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UnknownAnalysis CONSEBIDO

This document provides instructions for cation and anion analysis using various reagents. It lists reagents to add for each potential cation or anion and observations to look for such as color changes or precipitate formation that would indicate the presence of that ion. The goal is to determine what cations and anions are present in a solution by following the procedure and observing the results.

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Alfrie Carlo Consebido
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© Attribution Non-Commercial (BY-NC)
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268 views2 pages

UnknownAnalysis CONSEBIDO

This document provides instructions for cation and anion analysis using various reagents. It lists reagents to add for each potential cation or anion and observations to look for such as color changes or precipitate formation that would indicate the presence of that ion. The goal is to determine what cations and anions are present in a solution by following the procedure and observing the results.

Uploaded by

Alfrie Carlo Consebido
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOC, PDF, TXT or read online on Scribd
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LEGEND: Blue - Anion Red - Cation H+ - Acidify OH- - Make Alkaline UC Add until precipitation is complete X add in a few

ew drops in excess C Centrifuge S keep supernate

CONSEBIDO, Alfrie Carlo F. Chem 17 WFR/WFUV2 ANION ANALYSIS CH3COOH [3M]H+X + Heat + CaCl2 [0.1M, 1drp]UC
Yes
White Precipitate?

2010-00760 Experiments 12 and 13

No

C2O42Yes

HCl [3M]H++ BaCl2 [0.1M, 1drp]UC


White Precipitate?

No

SO42Yes
White Precipitate?

Magnesia Mixture
No

PO43Brown Solution?

MnCl2H2O in 12M HCl [saturated, 5drps]


No

Yes

CrO42- = CH3COOH [3M]H+X + Warm + BaCl2 [0.1M, 1drp]UC = Yellow NO3- = H2SO4 [6M, 1drp]H+ + FeSO4[0.1M, 3drps] + H2SO4 [18M, 2drps] = Brown Ring
Prussian Blue Precipitate?

HCl [3M]H+ + K3Fe(CN)6 [0.1M, 1drp] + FeCl3 [0.1M, 1drp]


Yes No

S2- = H2SO4 [6M, 2drps] + Warm = rotten egg smell S2O3 = H2SO4 [6M, 2drps] + Warm = burnt rubber smell, milky yellowish precipitate I = HNO3 [3M, 2drps] + FeCl3 [0.1M, 3drps] + toluene [6drps] = pink non-aqueous layer
2-

H2SO4 [6M;2drps] + Warm


Vinegar Smell?

Yes

No Yes

Effervescence

CH3COOBlood Red Solution?

No

CO32Yes

FeCl3 [0.1M, 3drps] + Warm


No

CNS-

Br- = (HNO3 [3M, 2drps] H++ KMnO4 [0.01M, 1drp] + toluene [6drps] = yellow non-aqueous layer

Cl- = HNO3 [3M] H+ + Heat + AgNO3 [0.1M, 1drp]UCCW + NH3 [3M, 1mL]= white precipitate

CATION ANALYSIS HCl [6M, 1drp]UC


Yes
White Precipitate?

No

Ag+
Yes
White Precipitate?

NH4NO3 [3M, 2drps] + NH3 [6M]OH- + (NH4)2CO3 [1.5M, 5drps]C


No

Ba2+ = K2CrO4 [1M]UC = yellow precipitate Ca2+ = (NH4)2C2O4 [0.1M;2drps] UC = white precipitate Mg2+ = (NH4)2CO3 [1.5M, 5drps] + HCl [1M] H+ + (NH4)2HPO4 [1.5M, 5drps]= opaque white solution
Yes

KSCN [0.1M, 2drps]


Blood Red Solution?

No

Fe3+
Deep Blue Solution?

NH3 [3M]X
No

Yes

Cu2+
Red to Blue Litmus?

NaOH [3M, 2drps] then Litmus paper-Watch glass system cover


No

Yes

NH4+
Yellow Precipitate?

K3Fe(CN)6 [0.1M, 2drps]


No

Yes

Zn2+
Yes
Yellow Color?

NaOH[6M]OH- + H2O2 [3%]CCh


No

Cr3+
Yes

NaOH[3M]XCS + HNO3 [3M] H+ + (NH4CH3COO [3M] + aluminon reagent) [10drops] + NH3 [6M]OHRed Lake?

No

Al3+

Co2+ = CH3COOH [3M]H++ NaNO2 [pinch] + Warm = Yellow Crystals

NH3 [6M]XCS

Ni2+ = C4H8O2N2 [drops] = Cherry Red Precipitate

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