TAKALKAR CLASSES BIBWEWADI

Total Marks: 200 Time: 60 Minutes

Chemistry Section A
Q.5 The solubility of N2 gas at 1 atm. pressure
at 25°C is 6.8 ×10-4 mol dm-3. The solubility
of N2 gas in mol dm-3 at 25°C if atmospheric
Q.1 0.1423 molal solution of a substance which pressure is 1 atmosphere and partial
on dissolving in benzene boils at 353.71 K. If pressure of N2 gas at this temperature and
boiling point of pure benzene is 353.35 K pressure is 0.78 atm. will be
then Kb for benzene in K kg mol–1 will be
A) 5.8344×10–4
A) 2.88 B) 2.23 B) 5.304×10–4
C) 2.53 D) 2.65 C) 6.483×10–4
D) 5.402×10–4
Q.2 100 ml of a solution containing 0.1 mole
solute has osmotic pressure 5 × 105 Nm − 2 at
300 K. When 0.5 mole of the solute is further Q.6 Which one of the following is incorrect for
added to the solution, the osmotic pressure ideal solution?
will be
A)
A) 5 × 105 Nm − 2 B) 2.5 × 105 Nm − 2
B)
C) 1 × 106 Nm − 2 D) 30 × 105 Nm − 2
C)
Q.3 Homogeneous mixture is formed by mixing
D)
A) phenol and water
B) iron filing and sand
Q.7 When mercuric iodide is added to the
C) silver chloride and water aqueous solution of KI, then the:
D) ethanol and water
A) Freezing point is raised
B) Freezing point is lowered
Q.4 When 2 g of NaOH is dissolved in 500 cm3 of
C) Freezing point does not change
water then molarity of NaOH will be (Molar
mass of NaOH = 40 gmol–1) D) Boiling point does not change

A) 0.1 moldm–3
Q.8 The van't Hoff factor i for a compound which
B) 0.1 dm–3 undergoes dissociation in one solvent and
C) 0.25 moldm–3 association in other solvent is respectively
D) 0.50 mol A) less than one and greater than one
B) less than one and less than one
C) greater than one and less than one
D) greater than one and greater than one.
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Q.9 For a dilute solution, Raoult’s law states that Q.13 5 L of a solution contains 25mg of CaCO3.
What is the concentration in ppm?
the lowering of vapour pressure is equal
A)
to the mole fraction of solute. (Mol. wt. of CaCO3 is100)

the relative lowering of vapour pressure A) 25 B) 1

B)
is equal to the mole fraction of solute. C) 5 D) 2500
the relative lowering of vapour pressure
C) is proportional to the amount of solute in
solution. Q.14 Vapour pressure of a solution of nonvolatile
solute is _______.
the vapour pressure of the solution is
D)
equal to the mole fraction of solvant. directly proportional to the mole fraction
A)
of the solvent
Q.10 In automobiles ethylene glycol is used as inversely proportional to the mole
B)
fraction of the solute
A) a fuel
inversely proportional to the mole
B) an anti-freezer C)
fraction of the solvent
C) a freezing agent directly proportional to the mole fraction
D)
D) a indicating agent of the solute

Q.15
Q.11 A pressure cooker reduces cooking time for
food because
A)
boiling point of water involved in cooking
A) B)
is increased
C)
the higher pressure inside the cooker
B) D)
crushes the food material.
cooking involves chemical changes
C) Q.16
helped by a rose in temperature.
heat is more evenly distributed in the A)
D)
cooking space B)
C)
Q.12 An azeotropic solution of two liquids has D)
boiling point lower than either of two liquid
when it.
Q.17 Which of the following solutes dissolved in
shows a negative deviation from Raoult’s water, having same
A)
law concentration exhibits highest value of
shows a positive deviation from Raoult’s colligative property?
B)
law
A) urea
C) shows no deviation from Raoult’s law
B) glucose
D) is saturated.
C) sucrose
D) sodium chloride
 TAKALKAR CLASSES BIBWEWADI

Q.18 What is the unit of cryoscopic constant? Q.23 Calculate the amount of solute dissolved in
160 gram solvent that boils at 85°C . the
A) K kgmol−1 B) K kg d3 molar mass of solute is 120g mol – 1.
C) K kg mol D) k Kg dm – 3 ( Kb for solvent = 2.7 °C kg mol−1 and boiling
point of solvent = 76°C )
Q.19 Which of the following laws represents the A) 64gram B) 42gram
quantitative relationship between the
solubility of gas in liquid and its pressure? C) 50gram D) 60gram

A) Charles’s law
Q.24 Calculate the cryoscopic constant when
B) Avogadro’s law 0.8gram nonvolatile solute with molar mass
C) Raoult’s law 64g mol – 1 dissolved in 43gram solvent lowers
D) Henry’s law the freezing point by 0.34 K .

