Volume 2 Science and Computer
Volume 2 Science and Computer
Police Constable
Volume - 2
Solids
● Matters which have fixed volume and shape.
● Eg - stone, wood, brick, ice, sugar, salt, coal, etc.
● All metals are solid except mercury and gallium.
Properties of solids
● Fixed volume.
● Fixed shape.
● High density.
● Heavy.
● Do not flow.
Liquids
● Matters which have fixed volume but indefinite shape.
● Eg - milk, water, petrol, kerosene, alcohol, oil, etc.
● Since liquid can flow, it is also called fluid.
Properties of liquids
● Definite volume.
● No definite shape.
● Get the shape of container in which they are kept.
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● Cannot be compressed much.
● Have less density compare to solid.
● Lighter than solid.
● Liquids flow and hence are called fluids.
Gas
● Matters which have indefinite shape and
volume.
● Eg - air, oxygen, hydrogen, nitrogen, carbon-
dioxide, etc.
Properties of gases
● Indefinite shape
● No fixed volume.
● Get the shape and volume of container.
● Fill the container completely.
● Have very low density.
○ So, gases are light.
● Can flow easily and hence are called fluids.
Solids
● The force of attraction between the particles of solids is very strong.
● There are minimum spaces between the particles of solids.
● The particles of solids have minimum kinetic energy.
● Because of great force of attraction particles of solids are closely packed together.
○ This makes the space between particles of solids almost negligible.
● The lowest kinetic energy of particles is not able to move the particles of solids.
● Hence, the great force of attraction and least space between particles of solids and lowest kinetic energy of particles
keep the particles at fixed places.
● Because of the combination of these characters matter exists in solid state.
Liquids
● The force of attraction between particles is strong but less strong than solids.
● The space between particles is more than that of solids but not less than liquids.
● The kinetic energy of particles is greater than solid.
● Strong force of attraction keeps the particles of liquids packed together.
○ But the force of attraction between particles of liquids is less strong than that of solid.
○ Because of this particles of liquids are loosely packed compared to solid.
● The kinetic energy of particles of liquids is greater than that of solids.
● Because of more space between particles and more kinetic energy than solids the particles of liquids slide over one
another.
● These characters make a matter to exist in liquid state.
● Liquid can flow because its particles can slide over one another.
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Gases
● The force of attraction between particles of gas is almost negligible.
● The space between particles of solid is greatest.
● The particles of gases have the greatest kinetic energy.
○ Because of negligible force of attraction the particles of gases are loosely packed consequently there are lots of
spaces between their particles.
○ Because of the greatest kinetic energy the particles of gas move with high speed.
● Because of negligible force of attraction between particles and greatest kinetic energy the particles of gas have a
tendency to escape out.
○ Because of these characteristics a matter exists in gaseous state.
● A matter exists in solid state because of the greatest force of attraction between its particles which
makes the particles closely packed.
● A matter exists in liquid state because of less force of attraction between its particles than a solid,
which makes the particles closely packed but allow them to slide over one another.
● A matter exists in gaseous state because of an almost negligible force of attraction between its
particles, which is unable to keep the particles bonded together.
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Bose-Einstein Condensate (BEC)
Atomic Structure
Fundamental Constituents of an Atom
Electron
● J. J. Thomson, in 1897, discovered negatively charged particles emitted by the cathode towards the anode in a cathode
ray experiment.
● These negatively charged particles are Electrons.
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● The characteristics of cathode rays (electrons) do not depend upon
the material of electrodes and the nature of the gas present in the
cathode ray tube.
● The experiment showed that the atom was not a simple, indivisible
particle and contained at least one subatomic particle – the
electron.
Protons
● Ernest Goldstein, in 1886, discovered that with a different condition
in the same chamber, anode emitted positively charged particles known as Canal rays or later named as Protons.
Neutrons
● J. Chadwick discovered a subatomic particle with no charge and a mass equivalent to protons in the nucleus of all atoms.
● These neutrally charged particles are Neutrons.
