solution ?

 A. 0.07692

B. 0.092

C. 0.7692

D. 0.007692

Answer: C

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20. What is the normality of 1 M H 3

P O4 solution ?

A. 0.5N

B. 1.0N

C. 2.0N

D. 3.0N
Answer: D

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21. Molarity of liquid HCl with density equal to 1.17g/cc is

A. 36.5 M

B. 32.05M

C. 18.25M

D. 42.10M

Answer: B

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22. An X molal solution of a compound in benzene has mol e

fraction of solute = 0.2. The value of X is

A. 14

B. 3.2

C. 1.4

D. 2

Answer: B

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23. The normality of orthophosphoric acid having purity of

70% by weight and specific gravity 1.54 is :

A. 11N
 B. 22N

C. 33N

D. 44N

Answer: C

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24. In acidic medium, equivalent weight of K2 Cr 2 O7

(molecular weight = M ) is

A. M

B. M/2

C. M/3

D. M/6
Answer: D

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25. The mole fraction of the solute in one molal aqueous

solution is:

A. 0.009

B. 0.018

C. 0.027

D. 0.036

Answer: B

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26. 5mL of N H CI, 20mL of N / 2H2 SO4 and 30 mL of

N / 3H N O3 are mixed together and volume made to one litre.

The normality of the resulting solution is

N
A.
5

N
B.
10

N
C.
20

N
D.
40

Answer: D

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27. Which of the following substances will lose its whose

solubility with increase in temperature?

 A. N aOH

B. N a 2
CO3

C. N a 2
SO4

D. All

Answer: D

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28. For a dilute solution, Raoult's law states that

A. the lowering of vapour pressure is equal to the mole

fraction of solute.

B. the relative lowering of vapour pressure is equal to the

mole fraction of solute.

 C. the relative lowering of vapour pressure isproportional

to the amount of solute in solution.

D. the vapour pressure of the solution is equal to the mole

fraction of solvent.

Answer: B

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29. If P
∘
and Ps are vapour pressure of solvent and its

solution, respectively, χ and 1

χ2 are mole fractions of solvent

and solute, respectively, then

A. p s
= p
∘
/ X2

B. p ∘
− ps = p
∘
X2
 C. ps
= p
∘
X2

∘
p − ps X1
D. =
ps X1 + X2

Answer: B

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30. The normal boiling point of water is 373 k. vapour of waterr

at temperature T is 19 mm hg. If enthalpy of vapoursed is 40.67

kJ/mol, them temperature Twould be

(use : log 2 = 0.3, R : 8.3J k −1

mol
−1
):

A. 250 K

B. 291.4K

C. 230K

D. 290 K
Answer: B

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31. For a binary ideal liquid solution, the total vapour of the

solution is given as:

A. P total
= P
∘
A
+ (P
∘
A
− P
∘
B
)XB

B. P total
= P
∘
B
+ (P
∘
A
− P
∘
B
)XA

C. P total
= P
∘
B
+ (P
∘
B
− P
∘
A
)XA

D. P total
= P
∘
B
+ (P
∘
B
− P
∘
A
)XB

Answer: B

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32. Mixture of volatile components A and B has a total vapour

pressure (in torr)p=254 − 119x is wherex mole fraction of A

A A

in mixture .HenceP and P are(in torr)

A
∘
B
∘

A. 254119

B. 119254

C. 135254

D. 154, 119

Answer: D

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33. Moles ofN a 2

SO4 to be dissoved in 12 mole water to lower

its vapour pressure by 10 mm Hg at a temperature at which

vapour pressure of pure water is 50 mm is:

 A. 1.5 mole

B. 2 mole

C. 1 mole

D. 3 mole

Answer: D

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34. Equimolar solutions in the same solvent have-

A. different boiling and different freezing points,

B. same boiling and same freezing points.

C. same freezing point but different boiling points.

D. same boiling point but different freezing points.

Answer: B

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35. The solubility of common salt is 36.0 g in 100 g of water at

20
∘
C . If systems I , II and III contains 20.0, 18.0and15.0 of the

salt added to 50.0 g of water in each case , the vapour

pressures would be in the order :

