Solutions

Question1
Arrange the following compounds in increasing order of their solubilities in chloroform: NaCl, CH3OH, cyclohexane,
CH3CN

Options:

A. NaCl < CH3CN < CH3 OH < Cyclohexane

B. CH3 OH < CH3 CN < NaCl < Cyclohexane

C. NaCl < CH3 OH < CH3 CN < Cyclohexane

D. Cyclohexane < CH3 CN < CH3 OH < NaCl

Question2
Mass of glucose (C6H12O6) required to be dissolved to prepare one litre of its solution which is isotonic
with 15gL−1 solution of urea (NH3CONH2) is (Given: Molar mass in gmol−1 C : 12, H : 1, O : 16,
N : 14 )

Options:
A 55 g

B 15 g

C 30 g

D 45 g

Question3
The Henry's law constant (KH) values of three gases (A, B, C) in water are 145,2 × 10−5 and 35 kbar,
respectively. The solubility of these gases in water follow the order:

Options:

A. B>A>C

B. B>C>A

C. A>C>B

D. A>B>C

Question4
During the preparation of Mohr's salt solution (Ferrous ammonium sulphate), which of the following acid is
added to prevent hydrolysis of Fe2* ion?

Options:
 A. dilute hydrochloric acid

B. concentrated sulphuric acid

C. dilute nitric acid

D. dilute sulphuric acid

Question5
The plot of osmotic pressure ( Π ) vs concentration (mol L−1) for a solution gives a straight line with slope
25.73L barmol−1. The temperature at which the osmotic pressure measurement is done is

(Use R = 0.083L barmol−1K−1)

Options:

A. 37∘C

B. 310∘C

C. 25.73∘C

D. 12.05∘C

Question6
Which amongst the following aqueous solution of electrolytes will have minimum elevation in boiling
point? Choose the correct option :-

Options:

A. 0.05M NaCl

B. 0.1M KCl

C. 0.1MMgSO4

E. 1M NaCl

Question7
In one molal solution that contains 0.5 mole of a solute, there is

Options:

A. 500mL of solvent

B. 500g of solvent

C. 100mL of solvent

D. 1000g of solvent

Question8
The density of the solution is 2.15gmL−1, then mass of 2.5 mL solution in correct significant figures is :
Options:

A. 53.75g
B. 5375 × 10−3g
C. 5.4g
D. 5.38g

Question9

where KH is Henry's Law constant in water. The order of their solubility in water is:

Options:

A. HCHO < CH4 < CO2 < Ar

B. Ar < CO2 < CH4 < HCHO

C. Ar < CO2 < CH4 < HCHO

D. HCHO < CO2 < CH4 < Ar

Question10
The following solutions were prepared by dissolving 10g of glucose (C6H 12O6) in 250ml of water (P1), 10g
of urea (CH 4N 2O) in 250ml of water (P2) and 10g of sucrose (C12H 22O11) in 250ml of water (P3). The
right option for the decreasing order of osmotic pressure of these solutions is :

Options:

A. P2 > P1 > P3

B. P1 > P2 > P3

C. P2 > P3 > P1

D. P3 > P1 > P2

Question11
The correct option for the value of vapour pressure of a solution at 45°C with benzene to octane in molar
ratio 3 : 2 is : [At 45°C vapour pressure of benzene is 280 mm Hg and that of octane is 420 mm Hg. Assume
Ideal gas]

Options:

A. 160 mm of Hg
B. 168 mm of Hg

C. 336 mm of Hg

D. 350 mm of Hg

Question12
The mixture which shows positive deviation from Raoult's law is

Options:

A. Benzene + Toluene

B. Acetone + Chloroform

C. Chloroethane + Bromoethane

D. Ethanol+ Acetone

Question13
The freezing point depression constant (K f ) of benzene is 5.12K kgmol −1. The freezing point depression
for the solution of molality 0.078m containing a non-electrolyte solute in benzene is (rounded off upto two
decimal places) :
Options:

A. 0.80K

B. 0.40K

C. 0.60K

D. 0.20K

Question14
For an ideal solution, the correct option is

Options:

A. ΔmixG = 0 at constant T and P

B. ΔmixS = 0 at constant T and P

C. ΔmixV ≠ 0 at constant T and P

D. ΔmixH = 0 at constant T and P.

Question15
The mixture that forms maximum boiling azeotrope is
(NEET 2019)

Options:
A. heptane + octane

B. water + nitric acid

C. ethanol + water

D. acetone + carbon disulphide.

Question16
Which of the following statements is correct regarding a solution of two components A and B exhibiting
positive deviation from ideal behaviour?