Affinity Attracts to positively charged Attracts to negatively Get attracted neither to positive nor
charged negative
Location Outside the nucleus Within the nucleus Inside the nucleus
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■ When the electrons revolve, they lose energy.
■ Soon electrons would collapse into the nucleus.
■ This tendency would make an atom highly unstable while the atom is highly stable
■ Rutherford’s structure of an atom failed to explain the atomic number concept as it explained only the presence
of protons in the nucleus
Bohr’s Model of an Atom
● Bohr devised a model in order to overcome the objections that
Rutherford’s model raised.
● So, he stated the following postulates:
○ An atom permits only a discrete amount of orbitals for the
electrons to orbit and make the outer structure of an atom
○ While revolving, the negatively charged particles do not lose
energy in these orbitals or energy levels
○ When the electron jumps from one energy shell to another, a
change in magnitude takes place
● Bohr’s model gives an elaborative explanation on the structure of an
atom and overcomes the objections faced by all the other models on
the structure of an atom.
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Mass Number (A)
● Measure of the total number of protons and neutrons in the nucleus of an atom.
● The notation A indicates the Mass number.
● N = total number of neutrons.
● Mass Number = Atomic Number + Number of Neutrons in the Nucleus
○ A = Z + n°
● aka Nucleon number.
Isotopes
● The atoms of the same elements with the same atomic number and different mass numbers.
● Hydrogen has three isotopes: Protium, Deuterium, Tritium.
Isobars
● The atoms of different molecules with the same mass number.
● Eg, in Calcium, atomic number 20, and argon, atomic number 18, the mass number of both these elements is 40.
○ This shows that the total number of nucleons is the same in the atoms.
Metalloids
● Elements which have the
properties of both metals
and non-metals are known
as metalloids.
○ For example, Boron,
Arsenic, etc.
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Properties of Metalloids
● They have a metallic luster but behave like non-metals.
● They are brittle, shiny substances
● They are solid at ambient temperatures and have relatively high melting points.
Melting Temperatures of Metalloids
Element Melting Temperature (°C)
Boron 2079
Silicon 1410
Germanium 938.3
Arsenic 817
Tellurium 449.5
Antimony 631
Boron An allotropic semimetal that is extremely hard and heat resistant. Used with silicon to make thermal shock-
Has an atomic number of 5. resistant glass.
Silicon A grey and shiny semiconductive metal. It has high melting (1,410 Commonly used for semiconductors.
°C) and boiling points (3,265 °C). Has an atomic number of 14.
Germanium Is hard and brittle in its elemental form. Has an atomic number Less commonly used for semiconductors.
of 32.
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Element Description Application
Arsenic A steel-grey semimetal known for being poisonous. It has an Often used as an insecticide.
atomic number of 33.
Tellurium Brittle in its elemental form. It is a chalcogen, along with selenium Used as a steel additive to improve
and sulfur. It has an atomic number of 52. machinability.
Antimony A hard and brittle semimetal with an atomic number of 51. Used to colour paints; often alloyed with
lead.
● Metallurgy - a process that is used for the extraction of metals in their pure form.
● Minerals - The compounds of metals mixed with soil, limestone, sand, and rocks.
● Metals are commercially extracted from minerals at low cost and minimum effort.
○ These minerals are known as ores.
● A substance which is added to the charge in the furnace to remove the gangue (impurities) is known as flux.
● Metallurgy deals with the process of purification of metals and the formation of alloys.
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■ The denser ore particles settle in the grooves, and the impurities are washed away by water.
○ Magnetic separation
■ The crushed ore is placed on a conveyor belt.
■ This belt rotates around two wheels in which one of the wheels is magnetic, and therefore the magnetic
particles get attracted to the magnetic wheel and fall apart from the non-magnetic particles.
○ Froth floatation
■ The crushed ore is taken in a large tank which contains oil and water.
■ A current of compressed air is passed through it.
■ The ore gets wet by oil and is separated from the impurities in the form of froth.
■ Ore is lighter, and so it comes on the surface and impurities are left behind.