A. IltIIltIII

B. IgtIIgtIII

C. I=II gt III

D. I=II ltIII

Answer: D

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36. Vapour pressure of benzene at 30
∘
C is 121.8 mm. When 15

g of a non-volatile solute is dissolved in 250 g of benzene its

vapour pressure decreased to 120.2 mm. The molecular weight

of the solute is (mol. Weight of solvent = 78)

A. 356.2

B. 456.8

C. 530,1

D. 656.7

Answer: A

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37. The vapour pressure of two liquids 'P' and 'Q' are 80 and 60

torr respectively. The total vapour pressure of solution

obtained by mixing 3 mole of P and 2 mol of Q would be

A. 72 torr

B. 140 torr

C. 68 torr

D. 20 torr

Answer: A

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38. In a mixture of A and B, components show negative

deviation when
 A. ΔV mix
> 0

B. ΔH mix
> 0

C. A - B interaction is weaker than A - A and B - B

interactions

D. A - B interaction is stronger than A - A and B - B

interactions

Answer: D

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39. 18g of glucose (C 6

H12 O6 ) is added to 178.2 g of water. The

vapour pressure of water for this aqueous solution at 100 ∘

C is

:
 A. 76.00 torr

B. 752.40 torr

C. 759. 00 torr

D. 7.60 torr

Answer: B

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40. The vapour pressure of pure benzene is 639.7mmH g and

the vapour pressure of solution of a solute in benzene at the

temperature is 631.9mmH g . Calculate the molality of the

solution.

A. 65.25

B. 130
 C. 40

D. 80

Answer: D

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41. An ideal solution is formed when its components same

A. have no volume change on mixing

B. have no enthalpy change on mixing

C. both (a) and (b) are correct

D. neither (a) nor (b) is correct

Answer: C

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42. Strutural isomers C2
H5 OH and CH 3
OCH3 have the same

value of

A. Boiling points

B. Vapour pressure at the same temperature

C. Heat of vaporization

D. Gaseous densities at the same temperature and pressure

Answer: D

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43. Which one of the following is non-ideal solution?

A. Benzene + toluene
 B. n-hexane + n - heptane

C. Ethyl bromide + ethyl iodide

D. CCl 4
+ CH Cl3

Answer: D

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44. When common salt is dissolved in water

A. the melting point of the solution increases.

B. the boiling point of solution decreases.

C. both melting point and boiling point decrease.

D. the boiling point of the solution increases.

Answer: D
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45. Camphor is often used in molecular mass determination

because

A. it is readily available

B. it has a very high cryoscoic constnat

C. it is volatile

D. it is solvent for organic substances.

Answer: B

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46. Normal boiling point of a liquid is that temperature which

vapour pressure of the liquid is equal to:

A. equal to 1 torr

B. equalt o 76 mm hg

C. equal to 2.0 atm

D. equal to 1 atm

Answer: D

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47. When solid SnO2 is added to an aqueous solution of

NaOH, the

A. vapour pressure is lowered.

 B. vapour pressure is raised.

C. osmotic pressure is increased.

D. boiling point is raised.

Answer: B

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48. The vapour pressure (V P ) of a dilute solution of non-

volatile solute is P and the VP of a pure solvent is P

∘
. The

lowering of the V P is

A. + ve

B. − ve

C. P / P ∘
 D. P ∘
/P

Answer: A

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49. What would be the freezing point of aqueous solution

containing 17 g of C2 H5 OH in 100 g of water

(Kf H2 O = 1.86Kmol
−1
kg) :

A. − 0.69 ∘
C

B. − 0.34 ∘
C

C. 0.0 ∘
C

D. 0.34 ∘
C

Answer: A
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50. If a thin slice of sugar beet is placed in concentrated

solution of N aCl, then

A. sugar beet will lose water from its cells.

B. sugar beet will absorb water from solution

C. sugar beet will neither absorb nor lose water.

D. sugar beet will dissolve in solution.

Answer: A

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51. Which salt shows maximum osmotic pressure in its 1m

solution.

A. AgN O 3

B. N a 2
SO4

C. (N H 4
) P O4
3

D. M gCl 2

Answer: C

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52. The osmotic pressure of a sugar solution at 24

∘
C is

2.5atm . The concentration of the solution in mole per litre is

A. 10.25
 B. 1.025

C. 1025

D. 0.1025

Answer: D

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53. Which has the maximum osmotic pressure at temperature

T ?

