1

Lakshya JEE 2.0 (2023)

DPP-02
Atoms
1. Energy levels A, B, C of a certain atom corresponding 7. An electron makes a transition from orbit n = 4 to the
to increasing values of energy i.e. EA < EB < EC . If λ1, orbit n = 2 of a hydrogen atom. The wave number of
λ2, λ3 are the wavelengths of radiations corresponding the emitted radiations (R = Rydberg's constant) will
to the transitions C to B, B to A and C to A respectively, be
which of the following statements is correct 16 2R
(1) (2)
3R 16
3R 4R
(3) (4)
16 16

1 2 8. Which of the following transitions in a hydrogen

(1) λ3 = λ1 + λ2 (2) λ3 =
1 +  2 atom emits photon of the highest frequency
(1) n = 1 to n = 2 (2) n = 2 to n = 1
(3) λ1 + λ2 + λ3 = 0 (4)  32 = 12 +  22
(3) n = 2 to n = 6 (4) n = 6 to n = 2
2. If the wavelength of the first line of the Balmer series
of hydrogen is 6561 Å, the wavelength of the second 9. The energy levels of a certain atom for first, second
line of the series should be E
and third levels are E, 4 and 2E respectively. A
(1) 13122 Å (2) 3280 Å 3
(3) 4860 Å (4) 2187 Å photon of wavelength λ is emitted for a transition
3 → 1. What will be the wavelength of emission for
3. What is the ratio of wavelength of radiations emitted transition 2 → 1?
when an electron in hydrogen atom jump from fourth

orbit to second orbit and from third orbit to second orbit (1) (2) 3λ
(1) 27 : 25 (2) 20 : 27 3
(3) 20 : 25 (4) 25 : 27 3 4
(3) (4)
4 3
4. The energy difference between the first two levels of
hydrogen atom is 10.2 eV. What is the corresponding
10. The radius of the orbit of an electron in a Hydrogen-
energy difference for a singly ionized helium atom?
(1) 10.2 eV (2) 20.4 eV like atom is 4.5a0 , where a0 is the Bohr radius. Its
(3) 40.8 eV (4) 81.6 eV 3h
orbital angular momentum is . It is given that h
2
5. The ratio of the wavelengths of the longest is Planck constant and R is Rydberg constant. The
wavelength lines in the Lyman and Balmer series of possible wavelength(s), when the atom de-excites, is
hydrogen spectrum is (are)
3 5 9 9
(1) (2) (1) (2)
23 27 32R 16R
7 9
(3) (4) 9 4
29 31 (3) (4)
5R 3R
6. A hydrogen atom is in an excited state of principle
quantum number n. It emits a photon of wavelength 11. An H-atom in its ground state is irradiated by light of
λ when returns to the ground state. the value of n is wavelength 970Å. Taking hc/e = 1.237 × 10–6 eVm
and the ground state energy of hydrogen atom as
R ( R − 1)
( R − 1) –13.6 eV, the number of lines present in the emission
(1) (2)
R spectrum is
R
(3) (4)  ( R − 1) (1) 4 (2) 6
R − 1 (3) 3 (4) 5
 2

Answer Key
1. (2) 7. (3)
2. (3) 8. (2)
3. (2) 9. (2)
4. (3) 10. (1, 3)
5. (2) 11. (2)
6. (3)

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