SOLUTION

DPPs By Sanjay Arya TG : Sanjay Arya Chemistry

LEVEL-1
Q1. A solution contains 2 moles of A and 3 moles of B. If the partial vapor pressure of A is 60 mm
Hg and that of B is 40 mm Hg, calculate the total vapor pressure of the solution.

A) 48 mm Hg

B) 52 mm Hg

C) 56 mm Hg

D) 60 mm Hg

Q2. Calculate the vapor pressure lowering when 10 g of urea (molar mass = 60 g/mol) is dissolved in
90 g of water. The vapor pressure of pure water is 31.82 mm Hg.

A) 0.56 mm Hg

B) 1.04 mm Hg

C) 0.62 mm Hg

D) 1.74 mm Hg

Q3. A solution of non-volatile solute freezes at -0.93°C. Calculate the molality of the solution if Kf for
water is 1.86 °C kg/mol.

A) 0.5 m

B) 0.3 m

C) 0.4 m

D) 0.6 m

Q4. In a solution of A and B showing negative deviation from Raoult’s law, what would be the
impact on vapor pressure?

A) Increases

B) Decreases

C) Remains constant

D) Unpredictable
Q5. Calculate the Van’t Hoff factor for a 0.1 M solution of K₄[Fe(CN)₆] if it completely dissociates in
water.

A) 5

B) 4

C) 3

D) 2

Q6. Which of the following solutions has the highest boiling point elevation: 1 M NaCl, 0.5 M K₂SO₄,
or 0.33 M AlCl₃?

A) 1 M NaCl

B) 0.5 M K₂SO₄

C) 0.33 M AlCl₃

D) All have the same elevation

Q7. A solution freezes at -0.372°C. Calculate the molality of the solution if Kf of water is 1.86 °C
kg/mol.

A) 0.2 m

B) 0.25 m

C) 0.3 m

D) 0.4 m

Q8. Which one of the following solutions would show positive deviation from Raoult’s law?

A) Ethanol and water

B) Benzene and toluene

C) Acetone and carbon tetrachloride

D) Acetic acid and water

Q9. If the total pressure of a benzene-toluene solution is 100 mm Hg and the mole fraction of
benzene is 0.5, what is the partial vapor pressure of benzene? (P° of benzene = 80 mm Hg, P° of
toluene = 60 mm Hg)

A) 40 mm Hg

B) 50 mm Hg

C) 60 mm Hg

D) 30 mm Hg
Q10. Calculate the freezing point of a solution prepared by dissolving 10 g of glucose (C₆H₁₂O₆) in
100 g of water. Kf for water is 1.86 °C kg/mol.

A) -0.93°C

B) -1.03°C

C) -0.31°C

D) -1.24°C

Q11. A solution of 2 moles of glucose in 500 g of water has a vapor pressure of 28.5 mm Hg at 298
K. The vapor pressure of pure water at 298 K is 31.82 mm Hg. Calculate the mole fraction of glucose
in the solution.

A) 0.03

B) 0.06

C) 0.08

D) 0.10

Q12. Determine the boiling point of a solution containing 10 g of urea (molar mass = 60 g/mol)
dissolved in 200 g of water. (Kb for water = 0.52 °C kg/mol)

A) 100.13°C

B) 100.43°C

C) 100.85°C

D) 100.52°C

Q13. For a solution with 0.1 m glucose in 1 kg of water, calculate the vapor pressure at 298 K given
the vapor pressure of pure water is 23.8 mm Hg.

A) 23.5 mm Hg

B) 23.7 mm Hg

C) 23.6 mm Hg

D) 23.4 mm Hg

Q14. Which of the following pairs would form a minimum boiling azeotrope?

A) Ethanol and water

B) Benzene and toluene

C) Methanol and acetone

D) Hexane and heptane

A) 0.25

B) 0.15

C) 0.50

D) 0.33

Q16. In a solution of 0.5 M NaCl and 0.3 M K₂SO₄, calculate the total Van’t Hoff factor assuming
complete dissociation.

A) 1.6

B) 1.9

C) 2.0

D) 2.4

Q17. Which of the following exhibits a positive deviation from Raoult's law?