A. 100mL of 1 M urea solution.

B. 300 mL of 1 M glucose solution.

C. Mixture of 100 mL of 1 M urea solution and 300 mL of 1 M

glucose solution
 D. All are isotonic.

Answer: D

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54. Choroform , CH Cl3 , boils at 61.7

∘
C. If the Kb for

choroform is 3.63
∘
C / molal , what is the boiling point of a

solution of 15.0 kg ofCH and 0.616 kg of acenaphthalene,

3

C12 H10 ?

A. 61.9 ∘
C

B. 62.0 ∘
C

C. 52.2 ∘
C

D. 62.67 ∘
C
Answer: D

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55. Which one of the following aqueous solutions will exhibit

highest boiling point ?

A. 0.015 M urea

B. 0.01 M KN O 3

C. 0.10M N a 2
SO4

D. 0.015 M glucose

Answer: C

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56. When a solution containg non- volatile solute freezes,

which equilibrium would exist?

A. solid solvent ⇒ liquid solvent

B. solid solute ⇒ liquid solution

C. solid solute ⇒ liquid solvent

D. solid solvent ⇒ liquid solution

Answer: D

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57. How much ethyl alcohol must be added to 1.00L of water

so that the solution will not freeze at − 4 ∘

F ?

A. lt 20 g
 B. lt 10.75 g

C. lt 494.5 g

D. gt 494.5 g

Answer: D

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58. A solution containing 1.8 g of a compound (empirical

formula CH2 O ) in 40 g of water is observed to freeze at

− 0.465
∘
C. The molecules formulea of the compound is (K of
f

water =1.86kg Kmol −1

):

A. C2
H4 O 2

B. C3
H6

C. C4
H8 O 4
 D. C 6
H12 O6

Answer: D

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59. Freezing point of the following equilibrium, liquid solvent

⇔ solid solvent is :

ΔH − ΔG
A.
T ΔS

ΔH
B.
ΔS

ΔG
C.
ΔS

ΔS
D.
ΔH

Answer: B

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60. The freezing point of equimolal aqueous solution will be

highest for

A. C6
H5 N H3 Cl

B. Ca(N O 3
)
2

C. La(N O 3
)
2

D. C6
H12 O6

Answer: D

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61. In a 0.5 molal solution KCl, KCl is 50% dissociated. The

freezing point of solution will be (K = 1.86 K kg mol

f
−1
):
 A. 274. 674 K

B. 271.60 K

C. 273K

D. None of these

Answer: B

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62. In a 2.0 molal aqueus solution of a weak acid HX the degree

of disssociation is 0.25. The freezing point of the solution will

be nearest to: (K f
= 1.86Kkgmol
−1
)

A. − 026 ∘
C

B. 0.465 ∘
C
 C. − 0.48 ∘
C

D. − 0.465 ∘
C

Answer: D

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63. Which one of the following statements is false ?

A. The correct order of osmotic pressure for 0.01 M

aqueous solution of each compound is

BaCl2 > KCl > CH3 COOH > socrose.

B. Isotonic solutions are those solutions which have the

same osmotic pressure.

 C. Raoult's law states that the vapour pressure of a

component over a solution is proportional to its mole

fraction in liquid state.

D. Two sucrose solution of same molality prepared in

different solvents will have the same freezing point

depression.

Answer: D

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64. 0.1 molal aqueous solution of an electrolyte AB 3 is 90%

ionised. The boiling point of the solution at 1 atm is (

Kb ( H
2O )
= 0.52kg mol
−1
)
 A. 273.19 K

B. 374.92 K

C. 376.4K

D. 373.19 K

Answer: D

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65. In the case of osmosis, solvent molecules move from :

A. higher vapour pressure to lower vapour pressure

B. higher concentration to lower concentration.

C. lower vapour pressure to higher vapour pressure.

 D. higher osmotic pressure solutions to lower osmotic

pressure.

Answer: A

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66. Which of the following solutions would have the highest

osmotic pressure:

A. Decinormal aluminium sulphate

B. Decinormal barium chloride solution

C. Decinormal sodium sulphate solution

D. Solution of equal volumes of decinormal barium chloride

and decinormal sodium sulphate solutions

Answer: A

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67. A 1% (mass/vol) KCl solution is ionised to the extent of 80%.