A) 2.5 K kgmol – 1
Q.20 Which among the following colligative B) 2.0 K kgmol – 1
properties is useful to determine molar C) 0.85 K kgmol – 1
masses of very expensive solutes?
D) 1.17 K kgmol – 1
A) Vapour pressure lowering
B) Osmotic pressure Q.25 Which among the following equations
C) Freezing point depression represents relation between cryoscopic
D) Boiling point elevation constant, depression in freezing point and
molality?

Q.21 What is the unit of Henry’s law constant? m

A) K f =
△ Tf
A) moldm−3
B) K f = △ T f × m
B) moldm3 bar−1
C) moldm−3 bar−1 △ Tf
C) K =
f m
D) moldm−3 bar
1
D) K f =
△ Tf × m
Q.22 Calculate the molar mass of solute when
1.5gram nonvolatile solute dissolved in
100mL solvent having density 0.8 g mL − 1
lowers its freezing point by 0.75 K .
(Freezing point depression constant for
solvent is 5 K kgmol−1)

A) 125g mol−1 B) 110g mol−1

C) 100g mol−1 D) 75g mol−1
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Q.26 Match List-I with List-II Q.29 What is the molality of solution of a
List-I List-II nonvolatile solute having boiling point
elevation 7.315K and molal elevation
Solvent molecules
constant 2.75K kgmol− 1 ?
pass through semi
A. Osmosis I. permeable A) 3.2 m B) 2.0 m
membrane towards
C) 2.6 m D) 3.8 m
solvent side
Movement of
charged colloidal Q.30 Calculate Van’t Hoff factor of K2SO4 if 0.1 m
particles under the aqueous solution of K2SO4 freezes at − 0.43 K
B. Reverse osmosis II. influence of applied and cryoscopic constant of water is
electric potential 1.86 K kgmol− 1.
towards oppositely
A) 2.3 B) 2.7 C) 3.1 D) 3.5
charged electrodes.
Solvent molecules
pass through semi Q.31 A solution of 5.6g nonvolatile solute in 50g
C. Electro osmosis III. permeable solvent has elevation in boiling point 2.75K
membrane towards What is the molar mass of solute?
solution side. (Kb = 3K kgmol−1)
Dispersion medium
A) 192gmol−1 B) 200gmol−1
D. Electrophoresis IV. moves in an electric
field. C) 184gmol−1 D) 176gmol−1
Choose the correct answer from the options
given below: Q.32 If K b denote molal elevation constant of
A) A → III, B → I, C → IV , D → II water, then boiling point of an aqueous
solution containing 36g glucose (molar mass
B) A → III, B → I, C → II, D → IV = 180) per dm3 is
C) A → I, B → III, C → II, D → IV
D) A → I, B → III, C → IV , D → II A) (A) (100 + 2Kb) °C
B) (B) (100 + Kb) °C
Q.27 Which among the following solutions has ⎛ K b ⎞⎟
minimum boiling point elevation? C) (C) ⎜⎜⎜100 + ⎟⎟ °C
⎝ 10 ⎠
A) 0.1m NaCl ⎛ 2K b ⎞⎟
D) (D) ⎜⎜⎜100 + ⎟⎟ °C
B) 0.2m KNO3 ⎝ 10 ⎠
C) 0.1m Na2SO4
D) 0.05m CaCl2 Q.33 Which of the following solutions exhibits
lowest value of boiling point elevation
assuming complete dissociation?
Q.28 Calculate osmotic pressure of solution of
0.025 mole glucose in 100ml water at 300K. A) 0.1 m AlCl3 B) 0.01m MgCl2
[R = 0.082atmdm3mol− 1k − 1]
C) 1 m KCl D) 0.5 m NaCl
A) 1.54atm B) 2.05atm
C) 6.15atm D) 3.08atm
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Q.34 Calculate the relative lowering of vapour Q.39 Given below are two statements: one is
pressure if the vapour pressure of benzene labelled as Assertion A and the other is
and vapour pressure of solution of non labelled as Reason R:
volatile solute in benzene are 640mmHg and Assertion A: Helium is used to dilute
590mmHg respectively at same temperature. oxygen in diving apparatus.
Reason R: Helium has high solubility in O2.