Options:

A. Intermolecular attractive forces between A − A and B − B are stronger than those between
A−B

B. ΔmixH = 0 at constant T and P.

C. Δ mixV = 0 at constant T and P.

D. Intermolecular attractive forces between A − A and B − B are equal to those between A − B.

Question17
In water saturated air, the mole fraction of water vapour is 0.02. If the total pressure of the saturated air is
1.2 atm, the partial pressure of dry air is
Options:

A. 1.18 atm

B. 1.76 atm

C. 1.176 atm

D. 0.98 atm.

Answer: C

Question18
If molality of the dilute solution is doubled, the value of molal depression constant (K f ) will be

Options:

A. halved

B. tripled

C. unchanged

D. doubled.

Question19
Which of the following is dependent on temperature?
Options:

A. Molarity

B. Mole fraction

C. Weight percentage
D. Molality

Question20
The van't Hoff factor (i) for a dilute aqueous solution of the strong electrolyte barium hydroxide is

Options:

A. 0

B. 1

C. 2

D. 3

Question21
Which one of the following is incorrect for ideal solution?
Options:

A. ΔH mix = 0

B. ΔU mix = 0

C. ΔP = Pobs − Pcalculated by Raoult′ s law = 0

D. ΔGmix = 0

Question22
Which of the following statements about the composition of the vapour over an ideal 1: 1 molar mixture of
benzene and toluene is correct? Assume that the temperature is constant at 25°C. (Given, vapour pressure
data at 25°C, benzene = 12.8 kPa, toluene = 3.85 kPa )

Options:

A. The vapour will contain equal amounts of benzene and toluene.

B. Not enough information is given to make a prediction.

C. The vapour will contain a higher percentage of benzene.

D. The vapour will contain a higher percentage of toluene.

Question23
At 100°C the vapour pressure of a solution of 6.5g of a solute in 100g water is 732 mm. If K b = 0.52, the
boiling point of this solution will be
Options:

A. 102°C

B. 103°C

C. 101°C
D. 100°C

Question24
What is the mole fraction of the solute in a 1.00 m aqueous solution?
Options:

A. 1.770
B. 0.0354

C. 0.0177

D. 0.177

Question25
Which of them is not equal to zero for an ideal solution?

Options:

A. ΔV mix

B. ΔP = Pobserved − PRaoult

C. ΔH mix

D. ΔSmix

Question26
Which one of the following electrolytes has the same value of van’t Hoff factor (i) as that of Al 2(SO4)3 (if
all are 100% ionised) ?
Options:

A. Al (N O3)3
B. K 4[F e(CN )6]

C. K 2SO4

D. K 3[F e(CN )6]

Question27
−1
The boiling point of 0.2 mol kg solution of X in water is greater than equimolar solution of Y in water.
Which one of the following statements is true in this case?
Options:

A. Molecular mass of X is less than the molecular mass of Y

B. Y is undergoing dissociation in water while X undergoes no change.

C. X is undergoing dissociation in water

D. Molecular mass of X is greater than the molecular mass of Y.

Question28
Of the following 0.10 m aqueous solutions, which one will exhibit the largest freezing point depression?

Options:

A. KCl
B. C6H 12O6

C. AL2(SO4)3

D. K 2SO4

Question29
How many grams of concentrated nitric acid solution should be used to
prepare 250 mL of 2.0 M H N O3? The concentrated acid is 70% H N O3
Options:

A. 70.0g conc. H N O3

B. 54.0g conc. H N O3

C. 45.0g conc. H N O3

D. 90.0g conc. H N O3

Question30
Vapour pressure of chloroform (CH Cl 3) and dichloromethane (CH 2Cl 2) at 25°C are 200 mm Hg and 41.5
mm Hg respectively. Vapour pressure of the solution obtained by mixing 25.5 g of CH Cl 3 and 40 g of CH
2Cl 2 at same temperature will be (Molecular mass of CH Cl 3 = 119.5 u and
molecular mmass of CH 2Cl 2 = 85u

Options:

A. 173.9 mm Hg

B. 90.63 mm Hg

C. 347.9 mm Hg

D. 285.5 mm Hg

Question31

PA and PB are the vapour pressure of pure liquid components, A and B,

respectively of an ideal binary solution. If xA represents the mole
fraction of component A,the total pressure of the solution will be
(2012)

Options:
A. PA + xA(PB − PA)
B. PA + xA(PA − PB)

C. PB + xA(PB − PA)

D. PB + xA(PA − PB)

Question32

200 mL of an aqueous solution of a protein contains its 1.26 g. The −1 osmotic pressure of this solution at
300 K is found to be 2.57x10 b1 −1 The molar mass of protein will be(R = 0.083 L bar mol − K ).