○ Roasting and calcination
■ Roasting - The process of heating a concentrated ore in the presence of oxygen.
● This process is applied in the case of sulfide ores.
○ Calcination - For ores containing carbonate or hydrated oxides, heating is done in the absence of air to melt the
ores.
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Alloys
● Alloys are mixtures of two or more metals and are formed by mixing molten metals thoroughly.
○ In a few cases, non-metals are mixed with metals to produce alloys.
● Alloying produces a metallic substance with more useful properties than the original pure metals from which it is made.
○ For example, the alloy brass is made from copper and zinc.
Properties of alloys
Alloys are prepared to impart some desirable properties which the individual metals do not possess. These are,
● Change in the chemical reactivity: Sodium acts vigorously with water, but Na–Hg amalgam reacts slowly to suit the
requirement of some chemical reactions.
● Hardness: Silver, gold, and soft metals become hard when alloyed with copper.
● Melting Points: Melting points of an alloy may be higher or lower than any of its components. Wood-metal, which is an
alloy of Bi, Pb, Sn and Cd, fuses at 60°C, while none of these metals fuses at this low temperature.
● Change of colour: Aluminium bronze is an alloy of aluminium and copper. It is of golden, yellow colour and is used in
making decoration articles, jewellery and coins while the colour of aluminium is white and that of copper is red.
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● Corrosion resistance: Iron gets corroded soon, whereas stainless Steel, an alloy of iron and chromium, resists corrosion.
● Casting: An alloy of lead and antimony is known as type metal and is used for casting type required in printing works.
Advantages of alloys
● Alloys do not get corroded or get corroded to a very less extent.
● They are harder and stronger than pure metals (For example, gold is mixed with copper, and it is harder than pure gold)
● They have less conductance than pure metals (For example, copper is a good conductor of heat and electricity, whereas
brass and bronze are not good conductors)
● Some alloys have lower melting points than pure metals (For example, solder is an alloy of lead and tin, which has a lower
melting point than each of the metals)
● When metal is alloyed with mercury, it is called amalgam.
Important Alloys
Alloys of Silver
Alloy Percentage composition Uses
Alloys of Iron
Stainless steel Fe = 73%, Cr = 18%, Ni = For making utensils, cutlery and ornamental pieces.
8% and carbon
Manganese Fe = 86%, Mn = 13% and For Making rock drills, safes etc.
steel carbon
Tungsten steel Fe = 94%, W = 5% and For making high speed cutting tools.
carbon
Invar Fe = 64%, Ni = 36% For making watches, meter scales, pendulum rods etc.
Nickel steel Fe = 98?96%, Ni = 2?4% For making wire cables, gears, drive shafts etc.
Permalloy Fe = 21%, Ni = 78% and For making electromagnets, ocean cables etc.
carbon
Chrome steel Fe = 98?96%, Cr = 2?4% For making axles, ball bearings and cutting tools such as files.
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Alloys of Copper
Bronze or Cu = 80, Zn = 10, Sn = 10 For making cooking utensils, statues, coins etc.
Copper bronze
German silver Cu = 60, Zn = 20, Ni = 20 For making silver wire, resistance wires etc.
Monel metal Cu = 30, Ni = 67, Fe and Mn = 3 For making acid pumps and acid containers.
Gold-copper Au = 90, Cu = 10 For making gold coins, jewellery, watch cases, spectacle rims
alloy etc.
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Alloys of Aluminium
Natural Indicators
● Indicators obtained from natural sources.
● Eg:
○ Litmus
■ Obtained from lichens.
■ The solution of litmus is purple in colour.
■ Litmus paper comes in two colours- blue and red.
■ An acid turns blue litmus paper red.
■ A base turns red litmus paper blue.
○ Turmeric:
■ Yellow in colour.
■ Turns reddish brown with base.
■ Des not change colour with acid.
○ Red Cabbage:
■ Juice of red cabbage is originally purple in colour. J
■ Turns reddish with acid and turns greenish with base.
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