ZEEMAN तक DPP - 11 20th MAY 2025

CHEMISTRY TAUSIF AHMAD Structure of Atom - 11

1. I f E e ,E  & E p r epr esent t he kinet ic ener gies of 8. If the de-Broglie’s wavelength of a particle of mass m is
25 times its velocity, then this wavelength is
an el ect r on , al ph a par t i cl e & a pr ot on
1 h h
r espect ively, each moving wit h same de-Br oglie (a) (b) 5
5 m m
wavelengt h t hen
1 m m
(c) (d) 5
(a) E e  E   E p (b) E e  E p  E 5 h h

(c) E e  E p  E (d) E e  E  E p 9. How fast is an electron moving if it has a wavelength

equal to the distance it travels in one second ?
2. Which of the following equation was suggested (a)
h
(b)
m
(c)
h
(d)
h
by de Broglie? m h p 2(KE)
p 10. If radius of 2nd orbit is x then de Broglie wavelength
(1) 2r = n (2)  
h
in 4th orbit is given by
(3) r2
= n (4) 2r  nh (1) 8 x

(2) 2 x
3. The momentum of a particle which has a de Broglie
(3) 4 x
wavelength of 0.1 nm is (h = 6.6 × 10–34 Js)
(4) 6 x
(1) 3.2 × 10–24 kg ms–1
11. Calculate the wavelength in nanometer associated with a
(2) 4.3 × 10–22 kg ms–1 proton moving at 1 × 103 ms −1 (mass of proton
(3) 5.3 × 10–22 kg ms–1 = 1.67 × 10−27 kg and h = 6.63 × 10−34 Js)
(a) 0.032 nm (b) 0.40 nm
(4) 6.62 × 10–24 kg ms–1
(c) 2.5 nm (d) 14 nm
4. For a microscopic object x is zero than v will
be (According to Heisenberg's principle) 12. In an atom, an electron is moving with a speed of 600 ms−1
(1) Zero with an accuracy of 0.05%. Certainity with which the
position of the electron can be located is
(2) Infinite
(h = 6.6 × 10−34 kg m 2s −1 , mass of electron,
(3) 10–23
e m = 9.1× 10−31 kg)
(4) 108
(a) 1.52 × 10−4 m (b) 5.10 × 10−3 m
5. U ncer t ai nt y i n t he posi t i on of an el ect r on i f (c) 1.92 × 10−3 m (d) 3.84 × 10−3 m
v = 3 10– 2 ms– 1 is
13. Uncertainty in the position of an electron
(mass = 9.1 × 10−31 kg) moving with a velocity 300 ms −1 ,
(a) 1.92  10 2
m
accurate upto 0.001% will be (h = 6.63 × 10−34 Js)
(b) 19.2  10 3 m
(a) 19.3 ×10−2 m (b) 5.76 × 10−2 m
(c) 6  104 m (c) 1.93 × 10−2 m (d) 3.84 × 10−2 m

(d) 1.1  1011 m 14. The de-Broglie wavelength of a tennis ball of mass 60 g
6. Uncertainty in position of an electron moving with a moving with a velocity of 10 ms −1 is approximately
velocity of 3 × 102 m s −1 accurate upto 0.001% will be (Planck’s constant, h = 6.63 × 10−34 Js)
(a) 0.0193 m (b) 0.0384 m (a) 10−33 m
(c) 0.0576 m (d) 0.0768 m
(b) 10−31 m
7. Speed of an electron of wavelength 3 cm is
(c) 10−16 m
−1
(a) 243 m s −1 (b) 24.3 m s
(d) 1025 m
(c) 0.243 m s −1 (d) 0.0243 m s −1

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ZEEMAN DPP 11 ANSWER KEY
Question 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Answer b a d b b b d b a b b c c a
1st FLOOR , DAYAL MEDICAL STORE, NAVAL KISHORE ROAD, HAZRATGANJ. LUCKNOW 7238010103, 9199880090
For Detail Solutions, Visit ZEEMAN CHEMISTRY app.
 ZEEMAN CHEMISTRY BY TAUSIF AHMAD

Solution
2. Sol. Answer (1) 8. (b) λ =
h
mv
Circumference = n Given, λ = 25v
λ
2r = n ∴ v=
25
h
3. Sol. Answer (4) ∴ λ=
λ
m  

 = 0.1 × 10–9 m  25 
h
h = 6.6 × 10–34 ∴ λ2 = 25
m
h h λ = 25 = 5
h h
  m m
mv p
h
6.6  10 34 9. (a) de-Brogle’s wavelength, h =
mv
 10–10 =
p velocity = v m s−1
Then, distance travelled in 1s = vm
p = 6.6 × 10–24 kg ms–1 v
∴ λ=v=
mv
4. Sol. Answer (2) h
∴ v2 =
h m
x, m.v  h
4 ∴ v=
m

10. Sol. Answer (2)

h
5. (b) x. V =
4 m r2 = x
0.005
V =  600  3  10 2 M J 1 r1 
x 4x
100  and r4   2x
2 2
h 6.626  1034 2r = n
x  
4xm V 4  3.14  9.1  10 31  3  10 2
 n = 2 × 2x [n = 2]
x  1.92  10 3
M  = 2x
h 6.63 × 10− 34
6. (a) By Heisenberg’s uncertainty 11. (b) λ = =
h mv 1.67 × 10− 27 × 1 × 103
principle, ∆x⋅ ∆p ≥
4π = 3.97 × 10− 10 m
h
∆x⋅ m∆v ≥ = 0.397 × 10−9 m
4π
h ≈ 0.40 nm
∆x⋅ ∆v ≥
4 πm 12. (c) By Heisenberg’s uncertainty principle,
0.001 h
∆v = 3 × 102 × ∆ x⋅ m∆v =
100 4π
= 3 × 10−3 m s−1 Also, ∆v =
600 × 0.005
= 0.03 m s−1
6.626 × 10−34 Js 100
∴∆x= 6.6 × 10−34
4 π × 3 × 10−3 m s−1 × 9.1 × 10−31 kg ∆ x × 9.1 × 10− 31 × 0.03 =
4 × 3.14
= 0.0193 m
6.6 × 10−34
■ 1 J = 1kg m2 s −2 Hence, ∆x=
4 × 3.14 × 0.03 × 9.1× 10−31
7. (d) de-Broglie’s wavelength, = 1.92 × 10− 3 m
h
λ= ■ 1 J = 1 kg m2 s –2
mv h
h 6.626 × 10−34 Js 13. (c) ∆x⋅ ∆v ≥
∴ v= = 4 πm
mλ 9.1 × 10−31 kg × 0.03 m ∆v = 300 × 0.001 × 10− 2 m s− 1
−1
= 0.0243 m s 6.63 × 10− 34
∆x =
■ 2
1 J = 1 kg m s −2
4 × 3.14 × 9.1 × 10−31× 300 × 0.001 × 10−2
= 0.01933
= 1.93 × 10− 2 m
1ST FLOOR , DAYAL MEDICAL STORE, NAVAL KISHORE ROAD, HARATGANJ. LUCKNOW 7238010103, 9199880090
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 ZEEMAN CHEMISTRY BY TAUSIF AHMAD
(a) Wavelength associated with the
14. velocity of tennis ball
h
λ= = 1.105 × 10− 33 m
mv

1ST FLOOR , DAYAL MEDICAL STORE, NAVAL KISHORE ROAD, HARATGANJ. LUCKNOW 7238010103, 9199880090
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