The osmotic pressure at 27 C of the solution will be :

∘

A. 6.95 atm

B. 5.94 atm

C. 2.71 atm

D. 3.30 atm

Answer: B

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68. Osmotic pressure nof blood is 7.40 atm, at 27 C. Number of
∘

moles of glcouse to be used per liter for an intravenous

injection that is to have same osmotic pressure of blood is :

A. 0.3

B. 0.2

C. 0.1

D. 0.4

Answer: A

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69. A solution containing 4.0 g of PVcC in 2 liter of dioxane

(industrial solvent ) was found to have an osmotic pressure 3.0

x 10
−4
atm at 27
∘
C . The molar mass of the polymer (g/mol)

will be :

A. 1.6 × 10 4

B. 1.6 × 10 5

C. 1.6 × 10 3

D. 1.6 × 10 2

Answer: B

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70. If the elevation in boiling point of a solution of 10 g of

solute (molecular weight = 100) in 100 g of water is ΔTb , the

ebullioscopic constant of water is

A. 10
 B. 10ΔT b

C. ΔT b

ΔTb
D.
10

Answer: C

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71. The boiling point of a solution of 0.11g of a substance is

15g of ether was found to be 0.1

∘
C higher than that of pure

ether. The molecular weight of the substance will be

(Kb = 2.16)

A. 148

B. 158

C. 168
 D. 178

Answer: B

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72. Which observation (s) reflect(s) colligative properties ?

(i) A 0.5m NaBr solution has a higher vapour pressure than a

0.5 m BaCl solution at the same temperature.

2

(ii) Pure water freezes at the higher temperature than pure

methanol.

(iii) A 0.1 m NaOH solution freezes at a lower temperature than

pure water.

Choose the correct answer from the codes given below

A. (i), (ii) and (iii)

 B. (i) and (ii)

C. (ii) and (iii)

D. (i) and (iii)

Answer: D

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73. An aqueous solution freezes at

− 0.186
∘
C(Kf = 1.86
∘
,K
b
= 0.512
∘
. What is the elevation

in boiling point?

A. 0.186 ∘
C

B. 0.512 ∘
C

C. 0.86 ∘
C
 D. 0.0512 ∘
C

Answer: D

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74. At temperature 327

∘
C and concentration C, the osmotic

pressure of a solution is P. The same solution at concentration

C/2 and a temperature 427 ∘

C of shows osmotic pressure of 2

atm. The value of P will be :

12
A.
7

24
B.
7

6
C.
5

5
D.
6
Answer: B

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75. The relationship between osmotic pressure at 273K when

10g glucose (P1 ), 10g urea (P2 ) and 10g sucrose (P3 ) are

dissolved in 250mL of water is:

A. P 1
> P2 > P3

B. P 3
> P1 > P2

C. P 2
> P1 > P3

D. P 2
> P3 > P1

Answer: C

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76. Consider the following statements

I : Osmosis takes place with increase of entropy.

II. Osmosis is a non-spontaeous process.

III : Free energy decreases during osmosis.

Which of the above is/are correct ?

A. I only

B. I and II

C. II and III

D. I and III

Answer: D

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77. Which of the following represents correcty the changes in

thermodynamic properties during the formation of 1 mole of

an ideal binary solution :

A.

B.

C.

D.
Answer: B

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78. 1.00 g of a non-electrolyte solute (molar mass 250g mol

–1
)

was dissolved in 51.2 g of benzene. If the freezing point

depression constant Kf of benzene is 5.12 K kg mol

–1
, the

freezing point of benzene will be lowered by:-

A. 0.3 K

B. 0.5 K

C. 0.4 K

D. 0.2

Answer: C

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79. In a 0.2 molal aqueous solution of a weak acid HX the

degree of ionization is 0.3. Taking Kf for water as 1.85, the

freezing point of the solution will be nearest to

A. − 0.360 ∘
C

B. − 0.260 ∘
C

C. + 0.481 ∘
C

D. − 0.481 ∘
C

Answer: D

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80. The elevation in boiling point of a solution of 13.44 g of

CuCl2 (molecular weight =134.4, k b

= 0.52Kmolality
−1
) in 1

kg water using the following information will be:

