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Solution and Colligative Properties 06.01.2025

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31 views2 pages

Solution and Colligative Properties 06.01.2025

Uploaded by

pratyush010507
Copyright
© © All Rights Reserved
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Solution and Colligative Properties

Q.1 Low concentration of oxygen in the (a) 60% (b) 70%


blood and tissues of people living at (c) 75% (d) 80%
high altitude is due to …….. Q.6 The empirical formula of a non-
(a) Low temperature electrolyte is CH2O. A solution
(b) Low atmospheric pressure containing 3g L-1 of the compound
(c) High atmospheric pressure exerts the same osmotic pressure as
(d) Both low temperature and high that of 0.05 M glucose solution. The
atmospheric pressure molecular formula of the compound
Q.2 The values of van’t Hoff factors for KCl, is:
NaCl and 𝐾2 𝑆𝑂4 , respectively, are ….. (a) CH2O (b) C2H4O2
(a) 2, 2 and 2 (b) 2, 2 and 3 (c) C4H8O4 (d) C3H6O3
(c) 1, 1 and 2 (d) 1, 1 and 1 Q.7 Equal volumes of 0.1 M urea and 0.1 M
Q.3 𝐾𝐻 value for Ar(g), CO2(g), HCHO(g) glucose are mixed. The mixture will
and CH4(g) are 40.39, 1.67, 1.83 have:
× 10−5 and 0.413 respectively. (a) lower osmotic pressure
Arrange these gases in the order of (b) same osmotic pressure
their increasing solubility. (c) higher osmotic pressure
(a) HCHO < CH4< CO2<Ar (d) none of these
(b) HCHO < CO2< CH4<Ar Q.8 6.0g of urea (molecular weight = 60)
(c) Ar< CO2< CH4< HCHO was dissolved in 9.9 moles of water. If
(d) Ar< CH4< CO2< HCHO the vapour pressure of pure water is
Q.4 Which solution has the highest vapour P, the vapour pressure of solution
pressure? is:
(a) 0.02 M NaCl at 50℃ (a) 0.10 P° (b) 1.10 P°
(b) 0.03 M sucrose at 15℃ (c) 0.90 P° (d) 0.99 P°
(c) 0.005 M CaCl2 at 50℃ Q.9 An ideal solution was found to have a
(d) 0.005 M CaCl2 at 25℃ vapour pressure of 80 torr when the
Q.5 One molal solution of a carboxylic acid mole fraction of a non-volatile solute
in benzene shows the elevation of was 0.2. What would be the
boiling point of 1.518 K. The degree of vapour pressure of the pure solvent at
association of dimerization of the acid in the same temperature?
benzene is (Kb for benzene = 2.53 (a) 64 torr (b) 80 torr
Kg mol-1) (c) 100 torr (d) 400 torr

Main Chowk, Kachi Chawni, Jammu 0191-2570372, 9419160372


Q.10 If liquids A and B form an ideal solution: Q.15 Azeotropic mixture of water and HCl
(a) The free energy of mixing is zero boils at 381.5 K. By distilling the mixture
(b) The free energy as well as the it is possible to obtain:
entropy of mixing are each zero (a) Pure HCl only
(c) The enthalpy of mixing is zero (b) Pure water only
(d) The entropy of mixing is zero (c) Neither HCl nor water
Q.11 Which solution will show maximum (d) Both water and HCl in pure water
elevation in b.pt?
(a) 0.1 M KCl
(b) 0.1 m BaCl2
(c) 0.1 M FeCl3
(d) 0.1 M Fe2(SO4)3
Q.12 For 1 molal solution of each compound
maximum freezing point will be
assuming complete ionisation in each
case:
(a) 𝐹𝑒 𝐻2 𝑂 6 𝐶𝑙3
(b) 𝐹𝑒 𝐻2 𝑂 5 𝐶𝑙 𝐶𝑙2 . 𝐻2 𝑂
(c) 𝐹𝑒 𝐻2 𝑂 4 𝐶𝑙2 𝐶𝑙. 2𝐻2 𝑂
(d) 𝐹𝑒 𝐻2 𝑂 3 𝐶𝑙3 . 3𝐻2 𝑂
Q.13 Which of the following aqueous
solutions should have the highest
osmotic pressure?
(a) 0.011 M AlCl3 at 50℃
(b) 0.03 M NaCl at 25℃
(c) 0.012 M (NH4)2 SO4 at 25℃
(d) 0.03 M NaCl at 50℃
Q.14 In cold countries, ethylene glycol is
added to water in the radiators of cars
during winters. It results in:
(a) Lowering boiling point
(b) Reducing viscosity
(c) Reducing specific heat
(d) Lowering freezing point

Main Chowk, Kachi Chawni, Jammu 0191-2570372, 9419160372

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