M.C.

Q class XI CHEMISTRY

Chapter 1
1. 10 g of hydrogen and 64 g of oxygen were filled in a steel vessel and exploded.
Amount of water produced in the reaction will be:
a. 3 mol
b. 4 mol
c. 2 mol
d. 1 mol
2. 200 mL of water is added to 500 mL of 0.2 M solution of HCl . What is the molarity
of the diluted solution
a. 0.5010 M
b. 0.2897 M
c. 0.7093 M
d. 0.1428 M
3. What is the mass % of Carbon in Carbon dioxide.
a. 0.034%
b. 27.27%
c. 3.4%
d. 28.7%
4. The empirical formula and molecular mass of a compound is CH2O and 180 g resp.
What is the molecular formula of the compound.
a. C9H18O9
b. CH2O
c. C6H12O6
d. C2H4O2

13. If water sample are taken from sea, rivers or lake, they will be found to contain hydrogen
and oxygen in the approximate ratio of 1 : 8.This indicates the law of :
a Multiple proportion
b Definite proportion
c Reciprocal proportions
d None of these
14. 20 g of an ideal gas contains only atoms of S and O occupies 5.6 L at NPT. What is
the mol. wt. of gas ?
a. 64
b 80
c 96
d None of these
15. One atom of an element weight 1.8* 10–22 g, its atomic mass is
a 29.9
b 18
c 108.36
d 154
16. How many molecules are present in one gram of hydrogen?
a 6.02 *´ 1023
b 3.01 *´ 1023
c 2.5 *´ 1023
d 1.5 *´ 1023
17. The mass percentage of oxygen in NaOH is
a 40
b 60
c 8
d 10
18. One mole of CO2 contains
a 6.02 *´ 1023 atoms of C
b 6.02 *´ 1023 atoms of O
c 18.1 *´ 1023 molecules of CO2
d 3 gram of carbon
19. What volume 0.8 M solution contains 0.1 mole of solute?
a 100 mL
b 125 mL
c 500 mL
d 0.125 mL

20. If 30 mL of hydrogen and 20 mL of oxygen reacts to form water, What is left at the
end of the reaction?
a. 10 mL of hydrogen
b. 10mL of oxygen
c. 5 mL of hydrogen
d. 5 mL of oxygen

Chapter 2 STRUCTURE OF ATOM

1. Two electrons occupying the same orbitals are distinguished by

a. Principal Quantum number
b. Magnetic quantum number
c. Azimuthal quantum number
d. Spin quantum number
2. The total number of atomic orbital in fourth energy level of an atom is
a. 16
b. 32
c. 4
d. 8
3 What is the maximum number of orbitals identified with the following quantum
numbers n-3, l= 1, m=0
a. 1
b. 2
c. 3
d. 4
4 Energy of the third orbit of Bohr’s atom is
a. -13.6eV
b. -3.4 eV
c. -1.5 eV
d. none of these
5 The number of unpaired electron in chromium (atomic number) is:
a. 2
b. 3
c. 5
d. 6
6 Magnetic quantum number specifies
a. Size of orbitals
b. shape of orbitals
c. Orientation of orbitals in space
d. nuclear stability
7 When the value of n=2 m can have:
a. 1 value
b. 3 value
c. 4 values
d. 7 values.
8. The correct set of quantum numbers for the unpaired electron of chlorine atom is
n l m
2 1 0
2 1 1
3 1 1
3 0 0

9. The speed of a 200 g golf ball is 5.0 metre per hour. The wavelength of this ball will b
of the order of
a. 10-10
b. 10-20
c. 10-30
d. 10-4
10. The isobars have:
a. Same atomic number
b. same number of neutrons
c. same number of electrons
d. same mass number
11. Maximum number of electrons in a subshell with l = 3 and n = 4 is
a. 12 and 4
b. 12 and 5
c. 16 and 4
d. 16 and 5
12. The maximum number of electron that can be accommodated in p-subshell is
a. 2
b. 6
c. 10
d. 14
13. For Balmer series the n1 is
a. 1
b. 3
c. 2
d. 4
14. Which of the following series lie in UV range of spectrum
a. Balmer series
b. Paschen series
c. Lyman series
d. Bracket series
15. The total energy of an electron in the nth orbit of a hydrogen atom is given by the
formula En = -13.6 eV/n2. What does the negative energy for an electron indicate?

a. Energy of electron in an atom is lower than energy of an electron far away from
nucleus
b. The electron has a negative charge.
c. The electron is far away from nucleus
d. Electrons have both wave and particle-like properties.

16. Which of the following is not true about Bohr’s model of the atom?

a. Electrons behave like waves and particles simultaneously.

b. Electrons revolve in discrete, quantized orbits only.
c. mvr = nh/ 2π
d. Atoms radiate discrete Electromagnetic energies only.