A. 0.16

B. 0.05

C. 0.1

D. 0.2

Answer: A

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81. The temperature at which 10% aqueous solution (w/v) of

glucose will exhibit the osmotic pressure of 14 bar is -

 A. 307.3 ∘
C

B. 307.3K

C. 34K

D. − 34 ∘
C

Answer: B

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82. KBr is 80% ionized in solution. The freezing point of 0.4

molal solution of KBr is :

Kkg
Kf ( H2 O )
= 1.86
mole

A. 274.339 K

B. − 1.339K
 C. 257.3K

D. − 1.339 ∘
C

Answer: D

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83. What is the freezing point of a solution containing 8.1gBr

in 100g water assuming the acid to be 90 % ionised(K for

f

water =1.8Kmole −1
)

A. 0.85 ∘
K

B. − 3.53 ∘
K

C. 0 ∘
K

D. − 0.35 ∘
K
Answer: B

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84. The correct order of osmotic pressure of 0.01M aqueous

solution of the following is

A. Sucrose > CH3 COOH > KCl

B. CH 3
COOH > Sucrose > KCl

C. Sucrose > KCl > CH3 COOH

D. KCl > CH3 COOH > Sucrose

Answer: D

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85. A solution of urea boils at 100.18
∘
C at the atmospheric

pressure. If K and K for water are 1.86 and

f b
0.512Kkgmol
−1

respectively, the above solution will freeze at,

A. 0.654 ∘
C

B. − 0.654 ∘
C

C. 6.54 ∘
C

D. − 6.54 ∘
C

Answer: B

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86. Consider the followign statements

1. Isotonic solutions have the same molar concentration at a

given temperature
2. The molal elevation constant Kb is a characteristic of a

solvent, and is independent of the solute added

3. The freezing point of a 0.1 M aqueous AlCl solution.

3

Which of these statements is correct

A. 1 and 2

B. 2 and 3

C. 1 and 3

D. 1,2 and 3

Answer: D

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87. For an ideal binary liquid solutions with P

∘
A
> P
∘
B
, which

relation between XA (mole fraction of A in liquid phase) and

YA (mole fraction of A in vapour phase) is correct:

A. y A
< yB

B. x A
> xB

yA xA
C. >
yB xB

yA xA
D. <
yB xB

Answer: C

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88. Formation of a solution from two componenets can be

considered as :

(i) pure sovent → separated solvent molecules, △ H1

(ii) Pure solute → separated molecules, △ H2

(iii) separated sovent and solute molecules → solution, △ H3

solution so formed will be ideal if :

A. ΔH soln
= ΔH3 − ΔH1 − ΔH2

B. ΔH soln
= ΔH1 + ΔH2 + ΔH3

C. ΔH soln
= ΔH1 + ΔH2 − ΔH3

D. ΔH soln
= ΔH1 − ΔH2 − ΔH3

Answer: B

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89. The volumes of 4N H CI and 10N H CI required to make 1

litre of 6N H CI are

A. 0.75 litre of 10 NHCl and 0.25 litre of 4NHCl

 B. 0.50 litre of 4NHCl and 0.50 litre of10 NHCl

C. 0.67 litre of 4 NHCl and 0.33 litre of 10 NHCl

D. 0.80 litre of 4NHCl and 0.20 litre of 10 NHCl

Answer: C

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90. The mole fraction of water in 20 % (wt. / wt. ) aqueous

solution of H 2
O2 is:

77
A.
68

68
B.
77

20
C.
80

80
D.
20
Answer: B

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91. 25 mL of a solution of barium hydroxide on titration with 0.1

molar solution of hydrochloric acid gave a titre value of 35 mL.

The molarity of barium hydroxide solution was

A. 0.07

B. 0.14

C. 0.28

D. 0.35

Answer: A

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92. A simple of thliqid H2 O at 18.0 g is inlected into an

evacuated 7.6 L flask maintained at 27.0

∘
C . If vapour pressure

of H 0
O at 27.0
∘
C is 24.63 mm Hg, what wight percentage of

the water will be vaproueied when the ssystem comes to

equilibrium? Assume water vapours behaves as an ideal gas.

