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Topic:-: Solutions

This document provides a chemistry practice test with 20 multiple choice questions covering topics related to solutions. Some of the topics addressed include osmotic pressure, vapor pressure, freezing point depression, and colligative properties. The questions require calculations and understanding of concepts such as Raoult's law, Henry's law, and ideal and non-ideal solutions.

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38 views3 pages

Topic:-: Solutions

This document provides a chemistry practice test with 20 multiple choice questions covering topics related to solutions. Some of the topics addressed include osmotic pressure, vapor pressure, freezing point depression, and colligative properties. The questions require calculations and understanding of concepts such as Raoult's law, Henry's law, and ideal and non-ideal solutions.

Uploaded by

Gnaneshwar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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CLASS : XIth SUBJECT : CHEMISTRY

DATE : DPP No. : 6

Topic :-SOLUTIONS

1. Osmotic pressure of a solution at a given temperature


a) Increases with concentration b) Decreases with concentration
c) Remains same d)Initially increases and then decreases

2. A solution has a 1 : 4 mole ratio of pentane to hexane. The vapour pressures of pure
hydrocarbons at 20 C are 440 mm Hg for pentane and 120 mm Hg for hexane. The mole
fraction of pentane in vapour phase would be :
a) 0.786 b) 0.549 c) 0.478 d)0.200

3. Distribution law cannot be applied for the system in which I2 is distributed between :
a) H2O and CS2
b) H2O and CCl4
c) H2O and ether
d) H2O and ethanol

4. The vapour pressure of pure liquid A is 0.80 atm. When a non-volatile B is added to A its
vapour pressure drops to 0.60 atm. The mole fraction of B in the solution is
a) 0.125 b) 0.25 c) 0.5 d)0.75

5. When a non-volatile solute is dissolved in a solvent, the relative lowering of vapour pressure is
equal to
a) Mole fraction of solute
b) Mole fraction of solvent
c) Concentration of the solute in gram per litre
d)Concentration of the solute in gram per 100 mL

6. The freezing point of one modal NaCl solution assuming NaCl to be 100 % dissociated in water
is (modal depression constant=1.86)
a) ―2.72℃ b) ―3.72℃ c) 2.72℃ d)3.72℃
7. On mixing, heptane and octane form an ideal solution. At 373 K, the vapour pressures of the
two liquid components (heptanes and octane) are 105 kPa and 45kPa respectively. Vapour
pressure of the solution obtained by mixing 25 g of heptanes and 35 g of octane will be (molar
mass of heptanes = 100 g 𝑚𝑜𝑙―1 and of octane = 114 g𝑚𝑜𝑙―1).
a) 72.0 kPa b) 36.1 kPa c) 96.2 kPa d)144.5 kPa

8. The van’t Hoff factor of BaCl2 at 0.01 M concentration is 1.98. The percentage of dissociation of
BaCl2 at this concentration is
a) 49 b) 69 c) 89 d)98

9. The relative lowering of vapour pressure of an aqueous solution containing non-volatile solute
is 0.0125. The molality of the solution is
a) 0.70 b) 0.50 c) 0.60 d)0.80

10. An aqueous solution of glucose was prepared by dissolving 18 g of glucose in 90 g of water. The
relative lowering in vapour pressure is
a) 0.01 b) 0.02 c) 1 d)20

11. In a 0.2 molal aqueous solution of a weak acid HX, the degree of ionisation is 0.3 Taking 𝑘𝑓 for
water as 1.85, the freezing point of the solution will be nearest to
a) MeV b) Cal c) Cm/s d)Atm

12. The unit of molality is


a) mol 𝐿―1 b) mol 𝑘𝑔―1 c) 𝑚𝑜𝑙―1 𝐿―1 d)mol L

13. An azeotropic solution of two liquids has boiling point lower than either when it
a) Shows a negative deviation from Raoult’s lawb) Shows a positive deviation from Raoult’s law
c) Shows no deviation from Raoult’s law d)Is saturated

14. The statement, “The mass of a gas dissolved in a given mass of a solvent at any temperature is
proportional to the pressure of the gas above the solvent” is
a) Henry’s law b) Law of mass action c) Dalton’s law d)None of these

15. The freezing point of water is depressed by 0.37℃ in a 0.01 mol NaCl solution. The freezing
point of 0.02 molal solution of urea is depressed by
a) 0.37℃ b) 0.74℃ c) 0.185℃ d)0℃

16. A solution of protein (extracted from crabs) was prepared by dissolving 0.75 g in 125 cm3 of an
aqueous solution. At 4 C an osmotic pressure rise of 2.6 mm of the solution was observed. Then
molecular weight of protein is : (Assume density of solution is 1.00 g/cm3)
a) 9.4 × 105 b) 5.4 × 105 c) 5.4 × 1010 d)9.4 × 1010
17. 2 N HCl solution will have same molar concentration as a
a) 4.0 N 𝐻2𝑆𝑂4 b) 0.5 N 𝐻2𝑆𝑂4 c) 1 N 𝐻2𝑆𝑂4 d) 2 N 𝐻2𝑆𝑂4

18. Molarity of a given orthophosphoric acid solution is 3 M. It’s normality is


a) 9N b) 0.3 N c) 3 N d)1 N

19. Which of the following is a colligative property?


a) Boiling point b) Freezing point c) Osmotic pressure d)Vapour pressure

20. A liquid is in equilibrium with its vapours at its boiling point. On the average the molecules in
the two phases have equal :
a) Potential energy
b) Total energy
c) Kinetic energy
d)Intermolecular forces

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