Options:

A. 51022 g mol −1
−1
B. 122044 g mol
−1
C. 31011 g mol

D. 61038 g mol −1

Question33
A 0.1 molal aqueous solution of a weak acid is 30% ionized.If K f for water is 1.86° m ,the freezing point of
the solution will be
Options:

A. -0.18°C

B. -0.54°C

C. -0.36°C

D. -0.24°C

Question34
Mole fraction of the solute in a 1.00 molal aqueous solution is
Options:

A. 0.1770

B. 0.0177

C. 0.0344

D. 1.7700
Question35
The van’t Hoff factor i for a compound which undergoes dissociation in one solvent and association in
other solvent is respectively

Options:
A. less than one and greater than one

B. less than one and less than one

C. greater than one and less than one

D. greater than one and greater than one

Question36
The freezing point depression constant for water is = 1.86°Cm−1.If 5.00gN a2SO4 is dissolved in 45.0gH 2O,
the freezing point is changed by -3.82°C. Calculate the van’t Hoff factor for N aSO4
Options:

A. 2.05

B. 2.63
C. 3.11

D. 0.381

Question37
−1
A solution of sucrose (molar mass = 342gmol ) has been prepared by dissolving 68.5 g of sucrose in 1000 g
of water. The freezing point of the solution obtained will be (K f for water = 1.86K kg mol−1.
Options:

A. −0.372°C

B. −0.520°C

C. +0.372°C

D. −0.570°C

Question38
An aqueous solution is 1.00 molal in KI. Which change will cause the vapour pressure of the solution to
increase?
Options:

A. Addition of NaCl

B. Addition of N a2SO4

C. Addition of 1.00 molal KI

D. Addition of water

Question39
A 0.0020 m aqueous solution of an ionic compound [Co(N H 3)5(N O2)]Cl freezes at −0.00732°C,Number of
moles of ions which 1 mol of ionic compound produces on being dissolved in water will be
(K fC= −1.86° m )
Options:

A. 3

B. 4

C. 1

D. 2

Question40
0.5 molal aqueous solution of a weak acid (HX) is 20% ionised. If K f for water is 1.86K kg mol−1, the
lowering in freezing point of the solution is
Options:

A. 0.56 K

B. 1.12 K

C. -0.56 K

D. -1.12 K

Answer: B

Question41
Concentrated aqueous sulphuric acid is 98% H 2SO4 by mass and has a density of 1.80gmL−1. Volume of
acid required to make one litre of 0.1M H 2SO4 solution is
Options:

A. 16.65 mL

B. 22.20 mL

C. 5.55 mL

D. 11.10 mL
Question42
During osmosis, flow of water through a semipermeable membrane is-
Options:

A. from solution having lower concentration only

B. from solution having higher concentration only

C. from both sides of semipermeable membrane with equal flow rates

D. from both sides of semipermeable membrane with unequal flow rates.

Question43
A solution of acetone in ethanol
Options:

A. obeys Raoult’s law

B. shows a negative deviation from Raoult’s law

C. shows a positive deviation from Raoult’s law

D. behaves like a near ideal solution.

Question44
1.00 g of a non-electrolyte solute (molar mass 250gmol−1 ) was dissolved in 51.2 g of benzene. If the
freezing point depression constant, −1 K f of benzene is 5.12 K kg mol , the freezing point of benzene will
belowered by
Options:

A. 0.2 K

B. 0.4 K

C. 0.3 K

D. 0.5 K

Question45
A solution containing 10 g per d m3 of urea (molecular mass = 60 g mol−1) is isotonic with a 5% solution of
a non volatile solute is
Options:

A. 200gmol−1
B. 250gmol−1

C. 300gmol−1
−1
D. 350gmol

Question46
The mole fraction of the solute in one molal aqueous solution is
Options:

A. 0.009

B. 0.018

C. 0.027

D. 0.036

Question47
The vapour pressure of two liquids P and Q are 80 and 60 torr, respectively. The total vapour pressure of
solution obtained by mixing 3 mole of P and 2 mol of Q would be
Options:
A. 72 torr

B. 140 torr

C. 68 torr

D. 20 torr

Question48
A solution has a 1: 4 mole ratio of pentane to hexane. The vapour pressures of the pure hydrocarbons at
20°C are 440 mm Hg for pentane and 120 mm Hg for hexane. The mole fraction of pentane in the vapour
phase would be
(2005)
Options:

A. 0.200

B. 0.549

C. 0.786

D. 0.478
Question49

A solution of urea (mol. mass 56gmol ) boils at 100.18°C at the atmospheric pressure. If K f and K b for
water are 1.86 and 0.512K kg mol respectively, the above solution will freeze at
Options:

A. 0.654°C

B. −0.654°C

C. 6.54°C

D. −6.54°C
Question50
A solution containing components A and B follows Raoult's law
Options:

A. A − B attraction force is greater than A − A and B − B

B. A − B attraction force is less than A − A and B − B

C. A − B attraction force remains same as A − A and B − B

D. volume of solution is different from sum of volume of solute and solvent.