The volume occupied by the liquid water is negligible

compared to the volume of the container:

A. 0.01

B. 0.1

C. 0.18

D. 0.2

Answer: A

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93. An ideal solution contains two volatile liquids A(P ∘
= 100

torr) and B(P

∘
= 200 torr). If mixture contain 1 mole of A

and 4 mole of B then total vapour pressure of the distillate is :

A. 150

B. 180

C. 188.88

D. 198.88

Answer: C

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94. Vapour pressure of solution containing 2 mol of liquid A (

P
∘
A
= 80 torr) and 3 mol of liquid B (P ∘
B
= 100 torr) is 87 torr.
We canconclude that

A. there is negative deviation from Raoult's law

B. boiling point is higher than that expected for ideal

solution

C. molecular attractions between unlike molecules

arestronger than those between like molecules

D. all of these statements are correct

Answer: D

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95. Liquids A and B from an ideal solution and the former has

stronger intermolecular forces. If XA and X' A are the mole

fractions of A in the solution and vapour inequilibrium, then

 X' A
A. = 1
XA

X' A
B. > 1
XA

X' A
C. = 1
XA

D. X' A
+ XA = 1

Answer: C

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96. A solution is prepared by mixing 8.5g of CH 2

Cl2 and 11.95g

of CH Cl . If vapour pressure of CH
3 2
Cl2 and CH Cl3 at 298 K

are 415 and 200 mm Hg respectively, the mole fraction of

CH Cl3 in vapour form is :

−1
(Molar mass of Cl = 35.5 g mol )

A. 0.162
 B. 0.675

C. 0.325

D. 0.416

Answer: D

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97. A solution at 20
∘
C is composed of 1.5 mol of benzene and

3.5 mol of toluene. If the vapour pressure of pure benzene and

pure toluene at this temperature are 74.7 torr and 22.3 torr,

respectively, then the total vapour pressure of the solution and

the benzene mole fraction in equilibrium with it will be,

respectively:

A. 35.8 torr and 0.280

 B. 38.0 torr and 0.589

C. 30.5 torr and 0.389

D. 30.5 torr and 0.480

Answer: B

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98. The vapour pressure at a given temperature of an ideal

solution containing 0.2mol of non-volatile solute and 0.8mol

of a solvent is 60mm of H g. The vapour pressure of the pure

solvent at the same temperature will be

A. 150 mm of Hg

B. 60mm of Hg

C. 75 mm of Hg
 D. 120 mm of Hg

Answer: C

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99. Select correct statement

A. Heats of vaporisation for a pure solvent and for a

solution are similar because similar intermolecular forces

between solvent molecules must be overcome in both

cases.

B. Entropy change between solution and vapour is smaller

than the entropy change between pure solvent and

vapour.
 C. Boiling point of the solution is larger than that of the

pure solvent.

D. All are correct statements.

Answer: D

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100. For 1 molal solution of each compound minimum freezing

point will be assuming compound ionisation in each case :

A. [F e(H 2
O) ]Cl3
6

B. [F e(H 2
O) Cl]Cl2 H2 O
5

C. [F e(H 2
O) Cl2 ]Cl.2H2 O
4

D. [F e(H 2
O) Cl3 ].3H2 O
3
Answer: A

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101. A 0.010 g sample ofCr(N H 3

) (SO4 )Cl
4
is dissolved in 25.0

nL of water and the osmotic pressure of the solution is 59.1

torr at 25
∘
C . How many moles of ions are produced per mole

of compound?

A. 1

B. 4

C. 2

D. 3

Answer: C

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102. Which of the following aquous solutions should have the

highest osmotic pressure?

A. 0.011 M AlCl 3
at 50
∘
C

B. 0.03 M NaCl at 25 ∘
C

C. 0.012M (N H 4
) SO4
2
at 25
∘
C

D. 0.03 m NaCl at 50 ∘
C

Answer: D

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103. At 760 torr pressure and 20

∘
C tempreature , 1 L of water

dissolves 0.04 gm of pure oxygen or 0.02 gm of pure nitrogen.

