Chapter 04 2023 (45marks)
Chapter 04 2023 (45marks)
Book – 2 Ch 04
NAME: --------------------------
Max. Marks: 45 Time : 1hr 30min
Q1. Encircle the correct option: (13)
(1). Which catalyst is used in contact process?
(a). Fe2O3 (b). V2O5 (c).SO3 (d). Ag2O
(2). Atomic number of Te is:
(a). 52 (b). 60 (c). 65 (d).80
(3). Laughing gas is:
(a). Nitrogen dioxide (b). Dinitrogen oxide (c). Nitrogen oxide (d). Dinitrogen tetraoxide.
(4). Oxidation of NO in air produces:
(a). N2O (b). N2O3 (c). NO2 (d). N2O5
(5). Which of the following statement is incorrect.
(a). H2SO4 acts as a strong oxidizing agent (b). H2SO4 acts as a strong reducing agent
(c). H2SO4 acts as a dehydrating agent (d). H2SO4 acts as a sulphonating agent
(6). SO3 is not absorbed in water directly to form H2SO4 because:
(a). The reaction does not go to completion (b). The reaction is quite slow
(c). The reaction is highly exothermic (d). SO3 is insoluble in water
(7). The oxidation state of nitrogen in nitric anhydride is:
(a). +3 (b). +5 (c). + 2 (d). +1
(8). Which of the following is not property of phosphorus:
(a). It means light bearing (b). It does not exist free in nature
(c). Rich source of phosphorus in bone ash (d). It does not exist in allotropic form
(9). Which specie has maximum number of unpaired electrons?
(a). O2 (b). O2+ (c). O2 – (d). O22 –
(10). The brown gas formed when metal reduces HNO3 is:
(a). N2O (b). N2O5 (c). NO2 (d). NO
(11). The element whose inorganic minerals are not much abundant in earth crust:
(a). Li (b). N (c). Na (d). O
(12). The reaction 2NO(g) N2(g) +O2(g) involves change of oxidation state of N from
(a). 0 to + 2 (b). + 2 to 0 (c). + 4 to 0 (d). + 5 to +3
(13). Gold dissolves in aqua regia to form:
(a). AuCl3 (b). AuI3 (c). AuI2 (d). Au2(SO4)3
Q2. Attempt any Sixteen short questions: (2x16 = 32)
(1). Write structural formulas of : (a)NO (b)N2O3(2). Give two properties of sulphuric acid as dehydrating agent.
(3). P2O5 is a powerful dehydrating agent. Prove it by giving example.
(4). How nitrogen differ from other elements of its group.
(5). What is structural formula of phosphorus molecules? How these molecules arrange to make red
phosphorus?
(6). Justify that H3PO4 is tribasic acid.
(7). Write two chemical reactions of NO in which it behaves as reducing agent.
(8). Write flow sheet diagram for the manufacturing of nitric acid by Birkland and Eyde’s process.
(9). Complete and balance the following equations:
(a). Cu + HNO3 (dil) (b). Zn + HNO3 (dil)
(10). Complete and balance the following chemical equations:(a). P + NO (b). NO + Cl2
(11). Complete and balance the following chemical equations.
(a). P + NO (b). KNO3 + H2SO4
(12). NO2 is strong oxidizing agent; prove with the help of two examples.
(13). Sulphuric acid can be prepared of any concentration by contact process. Discuss briefly
(14). Write down structure of two oxy – acids of nitrogen?
(15). Give four uses of sulphuric acid.
(16). Give two similarities and two differences between oxygen and sulphur.
(17). Give four uses of nitric acid.
(18). Why phosphorus shows trivalency and pentavalency in its compounds?
(19). Give names and formulas of oxyacids of phosphorus.
(20). Write two reactions of sulphuric acid as a strong acid.
Shahbaz Ali, Associate Professor of Chemistry, Govt. Graduate College (f/b), Satellite Town, Gujranwala.