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Alkyne Revision Slide

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Aditya Ram
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20 views43 pages

Alkyne Revision Slide

Uploaded by

Aditya Ram
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Alkyne

www.etoosindia.com
01. The compound with molecular formula C4H6 has -
(1) One double bond
(2) One triple bond or two double bonds
(3) All single bonds
(4) One triple bond and one double bond

Alkyne
02. Which of the following statements is not correct
about ethyne –
(1) It belongs to the homologous series with general
formula Cn H2n–2 where n = 2, 3 etc
(2) It is a linear molecule with bond angles of 180°
(3) It has triple bond in which the two carbon
atoms share 6 elements
(4) It undergoes eletrophilic addition more readily
than ethene
03. The reduction of 3- hexyne with H2/Lindlar’s
catalyst gives predominantly –
(1) n - Hexane
(2) trans - 3 - hexene
(3) cis-3-hexene
(4) A mixture of cis and trans-3-hexene
04. The conversion of HC  HC into CH2ClCHO takes
place in -
05. By the action of hydrobromic acid on ethyne we get
(1) Methyl iodide
(2) Ethyl iodide
(3) Ethyledene bromide
(4) 1, 2 - Dibromo ethane
06.
07. Reaction of alkenes and alkynes with hypochlorous
acid is called –
(1) Hydroxy chlorination
(2) Chlorohydroxylation
(3) Chlorination
(4) Hydroxylation
08. Hydration of propyne gives –
(1) 1-Propanol
(2) 2-Propanol
(3) Propanal
(4) Propanone
09. By the addition of CO and H2O on ethyne, the
following is obtained –
(1) Propenoic acid
(2) Propanal
(3) Propanoic acid
(4) Acetic acid
10. An alkyne which gives two moles of acetic acid on
ozonolysis to –
(1) 1- Butyne
(2) 2 - Butyne
(3) Methyl acetylene
(4) 3-methyl-1-butyne
11. An alkyne C7H12 on reaction with alk. KMnO4 and
subsequent acidification with HCl yields a mixture
of

The alkyne is –
(1) 3- Hexyne
(2) 2-Methyl-3-hexyne
(3) 2-Methyl-2-hexyne
(4) 2-Methyl-2-hexene
12.
13. A compound (C5H8) reacts with ammonical AgNO3
to give a white precipitate and reacts with excess of
KMnO4 solution to give (CH3)2CH – COOH.
The compound is –
(1) CH2 = CH – CH = CH – CH3
(2) (CH3)2CH – C  CH
(3) CH3(CH2)2C  CH
(4) (CH3)2C = C = CH2
14. Which of the following compounds will not give a
precipitate with Tollen’s reagent –
(1) Ethyne
(2) 1-Butyne
(3) 3-Methyl-1butyne
(4) 2-Pentyne
15. Westrosol is a solvent & it is prepared by –
(1) CH  CH + 2Cl2
(2) CH  CH + 2HCl & then Ca(OH)2
(3) CH  CH + 2Cl2 & Ca(OH)2
(4) None of these
16. An organic compound decolourises bromine in
CCl4 and can be reduced catalytically. Also, it gives
a precipitate with ammonical cuprous chloride. The
compound can be –
(1) CH3 – CH = CH – CH3
(2) CH3CH2C  CH
(3) CH3CH = CH2
(4) CH3C = CH2
17. 1 - Butyne is formed when ethyl bromide is heated
with –
(1) Sodium ethoxide
(2) Silver acrylate
(3) Sodium acetylide
(4) Silver acetate
18. Which one of the following formula correctly
represents the organic compound formed when
1, 2-dibromoethane is heated with NaOH in ethanol
solution ?
(1) C2H2 (2) C2H4
(3) C2H6 (4) CH3OH
19. In the reaction the major product formed is -
CH3 – C  C – Na +(CH3)2 CHCl ?
(1) 4 - Methyl-2-pentyne
(2) Propyne
(3) Propene
(4) 3-methyl-1-pentene
20. For preparing R – C  CH from Grignard’s reagent
we take –
(1) CH  CH, CH3MgBr & RI
(2) CH3 – C  CH + RMgBr + CH3I
(3) CH  CH, CH3MgBr + R'I
(4) None of these
21. Acetylene may be prepared using Kolbe’s
elecrtrolytic method employing –
(1) Pot. acetate
(2) Pot. succinate
(3) Pot. fumarate
(4) None of these
22. Acetylene is prepared industrially by passing
electric discharge through graphite electrods in the
atmosphere of –
(1) Air
(2) N2
(3) H2
(4) CO2
23.

(1) KOH / C2H5OH


(2) Zn
(3) HCI/H2O
(4) Na
24. CHCl3+ CH3CCl3 + 6Ag  (A) + 6AgCl.
The compound (A) is –
(1) CH  CH
(2) CH3– C  CH
(3) CH3 – CH = CH2
(4) CH2 = CH2
25. Propyne is formed by heating 1, 2-dibromopropane
with –
(1) C2H5ONa
(2) Alc. KOH and sodamide
(3) Aqueous alkali
(4) Sodalime
26. The reaction shown by 1 - alkyne is –
(1) Addition
(2) Substitution
(3) Polymerisation
(4) All of these
27. Ethyne adds on HCl to first give a -
(1) Carbanion
(2) A free radical
(3) A vinylic cation
(4) A biradical
28. The reduction of an alkyne to alkene using
Lindlar’s catalyst results into –
(1) Cis addition of hydrogen atoms
(2) Trans addition of hydrogen atoms
(3) A mixture obtained by cis and trans additions
of hydrogen which are in equilibrium with each
other
(4) A mixture obtained by cis and trans addtions of
hydrogen atoms which are not in equilibrium
with each other
29.
30.
31. Which among the following compound will give
mixutre of two ketones on hydration with
H2O/HgSO4–
(1) CH3– CH2– C  C – CH3
(2) CH3 – C  C – CH3
(3) C2H5 – C  C – C2H5
(4) All of these
32. Which of the following reactions will yield
2, 2 - dibromopropane –
(1) CH2 = CHBr + HBr
(2) CH3C  CCH3 + 2HBr
(3) CH3C  CH + 2HBr
(4) CH3CH = CHBr + HBr
33.
34. Consider following reaction sequence.

In the above reaction the reagent R is


(1) H2O2
(2) O2
(3) O3
(4) KMnO4
35. Consider following reaction sequence.

The products (1) and (2) are, respectively,


(1) CH3CH = CHBr and CH3CHBrCH2Br
(2) CH3CBr = CH2 and CH3CBr2CH3
(3) CH3CH = CHBr and CH3CH2CHBr2
(4) CH3CH = CHBr and CH3CBr2CH3
36. Orlon is a synthetic fibre obtained by the
polymerization of a monomer .The monomer can
be prepared by the reaction
37.
38. A hydrocarbon on heating with concentrated
KMnO4 solution produces propionic acid only, but
on reaction with cold dilute KMnO4 produces a
diketone. The hydrocarbon is
(1) 3-hexene
(2) 3-hexyne
(3) 1-butyne
(4) 1-butene
39. An alkyne on oxidation with hot concentrated
alkaline KMnO4 produces isobutyric acid and CO2.
The alkyne has the structure
(1) CH3CH2CH2C  CH
(2) (CH3)2CHCH2C  CH
(3) (CH3)2CHC  CH
(4) (CH3)2CHC  CCH(CH3)2
40.
41.
products (A) and (B) are –
(1) CH3CH2CHO, CH3COCH3
(2) CH3COCH3, CH3CH2CHO
(3) CH3COCH3, both
(4) CH3COCH3, CH3CH2CH2OH

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