A) 0.078 B) 0.175 In the light of the above statements, choose
C) 0.061 D) 0.092 the correct answer from the options given
below:
Q.35 Calculate the depression in freezing point of Both A and R are true but R is NOT the
solution when A)
correct explanation of A.
4g nonvolatile solute of molar mass
B) A is true but R is false.
126g mol−1 dissolved in 80ml water.
[Cryoscopic constant of water = C) A is false but R is true.
1.86K kgmol− 1] Both A and R are true but R is the correct
D)
explanation of A.
A) 0.55 K B) 0.74 K
C) 0.86 K D) 0.98 K
Q.40 Which amongst the following aqueous
solution of electrolytes will have minimum
Q.36 What is osmotic pressure of solution of 1.7g elevation in boiling point?
3
CaCl2 in 1.25 dm water at 300 K if van’t
Hoff factor and molar mass of CaCl2 are A) 0.05MNaCl B) 0.1MKCl
2.47 and 111 g mol-1 respectively C) 0.1MMgSO4 D) 1MNaCl
⎡⎢ R = 0.082dm3 atmmol − 1K − 1⎤⎥ ?
⎣ ⎦
A) 0.625atm B) 0.744atm Q.41 If a substance 'A' dissolves in solution of a
C) 0.827atm D) 0.936atm mixture of 'B' and 'C' with their respective
number of moles in n A ,nB and nC , mole
fraction C in the solution is
Q.37 Which of the following concentration terms
depends on temperature? nB nC
A) B)
A) Molality n A + nB n A − n B − nC
B) Molarity nC nC
C) D)
C) Mole fraction n A + n B + nC n A × n B × nC
D) Percent by mass
Q.42 Identify the mixture that shows positive
Q.38 A solution of 8g of certain organic compound deviations from Raoult’s law.
in 2 dm3 water develops osmotic pressure
0.6atm at 300K. Calculate the molar mass of A) (CH3) 2CO + C 6H5NH2
compound
⎡⎢ R = 0.082atmdm3mol− 1K − 1⎤⎥ B) CHCl3 + C 6H6
⎣ ⎦
C) CHCl3 + (CH3) 2CO
A) 148gmol−1 B) 164gmol−1
C) 172gmol−1 D) 180gmol−1 D) (CH3) 2CO + CS2
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Q.43 The Henry's law constant (KH) values of Q.48 Calculate ΔTf of aqueous 0.01m formic acid if
three gases (A , B , C) in water are van’t Hoff factor is 1.1 ⎢⎢⎣Ff = 1.86KKgmol− 1⎥⎥⎦
⎡ ⎤
145, 2 × 10− 5 and 35 kbar, respectivlty, The
solubility of these gases in water follow the A) 0.042K B) 0.020K
order C) 0.011K D) 0.033K
A) B > A > C B) B > C > A
C) A > C > B D) A > B > C Q.49 Mass of glucose (C6H12O6) required to be
dissolved to prepare one litre of its solution
which is isotonic with 15g L−1 solution of
Q.44 Molality (m) of 3 M aqueous solution of NaCl
urea (NH3CONH2) is (Given: Molar mass in
is:
gmol− 1C:12,H:1,O:16, N:14 )
(Given : Density of solution = 1.25 g mL-1,
A) 55 g B) 15 g
Molar mass in g mol-1: Na-23, Cl-35.5)
C) 30 g D) 45 g
A) 2.90 m B) 2.79 m
C) 1.90 m D) 3.85 m Q.50 What is the expected value of ΔTf for 0.2m
aqueous CaCl2 solution if ΔTf for 0.2m
Q.45 Calculate the molar mass of nonvolatile sucrose solution is x K?
solute when 5 g of it is dissolved in 50 g
solvent, boils ate 119.6°C x
A) x B) 2x C) 3x D)
[ Kb = 3.2Kkgmol− 1, boiling point of pure 2
solvent = 118°C ]

A) 180gmol−1 B) 210gmol−1
C) 200gmol−1 D) 190gmol−1

Q.46 A solution of nonvolatile solute has boiling

point elevation 1.75K . Calculate molality of
solution ⎢⎢⎣ Kb = 3.5 Kkgmol− 1⎥⎥⎦
⎡ ⎤

A) 0.77molkg − 1 B) 0.69molkg − 1
C) 0.50molkg − 1 D) 0.35molkg − 1

Q.47 Calculate vapour pressure of a solution

containing mixture of 2 moles of volatile
liquid A and 3 moles of volatile liquid B at
room temperature.
(P A = 420, P B = 610mmHg)
∘ ∘

A) 600mmHg B) 570mmHg
C) 534mmHg D) 480mmHg