JAC BOARD EXAM PREVIOUS YEAR QUESTIONS CHAPTER : 01

SOLUTIONS
A. Very short answer type questions : (1 marks each questions )
1. Which of the following is not a solid solution ?
(a) Brass
(b) Bronze
(c) Hydrated salt
(d) Aerated drinks [2024]
2. What is the molality of a solution formed when 58.5 g of NaCl is
dissolved in 2000 ml (or 2000 g) of water ?
(a) 29.25 m
(b) 0.50 m
(c) 0.0005 m
(d) 0.2925 m [2024]
3. Which of the following is a colligative property ?
(a) Relative lowering of fluid pressure
(b) Decrease in boiling point
(c) Decrease in freezing point
(d) Change in volume after mixing [2024]
4. The molarity of the solution containing 5g of NaOH in 500 ml of
aqueous solution is :
(a) 1M
(b) 2.5M
(c) 0.25M
(d) 0.025M [2023]
5. Relative lowering in vapour pressure is equal to
(a) Molarity of solution
(b) Molality of solution
(c) Mole fraction of solute
(d) Mole fraction of solvent [2023]
6. A molal solution is one that contains one mole of a solute in
 (i) 1000g of solvent
(ii) 1 litre of solution
(iii) 1 litre of solvent
(iv) 22.4 litre of the solution [2022]
7. Relative lowering in vapour pressure of solution is equal to :
(i) Molarity of solution
(ii) Molality of solution
(iii) Mole fraction of solute
(iv) Mole fraction of solvent [2022]
8. Colligative properties of the solutions depend on
(i) Nature of the solution
(ii) Nature of the solvent
(iii) Number of solute particles
(iv) Number of moles of the solvent [2022]
9. The mole fraction of benzene in solution containing 30% by
mass in carbon tetrachloride is (molar mass of benzene = 78u
and molar mass of CCl4 = 154u)
(i) 0.556 (ii) 0.992 (iii) 0.459 (iv) 0.783 [2022]
10. The Normality of 0.2M aqueous solution of a dibasic acid is-
(a) 0.4N (b) 0.1N
(c) 0.8N (d) None of these [2016,2008]
11. The value of colligative properties of a solution increases
when solute molecules undergo-
(a) association (b) dissociation
(c) both (d) none of these [2016,2013]
12. Define parts per million (ppm). [2016]
13. Which of the following aqueous solution has the highest
boiling point ?
(a) 1 % Glucose
(b) 1% Sucrose
 (c) 1% NaCl
(d) 1% CaCl2 [ 2015 ]
14. What will be the Van’t Hoff factor value for dilute aq.
Solution of BaCl2. [2009]
15. State Raoult’s law for non-volatile solute. [2007]
16. Define (a) Molarity (b) Molality [2006]
B. Short answer type questions : (2 marks each questions )
1. 6.02 x 1020 molecules of urea are present in 100 ml of its
solution. What is the concentration of the urea solution ?
[2017]
2. Distinguish between molarity and molality. [ 2017 ]
3. Write Raoult’s law for relative lowering of vapour pressure of
solutions containing
(a) Non-volatile solute (b) volatile solute [2013]
4. Differentiate between molarity and molality of a solution. What
is the effect change in temperature of a solution on its molarity
and molality ? [ 2011 ]
5. What are Isotonic solution ? Give an example. [2009]
C. Short answer type questions : ( 3 marks each question )
1. Define the following :
i) Molality
ii) Mole fraction [ 2024 ]
2. The vapour pressure of pure benzene at a certain temperature
is 0.850 bar. A non volatile, non electrolyte solid weighing 0.5 g
is added to 39.0 g of benzene (molar mass 78 g mol-1). The
vapour pressure of the solution obtained is 0.845 bar. What is
the molar mass of the solid substance ? [2023]
3. Define the following terms :
(i) Molarity (ii) Molality (iii) Mole fraction [2015]
 4. Find out the volume in mL of 0.1M HCl required to completely
neutralize 1g mixture of Na2CO3 and NaHCO3 containing equal
number of moles of NaHCO3. [2015]
5. 5% urea solution is isotonic with 12.5 % solution of an organic
compound. If the molecular mass of that organic compound.
[2013]
6. Calculate the osmotic pressure at 25 C of a 6% solution of Urea.
(M.W.=60 and R=0.082 L.atm/degree/mole.) [2011]
7. 45g of ethylene glycol (C2H6O2) is mixed with 600g of water.
Calculate- (a) the freezing point depression and (ii) the freezing
point of the solution. [2010]
8. At 298K, the vapour pressure of water is 23.75 mm of Hg.
Calculate the vapour pressure at the same temperature over
5% aqueous solution of urea. ( Molecular wt. of urea= 60)
[2008]
9. A solution of 12.5g urea in 170g of water gave a boiling point
elevation of 0.63K. calculate the molecular weight of urea
taking Kb= 0.52 K/m. [2007]
10. Define colligative properties of dilute solution. Write down
differet types of colligative properties. [2006]
D. Long answer type questions : ( 5 marks each question )
1. Calculate the mass of ascorbic acid ( vitamin c , C6H8O6 ) to be
dissolved in 75 g of acetic acid to lower its melting point by
1.5oC. Kf = 3.9 K.Kg.mol-1 [2024]
2. An antifreeze solution is prepared from 222.6 g of ethylene
glycol , C2H4(OH)2 and 200 g of water. Calculate the molality of
the solution. If the density of the solution is 1.072 g/ml, then
what shall be the molarity of the solution ? [ 2020,2018 ]
3. Vapour pressure of water at 293K is 17.535 mm Hg. Calculate
the vapour pressure of water at 293K when 25g of glucose is
dissolved in 450g of water. [2019]
 4. Discuss the following :
(i) Osmosis (ii) Osmotic pressure (iii) Semi-permeable
membrane [2014]
5. Boiling point of water at 750 mm Hg is 96.63 C. How much
sucrose (C12H22O11) is to be added to 500g of water such that it
boils at 100 C ? Molal elevation constant for water is 0.52
Kkg/mol. [2014]
6. (i) Define colligative properties of dilute solution. (ii) The vapour
pressure of 2% aqueous solution of non-volatile substance X at
373K is 755 torr. Calculate molar mass of the solute. Vapour
pressure of water at 373K as 760 torr. [2012]

ALL THE BEST…

YOUTUBE LINK : https://youtube.com/@CreativeclassesbyAmitkk

YOU CAN FOLLOW ME

CREATIVE CLASSES BY AMIT KK amit.kumarkk.9

CREATIVE CLASSES BY AMIT KK
creativeclassesbyamitkk

AMIT KUMAR KK 9507056168

amithzb825311@gmail.com
CREATIVE CLASSES BY AMIT KK
(only message)

By : Amit Sir ( Department of chemistry )