Target DPP Test Contact Number: 9667591930 / 8527521718

1. K4 [Fe (CN) ]
6
is 60% ionised. Then the 5. Match the items given in Column I and
value of Van't Hoff factor is Column II.
1. 1.6 Column I Column II
2. 2.4
3. 3 1. Solution having same osmotic
A. Saturated
4. 3.4 pressure at a given temperature
solution
as that of given solution.
B. Binary
2. C6 H6 freezes at 5.5°C. At what temperature 2. A solution whose osmotic
solution
will a solution of 10.44 g of C4 H10 in 200 g of pressure is less than that of
C. Isotonic
C6 H6 freeze ? Kf (C6 H6 ) = 5.12°C/m another.
solution
1. 4.60°C 3. Solution with two components.
D.
2. 0.89°C 4. A solution which contains
Hypotonic
3. 5.50°C maximum amount of solute that
solution
4. None of the above can be dissolved in a given
amount of solvent at a given
3. Isotonic solutions have the same temperature.
(1) vapor pressure
1) A-1,B-3,C-2,D-4 2)A-1,B-2,C-3,D-
(2) freezing temperature
4
(3) osmotic pressure
3)A-4,B-3,C-1,D-2 4)A-1,B-2,C-4,D-
(4) boiling temperature
3
4.
Maximum boiling azeotropes Solutions
1) ethanol—water mixture 6. . Match the items given in Column I with the
2) 68% HNO3 and 32% water by mass type of solutions given in Column II.
3) ethanol—methanol mixture Column I Column II
4) 68% H2SO4 and 32% water by mass 1. A solution of gas in
solid
A. Soda water 2. A solution of solid
B. Sugar solution in liquid
C. German silver 3. A solution of solid
D. Hydrogen gas in in solid
palladium 4. A solution of gas in
liquid

1)A-4,B-3,C-4,D-1
2)A-4,B-3,C-1,D-2
3)A-2,B-3,C-4,D-1
4)A-4,B-2,C-3,D-1

7. If 22 g of benzene is dissolved in 122 g of

carbon tetrachloride then the mass percentage
of carbon tetrachloride (CCl4) is-
1. 82.72%
2. 83.72%
3. 84.72%
4. 85.72%

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 Target DPP Test Contact Number: 9667591930 / 8527521718

8. The insoluble compound in water is /are 14. The molarity of 28% KOH solution (d = 1.2
1. Phenol g/ml) is-
2. Formic acid and toluene 1. 3 M
3. Phenol and toluene 2. 6 M
4. Toluene and chloroform 3. 9 M
4. 12 M
9. Molal depression constant for a solvent is 4.0
K kg mol–1 . The depression in the freezing 15. Which of the following solutions has the
point of the solvent for 0.03 mol kg–1 solution of minimum freezing point?
K2SO4 is : (Assume complete dissociation of the 1. 0.02 M NaCl
2. 0.05 M Urea
electrolyte)
3. 0.01 M M gCl2
1. 0.36 K
2. 0.18 K 4. 0.01 M KCl
3. 0.12 K
4. 0.24 K 16. Glucose is added to 1 litre of water to such
an extent that ΔTf /Kf becomes equal to
10. For 1 molal aqueous solution of the 1/1000. The amount of glucose added is-
following compounds, which one will show the 1. 180 g
highest freezing point ? 2. 18 g
1. [Co(H2O)6]Cl3 3. 1.8 g
2. [Co(H2O)5Cl]Cl2.H2O 4. 0.18 g
3. [Co(H2O)4Cl2]Cl.2H2O
17. 2 grams of non-volatile solute dissolves in
4. [Co(H2O)3Cl3].3H2O 200 grams each of two different solvents A and
B to attain the same molality. If the ratio of Kb
11. A non-ideal solution was prepared by of solvent A and B is 1:8 and the ratio of
mixing 30 mL chloroform and 50 mL acetone. elevation in boiling points is x:y, then the value
The volume of the mixture will be: of y is-
1. >80 mL 1. 4
2. <80 mL 2. 6
3. =80 mL 3. 10
4. ≥80 mL 4. 8

12. The molarity of NaNO3 solution is 2M. The 18. Given below are two statements:
density of solution is 1.2 gram/ml. The molality
of the solution will be (Molar weight of NaNO3 At 20 °C molality of KCl solution is 'X' m, and
= 85) S :
1 on decreasing temperature to -10 °C
1. 1.94 m molality remains unchanged.
2. 2 m On changing temperature mass remains
S2:
3. 2.06 m unchanged.
4. 1.85 m
1. Both S1 & S2 are true
13. The boiling point of 1M Urea solution is 2. Both S & S are false
1 2
101oC. At the same temperature, the boiling 3. S is true & S is false
1 2
point of 1M KCl solution will be
4. S 1 is false & S 2 is true
1. 101oC
2. 102oC
3. 202oC
4. Cannot be predicted (Insufficient Data)