Assuming that dry air is compound of 20% oxygen and 80%

nitrogen (by volume), the masses (in g/L) of oxygen and

nitrogen dissolved by 1 L of water at 20

∘
C exposed to air at a

total pressur of 706 torr are respectively :

A. 0.008,0.016

B. 0.016,0.008

C. 0.16.0.08

D. 0.04,0.02

Answer: A

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104. The correct equation for the degree of association ' α' of

an associating solute, 'n' molecules of which undergoes

association in solution, is

n(i − 1)
A. α =
1 − n

i(n − 1)
B. α =
1 + n

i(1 + n)
C. α =
1 − n

i(n + 1)
D. α =
n − 1

Answer: A

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105. Osmotic pressure of a solution at a given temperature

A. increases with concentration

B. decreases with concentration

C. remains same
 D. initially increases and then decreases

Answer: A

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106. The solution containing 4.0gm of a polyvinyl chloride

polymer in 1 litre dioxane was found to have an osmotic

pressure 6.0 × 10
−4
atmosphere at 300K ,the value of R used

is litre atmospheremole
0.082
−1
K
−1
.The molecular mass of

the polymer was found to be

A. 3.0 × 10 2

B. 1.6 × 10 5

C. 5.6 × 10 4

D. 6.4 × 10 2
Answer: B

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W
107. π 1
, π 2 , π 3 and π 4 are the osmotic pressure of 5% ( )
V

solution of ure ,frutose ,sucrose andKCl respectively at certain

temperatures.The correct order of their magnitude is

A. π 1
> π4 > π2 > π3

B. π 1
< π4 < π2 < π3

C. π 4
> π1 > π2 > π3

D. π 4
> π1 > π3 > π2

Answer: C

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108. In countries nearer to polar region, the roads are sprinkled

with CaCl . This is

2

A. to minimise the snow fall

B. to minimise pollution

C. to minimise the accumulation of dust on the road

D. to minimise the wear and tear of the roads

Answer: A

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109. If the various terms in the following expressions have

usual meanings, the van't Hoff factor 'i' cannot be calculated by

which of the following expression ?

 A. πV = √inRT

B. ΔT f
= iKf . m

C. ΔT b
= iKb . m

∘
P − Psolution n
D.
solvent
= i( )
∘
P N + n
solvent

Answer: A

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110. A 0.001 molal solution of [P t(N H3 ) CI4 ]

4
in water had a

freezing point depression of 0.0054 ∘

C . If K for water is
f
,
1.80

the correct formulation for the above molecule is

A. [P t(N H 3
) Cl3 ]Cl
4

B. [P t(N H 3
) Cl2 ]Cl2
4
 C. [P t(N H 3
) Cl]Cl3
4

D. [P t(N H 3
) Cl4 ]
4

Answer: B

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111. Which of the following has the highest freezing point ?

A. 0.1 m sucrose

B. 0.1 m urea

C. 0.1 m ethanol

D. 0.1 m glucose

Answer: C

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112. Which has the minimum freezing point ?

A. One molal NaCl aq. Solution

B. One molal CaCl aq. Solution

2

C. One molal KCl aq. Solution

D. One molal urea aq. Solution

Answer: B

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113. The freezing point (in .

∘
C) of a solution containing 0.1g

of K3 [F e(CN ) ]
6
(Mol. wt. 329) in 100g of water

(Kf = 1.86Kkgmol
−1
) is :
 A. − 2.3 × 10 −2

B. − 5.7 × 10 −2

C. − 5.7 × 10 −3

D. − 1.2 × 10 −2

Answer: A

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114. For a silute solution conatining 2.5g of a non-volatile non-

electrolyte solute in 100g of water, the elevation in boiling

point at 1 atm pressure is 2

∘
C . Assuming concentration of

solute is much lower than the concentration (take

−1
Kb = 0.76Kkgmol )

A. 724
 B. 740

C. 736

D. 718

Answer: A

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115. Which of the following statements is correct if the

intermolecular forces in liquid A, B and C are in the order

A < B < C ?

A. B evaporates more readily than A

B. B evaporates less readily than C

C. A and B evaporates at the same rate

 D. A evaporates more readily than C

Answer: D

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116. The relationshp between the values of osmotic pressure of

0.1 M solution of KN O 3
(P1 ) and CH3 COOH (P2 ) is :

P1 P2
A. =
P1 + P2 P1 + P2

B. P 1
> P2

C. P 2
> P1

D. P 1
= P2

Answer: B

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