A) Acetone and chloroform

B) Benzene and toluene

C) Water and nitric acid

D) Ethanol and cyclohexane

Q18. A mixture of benzene and toluene forms an ideal solution. If the mole fraction of benzene is
0.4, what is its partial vapor pressure given the vapor pressure of pure benzene is 95 mm Hg and
pure toluene is 28 mm Hg?

A) 38 mm Hg

B) 42 mm Hg

C) 46 mm Hg

D) 50 mm Hg

Q19. In an experiment, 15 g of mannitol was dissolved in 85 g of water, and the freezing point of the
solution decreased by 0.465 °C. Calculate the molar mass of mannitol. (Kf for water = 1.86 °C
kg/mol)

A) 752 g/mol

B) 608 g/mol

C) 706 g/mol

D) 680 g/mol
Q20. The Van't Hoff factor of a 0.1 M solution of KCl that shows 85% dissociation is:

A) 1.85

B) 1.90

C) 1.92

D) 2.00

Answers LEVEL 1

Q1 Q2 Q3 Q4 Q5 Q6 Q7 Q8 Q9 Q10

A B A B A A A C A A

Q11 Q12 Q13 Q14 Q15 Q.16 Q.17 Q.18 Q.19 Q.20

B B B A A B D A C A
 LEVEL-2
Q1. A solution contains 1.5 moles of a non-volatile solute in 500 g of benzene (molar mass of
benzene = 78 g/mol). Calculate the relative lowering of vapor pressure of benzene. (Vapor pressure
of pure benzene = 100 mm Hg)

A) 0.073

B) 0.082

C) 0.095

D) 0.189

Q2. Calculate the mole fraction of ethanol in the vapor phase when a solution containing 0.4 mole of
ethanol and 0.6 mole of water reaches equilibrium. (Vapor pressures: Ethanol = 44 mm Hg, Water =
55 mm Hg)

A) 0.42

B) 0.34

C) 0.48

D) 0.50

Q3. A solution has a boiling point elevation of 0.520°C. If the ebullioscopic constant (Kb) of the
solvent is 0.52 °C kg/mol, calculate the molality of the solution.

A) 0.5 m

B) 1.0 m

C) 1.5 m

D) 2.0 m

Q4. In a solution containing 1 mole of Na₂SO₄ dissolved in 1 kg of water, calculate the Van't Hoff
factor assuming complete dissociation.

A) 2

B) 2.5

C) 3

D) 3.5

Q5. Determine the molar mass of an unknown solute if 15 g dissolved in 250 g of water decreases
the freezing point by 1.24 °C. (Kf for water = 1.86 °C kg/mol)

A) 93.2g/mol

B) 77.2 g/mol

C) 89.8 g/mol
D) 79.2 g/mol

Q6. A solution of a volatile solute in water exhibits a vapor pressure of 22.5 mm Hg at 298 K. If the
vapor pressure of pure water is 24 mm Hg, calculate the mole fraction of the solute in the solution.

A) 0.0625

B) 0.067

C) 0.083

D) 0.042

Q7. Calculate the osmotic pressure of a solution containing 10 g of glucose (C₆H₁₂O₆) in 1 L of water
at 25 °C. (R = 0.0821 L atm K⁻¹ mol⁻¹)

A) 0.227 atm

B) 1. 36 atm

C) 0.275 atm

D) 0.302 atm

Q8. In a solution with 0.1 m acetic acid and 0.05 m NaOH, determine the pH if pKa of acetic acid is
4.75.

A) 4.75

B) 4.95

C) 5.05

D) 5.25

Q9. Which of the following would increase the solubility of CaF₂ in water?

A) Adding NaF

B) Adding CaCl₂

C) Adding HCl

D) Adding NaOH

Q10. A solution containing 0.1 M of HCl has a Van't Hoff factor of 1.9. Calculate the degree of
dissociation (α) of HCl.

A) 0.90

B) 0.85

C) 0.95

D) 0.80
Answers LEVEL 2

Q1 Q2 Q3 Q4 Q5 Q6 Q7 Q8 Q9 Q10

D B B C C A B A C A