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 Target DPP Test Contact Number: 9667591930 / 8527521718

19. Vapour pressure of pure A is 50 mm of Hg 23. One litre solution containing 20 g of sucrose
and vapour pressure of pure B is 100 mm of Hg (C12H22O11) is isotonic with a 450 ml solution
in a mixture of liquid A and B mole fraction of containing 1.65 g of boric acid. The molar mass
A is 0.3, then the mole fraction of B in the of boric acid is:
x
vapour phase is 17 . The value of x is: 1. 67.2 g mol-1
1. 14 2. 162.27 g mol-1
2. 17 3. 62.7 g mol-1
3. 20
4. 620.7 g mol-1
4. 23
24. When dissolved in 20 g of benzene (C6 H6 )
20. The values of the Henry's law constant of
1g of AB2 lowers the freezing point by 3 K
Ar, CO2, CH4 and O2 in water at 25°C are 40.30,
whereas 1g of AB4 lowers it by 2 K. The atomic
1.67, 0.41 and 34.86 kbar, respectively. The
mass of B is-
order of their solubility in water at the same
(Given: Molal depression constant for benzene
temperature and pressure is
1. Ar > O2 > CO2 > CH4 = 5.1 K kg mol-1)
1. 21.25 u
2. CH4 > CO2 > Ar > O2
2. 33.92 u
3. CH4 > CO2 > O2 > Ar 3. 42.65 u
4. Ar > CH4 > O2 > CO2 4. 52.11 u

21. The boiling point (in °C) of 0.1 molal 25. A mixture of phenol and aniline is an
aqueous of CuSO4·5H2O at 1 bar is closest to: example of:
[Given: Ebullioscopic (molal boiling point 1. Ideal solution.
elevation) constant of water, kb=0.512 K Kg mol- 2. Non-ideal solution exhibiting positive
1] deviation from Raoult's law.
3. Non-ideal solution exhibiting negative
1. 100.36 deviation from Raoult's law.
2. 99.64 4. Minimum boiling azeotrope.
3. 100.10
3. 99.90 26. The molarity of sucrose in the solution
prepared by dissolving its 114 g in water to
22. form 300 mL of solution is:
At high altitudes, the
Assertion (A):
atmospheric pressure is low.
1. 1.11 × 10 mol cm−3
−3

Liquids at high altitudes boil at −2 −3

2. 1.11 × 10 mol dm
Reason (R): higher temperatures in −3
3. 1.11 × 103 mol dm
comparison to that at sea level.
4. 1.11 × 10 mol cm−3
2

Both (A) and (R) are true and (R) is the

1. 27. 0.2 molal aqueous solution of a weak base,
correct explanation of (A).
(BOH) is 20 % ionised. If Kb for water is 0.52 K
Both (A) and (R) are true but (R) is not the
2.
correct explanation of (A). kg mol-1, the elevation in boiling point of the
solution is:
3. (A) is true but (R) is false.
1. 0.06 K
4. (A) is false but (R) is true. 2. 1.2 K
3. 0.12 K
4. 6.1 K

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 Target DPP Test Contact Number: 9667591930 / 8527521718

28. Vapour pressure of an aqueous solution

obtained after mixing 900 g H2O with 120 g Fill OMR Sheet*
urea at 373.15 K will be:
1. 650 mmHg *If above link doesn't work, please go to test link
2. 760 mmHg from where you got the pdf and fill OMR from
3. 730.77 mmHg there
4. 755 mmHg

29. Density of 3 M solution of NaCl is 1.25 g/mL.

Calculate the volume of water required to make
1000 mL of this NaCl solution. [Consider the
density of water as 1 g/mL]. CLICK HERE to get
1. 1074.5 mL
2. 824.5 mL FREE ACCESS for 2
3. 1250 mL
4. 1000 mL days of ANY
30. Assertion: Nitric acid and water form NEETprep course
maximum boiling azeotrope.
Reason: Azeotropes are binary mixtures having
the same composition in liquid and vapour
phase.
1. Assertion and reason both are correct
statements and reason is correct explanation
for assertion.
2. Assertion and reason both are correct
statements but reason is not correct
explanation for assertion.
3. Assertion is correct statement but reason is
wrong statement.
4. Assertion is wrong statement but reason is
correct statement.

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