17. In the absorption spectrum, the wavelengths which are absorbed, are missing and
they appear as:
a. Bright lines
b. Light bands
c. Bright bands
d. Dark lines

18. For Paschen series, the initial state n1 is :

a. 2
b. 4
c. 3
d. 1
19. Zeeman effect is the splitting of spectral line in presence of:
a. electricity
b. magnetic effect
c. molecule
d. electric field

20. EM spectrum shows all forms of radiation except one of the followings:
a. X-rays
b. Infra red
c. Gamma Rays
d. Beta rays

CHAPTER-3 : PERIODIC CLASSIFICATION

Q.1 Which one of th following pairs would have a large size ?

(i) K or K+ (ii) Br or Br - (iii) O2- or F- (iv) Li+ or Na+ (v) P or As (vi) Na+ or Mg 2+

Ans (i) K (ii) Br - (iii) O2- (iv) Na+ (v) As (vi) Na+

Q.2 Which of the following pairs of elements would you expect to have lower first ionization
enthalpy ?

(i) Cl or F (ii) Cl or S (iii) K or Ar (iv) Kr or Xe

Ans (i) Cl (ii) S (iii) K (iv) Xe

Q.3 Predict the formulae of the stable binary compounds that would be formed by the
following pairs of elements :

(a) Calcium and Oxygen (ii) Aluminium and Carbon

Ans (a) CaO (b) Al4C3

Q.4 Multiple Choice Questions:

(i) Atoms of the elements belonging to the same group of periodic table will have

(a) same number of protons (b) same number of electrons in the valence shell

(c ) same number of neutrons (d) same number of electrons

Ans (b)

(ii) Element with valence shell electronic configuration as (n-1) d5 ns1 is placed in which of
the following group and block of elements ?

(a) 1, s-block (b) 16, s-block (c) 7 , s-block (d) 6 , d-block

Ans (d)

(iii) Of the following pairs , the one containing examples of metalloid elements in the
periodic table is

(a) Na and K (b) F and Cl (c) Cu and Hg (d) Si and Ge

Ans (d)

(iv) Which of the following sets represents a collection of isoelectronic species ? (At. No. Cs
= 55 , Br = 35)

( a) Ca2+ , Cs , Br (b) Na + , Ca2+ , Mg2+ (c) N3- , F- , Na+ (d) Be , Al3+ , Cl-

Ans (c )

(v) Which of the following has highest value of ionic radius ?

(a) Li+ (b) B3+ (c) O2- (d) F-

Ans ( c)

(vi) The highly metallic element will have the configuration of

(a) 2,8,7 (b) 2,8,8,5 ( c) 2,8,8,1 (d) 2,8,2

Ans( c)

(vii) The correct order regarding the electronegativity of hybrid orbitals of carbon is

(a) sp< sp2< sp3 (b) sp<sp2>sp3 (c ) sp>sp2<sp3 (d) sp<sp2<sp3

Ans (d)

(viii) valence electrons in the element A are 3 and that in element B are 6 . Most probable
compound formed from A and B is

(a) A2B (b) AB2 (c) A6B3 (d) A2B3

Ans : (d)

(ix) The period number in the long form of periodic table is equal to

(a) magnetic quantum number of any element of the period.

(b) Atomic number of any element of the period .
(c) Maximum Principal quantum number of any element of the period
(d) Maximum azimuthal quantum number of any element of the period

Ans : (c)

(x) The elements in which electrons are progressively filled in 4f –orbital are called
(a) actinoids (b) transition elements (c) lanthanoids (d) halogens

Ans ( c)

(xi) Which of the following elements can show covalency greater than 4 ?

(a) Be (b) P (c ) S (d) B

Ans : (b,c)

(xii) Which of the following elements will gain one electron more readily in comparison to
other elements of their group ?

(a) S(g) (b) Na(g) (c ) O (g) (d) Cl (g)

Ans : (a,d)

(xiii) Which of the following statements are correct ?

(a) Helium has the highest first ionization enthalpy in the periodic table
(b) Chlorine has less negative electron gain enthalpy than Fluorine
(c) Mercury and Bromine are liquids at room temperature
(d) In any period, atomic radius of alkali metal is highest

Ans :( a , c )

(xiv) Which of the following have no unit ?

(a) Electronegativity (b) Electron gain enthalpy (c) Ionisation enthalpy ( d) Metallic
character

Ans (a , d)

Q.5 Fill in the blanks :

(i) s- and p- block elements are collectively called _______________ elements .

Ans representative

(ii) The general outermost shell electronic configuration of d-block elements is

____________.

Ans (n-1) d1-10 ns0-2 where n = 4 -7

(iii) all the lanthanoids and actinoids belong to group ______ of the periodic table.

Ans 3

(iv) The cation is __________ and anion is _________ than the neutral atom .

Anssmaller , larger
(v) In the periodic table, the element having the highest first ionization enthalpy is ___.

Ans He

(vi) Energy released when an electron is added to a neutral gaseous atom is called _______ of
the atom .

Ans Electron gain enthalpy

(vii) Among the halogens , the element having the most negative electron gain enthalpy is
____.

Ans Chlorine